text: Polyoxomolybdates include the wheel-shaped molybdenum blue anions and spherical keplerates. The cluster  consists of more than 700 atoms and is the size of a small protein. The anion is in the form of a tire (the cavity has a diameter of more than 20 Å) and an extremely large inner and outer surface. The incorporation of lanthanide ions in molybdenum blues is particularly intriguing. Lanthanides can behave like Lewis acids and perform catalytic properties. Lanthanide-containing polyoxometalates show chemoselectivity and are also able to form inorganic–organic adducts, which can be exploited in chiral recognition.