Although the origins of iron working in Africa have been the subject of scholarly interest since the 1860s, it is still not known whether this technology diffused into sub-Saharan Africa from the Mediterranean region, or whether it was invented there independently of iron working elsewhere. Although some nineteenth-century European scholars favored an indigenous invention of iron working in sub-Saharan Africa, archaeologists writing between 1945 and 1965 mostly favored diffusion of iron smelting technology from Carthage across the Sahara to West Africa and/or from Meroe on the upper Nile to central Africa. This in turn has been questioned by more recent research which argues for an independent invention.
The invention of radiocarbon dating in the late 1950s enabled dating of metallurgical sites by the charcoal fuel used for smelting and forging. By the late 1960s some surprisingly early radiocarbon dates had been obtained for iron smelting sites in both Niger and central Africa (Rwanda, Burundi), reviving the view that iron-making was independently invented by Africans in sub-Saharan Africa as far back as 3600 BCE. These dates preceded the known antiquity of ironworking in Carthage or Meroe, weakening the diffusion hypothesis. In the 1990s, evidence was found of Phoenician iron smelting in the western Mediterranean (900–800 BCE), though specifically in North Africa it seems to date only to the 5th to 4th centuries BCE, or the 7th century BCE at the earliest, contemporary to or later than the oldest known iron metallurgy dates from sub-Saharan Africa. According to archaeometallurgist Manfred Eggert, "Carthage cannot be reliably considered the point of origin for sub-Saharan iron ore reduction." It is still not known when iron working was first practiced in Kush and Meroe in modern Sudan, but the earliest known iron metallurgy dates from Meroe and Egypt do not predate those from sub-Saharan Africa, and thus the Nile Valley is also considered unlikely to be the source of sub-Saharan iron metallurgy.
From the mid-1970s there were new claims for independent invention of iron smelting in central Niger and from 1994 to 1999 UNESCO funded an initiative "Les Routes du Fer en Afrique/The Iron Routes in Africa" to investigate the origins and spread of iron metallurgy in Africa. This funded both the conference on early iron in Africa and the Mediterranean and a volume, published by UNESCO, that generated some controversy because it included only authors sympathetic to the independent-invention view.
Two reviews of the evidence from the mid-2000s found technical flaws in the studies claiming independent invention, raising three major issues. The first was whether the material dated by radiocarbon was in secure archaeological association with iron-working residues. Many of the dates from Niger, for example, were on organic matter in potsherds that were lying on the ground surface together with iron objects. The second issue was the possible effect of "old carbon": wood or charcoal much older than the time at which iron was smelted. This is a particular problem in Niger, where the charred stumps of ancient trees are a potential source of charcoal, and have sometimes been misidentified as smelting furnaces. A third issue is the weaker precision of the radiocarbon method for dates between 800 and 400 BCE, attributable to irregular production of radiocarbon in the upper atmosphere. Unfortunately most radiocarbon dates for the initial spread of iron metallurgy in sub-Saharan Africa fall within this range.
Controversy flared again in 2007 with the publication of excavations by Étienne Zangato and colleagues in the Central African Republic. At Oboui they excavated an undated iron forge yielding eight consistent radiocarbon dates of 2000 BCE. This would make Oboui the oldest iron-working site in the world, and more than a thousand years older than any other dated evidence of iron in Central Africa. Opinion among African archaeologists is sharply divided. Some specialists accept this interpretation, but archaeologist Bernard Clist has argued that Oboui is a highly disturbed site, with older charcoal having been brought up to the level of the forge by the digging of pits into older levels. Clist also raised questions about the unusually good state of preservation of metallic iron from the site. However, archaeologists such as Craddock, Eggert, and Holl have argued that such disturbance or disruption is highly unlikely given the nature of the site. Additionally, Holl, regarding the state of preservation, argues that this observation was based on published illustrations representing a small unrepresentative number of atypically well-preserved objects selected for publication. At Gbabiri, also in the Central African Republic, Eggert has found evidence of an iron reduction furnace and blacksmith workshop with earliest dates of 896–773 BCE and 907–796 BCE respectively.
In north-central Burkina Faso, remains of an iron smelting furnace near Douroula was also dated to the 8th century BCE, leading to the creation of the Ancient Ferrous Metallurgy Sites of Burkina Faso World Heritage Site. In the Nsukka region of southeast Nigeria (now Igboland), archaeological sites containing iron smelting furnaces and slag have been excavated dating to 750 BCE in Opi (Augustin Holl 2009) and 2,000 BCE in Lejja (Pamela Eze-Uzomaka 2009). According to Augustin Holl (2018), there is evidence of ironworking dated to 2,153–2,044 BCE and 2,368–2,200 BCE from the site of Gbatoro, Cameroon.
Archaeometallurgical scientific knowledge and technological development originated in numerous centers of Africa; the centers of origin were located in West Africa, Central Africa, and East Africa; consequently, as these origin centers are located within inner Africa, these archaeometallurgical developments are thus native African technologies. Iron metallurgical development occurred 2631 BCE – 2458 BCE at Lejja, in Nigeria, 2136 BCE – 1921 BCE at Obui, in Central Africa Republic, 1895 BCE – 1370 BCE at Tchire Ouma 147, in Niger, and 1297 BCE – 1051 BCE at Dekpassanware, in Togo.
In 2014, archaeo-metallurgist Manfred Eggert argued that, though still inconclusive, the evidence overall suggests an independent invention of iron metallurgy in sub-Saharan Africa. In a 2018 study, archaeologist Augustin Holl also argues that an independent invention is most likely.
While the origins of iron smelting are difficult to date by radiocarbon, there are fewer problems with using it to track the spread of ironworking after 400 BCE. In the 1960s it was suggested that iron working was spread by speakers of Bantu languages, whose original homeland has been located by linguists in the Benue River valley of eastern Nigeria and Western Cameroon. Although some assert that no words for iron or ironworking can be traced to reconstructed proto-Bantu, place-names in West Africa suggest otherwise, for example (Okuta) Ilorin, literally "site of iron-work". The linguist Christopher Ehret argues that the first words for iron-working in Bantu languages were borrowed from Central Sudanic languages in the vicinity of modern Uganda and Kenya, while Jan Vansina argues instead that they originated in non-Bantu languages in Nigeria, and that iron metallurgy spread southwards and eastwards to Bantu speakers, who had already dispersed into the Congo rainforest and the Great Lakes region. Archaeological evidence clearly indicates that starting in the first century BCE, iron and cereal agriculture (millet and sorghum) spread together southward from southern Tanzania and northern Zambia, all the way to the eastern Cape region of present South Africa by the third or fourth century CE. It seems highly probable that this occurred through migrations of Bantu-speaking peoples.