BACKGROUND OF THE INVENTION 
     This invention relates to insecticidal and nematicidal carbamates. 
     Insecticidal carbamates are known in the prior art, e.g. 
     (a) Belgian BE No. 848,912 discloses pesticidal symmetrical bis-N-substituted carbamyl sulfides of the formula ##STR1## where R and R&#39; represent substituents of varying scope; 
     (b) Belgian BE No. 848,913 discloses pesticidal unsymmetrical bis carbamyl sulfides of the formula ##STR2## where R, R 1  and R 2  represent substituents of varying scope; 
     (c) German DT No. 2,813,281 discloses pesticidal bis-carbamoyl-oximino-disulfides of the formula ##STR3## where R and R 1  represent substituents of varying scope. 
     SUMMARY OF THE INVENTION 
     This invention relates to novel compounds of Formula I, to agriculturally useful compositions of these compounds and to the method of use of these compounds as insecticides and nematicides. ##STR4## wherein R and R&#39; are independently ##STR5## R 1  is hydrogen, C 1  -C 4  alkyl, C 5  -C 6  cycloalkyl, C 1  -C 3  alkylthio, chlorine, chloromethyl, ##STR6##  phenyl or phenyl substituted with C 1  -C 4  alkyl; R 2  is hydrogen, C 1  -C 4  alkyl, C 5  -C 6  cycloalkyl, chlorine, C 1  -C 3  alkylthio, phenyl or phenyl substituted with C 1  -C 4  alkyl; 
     R 1  and R 2  can be taken together to form a carbocyclic bridge of three to five carbon atoms, or a bridge of the formula 
     
         --SCH.sub.2 CH.sub.2 S--; 
    
     R 3  is C 1  -C 3  alkyl; 
     R 4  is C 1  -C 3  alkyl; 
     R 5  is C 1  -C 3  alkyl; 
     R 6  is C 1  -C 6  alkyl; and 
     n is 0, 1 or 2; 
     provided that n is 0 when 
     (1) R 1  is chloromethyl or R 4  SCH 2 , or 
     (2) R 1  and R 2  are taken together to form a carbocyclic bridge or a bridge of the formula --SCH 2  CH 2  S--, or 
     (3) at least one of R 1  and R 2  is alkylthio; 
     and provided that when n is 0, 
     one of R 1  and R 2  cannot be H when the other is phenyl or phenyl substituted with C 1  -C 4  alkyl; 
     and further provided that when n is 1, 
     R 1  and R 2  cannot both be t-butyl, phenyl, phenyl substituted with C 1  -C 4  alkyl or combination thereof. 
     Also, this invention relates to novel intermediates of Formula II useful for preparation of compounds of Formula I ##STR7## wherein R 1 , R 2  and n are as previously defined. 
     DETAILED DESCRIPTION OF THE INVENTION 
     Preferred Compounds 
     Preferred for their high activity and/or favorable cost are compounds of Formula I wherein 
     (1) R and R&#39; are identical; or 
     (2) R 3  is CH 3  ; or 
     (3) R 1  and R 2  are independently hydrogen, C 1  -C 4  alkyl, ##STR8##  phenyl, phenyl substituted with C 1  -C 4  alkyl, or where R 1  and R 2  are taken together to form a carbocyclic bridge of three to five carbon atoms, or 
     (4) n is O. 
     More preferred for their higher activity and/or more favorable cost are the preferred compounds of Formula I wherein 
     R and R&#39; are ##STR9## R 1  and R 2  are independently hydrogen or C 1  -C 4  alkyl; and 
     n is 0; provided at least one of R 1  and R 2  is other than hydrogen. 
     Specifically preferred for their excellent activity and/or most favorable cost are 
     dimethyl N,N&#39;-[2,3-butanediylidenebis[nitrilooxycarbonyl(N-methylimino)thio(N-methylimino)carbonyloxy]]bis [ethanimidothioate] 
     dimethyl N,N&#39;-[1,2-propanediylidenebis[nitrilooxycarbonyl(N-methylimino)thio(N-methylimino)carbonyloxy]]bis [ethanimidothioate] 
     dimethyl N,N&#39;-[2,4-pentanediylidenebis[nitrilooxycarbonyl(N-methylimino)thio(N-methylimino)carbonyloxy]]bis[ethanimidothioate] 
     dimethyl N,N&#39;-[2,5-hexanediylidenebis[nitrilooxycarbonyl(N-methylimino)thio(N-methylimino)carbonyloxy]]bis[ethanimidothioate] 
     N-methyl-N-[N-methyl-N-(2-methyl-2-methylthiopropylideneaminooxycarbonyl)aminothio]carbamic acid, diester with 2,3-butanedione, dioxime 
     N,N&#39;-[2,3-butanediylidenebis[nitrilooxycarbonyl(N-methylaminothio-(N-methylimino)carbonyloxy]bis]-2-(dimethylamino)-2-oxoethanimidothioic acid, dimethyl ester. 
     Synthesis 
     The novel compounds of Formula I in which R and R&#39; are identical can be prepared by the reaction shown in Equation A. ##STR10## wherein R, R 1 , R 2  and n are as previously defined. 
     The reaction can be carried out in an inert solvent such as acetonitrile, tetrahydrofuran, toluene, xylene, methylene chloride, chloroform and the like at temperatures between -20° and 80° C., preferably, at -5° to 40° C. The acid acceptor used in this reaction can be an organic tertiary amine such as triethylamine, N,N-dimethylamiline, pyridine, and the like. 
     The reaction of a dioxime (III) and the carbamoyl fluoride (II) can be carried out in a heterogeneous system such as toluene-water, methylene chloride-water mixture and the like in the presence of a quaternary ammonium or phosphonium salt as a phase transfer catalyst at -15° C. to 60° C. An equivalent or a slight excess of metal hydroxide can be used as acid scavenger. It is preferred that the reaction be conducted at 10° C. to 30° C. by using sodium hydroxide or potassium hydroxide as acid acceptor in the presence of 10 to 30 mole percent of phase transfer catalyst such as cetyltrimethylammonium bromide or benzyltrimethylammonium hydroxide. 
     The reaction can also be carried out in the absence of acid acceptor by directly reacting the carbamyl fluoride of Formula II with a dianion of Formula III in an aprotic solvent such as tetrahydrofuran, toluene, acetonitrile, methylene chloride and the like at temperatures between -50° and 40° C., preferably, at -30° to 25° C. The dianion of Formula III is preferably generated in situ by reaction of the dioxime III with a metal hydride or metal amide in a proper solvent. 
     An alternate method to prepare the compounds of Formula I is shown by Equation B. ##STR11## wherein R, R 1 , R 2  and n are as previously defined. 
     The compounds of Formula I (R=R&#39;) can be obtained by treatment of the bis-carbamyl fluoride of Formula IV with either the metal salt of an oxime of Formula V or the oxime of Formula V itself in the presence of an organic tertiary amine as an acid acceptor under the conditions described previously. The metal salt of an oxime of Formula V as previously described can be generated and used in situ by reaction of the oxime with metal hydride in an aprotic solvent, e.g. tetrahydrofuran, toluene, acetonitrile, etc., at -5° to 20° C. 
     Compounds of Formula I where R and R&#39; are different can be conveniently prepared as Equation C. ##STR12## The intermediate VII can be prepared preferably by mixing an equivalent of an oxime V, bis-carbamoyl fluoride IV and an acid acceptor such as triethylamine at -15° C. to 40° C. in an inert solvent such as chloroform. Under similar reaction conditions, the subsequent reaction of the compound of Formula VII with another oxime VIII in the presence of, for example, triethylamine, would give the product of Formula I R≠R&#39;). 
     Required intermediates of Formula IV can be prepared by the reaction as given in Equation D. ##STR13## 
     The reaction shown in Equation D can be carried out in an inert solvent such as toluene, xylene, tetrahydrofuran, acetonitrile, methylene chloride at temperatures between -20° and 80° C., preferably, at -5° to 40° C. An organic tertiary amine such as triethylamine, N,N-dimethylaniline, or pyridine, or an inorganic metal bicarbonate or carbonate can be used as an acid acceptor. 
     The carbamyl fluoride of Formula II and bis(N-methyl-N-fluorocarbonylamino)sulfide (VI) can be prepared by the methods taught in DT No. 2654282. 
     In the above reaction procedures, pressure is not critical, but, for convenience, atmospheric pressure is preferred. 
    
