For many ores (e.g. those of Cu, Mo, W, Ni), the collectors are anionic sulfur ligands. Particularly popular for sulfide minerals are xanthate salts, including potassium amyl xanthate (PAX), potassium isobutyl xanthate (PIBX), potassium ethyl xanthate (KEX), sodium isobutyl xanthate (SIBX), sodium isopropyl xanthate (SIPX), sodium ethyl xanthate (SEX). Related collectors include related sulfur-based ligands: dithiophosphates, dithiocarbamates. Still other classes of collectors include the thiourea thiocarbanilide. Fatty acid carboxylates, alkyl sulfates, and alkyl sulfonates have also been used for oxide minerals.
For some minerals (e.g., sylvinite for KCl), fatty amines are used as collectors.