the ordinary ray, the plane of the ray and the axis was replaced by the plane bisecting the dihedral angle between the two planes each of which contained the ray and one axis (Biot's dihedral law). Biot's laws meant that a biaxial crystal with axes at a small angle, cleaved in the plane of those axes, behaved nearly like a uniaxial crystal at near-normal incidence; this was fortunate because gypsum, which had been used in chromatic-polarization experiments, is biaxial. First memoir and supplements (1821–22) Until Fresnel turned his attention to biaxial birefringence, it was assumed that one of the two refractions was ordinary, even in biaxial crystals. But, in a memoir submitted on 19 November 1821, Fresnel reported two experiments on topaz showing that neither refraction was ordinary in the sense of satisfying Snell's law; that is, neither ray was the product of spherical secondary waves. The same memoir contained Fresnel's first attempt at the biaxial velocity law. For calcite, if we interchange the equatorial and polar radii of Huygens's oblate spheroid while preserving the polar direction, we obtain a prolate spheroid touching the sphere at the equator. A plane through the center/origin cuts this prolate spheroid in an ellipse whose major and minor semi-axes give the magnitudes of the extraordinary and ordinary ray velocities in the direction normal to the plane, and (said Fresnel) the directions of their respective vibrations. The direction of the optic axis is the normal to the plane for which the ellipse of intersection reduces to a circle. So, for the biaxial case, Fresnel simply replaced the prolate spheroid with a triaxial ellipsoid, which was to be sectioned by a plane in the same way. In general there would be two planes passing through the center of the ellipsoid and cutting it in a circle, and the normals to these planes would give two optic axes. From the geometry, Fresnel deduced Biot's sine law (with the ray velocities replaced by their reciprocals). The ellipsoid indeed gave the correct ray velocities (although the initial experimental verification was only approximate). But it did not give the correct directions of vibration, for the biaxial case or even for the uniaxial case, because the vibrations in Fresnel's model were tangential to the wavefront—which, for an extraordinary ray, is not generally normal to the ray. This error (which is small if, as in most cases, the birefringence is weak) was