text: The hypophosphite ion is . The salts are prepared by heating white phosphorus in warm aqueous alkali e.g. Ca(OH):
  :P + 2 Ca(OH) + 4 HO → 2 Ca(HPO) + 2 H
  Hypophosphites are reducing agents:
  :  + 3 OH →  + 2 HO + 2 e
  Hypophosphites are used in electroless nickel plating as the reducing agent to deposit for example Ni metal from Ni salts. The hypophosphite ion is thermodynamically unstable, and disproportionates on heating to phosphine and phosphate salts:
  : 2  → PH +