    
     The preparation of compounds of Formula I can be more clearly illustrated by the following examples. All temperatures are in degrees centigrade and all percentages are by weight unless otherwise stated. 
     EXAMPLE 1 
     Dimethyl N,N&#39;-[2,3-butanediylidenebis[nitrilooxycarbonyl(N-methylimino)thio(N-methylimino)carbonyloxy]]bis[ethanimidothioate] 
     Two grams of dimethylglyoxime disodium salt octahydrate was added in portions to a solution of 3.7 g of O-[N-methyl-N-(N&#39;-methyl-N&#39;-fluorocarbonylaminosulfenyl)carbamoyl]-1-methylthioacetaldoxime in 30 ml of dry tetrahydrofuran (THF) at temperatures below -20° C. The mixture was stirred on an ice bath for 3 hours after the addition. Then ether and water were added into the reaction mixture. The precipitate was collected by filtration, washed with water, acetone and air-dried to give 2.6 g of dimethyl N,N&#39;-[2,3-butanediylidenebis[nitrilooxycarbonyl(N-methylimino)thio(N-methylimino)carbonyloxy]]bis[ethanimidothioate], m.p. 204°-206° C. 
     Alternatively, a solution of 5.5 g of O-[N-methyl-N-(N&#39;-fluorocarbonylaminosulfenyl)carbamoyl]-1-methylthioacetaldoxime in a mixture of 40 ml of toluene and 20 ml of tetrahydrofuran was added dropwise in 5 min. to a mixture of 3 g of dimethylglyoxime disodium salt octahydrate and 1 g of cetyltrimethylammonium bromide in 50 ml of water at 15° C. to 20° C. with vigorous stirring. 
     After stirring at room temperature for 30 minutes, the solid was collected by filtration, washed with water, toluene, and air-dried to give 2.6 g of dimethyl N,N&#39;-[2,3-butanediylidenebis[nitrolooxycarbonyl(N-methylimino)thio(N-methylimino)carbonyloxy]]-bis[ethanimidothioate]. 
     EXAMPLE 2 
     Dimethyl N,N&#39;-[1,2-propanediylidenebis[nitrilooxycarbonyl(N-methylimino)thio(N-methylimino)carbonyloxy]]bis[ethanimidothioate] 
     In a flask was charged 1 g of 50% of sodium hydride dispersed in mineral oil. Mineral oil was removed by washing the hydride with dry hexane under a nitrogen atmosphere, and the hexane solution was decanted. Then 20 ml. of dry THF was added. To the suspension 0.9 of methylglyoxime was added in portions at temperatures below 20° C. After stirring for 1 hour, a solution of 5 g of 0-[N-methyl-N-(N&#39;-methyl-N&#39;-fluorocarbonylaminosulfenyl)carbamoyl]-1-methylthioacetaldoxime in 30 ml. of dry THF was added rapidly at -20° to -30° C. The mixture was stirred on an ice bath for an hour. Then ether was added. The excess of sodium hydride was quenched by careful addition of water. The precipitate was collected by filtration, washed with water, then hexane, and was air-dried to give 2.5 g of dimethyl N,N&#39;-[1,2-propanediylidenebis[nitrolooxycarbonyl(N-methylimino)thio(N-methylimino)carbonyloxy]]bis[ethanimidothioate], m.p. 175°-178° C. (dec.). 
     EXAMPLE 3 
     Dimethyl N,N&#39;-[ethanediylidenebis[nitrilooxycarbonyl(N-methylimino)thio(N-methylimino)carbonyloxy]]bis[ ethanimidothioate] 
     A solution of 1.5 g of triethylamine in 10 ml. of dry acetonitrile was added dropwise to a mixture of 0.6 g of glyoxime and 3.9 g of 0-[N-methyl-N-(N&#39;-methyl-N&#39;-fluorocarbonylaminosulfenyl)carbamoyl]-1-methylthioacetaldoxime in 30 ml. of dry acetonitrile on an ice bath with stirring. The mixture was allowed to warm up slowly and stirred at ambient temperature for 17 hours. The precipitate was collected by filtration, washed with water, acetonitrile and air-dried to give 1 g of dimethyl N,N&#39;-[ethanediylidenebis[nitrilooxycarbonyl(N-methylimino)thio[N-methylimino)carbonyloxy]]bis[ethanimidothioate), m.p. 167°-168.5° C. (dec.). 
     EXAMPLE 4 
     N,N&#39;-[2,3-butanediylidenebis[nitrilooxycarbonyl(N-methylimino)thio]bis[N-methylcarbamic fluoride] 
     A solution of 4.1 g of triethylamine in 10 ml of dry acetonitrile was added dropwise to a mixture of 2.3 g of dimethylglyoxime and 7.4 g of bis(N-methyl-N-fluorocarbonylamino)sulfide in 40 ml of dry acetonitrile at 0° to 5° C. The mixture was stirred on an ice bath for 30 minutes and at ambient temperature for 3 hours. To the suspension, water and ether were added. The precipitate was collected by filtration, washed with water, a mixture of ether and n-chlorobutane, and air-dried to give 6 g of N,N&#39;-[2,3-butanediylidenebis[nitrilooxycarbonyl(N-methylimino)thio]bis[N-methylcarbamic fluoride], m.p. 212°-215° C. (dec.). 
     EXAMPLE 5 
     Methyl N-[N-[N-[N-[1,2-dimethyl-2[[N-methyl-N-[N-methyl-N-[[1-methylthio)ethylidene]aminooxycarbonyl]aminothio]amino]carbonyloxyimino]ethylidene]aminooxycarbonyl]-N-methylaminothio]-N-methylaminocarbonyloxy]-2-(dimethylamino)-2-oxoethanimidothioate 
     A solution of 1.1 g of triethylamine in 10 ml of methylene chloride was added dropwise to a suspension of 4.5 g of N,N&#39;-[2,3-butanediylidenebis[nitrilooxycarbonyl(N-methylamino)thio]]bis[N-methylcarbamic fluoride] and 1.1 g of methyl N-hydroxyethanimidothioate in 90 of methylene chloride at 0° to 5° to 30 minutes. The mixture was stirred on an ice bath 3 hours. The unreacted starting material was separated by filtration. The filtrate was washed with three 80 ml of portions of water and the organic layer was dried over anhydrous magnesium sulfate. The mixture was filtered and the filtrate was evaporated to give an oil, which was triturated with ether and methylene chloride mixture to give 3.1 g of methyl N-[N-[N-[N-[2[[N-[N-(fluorocarbonyl)-N-methylaminothio]-N-methylamino]-carbonyloxyimino]-1,2-dimethylethylidene]aminooxycarbonyl]-N-methylaminothio]-N-methylaminocarbonyloxy]ethanimidothioate. 
     IR (Nujol): 5.6μ, 5.7μ 
     NMR (CDCl 3 ) δ2.13, 2.33 and 2.40 (3S, 12H), 3.4 and 3.47 (2S, 12H). 
     This crude carbamic fluoride was used in the next reaction without further purification. 
     A solution of 1 g of triethylamine in 10 ml of methylene chloride was added dropwise to a solution of 3 g of the crude carbamic fluoride and 1.1 g of methyl 2-(dimethylamino)-N-hydroxy-2-oxoethanimidothioate in 50 ml of methylene chloride at 10° to 20° C. and stirred at room temperature for 2.5 hours. The solution was washed with three 50 ml portions of water, and the organic layer was dried over anhydrous magnesium sulfate. The mixture was filtered, and the filtrate was evaporated. Ether was added to the crude product followed by dilution with methylene chloride until the mass could flow freely. The solid was separated by filtration to give a mixture. The mother liquor was concentrated and diluted with ethers to give 0.5 g of the title compound, m.p. 87°-110° C. (glass). 
     IR (Nujol): 5.75μ, and 6.08μ 
     NMR (CDCl 3 ): δ2.3, 2.33 and 2.4 (3S, 15H), 3.02 and 3.08 (2S, 6H), 3.42 and 3.48 (2S, 12H). 
     Active compounds of Formula I that can be prepared according to the procedures demonstrated by the given examples are given, but not restricted, as follows: 
     
