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===================== Product Identification ===================== Product ID:262889 TYPE S DEVELOPER REPLENISHER 3-7-90 PART A Kit Part:Y Preparer's Name:ENGINEERING DEPT CAGE:0WG29 CAGE:0WG29 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 40-70% Other REC Limits:NONE RECOMMENDED Ingred Name:POTASSIUM SULFITE CAS:10117-38-1 RTECS #:WT3530000 Fraction by Wt: 10-15% Other REC Limits:NONE RECOMMENDED Ingred Name:SODIUM SULFITE CAS:7757-83-7 RTECS #:WE2150000 Fraction by Wt: 10-15% Other REC Limits:NONE RECOMMENDED Ingred Name:HYDROQUINONE (SARA 302/313) (CERCLA) CAS:123-31-9 RTECS #:MX3500000 Fraction by Wt: 5-10% Other REC Limits:NONE RECOMMENDED OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3; 9596 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:POTASSIUM HYDROXIDE (CERCLA) CAS:1310-58-3 RTECS #:TT2100000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED OSHA PEL:C 2 MG/M3 ACGIH TLV:C 2 MG/M3; 9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:POTASSIUM CARBONATE CAS:584-08-7 RTECS #:TS7750000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CONTACT CAUSES SKIN & EYE IRRITATION; MAY CAUSE ALLERGIC SKIN REACTION.. HARMFUL IF SWALLOWED; MAY CAUSE GI TRACT IRRITATION. NO KNOWN HEALTH EFFECTS ON INHALATION. CHRONIC: NONE SPECIFIED BY MANUFACT URER. Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. Effects of Overexposure:EYES, SKIN, RESPIRATORY AND GASTROINTESTINAL TRACTS IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. SKIN-FLUSH WITH WATER & WASH SKIN WITH A NON-ALKALINE SKIN CLEANER. EYE-FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. INHALED-REMOVE TO FRESH AIR. PROV IDE OXYGEN/ARTIFICIAL RESPIRATION IF NEEDED. INGESTED-IF CONSCIOUS, INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL PERSONNEL. CALL A PHYSICIAN/POISON CONTROL CENTER IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, ALCOHOL FOAM OR DRY CHEMICAL. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. COOL FIRE-EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNT OF WATER. OTHERWISE, ABSORB WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMI NATION. Neutralizing Agent:WEAK ACID. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BETWEEN 10-25C (50-80F). PROTECT SHIPMENTS FROM FREEZING. KEEP ABOVE 40F (4.4C). Other Precautions:WARNING! HARMFUL IF SWALLOWED. WASH THOROUGHLY AFTER HANDLING. AVOID BREATHING VAPORS. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. Ventilation:GOOD GENERAL VENTILATION IS SUFFICIENT FOR MOST CONDITIONS (10 ROOM VOLUMES PER HOUR). Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER. INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED. Work Hygienic Practices:THE ROUTINE USE OF A NON-ALKALINE (ACID) TYPE OF HAND CLEANER WILL HELP MINIMIZE THE POSSIBILITY OF ALLERGIC REACTION. Supplemental Safety and Health KEY1:C4. KIT CONSISTS OF 3 PARTS. SEE PNI B & C, SAME NSN. STRONGLY ALKALINE, MAY CAUSE ADVERSE ENVIRONMENTAL EFFECTS. MAY CAUSE OXYGEN DEPLETION IN AQUEOUS SYSTEMS. AFTER DILUTION WITH A LARGE AMOUNT OF WATER, FOLLOWED BY SECONDARY WASTE TREATMENT, THIS MATERIAL IS NOT EXPECTED TO CAUSE ADVERSE ENVIRONMENTAL EFFECTS. ================== Physical/Chemical Properties ================== HCC:C3 Spec Gravity:1.3 pH:11.2 Solubility in Water:COMPLETE Appearance and Odor:YELLOW/BROWN LIQUID, ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS & ACIDS. Stability Condition to Avoid:ALL SOLUTIONS STABLE UNDER NORMAL AMBIENT & ANTICIPATED STORAGE & HANDLING CONDITIONS OF TEMPERATURE & PRESSURE. Hazardous Decomposition Products:SULFUR DIOXIDE. Conditions to Avoid Polymerization:WILL NOT OCCUR WITH ANY SOLUTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE OR LOCAL REGULATIONS. DISPOSE IN AN APPROVED AND PERMITTED LANDFILL.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:KLISTER VIOLET K-120 CAGE:1DW38 CAGE:1DW38 ============= Composition/Information on Ingredients ============= Ingred Name:WOOD ROSIN (ALL GRADES) Fraction by Wt: >= 60% Other REC Limits:NONE SPECIFIED OSHA PEL:NOT ESTABLISHED. ACGIH TLV:NOT ESTABLISHED. Ingred Name:SYNTHETIC RUBBER Fraction by Wt: 10 - 20% Other REC Limits:NONE SPECIFIED OSHA PEL:NOT ESTABLISHED. ACGIH TLV:NOT ESTABLISHED. Ingred Name:WHITE OIL/MEDICAL WHITE OIL Fraction by Wt: 10 - 20% Other REC Limits:NONE SPECIFIED OSHA PEL:NOT ESTABLISHED. ACGIH TLV:NOT ESTABLISHED. ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE- NO EFFECTS KNOWN ON HUMAN FROM SHORT-TERM EXPOSURE. PROLONGED OR REPEATED CONTACT MAY CAUSE SKIN IRRITATION OR SENSITIZATION IN SENSITIVE SUBJECTS. CHRONIC- NONE KNOWN. Effects of Overexposure:PROLONGED OR REPEATED CONTACT MAY CAUSE SKIN IRRITATION OR SENSITIZATION IN SENSITIVE SUBJECTS. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. SKIN:WASH WITH SOAP & WATER. EYE:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. INHALED:REMOVE TO FRESH AIR. ORAL:WASH OUT MOUTH WITH WATER. DRINK LA RGE AMOUNT OF WATER. CALL A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:>338F,>170C Extinguishing Media:WATER SPRAY, CO2, SAND, DRY CHEMICAL. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL & FLUSH SPILLS AWAY. Fire Fighting Procedures:WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:OVERHEATING TO BE AVOIDED, ESPECIALLY BY DIRECT CONTACT WITH NAKED FLAMES. ================== Accidental Release Measures ================== Spill Release Procedures:STOP RELEASE. DIKE TO CONTAIN LIQUID. USE INERT ABSORBENT MATERIAL. TRANSFER TO PROPER CONTAINER FOR DISPOSAL. PREVENT THE DISPERSION OF THIS MATERIAL TO THE ENVIRONMENT. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE-KEEP AWAY FROM HEAT, SPARKS & OPEN FLAME. USE ADEQUATE VENTILATION. Other Precautions:DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR DRINKING. REMOVE CONTAMINATED CLOTHING PROMPTLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NON REQUIRED UNDER NORMAL CONDITIONS. Ventilation:ADEQUATE Other Protective Equipment:EYE BATH & SAFETY SHOWER Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:1.008 Appearance and Odor:VISCOUS LIQUID - TYPICAL ROSIN ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:EXCESSIVE HEAT AND FLAMES Hazardous Decomposition Products:NONE KNOWN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:PRIMARY BATTERY,MERCURY BA1533/U CAGE:06121 CAGE:06121 CAGE:2A917 ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM HYDROXIDE (SARA III).2.3 G;BP 2408F;VP 1 MMHG @ 719C;SPEC GRAV 2.04 (WATER=1);SOL APPRECIABLE IN WATER. CAS:1310-58-3 RTECS #:TT2100000 Fraction by Wt: 7.4% Other REC Limits:NONE SPECIFIED OSHA PEL:2 MG/M3 CEILING ACGIH TLV:2 MG/M3 CEILING EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:MERCURIC OXIDE (SARA III).7.8 G;SPEC GRAVITY 3.97 (WATER=1);SOL IN WATER NEGLIGIBLE.OSHA PEL IS CEILING VALUE. CAS:21908-53-2 RTECS #:OW8750000 Fraction by Wt: 25.0% Other REC Limits:NONE SPECIFIED OSHA PEL:0.1 MG(HG)/M3 SKIN ACGIH TLV:0.1 MG(HG)/M3 SKIN Ingred Name:MERCURY (SARA III).0.2 G;BP 674F;VP 1 MMHG @ 186C;SPEC GRAV 13.6 (WATER=1);SOL IN WATER NEGLIGIB.OSHA PEL CEILING VALUE. CAS:7439-97-6 RTECS #:OV4550000 Fraction by Wt: <5.0% Other REC Limits:NONE SPECIFIED OSHA PEL:0.1 MG(HG)/M3 SKIN ACGIH TLV:0.05 MG/M3 SKIN EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT KNOWN Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SEE SIGNS AND SYMPTOMS OF OVEREXPOSURE. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES:POTASSIUM HYDROXIDE IS CAUSTIC CAUSING DAMAGE TO EYE.SKIN:POTASSIUM HYDROXIDE IS CAUSTIC CAUSING DAMAGE TO SKIN. Medical Cond Aggravated by Exposure:NOT KNOWN ======================= First Aid Measures ======================= First Aid:EYES:FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES AND SEE PHYSICIAN.SKIN:WASH WITH WATER IMMEDIATELY. ===================== Fire Fighting Measures ===================== Lower Limits:NOT KNOWN Upper Limits:NOT KNOWN Extinguishing Media:NOT KNOWN Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS (SCBA) AND FULL TURNOUT GEAR WHEN BATTERIES ARE IN FIRE. Unusual Fire/Explosion Hazard:CAN EXPLODE WHEN SUBJECTED TO EXCESSIVE HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:NOT KNOWN Neutralizing Agent:NOT KNOWN ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AT ROOM TEMPERATURE. Other Precautions:DO NOT BURN,CAN EXPLODE WHEN SUBJECTED TO EXCESSIVE HEAT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:CONTACT LOCAL SAFETY/INDUSTRIAL HYGIENE OFFICE TO DETERMINE IF RESPIRATORY PROTECTION IS REQUIRED . Ventilation:CONTACT LOCAL SAFETY/INDUSTRIAL HYGIENE OFFICE TO DETERMINE IF LOCAL EXHAUST VENTILATION IS NEEDED . Other Protective Equipment:NOT KNOWN Work Hygienic Practices:AVOID SKIN AND EYE CONTACT. Supplemental Safety and Health DIMENSIONS OF BATTERIES:GROSS WEIGHT (LB) 0.07;OUTSIDE PACKAGE DIMENSIONS (INCHES):2.4(L),0.3(W),1.1(H). ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:NOT KNOWN Melt/Freeze Pt:M.P/F.P Text:NOT KNOWN Decomp Temp:Decomp Text:NOT KNOWN Vapor Pres:NOT KNOWN Vapor Density:NOT KNOWN Spec Gravity:NOT KNOWN Evaporation Rate & Reference:NOT KNOWN Solubility in Water:NOT KNOWN Appearance and Odor:POTASSIUM HYDROXIDE:CLEAR LIQUID.MERCURY:SILVER.MERCURY OXIDE:ORANGE-RED POWDER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NOT KNOWN Stability Condition to Avoid:TEMPERATURES ABOVE 500F. Hazardous Decomposition Products:MERCURIC OXIDE ON EXPOSURE TO LIGHT OR 500F DECOMPOSES TO OXYGEN AND MERCURY. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,STATE,AND LOCAL REGULATIONS.COORDINATE WITH SUPPORTING INSTALLATION AND/OR MACOM ENVIRONMENTAL OFFICE PRIOR TO DISPOSAL .DO NOT DISCARD.CONTACT LOCAL DEFENSE PROPERTY DISPOSAL OFFICE (DPDO).
