of spherical coordinates here is that an orbital wave function is a product of three factors each dependent on a single coordinate: . The angular factors of atomic orbitals generate s, p, d, etc. functions as real combinations of spherical harmonics (where and are quantum numbers). There are typically three mathematical forms for the radial functions which can be chosen as a starting point for the calculation of the properties of atoms and molecules with many electrons: The hydrogen-like orbitals are derived from the exact solutions of the Schrödinger Equation for one electron and a nucleus, for a hydrogen-like atom. The part of the function that depends on distance r from the nucleus has radial nodes and decays as . The Slater-type orbital (STO) is a form without radial nodes but decays from the nucleus as does a hydrogen-like orbital. The form of the Gaussian type orbital (Gaussians) has no radial nodes and decays as . Although hydrogen-like orbitals are still used as pedagogical tools, the advent of computers has made STOs preferable for atoms and diatomic molecules since combinations of STOs can replace the nodes in hydrogen-like orbitals. Gaussians are typically used in molecules with three or more atoms. Although not as accurate by themselves as STOs, combinations of many Gaussians can attain the accuracy of hydrogen-like orbitals. History The term "orbital" was coined by Robert Mulliken in 1932 as short for one-electron orbital wave function. Niels Bohr explained around 1913 that electrons might revolve around a compact nucleus with definite angular momentum. Bohr's model was an improvement on the 1911 explanations of Ernest Rutherford, that of the electron moving around a nucleus. Japanese physicist Hantaro Nagaoka published an orbit-based hypothesis for electron behavior as early as 1904. These theories were each built upon new observations starting with simple understanding and becoming more correct and complex. Explaining the behavior of these electron "orbits" was one of the driving forces behind the development of quantum mechanics. Early models With J. J. Thomson's discovery of the electron in 1897, it became clear that atoms were not the smallest building blocks of nature, but were rather composite particles. The newly discovered structure within atoms tempted many to imagine how the atom's constituent parts might interact with each other. Thomson theorized that multiple electrons revolve in orbit-like rings within a positively charged jelly-like substance, and between the electron's discovery and 1909, this "plum