                       TABLE 1______________________________________ ##STR14##                                   meltingR.sub.3 R.sub.4 R.sub.1     R.sub.2   n   point °C.______________________________________CH.sub.3 CH.sub.3         CH.sub.3    CH.sub.3  1   131-140                                   (dec.)CH.sub.3 CH.sub.3         C.sub.6 H.sub.5                     C.sub.6 H.sub.5                               0   214-216.5                                   (dec.)CH.sub.3 CH.sub.3          ##STR15##  CH.sub.3  0   184-189 (dec.)CH.sub.3 CH.sub.3         CH.sub.3    CH.sub.3  2   178-188CH.sub.3 CH.sub.3         Cl          Cl        0    96-99.5CH.sub.3 CH.sub.3         CH.sub.3 S  CH.sub.3 S                               0   200-202.5                                   (dec.)CH.sub.3 CH.sub.3         CO.sub.2 CH.sub.3                     CH.sub.3  0   173-176.5                                   (dec.)CH.sub.3 CH.sub.3         CO.sub.2 (n-C.sub.6 H.sub.13)                     CH.sub.3  0CH.sub.3 CH.sub.3          ##STR16##                      ##STR17##                               0CH.sub.3 CH.sub.3         n-C.sub.3 H.sub.7 S                     n-C.sub.3 H.sub.7 S                               0   180-183.5                                   (dec.)CH.sub.3 CH.sub.3         CH.sub.3 SCH.sub.2                     CH.sub.3  0   oilCH.sub.3 CH.sub.3         n-C.sub.3 H.sub.7 SCH.sub.2                     CH.sub.3  0   100-115                                   (dec.)CH.sub.3 CH.sub.3         ClCH.sub.2  CH.sub.3  0   166-168.5                                   (dec.)CH.sub.3 CH.sub.3         n-C.sub.4 H.sub.9                     n-C.sub.4 H.sub.9                               0CH.sub.3 CH.sub.3          ##STR18##                      ##STR19##                               0CH.sub.3 CH.sub.3         CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2                             0CH.sub.3 CH.sub.3         t-Bu        CH.sub.3 S                               0CH.sub.3 CH.sub.3         t-Bu        H         0CH.sub.3 CH.sub.3         CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2                             0   170-173                                 (dec.)CH.sub.3 CH.sub.3         CH.sub.2 CH.sub.2 CH.sub.2                             0CH.sub.3 CH.sub.3          ##STR20##                      ##STR21##                               0CH.sub.3 CH.sub.3          ##STR22##                      ##STR23##                               0CH.sub.3 CH.sub.3          ##STR24##                      ##STR25##                               0CH.sub.3 CH.sub.3         CH.sub.3 CH.sub.2                     CH.sub.3 CH.sub.2                               0CH.sub.3 CH.sub.3         CH.sub.3 CH.sub.2 CH.sub.2                     CH.sub.3 CH.sub.2 CH.sub.2                               0CH.sub.3 CH.sub.3         (CH.sub.3).sub.2 CH                     (CH.sub.3).sub.2 CH                               0CH.sub.3 CH.sub.3         CH.sub.3 CH.sub.2 SCH.sub.2                     CH.sub.3  0CH.sub.3 CH.sub.3         CH.sub.3 CH.sub.2 S                     CH.sub.3 CH.sub.2 S                               0CH.sub.3 CH.sub.3         C.sub.6 H.sub.5                     CH.sub.3  0   167-170                                   (dec.)CH.sub.3 CH.sub.3         CH.sub.3    CH.sub.3 S                               0CH.sub.3 CH.sub.3         SCH.sub.2 CH.sub.2 S                             0   204-207                                 (dec.)CH.sub.3 CH.sub.3         CH.sub.3    CH.sub.3 CH.sub.2                               0   193-195.5                                   (dec.)C.sub.2 H.sub.5 CH.sub.3         CH.sub.3    CH.sub.3  0CH.sub.3 n-C.sub.3 H.sub.7         CH.sub.3    CH.sub.3  0n-C.sub.3 H.sub.7 CH.sub.3         CH.sub.3    CH.sub.3  0CH.sub.3 CH.sub.3         CH.sub.3    CH.sub.3 (CH.sub.2).sub.3                               0    99-104______________________________________ 
    