1
gloves_mandatory
======================================================= Product ID: ACID REAGENT (25 ML), 6392 Cage: 4T252 ======================================================= Contractor Summary ======================================================= Cage: 4T252 Box: 907 ======================================================= Ingredients ======================================================= Cas: 5329-14-6 RTECS #: WO5950000 % Wt: <85 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 7647-14-5 RTECS #: VZ4725000 % Wt: <25 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: NO Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: THIS PRODUCT MAY BE CORROSIVE TO EYES, IRRITATING TO RESPIRATORY TRACT. MODERATELY TOXIC. CHRONIC: NONE SPECIFIED BY MANUFACTURER. Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: CAUSES EYE BURNS. MAY CAUSE RESPIRATORY TRACT IRRITATION. Medical Cond Aggravated By Exposure: PREEXISTING EYE AND RESPIRATORY TRACT CONDITIONS. First Aid: EYES/SKIN: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES. REMOVE CONTAMINATED CLOTHING. CALL MD. INGESTION: DO NOT INDUCE VOMITING. GIVE 1-2 GLASSES OF WATER. CALL MD IMMEDIATELY. NEVER GIVE AN YTHING BY MOUTH TO AN UNCONSCIOUS PERSON. INHALATION: REMOVE TO FRESH AIR. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: COVER CONTAM SURF W/SODA ASH/SODIUM BICARBONATE. MIX & ADD WATER IF NEC. USE LITMUS PAPER TO MAKE SURE PH OF SLURRY IS NEUT/ADD NEUT UNTIL MIX STOPS BUBBLING. SCOOP UP SLURRY & WASH NEUTRAL WASTE DOWN DRAIN W/EXCESS WATER. WASH SITE W/SODAASH SOLN. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE, AND LOCAL REGULATIONS. Handling And Storage Precautions: AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. DO NOT BREATHE DUST. KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME. STORE TIGHTLY CLOSED IN A DRY PLACE. Other Precautions: NONE SPECIFIED BY MANUFACTURER. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: WATER OR DRY CHEMICAL. Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: REACTS VIOLENTLY WITH CHLORINE, FUMING NITRIC ACID, MAY EMITE TOXIC FUMES IN FIRE. ======================================================= Control Measures ======================================================= Respiratory Protection: USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). Ventilation: ADEQUATE VENTILATION. Other Protective Equipment: EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA (FP N). LAB COAT. Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. LENGTH FACESHIELD (FP N). ======================================================= Physical/Chemical Properties ======================================================= M.P/F.P Text: 401F,205C Spec Gravity: 2.00 PH: SUPDAT Solubility in Water: SOLUBLE Appearance and Odor: WHITE CRYSTALLINE POWDER, WITH NO ODOR ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: HEAT, FLAME. Materials To Avoid: CONTACT WITH CHLORINE, FUMING NITRIC ACID, LITHIUM, BROMINE TRIFLUORIDE. Hazardous Decomposition Products: MAY EMIT TOXIC FUMES OF SULFUR OXIDES AND NITROGEN OXIDES IN FIRE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: ACID REAGENT (25 ML), 6392 Cage: 4T252 Company Name: HACH COMPANY Street: 100 DAYTON RD. PO Box: 907 Zipcode: 50010 Label Required IND: Y Date Of Label Review: 09/12/1996 Status Code: C Label Date: 09/12/1996 Origination Code: G Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Severe Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: AVOID EYE CONTACT. ACUTE: THIS PRODUCT MAY BE CORROSIVE TO EYES, IRRITATING TO RESPIRATORY TRACT. MODERATELY TOXIC. CHRONIC: NONE SPECIFIED BY MANUFACTURER. =======================================================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:FP-94 PENETRANT,FLUORESCENT CAGE:NO323 CAGE:98733 CAGE:NO323 ============= Composition/Information on Ingredients ============= Ingred Name:DISTILLATE (PETROLEUM),HYROTREATED MIDDLE; ON MSDS MFR SIMPLY NOTED AS "PETROLEUM HYDROCARBON" FOR ABOVE CAS NO. CAS:64742-46-7 RTECS #:JN9379645 OSHA PEL:5MG/CUM ACGIH TLV:5MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY CAUSE SLIGHT SKIN IRRITATION;VAPORS OR OIL MIST MAY CAUSE MILD IRRITATION OF UPPER RESPIRATORY. Effects of Overexposure:EYES:PRESUMED NON-IRRITATING;SKIN:SLIGHT IRRITATION ON LIQUID CONTACT;INHALATION:VAPORS OF OIL MIST MAY CAUSE MILD IRRITATION OF UPPER RESPIRATORY TRACT;INGESTION:MAY RESULT IN VOMITING. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRIDUCT, ======================= First Aid Measures ======================= First Aid:EYES:FLUSH WITH WATER.GET MEDICAL HELP IF IRRITATION OCCURS OR PERSISTS; SKIN:FLUSH WITH WATER.WASH WITH WATER & SOAP.GET MED ATTN FOR PERSISTING IRRITATION; INHALATION:REMOVE TO FRESH AIR.PROVIDE OXY GEN IF BREATHING IS DIFFICULT GET MED ATTN IF NEEDED; INGESTION:DO NOT INDUCE VOMITING.GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:210F(98.9C) Extinguishing Media:WATER FOG,DRY CHEMICAL,CARBON DIOXIDE OR FOAM; DO NOT USE DIRECT STREAM OF WATER. Fire Fighting Procedures:IN CONFINED AREA,DO NOT ENTER WITHOUT A FULL BUNKER GEAR INCLUDING A POSITIVE PRESSURE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:NOT KNOWN ================== Accidental Release Measures ================== Spill Release Procedures:ELIM IGNITION SOURCES.WEAR APPROPRIATE PROTECTIVE CLOTHING & RESPIRATOR.DIKE & TRANSFER LIQ TO A SAVAGE TANK.SOAK UP RESIDUE WITH ABSORBENT CLAY,SAND OR OTHR MATL.PLACE RAGS & ABSORBED WASTE MARERL IN COVERED NON-LEAKING CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT/IGNITION SOURCES. STORE IN DRY,COOL,& VENTILATED LOCATION.DO NOT STORE NEAR OXIDIZING MATERIAL. AVOID PHYSICAL DAMAGE TO CANS. Other Precautions:MINIMIZE SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURE EXCEEDS TLV,USE NIOSH APPRVD RESPIRATOR TO PREVENT OVEREXPOSURE. Ventilation:PER MANUFACTURER,PROVIDE LOCAL EXHAUST,OR MECHANICAL(GENERAL) VENTILATION TO MAINTAIN TLV. Other Protective Equipment:EYE WASH FOUNTAIN AND SAFETY SHOWERS. Work Hygienic Practices:WASH WITH SOAP AND WATER BEFORE EATING, DRINKING,SMOKING OR USING TOILET FACILITIES. Supplemental Safety and Health PER QPL-25135-15,THREE PENETRANTS,FP-91B FP-94 & FP-901 ARE QUALIFIED ITEMS FOR NSN OF TYPE I,METHOD C,LEVEL 1 UNDER THE MILI-25135,REV D;THE MFR MAY SHIP/SUPLY ONE OF THESE THREE PENETRANTS UNDER THI S NSN.THIS DATA ENTRY IS OF FP-94 ;OTHER TWO PENETRANTS ARE UNDER PNI A & C, THIS NSN. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>400F/>204C Spec Gravity:0.86 Solubility in Water:NEGLIGIBLE Appearance and Odor:YELLOW-GREEN LIQUID,SLIGHT HYDROCARBON ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:NO OXIDIZING MATERIAL Stability Condition to Avoid:HEAT & IGNITION SOURCES. Hazardous Decomposition Products:CARBON MONOXIDE & OTHER UNIDENTIFIED ORGANIC COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF AS EPA HAZARDOUS WASTE #D001,IGNITABLE WASTE.PLACE WASTE MATERIAL IN AN APPROPRIATE DISPOSAL FACILITY,OR DISPOSE OF IN COMPLIANCE WITH FEDERAL,STATE & LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:10 REINFORCED VINYL TILE ADHESIVE CAGE:12851 CAGE:12851 ============= Composition/Information on Ingredients ============= Ingred Name:SBR LATEX(STYRENE BUTADIENE RUBBER) Ingred Name:ASPHALT (PETROLEUM) CAS:8052-42-4 RTECS #:CI9900000 ACGIH TLV:5 MG/M3; (FUME);9192 Ingred Name:CLAY Ingred Name:ROSIN SOAP Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 40% ===================== Hazards Identification ===================== Effects of Overexposure:NONE (MFR STATES) ======================= First Aid Measures ======================= First Aid:IF EYE CONTACT, WASH W/CLEAR WATER FOR 15 MIN. IF IRRITATION PERSISTS, CONSULT A PHYSICIAN. IF IRRITATION PERSISTS, CONSULT A PHYSICIAN. IF INGESTED DO NOT INDUCE VOMITING. CALL A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER, CO*2, DRY CHEMICALS, FOAM Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY BURST IN FIRE AREA DUE TO STEAM FORMATION. ================== Accidental Release Measures ================== Spill Release Procedures:NORMAL CLEAN UP. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP FROM FREEZING. STORE AT TEMPERATURES NOT EXCEEDING 100F. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED Ventilation:NONE REQUIRED Supplemental Safety and Health DATE OF PREP: 6-11-79 ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:0.9856 Percent Volatiles by Volume:40 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IAW FEDERAL, STATE & LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:EUAC080A MIL-C-85285B TYPE I CLEAR Kit Part:Y Preparer's Name:JIM SCHMIDT CAGE:0ULT0 CAGE:0ULT0 ============= Composition/Information on Ingredients ============= Ingred Name:MODIFIED POLYOL Fraction by Wt: <10% Ingred Name:2,4-PENTANEDIONE, ACETYLACETONE CAS:123-54-6 RTECS #:SA1925000 Fraction by Wt: <10% Ingred Name:2-HEPTANONE, METHYL N-AMYL KETONE CAS:110-43-0 RTECS #:MJ5075000 Fraction by Wt: <25% Other REC Limits:50 PPM OSHA PEL:465 MG/CUM ACGIH TLV:233 MG/CUM Ingred Name:2-BUTANONE (METHYL ETHYL KETONE) (MEK) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: <10% Other REC Limits:590 MG/CUM OSHA PEL:200 PPM ACGIH TLV:590 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:HEXONE, METHYL ISOBUTYL KETONE (MIBK), 4-METHYL-2-PENTANONE CAS:108-10-1 RTECS #:SA9275000 Fraction by Wt: <25% Other REC Limits:50 PPM OSHA PEL:410 MG/CUM ACGIH TLV:205 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BUTYL ACETATE (N-BUTYL ACETATE) *96-1* CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: <10% Other REC Limits:150 PPM OSHA PEL:710 MG/CUM ACGIH TLV:713 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PROPYLENEGLYCOL MONOMETHYL ETHER ACETATE, 1-METHOXY-2-PROPANOL ACETATE CAS:108-65-6 RTECS #:AI8925000 Fraction by Wt: <10% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:MAY CAUSE NOSE, THROAT & RESPIRATORY TRACT IRRITATION. SPRAY MISTS/VAPORS MAY CAUSE IRRITATION TO EYES, MUCOUS MEMBRANE, NOSE, THROAT, RESPIRATORY TRACT & SKIN. CAN BE ABSORBED THROUGH SKIN CAUSING OR GAN DAMAGE. REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSE PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. Explanation of Carcinogenicity:SEE INGREDIENTS Effects of Overexposure:IRRITATION ======================= First Aid Measures ======================= First Aid:EYES/SKIN: FLUSH W/LUKE WARM WATER FOR 15 MINS. INHALATION: REMOVE TO FRESH AIR. RESTORE BREATHING IF REQUIRED. INGESTION: RINSE MOUTH IMMEDIATELY. GIVE 6-8OZ OF LIQUID. NEVER GIVE ANYTHING TO AN UNCO NCSIOUS PERSON. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:23F Lower Limits:1 Upper Limits:11.4 Extinguishing Media:CO2, DRY CHEMICALS/ALCOHOL FOAM Fire Fighting Procedures:EVACUATE AREA. DON'T ENTER CONFINED SPACE W/O PROTECTIVE EQUIPMENT & POSITIVE PRESSURE NIOSH-APPROVED SCBA. COOL CONTAINERS W/WATER.FIGHT FROM A PROTECTED AREA. Unusual Fire/Explosion Hazard:VAPORS MAY BE HEAVIER THAN AIR & TRAVEL ALONG THE GROUND TO DISTANT IGNITION SOURCE & FLASH BACK. LIQUID/VAPORS ARE DANGEROUS FIRE/EXPLOSION HAZARD WHEN HEATED. ================== Accidental Release Measures ================== Spill Release Procedures:STAY UPWIND & AWAY UNLESS WEARING APPROPRIATE PROTECTIVE EQUIPMENT. STOP &/CONTAIN SAFELY. KEEP ALL SOURCES OF IGNITION AWAY. VENTILATE AREA. USE NON-SPARKING TOOLS. COVER W/INERT MATERIAL TO REDUCE F UMES. (SEE SUPP) ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS COOL, DRY & AWAY FROM SOURCES OF IGNITION. USE & STORE W/ADEQUATE VENTILATION. DON'T SMOKE IN STORAGE AREAS. Other Precautions:KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS & OPEN FLAME. AVOID CONTACT/BREATHING VAPORS/MIST. DON'T FLAME CUT/WELD EMPTY DRUMS. KEEP WELDING/CUTTIN G EQUIPMENT AWAY FROM PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE HALF-MASK RESPIRATOR W/ORGANIC VAPOR CARTRIDGE APPROVED BY NIOSH/MSHA WHERE EXCESSIVE EXPOSURE TO VAPORS MAY OCCUR. USE AN APPROPRIATE, PROPERLY FITTED RESPIRATOR (NIOSH/MSHA APPROVED) DURING & AF TER APPLICATION. Ventilation:REQUIRED TO CONTROL VAPOR/DUST/MIST CONCENTRATION. Other Protective Equipment:EYEWASH STATIONS & SAFETY SHOWERS Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:175-469F Vapor Density:>1 VOC Grams/Liter:4.09 Evaporation Rate & Reference:(BU AC=1): >1 Solubility in Water:INSOLUBLE Appearance and Odor:CLEAR LIQUID W/MODERATE KETONE ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES N-BUTYL ACETATE: STRONG OXIDIZERS, ACIDS, BASES & ALKALIES. Stability Condition to Avoid:SPARKS, OPEN FLAME, HOT SURFACES & ALL OTHER SOURCES OF HEAT & IGNITION. Hazardous Decomposition Products:OXIDES OF CARBON & VARIOUS HYDROCARBONS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. ======================= Other Information =======================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:M-E PLASTIC CLEANER CAGE:97155 CAGE:97155 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM SALTS (A MIXTURE OF) ===================== Hazards Identification ===================== Effects of Overexposure:IRRITATING TO EYES. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER. SKIN: FLUSH W/WATER. INHALATION: REMOVE FROM EXPOSURE. ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL (WATER WILL LIBERATE OXYGEN) ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP MATERIAL & DISCARD IN APPROVED LANDFILL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN DRY AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED DUST MASK Ventilation:YES Other Protective Equipment:FULL COVER CLOTHING Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Solubility in Water:VERY SOLUBL Appearance and Odor:WHITE GRANULAR POWDER,ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:NO SPECIAL HANDLING. WASTE DISPOSAL MUST BE IAW FEDERAL,STATE & LOCAL REGULATIONS.
0
gloves_not_mandatory
===================== Product Identification ===================== Product ID:B1027 BORAX CAGE:60928 CAGE:60928 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM TETRABORATE, DECAHYDRATE CAS:1303-96-4 RTECS #:VZ2275000 OSHA PEL:10 MG/M3 ACGIH TLV:5 MG/M3; 9192 ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LDLO (MAN): 709 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:HARMFUL IF SWALLOWED, INHALED OR ABSORBED THROUGH THE SKIN. IRRITATING TO SKIN, EYES, MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT. Explanation of Carcinogenicity:NONE Effects of Overexposure:INGESTION: 5-10 GRAMS HAS PRODUCED SEVERE VOMITING, DIARRHEA, SHOCK & DEATH. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. SKIN: WASH W/SOAP & PLENTY OF WATER. INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. INGESTION: WASH OUT MOUTH W/WATER PROVIDED PERSON IS CONSCIOUS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:CO2, DRY CHEMICAL POWDER OR APPROPRIATE FOAM. NS Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. WEAR PROTECTIVE EQUIPMENT. SWEEP UP, PLACE IN A BAG & HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA & WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP TIGHTLY CLOSED. STORE IN A COOL DRY PLACE. PRODUCT IS HYGROSCOPIC. Other Precautions:AVOID CONTACT W/EYES, SKIN, CLOTHING & BREATHING OF DUST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:MECHANICAL EXHAUST REQUIRED Other Protective Equipment:SUITABLE PROTECTIVE CLOTHING, SAFETY SHOWER, EYE BATH Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING/SHOES BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health THE HYDROLYSIS & NEUTRALIZATION REACTIONS MAY GENERATE HEAT & FUMES WHICH CAN BE CONTROLLED BY THE RATE OF ADDITION. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:741C Spec Gravity:2.367 Appearance and Odor:WHITE CRYSTALLINE POWDER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Hazardous Decomposition Products:BORON OXIDES ==================== Disposal Considerations ==================== Waste Disposal Methods:SMALL: CAUTIOUSLY ADD TO A LARGE STIRRED EXCESS OF WATER. ADJUST PH TO 7, SEPARATE ANY INSOLUBLE SOLIDS OR LIQUIDS & PACKAGE THEM FOR HAZARDOUS WASTE DISPOSAL. FLUSH SOLUTION DOWN DRAIN W/PLENTY OF WA TER. OBSERVE ALL FEDERAL, STATE & LOCALLAWS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:A0119C000S CLEAN & ETCH Preparer's Name:BARBARA STELLER CAGE:DO668 CAGE:93981 CAGE:DO668 ============= Composition/Information on Ingredients ============= Ingred Name:METHANOL (METHYL ALCOHOL), COLUMBIAN SPIRITS CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 10% Other REC Limits:200 PPM OSHA PEL:S,200PPM/250STEL ACGIH TLV:S,200PPM/250STEL; 93 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PHOSPHORIC ACID CAS:7664-38-2 RTECS #:TB6300000 Fraction by Wt: 44% Other REC Limits:1 MG/CUM OSHA PEL:1 MG/CUM ACGIH TLV:1 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:HYDROCHLORIC ACID, HYDROGEN CHLORIDE, MURIATIC ACID HYDROCHLORIDE CAS:7647-01-0 RTECS #:MW4025000 Fraction by Wt: 10% Other REC Limits:7 PPM OSHA PEL:5 PPM ACGIH TLV:C 11 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: NASAL & RESPIRATORY IRRITATION, FATAL. SKIN: ABSORPTION, SEVERE IRRITATION. EYES: MAY CAUSE PERMANENT DAMAGE, CHEMICAL BURNS. INGESTION: GASTRINTESTINAL IRRITATION, FATAL. OVEREXPOSURE TOMETHANOL CAUSES EYE DAMAGE; MUTAGENIC. