theory in the mid-1990s in a freestanding state, and then demonstrated as distinct monoatomic layers on substrates by Zhang et al., different borophene structures were experimentally confirmed in 2015. Ge: germanene Germanene is a two-dimensional allotrope of germanium with a buckled honeycomb structure. Experimentally synthesized germanene exhibits a honeycomb structure. This honeycomb structure consists of two hexagonal sub-lattices that are vertically displaced by 0.2 A from each other. Si: silicene Silicene is a two-dimensional allotrope of silicon, with a hexagonal honeycomb structure similar to that of graphene. Its growth is scaffolded by a pervasive Si/Ag(111) surface alloy beneath the two-dimensional layer. Sn: stanene Stanene is a predicted topological insulator that may display dissipationless currents at its edges near room temperature. It is composed of tin atoms arranged in a single layer, in a manner similar to graphene. Its buckled structure leads to high reactivity against common air pollutants such as NOx and COx and it is able to trap and dissociate them at low temperature. A structure determination of stanene using low energy electron diffraction has shown ultra-flat stanene on a Cu(111) surface. Pb: plumbene Plumbene is a two-dimensional allotrope of lead, with a hexagonal honeycomb structure similar to that of graphene. P: phosphorene Phosphorene is a 2-dimensional, crystalline allotrope of phosphorus. Its mono-atomic hexagonal structure makes it conceptually similar to graphene. However, phosphorene has substantially different electronic properties; in particular it possesses a nonzero band gap while displaying high electron mobility. This property potentially makes it a better semiconductor than graphene. The synthesis of phosphorene mainly consists of micromechanical cleavage or liquid phase exfoliation methods. The former has a low yield while the latter produce free standing nanosheets in solvent and not on the solid support. The bottom-up approaches like chemical vapor deposition (CVD) are still blank because of its high reactivity. Therefore, in the current scenario, the most effective method for large area fabrication of thin films of phosphorene consists of wet assembly techniques like Langmuir-Blodgett involving the assembly followed by deposition of nanosheets on solid supports. Sb: antimonene Antimonene is a two-dimensional allotrope of antimony, with its atoms arranged in a buckled honeycomb lattice. Theoretical calculations predicted that antimonene would be a stable semiconductor in ambient conditions with suitable performance for (opto)electronics. Antimonene was first isolated in 2016 by micromechanical exfoliation and it was found to be very stable under ambient conditions. Its properties make it also