     
                                           TABLE 2__________________________________________________________________________ ##STR26##R         R&#39;        R.sub.1                      R.sub.2                           n melting point °C.__________________________________________________________________________ ##STR27##      ##STR28##               CH.sub.3                      CH.sub.3                           0 185-188 (dec.) ##STR29##      ##STR30##               CH.sub.3                      CO.sub.2 CH.sub.3                           0 ##STR31##      ##STR32##               CH.sub.3 S                      CH.sub.3 S                           0 ##STR33## ##STR34##     CH.sub.3 CH.sub.2               CH.sub.3 CH.sub.2                      0 ##STR35##      ##STR36##               CH.sub.3 (CH.sub.2).sub.3                      CH.sub.3                           0 ##STR37##      ##STR38##               CH.sub.3                      CH.sub.3                           0 ##STR39##      ##STR40##               CH.sub.3                      CH.sub.3                           0 ##STR41##      ##STR42##               CH.sub.3                      CH.sub.3                           0 117-118.5 ##STR43##      ##STR44##               CH.sub.3 CH.sub.2                      CH.sub.3 CH.sub.2                           0 ##STR45##      ##STR46##               CH.sub.3                      CH.sub.3                           0 ##STR47##      ##STR48##               CH.sub.3                      CH.sub.3                           O ##STR49##      ##STR50##               CH.sub.3                      CH.sub.3                           0 155-161 (dec.) ##STR51##      ##STR52##               CH.sub.3                      CH.sub.3                           0 ##STR53##      ##STR54##               CH.sub.3                      CH.sub.3                           0 ##STR55##      ##STR56##               CH.sub.3                      CH.sub.3                           0 ##STR57##      ##STR58##               CH.sub.3                      CH.sub.3                           0 ##STR59##      ##STR60##               CH.sub.3                      CH.sub.3                           0 ##STR61##      ##STR62##               C.sub.6 H.sub.5                      C.sub.6 H.sub.5                           0__________________________________________________________________________ 
    
     FORMULATION 
     Useful formulations of the compounds of Formula I can be prepared in conventional ways. They include dusts, granules, pellets, solutions, wettable powders, and the like. Many of these may be applied directly. Sprayable formulations can be extended in suitable media and used at spray volumes of from a few pints to several hundred gallons per acre. High strength compositions are primarily used as intermediates for further formulations. The formulations, broadly, contain about 1% to 99% by weight of active ingredient(s) and at least one of (a) about 0.1% to 20% surfactant(s) and (b) about 1% to 99% solid or liquid diluent(s). More specifically, they will contain these ingredients in the following approximate proportions: 
     
                       TABLE 3______________________________________       Active       Ingredient               Diluent(s)                         Surfactant(s)______________________________________Wettable Powders         20-90      0-74     1-10Oil Suspensions,          5-50     40-95     0-15SolutionsAqueous Suspensions         10-50     40-84     1-20Dusts          1-25     70-99     0-5Granules and Pellets          1-95      5-99     0-15High Strength 90-99      0-10     0-2Compositions______________________________________ 
    