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE, UNCONSCIOUSNESS, DEATH. SKIN/EYE: IRRITATION, BURNS. INHALATION: NAUSEA, VOMITING, DIARRHEA, BLINDNESS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF BREATHING STOPS, APPLY ARTIFICIAL RESPIRATION. INGESTION: DON'T INDUCE VOMITING. SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/PLENTY OF WATER FOR 15 MIN. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:52F Lower Limits:5.5% Extinguishing Media:ALCOHOL FOAM, CO2, & DRY CHEMICAL Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & FULL TURN OUT GEAR. SURROUNDING FIRE, COOL CONTAINERS W/WATER. Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR & MAY TRAVEL ALONG GROUND/MOVED BY VENTILATION TO IGNITION SOURCES. REACTS W/METALS TO FORM HYDROGEN GAS, CAUSING FIRE/EXPLOSIONS. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE IGNITION SOURCES & PROVIDE GOOD VENTILATION. LARGE SPILL: WEAR APPROPRIATE RESPIRATORY PROTECTION. DIKE SPILL AREA, SOAK UP W/INERT ABSORBENT MATERIAL & PLACE IN CLOSED CONTAINERS FOR PROPER DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:ALL FIVE GALLON PAILS & LARGER METAL CONTAINERS SHOULD BE GROUNDED &/OR BONDED WHEN MATERIAL IS TRANSFERRED. Other Precautions:PRODUCT IS CORROSIVE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURE EXCEEDS TLV USE APPROPRIATE NIOSH-APPROVED RESPIRATORY PROTECTIVE EQUIPMENT WITHIN USE LIMITAITONS OF THESE DEVICES. IN ALL OTHER SITUATIONS USE SELF-CONTAINED BREATHING APPARATUS (SCUBA). Ventilation:EXPLOSION PROOF LOCAL & MECHANICAL (GENERAL) EXHAUST AT POINT OF CONTAMINANT RELEASE. Other Protective Equipment:EYE BATH, SAFETY SHOWER, BARRIER CREAM & PROTECTIVE CLOTHING. Work Hygienic Practices:REMOVE/LAUNDER CLOTHING BEFORE REUSE. MAINTAIN GOOD HOUSEKEEPING. AFTER USAGE, WASH HANDS THOROUGHLY. Supplemental Safety and Health DISCARD CONTAMINATED LEATHER PRODUCTS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:147F Vapor Density:>1 Spec Gravity:1.3 Evaporation Rate & Reference:SLOWER THAN ETHER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, ALKALIS, CYANIDES, METAL COMPOUNDS & REACTIVE METALS. Stability Condition to Avoid:EXCESSIVE HEAT, IGNITION SOURCES. Hazardous Decomposition Products:TOXIC FUMES, CO, CO2, VARIOUS HYDROCARBONS, HYDROGEN GAS & OXIDES OF PHOSPHORUS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:PHENOLINE, 302 Preparer's Name:JKM CAGE:06634 CAGE:06634 ============= Composition/Information on Ingredients ============= Ingred Name:DIETHYLENE TRIAMINE CAS:111-40-0 RTECS #:IE1225000 Fraction by Wt: < 20% OSHA PEL:1 PPM ACGIH TLV:S, 1 PPM; 9192 Ingred Name:EPOXY RESIN CAS:25068-38-6 RTECS #:KD4380000 Fraction by Wt: < 30% Ingred Name:PETROLEUM HYDROCARBON FRACTION. VP=2. Fraction by Wt: < 15% Ingred Name:ISOPROPYL ALCOHOL (SARA III) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: < 15% OSHA PEL:400 PPM/500 STEL ACGIH TLV:400 PPM/500STEL;9192 Ingred Name:METHYL ISOBUTYL KETONE (SARA III) CAS:108-10-1 RTECS #:SA9275000 Fraction by Wt: < 35% OSHA PEL:100 PPM/75 STEL ACGIH TLV:50 PPM/75 STEL; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE TOXICITY: OVEREXP CAN LEAD TO CNS DEPRESS PRDC HEADACHE, DIZZINESS, NAUSEA, & LOSS OF CONSCIOUSNESS. EYE: SHORT-TERM CONTACT MAY RESULT IN SLIGHT EYE IRRIT. PRLNG & RPTD CONTACT MAY IRRIT MORE. SKIN: PRLNG/RPTD LIQ CONTACT CAN CAUSE DEFATTING DRYING OF THE SKIN WHICH MAY RESULT IN SKIN IRRIT/(SEE EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:DERMATITIS. INHAL:HIGH CONC/PRLNG EXP TO LOWER CONC MAY BE SLIGHTLY IRRIT TO MUC MEMB. CAUSES EYE IRRIT/BURNS. MAY CAUSE ALLERGIC SKIN RXN. HARMFUL IF SWALLOWED. MAY BE FATAL IF ABSORBED THRU SKIN. MAY CAUSE LUNG IRRIT & ALLERGIC RESP RXN. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH WITH WATER FOR AT LEAST 15 MIN WHILE HOLDING EYE OPEN. GET MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES. CLEAN BEFORE REUSING. IF PERSISTENT IRR ITATION OCCURS, GET MEDICAL ATTENTION. INHAL: REMOVE TO FRESH AIR. PROVIDE OXYGEN IF BREATHING IS DIFFICULT. GIVE ARTF RESP IF NOT BREATHING. GET MD. SWALLOWED: DO NOT INDUCE VOMITING! ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:53.0F,11.7C Lower Limits:1.0 % Upper Limits:12.7 % Extinguishing Media:DRY CHEMICAL, FOAM, WATER FOG. Fire Fighting Procedures:EVAC HAZARD AREA, WEAR PROT CLOTHING USE A NIOSH/MSHA SCBA. COOL FIRE-EXPOS CONTRS W/H*2O. IN CASE OF LARGE FIRES, COOL SURROUND EQUIP W/H*2O. Unusual Fire/Explosion Hazard:VAPS ARE HEAVIER THAN AIR & MAY ACCUM. VAPS MAY BE IGNITED AT LOCATIONS DISTANT FROM THE HANDLING SITE. FLASHBACK OF FLAME TO THE HANDLING SIGHT MAY OCCUR. ================== Accidental Release Measures ================== Spill Release Procedures:WARNING! FLAMM. ELIM ALL IGNITION SOURCES. HANDLING EQUIP MUST BE GROUNDED TO PREVENT SPARKING. LARGE SPILL: EVACUATE THE HAZ AREA OF UNPROTECTED PERSONNEL. WEAR APPROPRIATE RESPIRATOR AND PROT CLOTHI NG. DIKE AND CONTAIN. TRANSFER (SEE SUPP DATA) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT/SPARKS/OPEN FLAME/STRONG OXIDN AGENTS. KEEP CNTNRS CLSD. STORE IN COOL, DRY PLACE W/ADEQ VENT. GROUND EQUIP TO PVNT ACCUM (SUPDAT) Other Precautions:DO NOT WELD, HEAT OR DRILL ON OR NEAR CONTAINER; EVEN EMPTIED CONTAINERS CAN CONTAIN EXPLOSIVE VAPORS. PROVIDE RESPIRATORY PROTECTION AGAINST SMOKE AND FUMES GENERATED DURING BURNING OR DUSTS GENERATE D DURING REMOVAL OF DRY COATINGS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL EXPOSURE LIMITS USE A NIOSH/MSHA APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. IN ACCORD W/29 CFR 1910.134 USE EITHER AN ATMOSPHERE-SUPPLYING RESPIRATOR OR A N AIR-PURIFYING RESP FOR ORGANIC VAPORS. Ventilation:USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL VAPOR CONCENTRATIONS. Other Protective Equipment:PROTECTIVE CLOTHING AS REQUIRED TO PREVENT SKIN CONTACT. Work Hygienic Practices:WASH W/SOAP & WATER BEFORE EATING/DRINKING/SMOKING/USING TOILET FACILITIES. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health SPILL PROC: TO STORAGE/SALVAGE VESSELS. SOAK UP RESIDUAL W/ABSORB SUCH AS CLAY/SAND. FLUSH AREA W/H*2O/DISPOSE FLUSH SOLUTION AS INDICATED. SML: TAKE UP W/ABSORB MATERIAL/SEAL TIGHTLY/DISPOSE PROPERLY . HNDLG/STOR PREC: OF STATIC CHARGE. IFPOURING/TRANSFERRING MATERIALS, CONTAINERS MUST BE BONDED AND GROUNDED. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:180F,82C Vapor Pres:SEE INGRED Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:62.4 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HEAT, SPARKS, AND OPEN FLAME. Hazardous Decomposition Products:CARBON MONOXIDE AND UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED DURING COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:PLACE CONTAMINATED MATERIAL IN SUITABLE CONTAINERS FOR DISPOSAL. PLACE IN A DISPOSAL FACILITY APPROVED UNDER RCRA REGULATIONS FOR HAZARDOUS WASTE. USE NON-LEAKING CONTAINERS, SEAL TIGHTLY AND LABEL PR OPERLY.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:RUST PEL #42 Preparer's Name:ROBERT W. FARRELL CAGE:FO026 CAGE:03275 CAGE:FO026 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL OIL (EXPOSURE REGULATED AS 'OIL MIST') CAS:8012-95-1 RTECS #:PY8030000 Other REC Limits:10 MG/CUM STEL OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3/10 STEL;9192 Ingred Name:STODDARD SOLVENT CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 65-84% Other REC Limits:350 MG/CUM OSHA PEL:500 PPM ACGIH TLV:100 PPM; 9293 Ingred Name:PETROLEUM SULFONATE Fraction by Wt: 8-12% OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3/10 STEL;8990 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: DIZZINESS, HEADACHE, & UNCONSCIOUSNESS. SKIN: DRYNESS, DEFATTING, IRRITATION, & DERMATITIS. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: DIZZINESS, HEADACHE, UNCONSCIOUSNESS, & RESPIRATORY INFLAMMATION. SKIN: DRYNESS, DEFATTING, IRRITATION, & DERMATITIS. Medical Cond Aggravated by Exposure:DERMATITIS ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. CALL PHYSICIAN. IF BREATHING IS IRREGULAR OR STOPPED, START RESUSCITATION. ADMINISTER OXYGEN. INGESTION: DON'T INDUCE VOMITING. CALL PHYSICIAN. SKIN/EYES: FLUSH W/WATE R FOR 15 MINUTES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:108F Extinguishing Media:FOAM, DRY CHEMICAL, CO2 Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & FULL PROTECTIVE CLOTHING WHEN FIGHTING FIRES. ================== Accidental Release Measures ================== Spill Release Procedures:ADD ABSORBENT TO SPILL AREA. AVOID BREATHING VAPORS, VENTILATE AREA. PREVENT SPILL FORM ENTERING SEWERS OR WATER COURSES. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. USE WITH ADEQUATE VENTILATION. AVOID PROLONGED OR PEATED CONTACT WITH SKIN. Other Precautions:AVOID BREATHING VAPORS. ============= Exposure Controls/Personal Protection ============= Ventilation:LOCAL EXHAUST: SUFFICIENT VENTILATION TO KEEP <TLV. Other Protective Equipment:NONE Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:302F Vapor Pres:<10 Vapor Density:4.8 Spec Gravity:0.789-0.816 Evaporation Rate & Reference:(BU AC = 1): 0.1 Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR, AMBER COLOR, MINERAL SPIRITS ODOR. Percent Volatiles by Volume:65-84% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDANTS LIKE LIQUID CHLORINE & CONCENTRATED OXYGEN. Stability Condition to Avoid:HEAT, OPEN FLAMES, SPARKS Hazardous Decomposition Products:CO, SMOKE ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT W/FEDERAL, STATE, & LOCAL ENVIRONMENTAL AUTHORITIES OR PROPER METHODS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:CAT,MIL-C-85285B,24052,TYPE II;04GN003CAT Kit Part:Y Preparer's Name:NORM GAUL CAGE:33461 CAGE:33461 ============= Composition/Information on Ingredients ============= Ingred Name:HOMOPOLYMER OF HEXAMETHYLENE DIISOCYANATE (HDI) CAS:28182-81-2 RTECS #:NQ9170000 Fraction by Wt: 90% Other REC Limits:NONE RECOMMENDED Ingred Name:1,6-DIISOCYANATOHEXANE (HEXAMETHYLENE DIISOCYANATE) CAS:822-06-0 RTECS #:MO1740000 Fraction by Wt: 0.5-1.6% Other REC Limits:NONE RECOMMENDED ACGIH TLV:0.005 PPM; 9394 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:NAPHTHA, LIGHT AROMATIC (SOLVENT NAPHTHA) CAS:64742-95-6 RTECS #:WF3400000 Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED Ingred Name:N-BUTYL ACETATE (SARA III) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:150 PPM ACGIH TLV:150 PPM/200STEL;9394 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 738MG/KG FOR HDI Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES/SKIN:ISOCYANATES REACT WITH SKIN PROTEINS AND MOISTURE TO CAUSE IRRITATION.SKIN ABSORPTION MAY CAUSE DEFATTING.INHAL:MAY CAUSE RESPIRATORY IRRITATION AND NERVIOUS SYSTEM DEPRESSION.INGEST:CORROSI VE TO MUCOSAL TISSUE.MAY CAUSE LUNG DAMAGE IF VOMITED AFTER INGESTING.CHRONIC:ISOCYANATE SENSITIZATION. Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1% WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA. Effects of Overexposure:INHAL:DIFFICULT BREATHING,HEADACHE,DIZZINESS,STAGGERING GAIT,CONFUSION,LEADING TO UNCONSCIOUSNESS OR COMA.SKIN/EYES:SWEELING REDNESS,RASH,DRYNESS,CRACKING.CHRONIC OVEREXPOSURE WILL RESULT IN REACTION TO PROGRESSIVELY SMALLER DOSES OF ISOCYANTES. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING RESPIRATORY,SKIN AILMENTS OR ISOCYANATE SENSITIZATION MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH SOAP AND WATER.EYES:FLUSH WITH LUKEWARM WATER FOR 15 MINUTES.INHAL:NOTE-ASTHMATIC RESPONSE MAY BE DELAYED.REMOVE TO FRESH AIR.GIVE OXYGEN OR ARTIFICIAL RESP IRATION IF NEEDED.INGEST:DO NOT INDUCE VOMITING.GET PROMPT QUALIFIED MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:76.0F,24.4C Lower Limits:1.00 Upper Limits:7.6 Extinguishing Media:WATER FOG,DRY CHEMICAL,CARBON DIOXIDE,FOAM,ALCOHOL FOAM. Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT.COOL FIRE EXPOSED CONTAINERS WITH WATER FOG. Unusual Fire/Explosion Hazard:FIRE CONDITIONS MAY EVOLVE TOXIC FUMES.CONTAINERS MAY BURST FROM HEAT OF FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE SOURCES OF IGNITION.USE PROPER RESPIRATORY AND PROTECTIVE EQUIPMENT.SHUT OFF LEAK IF SAFE.DIKE.SOAK UP WITH A NON-COMBUSTIBLE INERT ABSORBANT(CLAY,SAND);PLACE IN PROPER CONTAINER FOR DISPOSA L.USE NON-SPARKING TOOLS. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,WELL-VENTILATED PLACE.KEEP CONTAINER CLOSED WHEN NOT IN USE.AVOID HEAT,SOURCES OF IGNITION,MOISTURE AND INCOMPATIBLE MATERIALS. Other Precautions:EMPTY CONTAINERS MAY CONTAIN HAZARDOUS RESIDUE;DISPOSE OF PROPERLY.AVOID SKIN AND EYE CONTACT.DO NOT BREATHE VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN ENCLOSED SPACES USE EITHER A SELF-CONTAINED BREATHING APPARATUS OR A NOISH/MSHA APPROVED RESPIRATOR FOR ORGANIC VAPOR PARTICULATES(TC23C),DEPENDING ON TH E AIRBORN CONCENTRATION. Ventilation:LOCAL VENTILATION AT THE WORKSITE;MECHANICAL(GENERAL) VENTILATION TO MAINTAIN TLV/PEL.USE NON-SPARKING EQUIPMENT. Other Protective Equipment:PROTECTIVE CLOTHING,AS NEEDED.PROVIDE A LOCAL EYE WASH STATION AND SAFETY SHOWER. Work Hygienic Practices:WASH HANDS.SEPERATE WORK CLOTHES FROM STREET CLOTHES.LAUNDER WORK CLOTHES BEFORE REUSE.KEEP FOOD OUT OF THE WORK AREA. Supplemental Safety and Health KEY1;F4.CONCENTRATION OF FREE HDI MONOMER INCREASES AFTER 3-6 MONTHS OF STORAGE-USE CAUTION FOR PRESSURE BUILDUP IN CONTAINERS REMOVED FROM STORAGE. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:260F-335F Vapor Density:>1 Spec Gravity:1.128 Evaporation Rate & Reference:0.44 (N-BUTYL ACETATE=1) Appearance and Odor:LIQUID;AMBER;SOLVENT ODOR Percent Volatiles by Volume:12.9 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER,AMINES,STRONG BASES,ALCOHOLS,METAL COMPOUNDS,SURFACE ACTIVE MATERIALS. Stability Condition to Avoid:MOISTURE,HIGH HEAT. Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE,OXIDES OF NITROGEN,TRACES OF HCN AND HEXAMETHYLENEDIISOCYANATE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS.EPA CODES:D001,F003,F005;WASTE CHARACTERISTICS:IGNITABILITY,REACTIVITY.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:CIMCLEAN 30 PINK, 605 CAGE:86167 CAGE:86167 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOL, 2-AMINO-; (ETHANOLAMINE) CAS:141-43-5 RTECS #:KJ5775000 Fraction by Wt: 15% OSHA PEL:3 PPM ACGIH TLV:3 PPM/6 STEL Ingred Name:NONANOIC ACID; (PELARGONIC ACID) CAS:112-05-0 RTECS #:RA6650000 Fraction by Wt: 5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:GLYCOLS, POLYETHYLENE, MONO(NONYLPHENYL)ETHER; (NONYLPHENOL POLYETHOXATE) CAS:9016-45-9 RTECS #:MD0900000 Fraction by Wt: 5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUP DAT: INHALATION: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE OXYGEN OR ARTIFICIAL RESPIRATION) . RTECS #:9999999ZZ Ingred Name:WASTE DISP METH: FOR UNUSED CONCENTRATE: CONCENTRATE IS NOT A HAZ WASTE, AS DEFINED UNDER 40 CFR 261. CIMCOOL (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: TECHNICAL SERVICES (513-841-8133) CAN PROVIDE A LIST OF WASTE HAULERS FOR YOUR AREA. "EMPTY" CONTRS WILL (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: CONTAIN RESIDUE WHICH IS NOT CONSIDERED HAZ WASTE UNDER RCRA REGS. DRUMS CAN BE DRAINED TO A "DRIP DRY" (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: CONDITION BY INVERSION AND CAN BE OFFERED FOR RECYCLING OR SCRAP. RTECS #:9999999ZZ Ingred Name:VENT: CLOSE TOGETHER/VENT IS INADEQ, OPERATORS MAY EXPERIENCE RESP IRRIT. FOR SUCH APPLICATIONS, USE OF SPLASH (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: GUARDS OR MIST COLLECTORS IS RECOMMENDED. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: PROD CONCENTRATE: EYE/SKIN: PRIMARY IRRIT. INGEST: NOT TOX. PROD AS USE DILUTION: INHAL: EXTENDED EXPOS TO MISTS MAY CAUSE UPPER RESP IRRIT. EYE: WILL CAUSE STINGING SENSATION. SKIN: NOT IRRIT TO SKIN WHEN USED AS DIRECTED & GOOD PERS HYGIENE IS PRACTICED. INGEST: SWALLOWING SML QTYS MAY CAUSE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: NAUS/DIARR. MILD SKIN IRRIT (REDNESS & DRYNESS OF HANDS) MAY BE EXPERIENCED WHEN DILUTED PROD HAS BEEN CONTAM BY CERTAIN OILS, BY DISSOLVED METALS/WHEN MIX RATIO IS TOO STRONG. WHEN PROBLEMS OCCURS, USE OF WATER-RESIST BARRIER CREAMS MAY BE A TEMPORARY CTL MEASURE. SIGNS & SYMPS OF EXPOS: EYE INJURY (SUP DAT) Medical Cond Aggravated by Exposure:MAY AGGRAVATE EXISTING SKIN IRRITATION WHERE FURTHER DEFATTING OR SKIN PENETRATION COULD OCCUR. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH IMMED W/RUNNING WATER FOR AT LEAST 15 MIN, THEN IMMED GET MED ATTN TO CHECK FOR POSS IRRIT. SKIN: WASH W/WATER AS SOON AS POSS. REMOVE SEV CONTAM CLTHG, INCL SHOES. LAUNDER BEFORE REUSE. I F IRRIT PERSISTS, GET MED ATTN. INGEST:DO NOT INDUCE VOMIT. DILUTE BY DRINKING WATER/MILK. IMMED CONT MD & OBTAIN TREATMENT. SWALLOWING SML QTYS OF DILUTED PROD IS NOT EXPECTED TO CAUSE (SUP DAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN THE SPILL, COLLECT ON ABSORBENT MATERIAL AND DISCARD AS DICTATED BY FEDERAL, STATE AND LOCAL REGULATIONS THAT MAY APPLY. FLUSH AREA THOROUGHLY WITH WATER. REPORTABLE QUANTITY: NONE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE ONLY AS RECOMMENDED BY MANUFACTURER. AVOID ALL CONTACT WITH EYES OR SKIN. DO NOT SWALLOW. IF FROZEN, THAW COMPLETELY AT ROOM TEMPERATURE. Other Precautions:CONTAINS AMINES. DO NOT ADD SODIUM NITRITE OR OTHER NITROSATING AGENTS TO THIS PRODUCT. SUSPECTED CANCER-CAUSING NITROSAMINES COULD BE FORMED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:PRODUCT IS NOT VOLATILE. USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:FOR MOST APPLICATIONS, NORM SHOP VENT IS ADEQ. HOWEVER, WHEN HIGH MIST LEVELS ARE GENERATED/WHERE MACHINES ARE (ING 9) Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH & DELUGE SHOWER . EFFECTIVE METALWORKING PLANT PROTECTIVE CLOTHING AS APPROPRIATE. Work Hygienic Practices:GOOD PERSONAL HYGIENE SHOULD ALWAYS BE FOLLOWED. Supplemental Safety and Health PH: 11.5-12.1 (CONCENTRATE); 8.8-9.2 (1% MIX). EFTS OF OVEREXP: MAY RSLT FROM CONT W/CONCENTRATED PROD. SKIN IRRIT CAN RSLT FROM IMPROPER USE & HNDLG OF CONCENTRATE/MIX. FIRST AID PROC: INJURY/ILLNESS ; BUT, AS SHOULD BE EXPECTED WHEN DRINKING OILY, SOAPY WATER, NAUS, DIARR/ABDOM DISTRESS MAY BE EXPERIENCED. (ING 4) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Vapor Pres:LIKE WATER Spec Gravity:1.084-1.094 pH:SUPDAT Evaporation Rate & Reference:LIKE WATER Solubility in Water:COMPLETE Appearance and Odor:CLEAR/CHEMICAL ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID ADDITION OF STRONG ACIDS TO PRODUCT CONCENTRATE. Stability Condition to Avoid:NOT APPLICABLE. Hazardous Decomposition Products:SMOKE, FUMES AND OXIDES OF CARBON. ==================== Disposal Considerations ==================== Waste Disposal Methods:FOR USED MIX: DISP PROC MUST COMPLY W/LOC, COUNTY, STATE & FED REGS. IF PRE-TREATMENT IS NEEDED, CHEM EMULSION BREAKING/ULTRAFILTRATION MAY BE USED. CONT CIMCOOL TECHNICAL SERVICES (513-841-8133) FOR ASSIST. (ING 5)
1
gloves_mandatory
===================== Product Identification ===================== Product ID:HYDROBROMIC ACID POTASSIUM SALT, PX1378 CAGE:DO242 CAGE:63612 CAGE:DO242 ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM BROMIDE CAS:7758-02-3 RTECS #:TS7650000 Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY CAUSE IRRITATION ON CONTACT WITH SKIN, EYES OR MUCOUS MEMBRANES. DUST INHALATION MAY BE IRRITATING TO RESPIRATORY SYSTEM. PROLONGED INHALATION CAN CAUSE BRONCHITIS. INGESTION CAN CAUSE NAUSEA, VOM ITING AND DEPRESSION. RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO DUST. TESTS ON LABORATORY (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZS:ANIMALS INDICATE MATERIAL MAY PRODUCE ADVERSE MUTAGENIC EFFECTS. Medical Cond Aggravated by Exposure:RESPIRATORY CONDITIONS. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE. EYES:IMMEDIATELY FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. SKIN:WASH THOROUGHLY WITH SOAP AND WATER. INHALATION:REMOVE TO FRESH AIR; GI VE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. INGESTION:IF CONSCIOUS, DRINK WATER AND INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL PERS. NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERSON. ===================== Fire Fighting Measures ===================== Flash Point:NONCOMBUSTIBLE Extinguishing Media:USE ANY SUITABLE FOR ADJACENT MATERIALS. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA OF ALL UNNEC PERS. WEAR SUITABLE PROT EQUIP LISTED UNDER CTL MEASURES. ELIM ANY IGNIT SOURCES UNTIL AREA IS DETERM TO BE FREE FROM EXPLO/FIRE HAZS. CNTN RELS & ELIM ITS SOURCE, IF THIS C AN BE DONE W/OUT RISK. TAKE UP & (SUPP DATA) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. STORE AT CONTROLLED ROOM TEMPERATURE. DO NOT BREATHE DUST. DO NOT GET IN EYES. AVOID PROLONGED OR REPEATED SKIN CONTACT. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:MATERIAL SHOULD BE HANDLED OR TRANSFERRED IN AN APPROVED FUME HOOD OR WITH ADEQUATE VENTILATION. Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE SHOWER . Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT TAKE INTERNALLY. Supplemental Safety and Health SPILL PROC:CONTAINERIZE FOR PROPER DISPOSAL AS DESCRIBED UNDER DISPOSAL. COMPLY WITH FEDERAL, STATE AND LOCAL REGULATIONS ON PREVENT SKIN CONTACT. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:2516F,1380C Melt/Freeze Pt:M.P/F.P Text:1346F,730C Spec Gravity:2.75 (H*2O=1) Solubility in Water:53% Appearance and Odor:WHITE CRYSTALS OR GRANULES, ODORLESS. Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, OXIDIZERS. Stability Condition to Avoid:DUSTING. Hazardous Decomposition Products:BROMINE. ==================== Disposal Considerations ==================== Waste Disposal Methods:MATERIAL DOES NOT HAVE AN EPA WASTE NUMBER AND IS NOT LISTED WASTE. HOWEVER CONSULTATION W/PERMITTED WASTE DISP SITE (TSD) SHOULD BE ACCOMPLISHED. ALWAYS CONT PERMITTED TSD TO ASSURE COMPLIANCE W/ALL CURRENT LOC, STATE & FED REGS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:517-, ACUFLEX Preparer's Name:ROBERT J. HARRIS CAGE:70103 CAGE:70103 ============= Composition/Information on Ingredients ============= Ingred Name:EPOXY RESIN Ingred Name:POLYURETHANE RESIN Ingred Name:SILICONE RESIN Ingred Name:OIL-MODIFIED ALKYD RESIN Ingred Name:BACKING (CLOTH, FIBER, PAPER); (SUBSTRATE (CLOTH, MAT, FILM, PAPER)) Ingred Name:COATING CONTAINING INGREDIENT 9 OR 10 RTECS #:9999999ZZ Ingred Name:ACRYLIC ADHESIVE;(PRESSURE-SENSITIVE ACRYLIC ADHESIVE) Ingred Name:MICA;(MICA DUST) CAS:12001-26-2 RTECS #:VV8760000 OSHA PEL:20 MPPCF ACGIH TLV:3 MG/M3 RDUST; 9293 Ingred Name:FULLY CURED RESINS (CONSISTING OF INGREDIENTS 2-6). IMPREGNATED OR COATED ON INGREDIENT 7. RTECS #:9999999ZZ Ingred Name:POLYESTER RESIN ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NO ADVERSE ACUTE OR CHRONIC HEALTH EFFECTS ARE EXPECTED FROM HANDLING THESE MATERIALS. SOME INDIVIDUALS MAY EXPERIENCE MILD TRANSIENT SKIN IRRITATION FROM REPEATED HANDLING, AND EXPOSED FIBERGLASS ALO NG SLIT EDGES OF MATERIAL MAY ALSO CAUSE MINOR SKIN IRRITATION. IF MATERIAL IS SUPPLIED WITH MICA (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:DUST, INHALATION OF THIS DUST MAY PRODUCE MECHANICAL IRRITATION OF NOSE, THROAT AND UPPER RESPIRATORY TRACT. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH WITH POTABLE WATER FOR A MINIMUM OF 15 MINUTES. GET MD . INHAL:MOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O2/ARTF RESP) . SKIN:FLUSH WITH COPIOUS AMOUNTS OF WATER. CALL MD . INGEST:CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NONE Upper Limits:NONE Extinguishing Media:WATER, DRY CHEMICAL, CO2 OR FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . USE STANDARD METHODS. Unusual Fire/Explosion Hazard:DECOMPOSITION AND COMBUSTION PRODUCTS MAY BE TOXIC. ================== Accidental Release Measures ================== Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH/MSHA APPROVED DUST MASK SHOULD BE WORN IF NECESSARY FOR WORKER COMFORT OR IN THE UNLIKELY EVENT THAT AIRBORNE DUST CONCENTRATIONS GENERATED DURING HANDLING EXCEED THE OSHA PEL. Ventilation:THOROUGH GENERAL VENTILATION. Other Protective Equipment:NO SPECIFIC PROTECTIVE EQUIPMENT IS REQUIRED. Work Hygienic Practices:PROPER INDUSTRIAL HYGIENE RECOMMENDED. Supplemental Safety and Health APPEAR/ODOR:IN COLOR. BLACK OLEORESINOUS- VARNISHED MATERIAL MAY HAVE CHARACTERISTIC GREASY FINISH. ================== Physical/Chemical Properties ================== HCC:N1 Appearance and Odor:FLEXIBLE SHEETS OR TAPES; YELLOW TAN, WHITE, GRAY, BLACK, BROWN OR BLUE (SUPDAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:FULLY CURED INSULATION IS NOT A HAZARDOUS WASTE UNDER CURRENT RCRA AND CERCLA DEFINITIONS. DISPOSAL MUST BE IN ACCORDANCE WITH ALL LOCAL, STATE, AND FEDERAL REGULATIONS .
