text: Perhaps surprisingly, molecular vibrations can be treated using Newtonian mechanics to calculate the correct vibration frequencies. The basic assumption is that each vibration can be treated as though it corresponds to a spring. In the harmonic approximation the spring obeys Hookes law: the force required to extend the spring is proportional to the extension. The proportionality constant is known as a force constant, k'. The anharmonic oscillator is considered elsewhere.
  By Newtons second law of motion this force is also equal to a reduced mass, μ', times acceleration.
  Since this is one and the same force the ordinary differential equation follows.
  The solution to this equation of simple harmonic motion is
  A is the maximum amplitude of the vibration coordinate Q. It remains to define the reduced mass, μ. In general, the reduced mass of a diatomic molecule, AB, is expressed in terms of the atomic masses, m and m, as
  The use of the reduced mass ensures that the centre of mass of the molecule is not affected by the vibration. In the harmonic approximation the potential energy of the molecule is a quadratic function of the normal coordinate. It follows that the force-constant is equal to the second derivative of the potential energy.
  When two or more normal vibrations have the same symmetry a full normal coordinate analysis must be performed (see GF method). The vibration frequencies, ν, are obtained from the eigenvalues, λ, of the matrix product GF. G is a matrix of numbers derived from the masses of the atoms and the geometry of the molecule. F is a matrix derived from force-constant values. Details concerning the determination of the eigenvalues can be found in.