     Lower or higher levels of active ingredient can, of course, be present depending on the intended use and the physical properties of the compound. Higher ratios of surfactant to active ingredient are sometimes desirable, and are achieved by incorporation into the formulation or by tank mixing. 
     Typical solid diluents are described in Watkins, et al., &#34;Handbook of Insecticide Dust Diluents and Carriers&#34;, 2nd. Edn., Dorland Books, Caldwell, N.J. The more absorptive diluents are preferred for wettable powders and the denser ones for dusts. Typical liquid diluents and solvents are described in Marsden, &#34;Solvents Guide&#34;, 2nd. Edn., Interscience, New York, 1950. Solubility under 0.1% is preferred for suspension concentrates; solution concentrates are preferable stable against phase separation at 0° C. McCutcheon&#39;s &#34;Detergents and Emulsifiers Annual&#34;, MC Publishing Co., Ridgewood, N.J., as well as Sisely and Wood, &#34;Encyclopedia of Surface Active Agents&#34;, Chemical Publ. Co., Inc., N.Y., 1964, list surfactants and recommended uses. All formulations can contain minor amounts of additives to reduce foam, caking, corrosion, microbiological growth, etc. Preferably, ingredients should be approved by the U.S. Environmental Protection Agency for the use intended. 
     The method of making such compositions are well known. Solutions are prepared by simply mixing the ingredients. Fine solid compositions are made by blending and, usually, grinding as in a hammer or fluid energy mill. Suspensions are prepared by wet milling (see, for example, Littler, U.S. Pat. No. 3,060,084). Granules and pellets may be made by spraying the active material upon preformed granule carriers or by agglomeration techniques. See J. E. Browning, &#34;Agglomeration&#34;, Chemical Engineering, Dec. 4, 1967, pp. 147ff. and &#34;Perry&#39;s Chemical Engineer&#39;s Handbook&#34;, 4th Edn., McGraw-Hill, N.Y., 1963, pp. 8-59ff. 
     For further information regarding the art of formulation see for example: 
     J. B. Buchanan, U.S. Pat. No. 3,576,834, Apr. 27, 1971, Col. 5, lines 36 through Col. 7, Line 70 and Ex. 1-4, 17, 106, 123-140; 
     R. R. Shaffer, U.S. Pat. No. 3,560,616, Feb. 2, 1971, Col. 3, Line 48 through Col. 7, line 26 and Ex. 3-9, 11-18; 
     E. Somers, &#34;Formulation&#34;, Chapter 6 in Torgeson, &#34;Fungicides&#34;, Vol. I, Academic Press, New York, 1967. 
     EXAMPLE 6 
     
         ______________________________________Wettable Powder______________________________________Dimethyl N,N&#39; [2,3-butanediylidenebis-                      30%[nitrilooxycarbonyl(N-methylimino)-thio(N-methylimino)carbonyloxy]]bis-[ethanimidothioate]Dicotyl sodium sulfosuccinate                      1.5%Sodium ligninsulfonate     3%Low viscosity methyl cellulose                      1.5%Attapulgite                64%______________________________________ 
    
     The ingredients are thoroughly blended, passed through an air mill to produce an average particle size under 15 microns, reblended, and sifted through a U.S. Ser. No. 50 sieve (0.3 mm opening) before packaging. 
     All compounds of the invention may be formulated in the same manner. 
     
         ______________________________________Wettable Powder______________________________________Dimethyl N,N&#39;-[1,2-propanediylidenebis-                      50%[nitrilooxycarbonyl(N-methylimino)-thio(N-methylimino)carbonyloxy]]bis-[ethanimidothioate]Sodium alkylnaphthalenesulfonate                      2%Low viscosity methyl cellulose                      2%Diatomaceous earth         46%______________________________________ 
    
     The ingredients are blended, coarsely hammer-milled and then air milled to produce particles of active essentially all below 10 microns in diameter. The product is reblended before packaging. 
     EXAMPLE 8 
     
         ______________________________________Dust______________________________________Wettable powder of Example 7                     10%Pyrophyllite (powder)     90%______________________________________ 
    
     The wettable powder and the pyrophyllite diluent are thoroughly blended and then packaged. The product is suitable for use as a dust. 
     EXAMPLE 9 
     
         ______________________________________Solution______________________________________Dimethyl N,N&#39;-[2,4-pentanediylidenebis-                      30%[nitrilooxycarbonyl(N-methylimino)-thio(N-methylimino)carbonyloxy]]bis-[ethanimidothioate]Dimethylformamide          70%______________________________________ 
    
     The ingredients are combined and stirred to produce a solution, which can be used for low volume applications. 
     EXAMPLE 10 
     
         ______________________________________Granule______________________________________Wettable powder of Example 6                     15%Gypsum                    69%Potassium sulfate         16%______________________________________ 
    
     The ingredients are blended in a rotating mixer and water sprayed on to accomplish granulation. When most of the material has reached the desired range of 1.0 to 0.42 mm. (U.S.S. No. 18 to 40 sieves), the granules are removed, dried, and screened. Oversize material is crushed to produce additional material in the desired range. These granules contain 4.5% active ingredient. 
     EXAMPLE 11 
     
         ______________________________________Extruded Pellet______________________________________Dimethyl N,N&#39;-[2,5-hexanediylidenebis-                      25%[nitrilooxycarbonyl(N-methylimino)-thio(N-methylimino)carbonyloxy]]bis-[ethanimidothioate]Anhydrous sodium sulfate   10%Crude calcium ligninsulfonate                      5%Sodium alkylnaphthalenesulfonate                      1%Calcium/magnesium bentonite                      59%______________________________________ 
    