1
gloves_mandatory
===================== Product Identification ===================== Product ID:NITROGEN, 4594755 CAGE:53811 CAGE:0Z5B2 CAGE:53811 ============= Composition/Information on Ingredients ============= Ingred Name:NITROGEN CAS:7727-37-9 RTECS #:QW9700000 Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:ASPHYXIANT ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:MIXTURE ACTS AS A SIMPLE ASPHYXIANT BY DISPLACING AIR NECESSARY FOR LIFE. SYMPTOMS INCLUDE RAPID RESPIRATION, MUSCULAR INCOORDINATION, FATIGUE, NAUSEA, VOMITING AND UNCONSCIOUSNESS. CHRONIC:NONE . Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:RESPIRATORY PROBLEMS. ======================= First Aid Measures ======================= First Aid:INGESTION:CALL MD IMMEDIATELY . EYES:IMMEDIATELY FLUSH W/POTABLE WATER FOR A MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM MD . SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . INHALAT ION:IMMEDIATELY REMOVE TO FRESH AIR. IFBREATHING HAS STOPPED, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:USE WHAT IS APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . USE WATER SPRAY TO KEEP FIRE EXPOSED CYLINDERS COOL. Unusual Fire/Explosion Hazard:DO NOT EXPOSE TO HEAT OR FLAMES, CONTAINER MAY RUPTURE UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AND VENTILATE AREA. REMOVE LEAKING CYLINDER TO EXHAUST HOOD OR SAFE OUTDOORS AREA. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN WELL VENTILATED AREAS ONLY. KEEP VAVLE PROTECTION CAP ON CYLINDERS WHEN NOT IN USE AND SECURE CYLINDER WHEN USING TO PROTECT FROM FALLING. Other Precautions:NO PART OF THE CYLINDER SHOULD BE EXPOSED TO TEMPERATURES ABOVE 125F. PROTECT CNTNRS FROM PHYSICAL DMG. DO NOT DEFACE CYLS/LBLS. CYLS MAY NOT BE REFILLED. RE-FILLING OF CYLS IS IN VIOLATION OF FEDERAL LAW (49 CFR). ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE A NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING APPARATUS IN CASE OF EMERGENCY OR NON-ROUTINE USE. Ventilation:PROVIDE ADEQUATE GENERAL AND LOCAL EXHAUST VENTILATION. Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:-320F,-196C Vapor Pres:GAS Vapor Density:0.967 Solubility in Water:0.015 @ 17C V/V Appearance and Odor:COLORLESS, ODORLESS. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACTS VIOLENTLY WITH LI, ND AND TI UNDER PROPER CONDITIONS (AT HIGH TEMPERATURES). Stability Condition to Avoid:HIGH TEMPERATURES. Hazardous Decomposition Products:NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS . RETURN CYLINDERS TO SUPPLIER FOR PROPER DISPOSAL WITH ANY VALVE OUTLET, PLUGS/CAPS SECURED AND VALVE PROT CAP IN PLACE. ALLOW GAS TO DISCHARGE AT A SLO W RATE IN AN UNCONFINED SPACE/EXHAUST HOOD.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:T-PREP 10% SOLUTION CAGE:FO911 CAGE:6A626 CAGE:FO911 ============= Composition/Information on Ingredients ============= Ingred Name:IODINE CAS:7553-56-2 RTECS #:NN1575000 Other REC Limits:0.1 PPM OSHA PEL:C 0.1 PPM ACGIH TLV:C 0.1 PPM; 9192 Ingred Name:WATER, H2O CAS:7732-18-5 RTECS #:ZC0110000 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES: IRRITATION. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH THOROUGHLY W/WATER. OBTAIN MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE ANY APPROPRIATE EXTINGUISHING MEDIA. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE & VENTILATE AREA. CONTAIN LIQUID IF POSSIBLE, & PUMP OR SCOOP INTO DRUMS. IF LIQUID CANNOT BE CONTAINED, ABSORB W/DIATOMACEOUS EARTH & SHOVEL INTO DRUMS. FLUSH RESIDUE TO DRAIN W/LARGE AMOUNT S OF WATER IF PERMITTED BY ALL REGULATIONS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. ============= Exposure Controls/Personal Protection ============= Ventilation:AS REQUIRED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text: 212F Vapor Pres:AS WATER Vapor Density:AS WATER Spec Gravity:1.04 Solubility in Water:COMPLETE Appearance and Odor:DARK BROWN LIQUID W/SLIGHT IODINE ODOR. Percent Volatiles by Volume: 90% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING OR REDUCING AGENTS ==================== Disposal Considerations ==================== Waste Disposal Methods:DUMP IN APPROVED LANDFILL. COMPLY W/ALL LOCAL, STATE, & FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:0865 INTRAWITE OB CAGE:69389 CAGE:69389 ============= Composition/Information on Ingredients ============= Ingred Name:BENZOXAZOLE, 1-OXA-3-AZAINDENE CAS:273-53-0 RTECS #:DM4375000 ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL (LAB ANIMAL) >10 G/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. SKIN: WASH THOROUGHLY W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. GIVE CPR OR OXYGEN IF NEEDED. INGESTION: DRINK PLENTY WATER & INDUCE VOMITING . NEVER GIVE ANYTHING BY MOUTH OR INDUCE VOMITING TO AN UNCONSCIOUS PERSON. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER, DRY CHEMICAL & CO2 Fire Fighting Procedures:WEAR SELF-CONTAINING BREATHING APPARATUS Unusual Fire/Explosion Hazard:AVOID DUSTING ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. CONTAIN/CLEAN UP SPILL & PREVENT ENTERING FLOOR DRAINS. CONTAIN LIQUIDS USING ABSORBENTS. SWEEP POWDERS CAREFULLY MINIZING DUSTING. SHOVEL ALL SPILL MATERIALS INTO DISPOSAL DRUM. SCRUB SPILL W/DETERGENT & FLUSH W/WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID EYE & SKIN CONTACT & INHALATION OF DUSTS OR VAPORS. Other Precautions:KEEP CONTAINERS CLOSED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED DUST RESPIRATOR Ventilation:LOCAL Other Protective Equipment:APRON, OVERALLS Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:1.26 Solubility in Water:INSOLUBLE Appearance and Odor:YELLOW POWDER W/NO ODOR Percent Volatiles by Volume:<0.5% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:CO, CO2 & NITROGEN ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE OR BURY IN COMPLIANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:SN60 WRAP3 Preparer's Name:ROBERT L.GILBERT CAGE:03051 CAGE:02750 CAGE:03051 ============= Composition/Information on Ingredients ============= Ingred Name:LEAD (SARA III) CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: 55-60% Other REC Limits:0.05MG/CUM OSHA PEL:0.05 MG/M3;1910.1025 ACGIH TLV:0.15 MG/M3;DUST 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:TIN CAS:7440-31-5 RTECS #:XP7320000 Fraction by Wt: 35-40% OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3; 9192 Ingred Name:ROSIN CAS:8050-09-7 Fraction by Wt: 2-3% Ingred Name:OTHER COMPONENTS IN CONCENTRATIONS OF <1% ACCORDING TO SPEC QQ-S-571:SB,BI,CU,FE,ZN,AL,AS RTECS #:9999999ZZ ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: WEAKNESS, VOMITING, LOSS OF APPETITE, CONVULSIONS, STUPOR AND POSSIBLY COMA. CHRONIC: WEAKNESS, INSOMNIA, HYPERTENSION, SLIGHT IRRITATION OF THE EYES, HEADACHE, POSSIBLE PARALYSIS. CHRONIC OVER EXPOSURE TO LEAD MAY RESULT IN DAMAGE TO BLOOD-FORMING, NERVOUS, URNIARY AND REPRODUCTIVE SYSTEM. Explanation of Carcinogenicity:IARC STATE THE WORKING GROUP CONCLUDED THAT LEAD AND LEAD COMPOUNDS, INORGANIC ARE POSSIBLE CARCINOGENIC. Effects of Overexposure:DUST,VAPOR AND/OR FUMES MAY BE IRRITATING TO SKIN,EYES & RESPIRATORY SYSTEM. Medical Cond Aggravated by Exposure:NOTE TO PHYSICIANS: LEAD AND ITS INORGANIC COMPOUNDS ARE NEUROTOXINS WHICH MAY PRODUCE NEUROPATHY. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH WITH LARGE AMOUNTS OF WATER.GET IMMEDIATE MEDICAL ATTENTION. SKIN:WASH WITH SOAP AND WATER. INHALATION: REMOVE FROM EXPOSURE.GET MEDICAL ATTENTION IF EXPERIENCING EFFECT OF OVEREXPOSURE. ===================== Fire Fighting Measures ===================== Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL Fire Fighting Procedures:USE FULL BODY PROTECTIVE CLOTHING & FULL- FACE PIECE,SCBA IN A POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:DO NOT USE WATER ON FIRES WHERE MOLTEN METAL IS PRESENT. HIGH TEMPERATURES MAY PRODUCE HEAVY METAL FUMES, DUST AND/OR VAPOR. ================== Accidental Release Measures ================== Spill Release Procedures:PARTICULATE MATTER SHOULD BE STORED IN DRY CONTAINERS FOR LATER DISPOSAL. DUST MATERIAL SHOULD BE VACUUMED OR WET SWEPT. DO NOT USE COMPRESSED AIR OR DRY SWEEPING AS A MEANS OF CLEANING. ======================Handling and Storage ====================== Handling and Storage Precautions:WASH HANDS WITH SOAP AFTER HANDLING SOLDER. STORE IN DRY AREAS. AVOID SKIN CONTACT. AVOID BREATHING SMOKE DURING SOLDERING. Other Precautions:NONE KNOWN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AS SPECIFIED BY 29 CFR 1910.1025 (F) IF EXPOSURE EXCEEDS PEL. Ventilation:LOCAL EXHAUST Other Protective Equipment:PERSONAL CLOTHING AND SHOES SHOULD BE PROTECTED FROM CONTAMINATION. Work Hygienic Practices:WASH HANDS THOROUGHLY BEFORE EATING OR SMOKING. Supplemental Safety and Health ROSIN MAY DECOMPOSE DURING SOLDERING TO EMIT FORMALDEHYDE (TLV=0.1 MG/CUM) OR TURPENTINE (TLV=100PPM) ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:M.P/F.P Text:362F,183C Spec Gravity:8 Solubility in Water:INSOLUBLE Appearance and Odor:GRAY METAL WITH NEUTRAL ODOR. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:NONE KNOWN Hazardous Decomposition Products:HIGH TEMPERATURES MAY PRODUCE HEAVY METAL FUMES,DUST,AND/OR VAPORS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF HAZARDOUS WASTES IAW FEDERAL,STATE & LOCAL REGULATIONS. CONSULT A LICENSED HAZARDOUS WASTE COMPANY.