text: According to their properties, cations are usually classified into six groups.  Each group has a common reagent which can be used to separate them from the solution. To obtain meaningful results, the separation must be done in the sequence specified below, as some ions of an earlier group may also react with the reagent of a later group, causing ambiguity as to which ions are present. This happens because cationic analysis is based on the solubility products of the ions. As the cation gains its optimum concentration needed for precipitation it precipitates and hence allowing us to detect it.  The division and precise details of separating into groups vary slightly from one source to another; given below is one of the commonly used schemes.