     The ingredients are blended, hammer milled and then moistened with about 12% water. The mixture is extruded as cylinders about 3 mm diameter which are cut to produce pellets about 3 mm long. These may be used directly after drying, or the dried pellets may be crushed to pass a U.S.S. No. 20 sieve (0.84 mm opening). The granules held on a U.S.S. No. 40 sieve (0.42 mm opening) may be packaged for use and the fines recycled. 
     EXAMPLE 12 
     
         ______________________________________Aqueous Suspension______________________________________Dimethyl N,N&#39;-[2,3-butanediylidenebis-                     25%[nitrilooxycarbonyl(N-methylimino)-thio(N-methylimino)carbonyloxy]]bis-[ethanimidothioate]Hydrated attapulgite      3%Crude calcium ligninsulfonate                     10%Sodium dihydrogen phosphate                     0.5%Water                     61.5%______________________________________ 
    
     The ingredients are ground together in a ball or roller mill until the solid particles have been reduced to diameters under 10 microns. 
     Use 
     The compounds of this invention of Formula I are useful for the control of arthropods and nematodes which are detrimental to agricultural, animals important to man, forestry, horticulture, the household, man-made structures, public health and stored products. 
     As demonstrated in the following examples, the compounds have provided a high degree of control of important pests with minimization of side effects known in prior art compounds such as phytotoxicity. 
     The compounds readily control pestiferous arthropods belonging to such orders as Acari, Lepidoptera, Hymenoptera, Isoptera, Coleoptera, and Diptera. More specifically, arthropods controlled by the compounds of this invention include, but are not limited to, southern armyworm (Spodoptera eridanis), fall armyworm (Spodoptera frugiperda), soybean looper (Pseudoplusia includens), Mexican bean beetle (Edplachna varivestis), the housefly (Musca domestica), tobacco budworm (Heliothis virescens), bollworm (Heliothis zea), eastern tent caterpillar (Malacosoma americanum), brown dog tick (Rhipicephalus sanguineus), and black carpenter ant (Camponotus pennsylvanicus). 
     These compounds readily control pestiferous nematodes. More specifically, nematodes controlled by compounds of this invention include, but are not limited to, the root-knot nematode, Meloidogyne incognita; lesion nematode, Pratylenchus spp. and dagger nematode, Xiphinima. 
     The insects are controlled by applying one or more of the compounds to the locus of infestation, to the area to be protected, or to the pests themselves. For the control of insects on agricultural crops, compounds of this invention are generally applied to the foliage or other plant parts which are infested or which are to be protected. Effective amounts to be applied depend upon the specific compound used, the species to be controlled, its life stage, its size and location, the amount of rainfall, the time of year, moisture, temperature, type of application plant spacing, and other variables. In general, 0.05 to 10.0 kg/ha may be required for insect control in agriculture with rates of 0.15 to 5.0 kg/ha usually being sufficient in many situations. In large scale field operations, rates in the range of 0.25 to 3.0 kg/ha are generally used. 
     For the control of pestiferous arthropods of animals important to man, the household, man-made structures and stored products, compounds of this invention of formula I are generally applied to the item(s) which are infested or which are to be protected. Effective amounts to be applied depend upon the specific compound used, the species to be controlled, its life stage, its size and location, the amount of rainfall, the time of year, moisture, temperature, type of application and other variables. In general, 0.001% to 10% (by weight) preferably 0.05 to 5% and more preferably 0.01 to 2.5% of the compound of this invention will be applied in a composition such as in the form of a solution dispersion or dust. 
     Nematodes are controlled by applying the compounds to the locus of infestation, to the area to be protected or to the pest themselves. For the control of nematodes in agricultural crops, a compound of this invention is generally applied to a portion of the plant or surrounding soil which is infested or which is to be protected. Effective amounts to be applied depend upon the species to be controlled, its life stage, its size and location, the amount of rainfall, the time of year, moisture, temperature, soil type, percentage of area treated, type of application, and other variables. In general, 3 to 30 kg/ha may be required for nematode control in agriculture with rates of 5 to 10 kg/ha usually being sufficient in many situations. 
     The compounds of this invention of formula I possess significant advantages over prior art compounds. For example, their improved residual insecticidal activity can reduce the need for closely spaced multiple sprays resulting in greater economy to the grower and dissemination of less insecticide in the environment. An additional advantage is the reduced side-effects on cotton. Treated leaves remain green and free of reddening. 
     The compounds of this invention of formula I can be mixed with fungicides, bactericides, acaricides, nematicides, insecticides, or other biologically active compounds in order to achieve desired results with a minimum expenditure of time, effort and material. Amounts of these biologically active materials added for each part by weight of the composition of this invention may vary from 0.05 to 25 parts by weight. Suitable agents of this type are well-known to those skilled in the art. Some are listed below: 
     Fungicides 
     methyl 2-benzimidazolecarbamate (carbendazim), 
     tetramethyl thiuram disulfide (thiram), 
     n-dodecylguanidine acetate (dodine), 
     manganese ethylenebisdithiocarbamate (maneb), 
     1,4-dichloro-2,5-dimethoxybenzene (chloroneb), 
     methyl 1-(butylcarbamoyl)-2-benzimidazolecarbamate (benomyl), 
     2-cyano-N-ethylcarbamoyl-2-methoxyimino acetamide (cymoxamide), 
     N-trichloromethylthiotetrahydrophthalimide (captan), 
     N-trichloromethylthiophthalimide (folpet); 
     Bactericides 
     tribasic copper sulfate, 
     streptomycin sulfate; 
     Acaricides 
     senecioic acid, ester with 2-sec-butyl-4,6-dinitrophenyl (Morocide®), 
     6-methyl-1,3-dithiolo[2,3-B]quinoolin-2-one (Morestan®), 
     ethyl 4,4&#39;(p-chlorophenyl)-2,2,2-trichloroethanol (Kelthane®), 
     bis(pentochloro-2,4-cyclopentadien-1yl) (Pentac®), 
     trichlohexyltin hydroxide (Plictran®); 
     Nematicides 
     2-[diethoxyphoxphinylimino]-1,3-dithietane (Nematak®), 
     S-methyl 1-(dimethylcarbamoyl)-N-(methylcarbamoyloxy)thioformimidate (Vydate®), 
     S-methyl 1-carbamoyl-N-(methylcarbamoyloxy)thioformidate, 
     N-isopropylphosphoramidic acid, O-ethyl-O&#39;[4-(methylthio)-m-tolyl]diester (Nemacur®), 
     Insecticides 
     3-hydroxy-N-methylcrotonamide(dimethylphosphate)ester (Azodrin®), 
     methylcarbamic acid, ester with 2,3-dihydro-2,2-dimethyl-7-benzofuranol (Furadan®), 
     O-[2,4,5-trichloro-α-(chloromethyl)benzyl]phosphoric acid, O&#39;,O&#39;-dimethyl ester (Gardona®), 
     2-mercaptosuccinic acid, diethyl ester, S-ester with thionophosphoric acid, dimethyl ester (Malathion®), 
     phosphorothioic acid, O,O-dimethyl, O-p-nitrophenyl ester(methyl parathion) 
     methylcarbamic acid, ester with α-naphthol (Sevin®), 
     methyl O-(methylcarbamoyl)thiolacetohydroxamate (methomyl) 
     N&#39;-(4-chloro-o-tolyl)-N,N-dimethylformamidine (Galecron®), 
     O,O-diethyl-O-(2-isopropyl-4-methyl-6-pyrimidylphosphorothioate (Diazinon®), 
     octachlorocamphene (toxaphene) 
     O-ethyl O-p-nitrophenyl phenylphosphonothioate (EPN) cyano(3-phenoxyphenyl)-methyl-4-chloro-α-(1-methylethyl)benzeneacetate (Pydrin®), 
     (3-phenoxyphenyl)methyl(+)-cis, trans-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate, (Ambush®), 
     dimethyl N,N&#39;-[thiobis[(n-methylimino)carbonyloxy]]bis[ethanimidothioate] (Larvin®), 
     O-ethyl-S-(p-chlorophenyl)ethylphosphonodithioate (Curacron®), 
     phosphorothiolothionic acid, O-ethyl-O-[4-(methylthio)phenyl]-S-n-propyl ester (Bolstar®). 
     Additional biological active agents which can be mixed with compounds of this invention of formula I include: 
     O,O-dimethyl O-(2,4,5-trichlorophenyl)phosphorothioate (Ronnel®); 
     O,O-diethyl O-(3-chloro-4-methyl-2-oxo-2H-1-benzapyran-7-yl)phosphorothioate (Co-Ral.RTM.); 
     Dimethyl 2,2-dichlorovinyl phosphate (Dichlorvos); 
     N-(mercaptomethyl)phthalimide S-(O,O-dimethyl phosphorodithioate (Imidan®); 
     2,2-Bis(p-methoxyphenyl)-1,1,1-trichloroethane (Methoxychlor); 
     Octachloro-4,7-methanotetrahydroindane (Chlordane); 
     O,O-diethyl-O-(2-ispropyl-6-methyl-5-pyrimidinyl) phosphorothioate (Diazinon); 
     DL-2-allyl-4-hydroxy-3-methyl-2-cyclopenten-1-one ester of dicistranschrysanthemum monocarboxylic acid (Allethrin). 
     EXAMPLE 13 
     The foliage only of red kidney bean plants in the two-leaf stage is sprayed to run-off with dispersions of compounds of this invention at various concentrations. Dispersions are prepared by dissolving appropriately weighed quantities of the active ingredient in 10 ml of acetone and diluting to 100 ml of water containing surface active agent (Duponol® L-144 WDG) at 1:3000. After drying, leaves are excised and placed in covered 10 cm petri dishes along with moist filter paper to keep them fresh. Ten southern armyworm larvae are placed in each dish. The units are kept in a room maintained at 25°±2° C. 53±5% RH. Results are recorded at the end of two days. 
     
