text: Thermometric titrations of silver nitrate with halides and cyanide are all possible. The reaction of silver nitrate with chloride is strongly exothermic. For instance, the reaction enthalpy of Ag with Cl is a high −61.2 kJ/mol. This permits convenient determination of chloride with commonly available standard 0.1 mol/L AgNO. Endpoints are very sharp, and with care, chloride concentrations down to 15 mg/L can be analyzed. Bromide and chloride may be determined in admixture.