         ______________________________________Compound         Concentration %                         Mortality %______________________________________dimethyl N,N&#39;-[2,3-butane-            .004         95diylidenebis[nitrilooxy-            .002         90carbonyl(N-methylimino)-thio(N-methylimino)carbonyl-oxy]]bis[ethanimidothioate]dimethyl N,N&#39;-[1,2-propane-            .01          100diylidenebis[nitrilooxy-            .005         100carbonyl(N-methylimino)thio-            .0025        95(N-methylimino)carbonyl-oxy]]bis[ethanimidothioate]dimethyl N,N&#39;-[2,4-pentane-            .01          100diylidenebis[nitrilooxy-            .005         80carbonyl(N-methylimino)thio-(N-methylimino)carbonyl-oxy]]bis[ethanimidothioate]dimethyl N,N&#39;-[2,5-hexane-            .01          100diylidenebis[nitrilooxy-            .005         90carbonyl(N-methylimino)-thio(n-methylimino)carbonyl-oxy]]bis[ethanimidothioate]Untreated        --           0______________________________________ 
    
     EXAMPLE 14 
     The foliage of red kidney bean plants in the two-leaf stage is sprayed to run-off with dispersions of compounds of this invention at various concentrations. Dispersions are prepared by dissolving appropriately weighed quantities of the active ingredient in 10 ml of acetone and diluting to 100 ml with water containing surface active (Duponol® L-144 WDG) at 1:3000. After drying, plants are placed under artificial light in a room maintained at 25±2° C., 54±5% RH. After the designated period, leaves are excised and placed in covered 10 cm petri dishes along with moist filter paper to keep them fresh. Ten southern armyworm larvae are placed in each dish. The units are kept in a room maintained at 25±2° C., 54% RH. Results are recorded at the end of two days. 
     
         ______________________________________            Concen-  Days    (% Dead)Compound         tration %                     2       7______________________________________dimethyl N,N&#39;-[2,3-butane-            .01       90     100diylidenebis[nitrilooxy-            .005     100      95carbonyl(N-methylimino)-thio(N-methylimino)carbonyl-oxy]]bis[ethanimidothioate]Untreated Check           0       0______________________________________ 
    
     EXAMPLE 15 
     Potted cotton plants approximately 25 cm high having 3-4 true leaves are sprayed to run-off with aqueous dispersions of compounds of this invention at 500 ppm. The sprays contain surface active agent (Duponol® L-144 WDG) at a concentration of 1:3000. Another set of plants is similarly treated with methomyl. After drying, plants are set out in the greenhouse and held for observations. 
     
         ______________________________________Compound (500 ppm AI.sup.1)              Rating.sup.2 (5 Days)______________________________________dimethyl N,N&#39;-[2,3-butane-diylidenebis[nitrilooxy-              0carbonyl(N-methylimino)-thio(N-methylimino)carbonyloxy]]bis[ethanimidothioate]Methomyl           4RUntreated Control  0______________________________________ AI.sup.1  = active ingredient .sup.2 &#34;R&#34; denotes typical methomyl effect, i.e., reddening of older leaves, slight puckering and black stippling of younger leaves. Rating is on the basis of 0 to 10, with 10 indicating total leaf area involvement. 
    
     EXAMPLE 16 
     Tobacco budworm (Heliothis virescens) larvae are treated topically with compounds of the invention. One microliter of each concentration used is applied to the dorso-thoracic area of each larva tested. The stock solutions are prepared by dissolving appropriately weighed quantities of active ingredient in predetermined quantities of acetone. Further diluting with acetone yields the desired concentrations. Larvae were treated in individual 1-oz. cups in which were reared on artificial diet. Fifteen or twenty larvae were treated with each desired concentration and kept in a room at 25±2° C. Results were recorded 2 days after treatment. 
     
         ______________________________________             Concentration                         % MortalityCompound          (μg/larva)                         (48 hrs)______________________________________dimethyl N,N&#39;-[2,3-butane-             0.25        93diylidenebis[nitrilooxy-              0.125      85carbonyl(N-methylimino)-thio(N-methylimino)carbonyl-oxy]]bis[ethanimidothioate]dimethyl N,N&#39;-[2,4-pentane-             0.5         87diylidenebis[nitrilooxy-             0.25        73carbonyl(N-methylimino)thio-(N-methylimino)carbonyl-oxy]]bis[ethanimidothioate]Untreated         --           0______________________________________ 
    
     EXAMPLE 17 
     Dimethyl N,N&#39;-[[1,2-ethanediylidenebis[nitrilooxycarbonyl(N-methylimino)thio(N-methylimino)carbonyloxy]]]-bis-[ethanimidothioate], was dissolved in acetone and mixed into soil containing the rootknot nematode, Meloidogyne incognita. Dimethyl N,N&#39;-[[1,3-propanediylbis[nitrilooxycarbonyl(N-methylimino)thio(N-methylimino)carbonyloxy]]]bis-[ethanimidothioate], was similarly dissolved in acetone and mixed into soil containing the rootknow nematode, Meloidogyne incognita. The treated soil samples were planted with cucumber seeds. After two weeks, the roots were examined for nematode injury and the results are summarized below. 
     
         ______________________________________                       % NematodeCompound          kg/ha     Control______________________________________dimethyl N,N&#39;-[2,3-butane-             15        100diylidenebis[nitrilooxy-carbonyl(N-methylimino)-thio(N-methylimino)carbonyl-oxy]]bis[ethanimidothioate]Untreated Control --        0______________________________________ 
    
     EXAMPLE 18 
     Four-ounce wide mouth jars, each containing 10 black carpenter ants (Camponotus Pennsylvanicus) were sprayed with 100 and 10 ppm concentration of the indicated compound in acetone solution. The ants were confined with caps which were also sprayed. Forty-eight hours later, percent mortality was determined. 
     
         ______________________________________            Spray ConcentrationCompound           ppm    % Mortality______________________________________dimethyl N,N&#39;-[2,3-butane-              100    100diylidenebis[nitrilooxy-               10    100carbonyl(N-methylimino)-thio(N-methylimino)-carbonyloxy]]bis[ethan-imidothioate]______________________________________ 
    
     EXAMPLE 19 
     Four-ounce wide mouth jars, each containing 10 brown dog ticks (Rhipicephalus sanguineus) were sprayed with 10 and 5 ppm concentration of the indicated compound in acetone solution. The ticks were confined with caps which were also sprayed. Forty-eight hours later, percent mortality was determined. 
     
         ______________________________________            Spray ConcentrationCompound           ppm    % Mortality______________________________________dimethyl N,N&#39;-[2,3-butane-              10     100diylidenebis[nitrilooxy-               5     100carbonyl(N-methylimino)-thio(N-methylimino)-carbonyloxy]]bis[ethan-imidothioate]______________________________________ 
    
     EXAMPLE 20 
     Uniform test units consisting of cut branches of wild cherry trees bearing four eastern tent caterpillar nests in can-type vases were prepared and sprayed with dispersions of this compound. They were kept out of doors and results were read 5 days after treatment. 
     Evaluation was made by counting all caterpillars inside and outside the nests. 
     
         ______________________________________          ConcentrationCompound       oz(ai)/100 gal                       % Mortality______________________________________dimethyl N,N&#39;-[2,3-butane-          1            99diylidenebis[nitrilooxy-          0.25         99carbonyl(N-methylimino)-thio(N-methylimino)-carbonyloxy]]bis[ethan-imidothioate]______________________________________
Carbamoyl sulfides such as dimethyl N,N'-[2,3-butanediylidenebis[nitrilooxycarbonyl(N-methylimino)thio(N-methylimino)carbonyloxy]]bis[ethanimidothioate] useful for control of insects and nematodes. This application is a divisional of application Ser. No. 139,836, filed Apr. 24, 1980, now U.S Pat. No. 4,254,141, which is a continuation-in-part of application Ser. No. 18,293, filed Mar. 6, 1979, and now abandoned.