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:MOPAR ASBESTOS BRAKE Preparer's Name:G W WEAVER CAGE:KO776 CAGE:86403 CAGE:KO776 ============= Composition/Information on Ingredients ============= Ingred Name:ASBESTOS, CHRYSOTILE CAS:12001-29-5 RTECS #:CI6478500 Fraction by Wt: 30-60% Other REC Limits:NONE RECOMME OSHA PEL:0.2 FIBERS/CC ACGIH TLV:2 FIBERS/CC; A1;9394 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT KNOWN. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE:INHAL:OPERATIONS THAT PRODUCE DUST MAY CAUSE AN INHAL HAZ. SKIN:SHOULD NOT BE HARMFUL. EYE:IRRIT. INGEST:MAY BE HARMFUL. CHRONIC:INHAL:LUNG DISEASE. CANCER. Explanation of Carcinogenicity:CONTAINS A [1332-21-4] WHICH IS LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN. Effects of Overexposure:INHAL:LUNG DISEASE, CANCER. EYE:TEARAING, DISCOMFORT. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. IF PULMONARY SYMPTOMS DEVELOP, SEE DOCTOR. SKIN:REMOVE CONTAMINATED CLOTHING. WASH W;SOAP & WATER. INGEST: DO NOT MAKE UNCONSCIOUS PATIENT VOMIT. RINSE MOUTH W/WATER. IF CON DITIN PERSISTS, CONSULT DOCTOR. EYE:RINSE IMMED W/LG AMTS OF WATER LIFTING EYELIDS. CONTINUE FOR 15MINS. CONTACT DOCTOR. ===================== Fire Fighting Measures ===================== Extinguishing Media:FOAM, DRY CHEMICAL, CARBON DIOXIDE, WATER. Fire Fighting Procedures:USE PROTECTIVE CLOHTING. AVOID BRATHING VAPOR OR FUMES. USE SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:BURNING MAY PRODUCE AIRBORNE FIBERS OR PARTICLUATE. ================== Accidental Release Measures ================== Spill Release Procedures:RECOVER MATERIAL IF POSSIBLE. A CLEANUP PROCEDURE WHICH MINIMIZES EXPOSURE IS REQUIRED. VACUUMING W/HEPA FILTERED VACUUM IS PREFERRED. PLACE ALL MATLS IN CLOSED CONTAINERS. DO NOT USE COMPRESSED AIR F OR CLEANING. WEAR RESPIRATOR IF NEEDED. Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM OPEN FLAMES. AVOID BREATHING DUST. DO NOT WEAR CONTAMINATED CLOTHING HOME. DO NOT USE COMPRESSED AIR TO BLOW DUST OFF CLOTHES. Other Precautions:AVOID GENERATION OF DUST CLOUD FROM CONTAINERS. SOME ASBESTOS FIBERS MAY BE IN THE BOTTOM OF CARTONS CONTAINING PARTS. WHEN DISPOSISNG OF CARTONS, AVOID INHALING DUST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO SPECIAL PROTECTION NEEDED UNDER NORMAL CONDITIONS. FOR GRINDING, SANDING OR OTHER OPERAIONS WHICH GENERATE DUST USE RESIRATOR APPROVED FOR ASBESTOS. Ventilation:NO SPECIAL PROTECTION NEEDED UNDER NORMAL CONDITONS. LOCAL EXHAUST VENTILATION WHEN GENERATING DUST. Other Protective Equipment:NO SPECIAL PROTECTION NEEDED UNDER NORMAL CONDITIONS. Work Hygienic Practices:WASH HANDS AFTER HANDLING. DON'T SMOKE/EAT/DRINK IN WORK AREA.MAIANTAIN GOOD HOUSEKEPPING AND HYDGIENIC PRACTICES. Supplemental Safety and Health MFG'S GENERIC DATA SHEET FOR ASBESTOS BRAKE. ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:>1.000 Solubility in Water:NEGLIGIBLE Appearance and Odor:TAN COLORED SOLID, ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACID, STRONG OXIDIZING AGENTS AND STRONG ALKALI. Stability Condition to Avoid:SPARKS OR OPEN FLAME. PHYSICAL DAMAGE THAT MAY RESULT IN ASBESTOS BECOMING AIRBORNE. Hazardous Decomposition Products:FREE ASBESTOS FIBERS FROM GROUNDING/DRILLING/SANDING/BURNIN. ACRID SMOKE, FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A LANDFILL. DIPSOSE OF IN A MANNER CONSISTENT WITH STATE, PROVINCIAL, LOCAL AND FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:369B1046 DEVTHANE 369 DESERT SAND BASE, DV369B10188 Kit Part:Y Preparer's Name:H. KLINE CAGE:55849 CAGE:55849 ============= Composition/Information on Ingredients ============= Ingred Name:TITANIUM DIOXIDE (CONTAINING INGREDIENTS 2-3) CAS:13463-67-7 RTECS #:XR2275000 < Wt:25. OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:ALUMINUM HYDROXIDE CAS:21645-51-2 RTECS #:BD0940000 = Wt:2.5 Ingred Name:AMORPHOUS SILICA FUME; (AMORPHOUS SILICA) CAS:69012-64-2 RTECS #:VV7312000 = Wt:3. ACGIH TLV:2 MG/M3 Ingred Name:ACRYLIC RESIN < Wt:25. Ingred Name:BUTYL ACETATE VP: 10 MMHG @ 68F CAS:123-86-4 RTECS #:AF7350000 < Wt:18.2 OSHA PEL:710 MG/M3;150 PPM ACGIH TLV:713 MG/M3;150 PPM ACGIH STEL:950 MG/M3;200 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BARIUM SULFATE (AS BA) (CONTAINING INGREDIENTS 7-11) CAS:7727-43-7 RTECS #:CR0600000 < Wt:15. OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:SILICA % WT: 1000 PPM CAS:7631-86-9 < Wt:.1 Ingred Name:LEAD % WT: 10 PPM CAS:7439-92-1 RTECS #:OF7525000 < Wt:.1 ACGIH TLV:0.15 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:CADMIUM CAS:7440-43-9 RTECS #:EU9800000 < Wt:.1 OSHA PEL:see 1910.1027 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:CHROMIUM % WT: 2 PPM CAS:7440-47-3 RTECS #:GB4200000 < Wt:.1 ACGIH TLV:0.5 MG/M3 Ingred Name:ARSENIC % WT: 1 PPM CAS:7440-38-2 RTECS #:CG0525000 < Wt:.1 ACGIH TLV:0.01 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:HEXANOL, ACETATE, BRANCHED AND LINEAR; (OXOHEXYL ACETATE) VP: 1.4 MMHG @ 68F CAS:88230-35-7 < Wt:7.2 ACGIH TLV:50 PPM Ingred Name:ACRYLIC RESIN (CONTAINING INGREDIENT 14) < Wt:10. Ingred Name:RESIDUAL MONOMERS = Wt:.8 Ingred Name:1-METHOXY-2-ACETOXYPROPANE; (PROPYLENE GLYCOL METHYL ETHER) VP: 3.7 MMHG @ 68F CAS:108-65-6 RTECS #:AI8925000 < Wt:3.1 Ingred Name:TOLUENE VP: 22 MMHG @ 68F (CONTAINING INGREDIENT 17) CAS:108-88-3 RTECS #:XS5250000 < Wt:1.3 OSHA PEL:see Table Z-2 ACGIH TLV:188 MG/M3;50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BENZENE WT %: <300 PPM CAS:71-43-2 RTECS #:CY1400000 < Wt:.1 OSHA PEL:see 1910.1028 ACGIH TLV:32 MG/M3;10 PPM EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:XYLENE (CONTAINING INGREDIENT 17, BENZENE @ 5 PPM) VP: 6.6 MHG @ 68F CAS:1330-20-7 RTECS #:ZE2100000 < Wt:1.2 ACGIH TLV:434 MG/M3;100 PPM ACGIH STEL:651 MG/M3;150 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:IRON OXIDE YELLOW; (AS IRON OXIDE FUMES) CAS:51274-00-1 < Wt:5. ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:VAP/SPRAY MIST OR SPATTERED MATL CAN BE HARMFUL. IRRITATING TO EYES, SKIN & IF INHALED, TO NOSE & THROAT. EXCESSIVE/PRLNGD INHAL CAN CAUSE HDCH, NAUS OR DIZZ. RPTD & PRLNGD INHAL CAN CAUSE HDCH, NAUS OR DIZZ. RPTD & PRLNGD OCCUP OVEREXP TO SOLVS IS ASSOC W/PERM BRAIN & NERVOUS SYS DMG. INTENTIONAL ABUSE, MISUSE OR OTHER MASSIVE EXPOS TO SOLVS MAY CAUSE MULTIPLE ORGAN DMG &/OR DEATH. OVEREXP (PRLNG D/RPTD USE): CAN AGGRAVATE OR ACCENTUATE ANY OF THESE EFTS. SKIN: SEV IRRITANT. CAN BE ABSORBED THRU SKIN. CAN CAUSE DEFATTING & DRYING OF SKIN. INHAL: IRRITANT. LUNG INJURY. CNS DMG. SMOKING AGGRAVAT ES PROBS. (EFTS OF OVEREXP) Effects of Overexposure:HLTH HAZS: CHEM PNEUM. XYLENE OR TOLUENE MAY CAUSE IRREGULAR HEART BEAT. RPTD EXPOS TO IRON DUST CAN CAUSE SIDEROSIS. EYES: SEV IRRITANT. CORNEAL INJURY. DO NOT WEAR CONTACT LENSES WHEN USING THIS MAT L. INGEST: HARMFUL IF SWALLOWED. ASPIR INTO LUNGS CAN DMG LUNGS & CAUSE CHEM PNEUM. TARGET ORGANS: KIDNEYS. LIVER. LUNGS. HEART. SKIN. EYES. STOMACH. CNS. REPRO ORGANS. FETAL DEFECTS. NOTE: TOLUENE & LEAD APPEAR ON THE NAVY LIST OF OCCUP CHEM REPRO HAZS. SEEK CONSULTATION FROM APPROP HEALTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO . Medical Cond Aggravated by Exposure:KIDNEYS. LIVER. HEART. SKIN. EYES. RESPIRATORY. LUNGS. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. RESTORE NORMAL BREATHING. TREAT SYMPTOMATICALLY. SEE MD. SKIN: WASH THOROUGHLY W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING. CONSULT MD IF IRRITATION PERSISTS. EYES: FLUSH IMMEDIATELY W/PLENTY OF WATER FOR AT LEAST 15 MINUTES & GET MEDICAL ATTENTION. INGEST: DRINK 1 OR 2 GLASSES OF WATER TO DILUTE. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DO NOT INDUCE VO MITING. CONSULT MD OR POISON CONTROL CENTER IMMEDIATELY. TREAT SYMPTOMATICALLY. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:=26.7C, 80.F Lower Limits:1.0% Upper Limits:13.1% Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. Unusual Fire/Explosion Hazard:OSHA-FLAMMABLE-CLASS IC. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT AND PRESSURE BUILDUP. MAY PRODUCE A FLOATING FIRE HAZARD. ISOLATE FROM ELECTRICAL EQUIPMENT, SPARKS, HEAT AND OPEN F LAME. VAPORS MAY SPREAD LONG DISTANCES, CAUSE FLASH FIRE OR IGNITE EXPLOSIVELY. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. AVOID BREATHING VAPORS. VENTILATE AREA. USE ABSORBENT, INERT CLEANUP MATERIALS. (DO NOT USE SAWDUST.) REMOVE ABSORBENT MATERIAL WITH NON-SPARKING TOOLS. PLACE IN SEPARA TE CONTAINER. KEEP OUT OF SEWERS AND WATERWAYS. IF ENTRY IS THREATENED OR OCCURS, NOTIFY LOCAL AUTHORITIES. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED, UPRIGHT WHEN NOT IN USE. STORE IN COOL, DRY, WELL-VENTILATED AREA. AVOID PROLONGED STORAGE TEMPERATURES ABOVE 100F. USE CAUTION WHEN POURING. AVOID BREATHING SANDING DUST. DO NO T WELD OR FLAME CUT ON EMPTY CONTAINER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH APPRVD RESP DESIGNED TO REMOVE A COMBINATION OF PARTICULATES (DUST/SPRAY MIST) & VAP. WHEN BRUSHING, ROLLING OR SPREADING; SELECT APPROP NIOSH APPRVD RESP PROT FOR CNDTNS. FOR SPECIFIC CNDT NS, REFER TO CURRENT "NIOSH POCKET GUIDE TO CHEM HAZS." IN CONFINED OR RESTRICTED VENT AREAS USE NIOSH APPRVD AIR-LINE RESPS/HOODS. REFER TO 29 CFR, (SUPDAT) Ventilation:IMPLEMENT ADMINISTRATIVE & ENGINEERING CTLS TO REDUCE EXPOS. PROVIDE SUFFICIENT VENT IN VOL & PATTERN TO KEEP AIR CONTAMINANT CONCS BELOW TLV LIMS. (SUPDAT) Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . SHOE COVERINGS TO PVNT SKIN CNTCT. CONSULT 29 CFR 1910.132, 133, 136, 138; (OTHER INFO) Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING & BEFORE EATING, SMOKING OR USING TOILET. LAUNDER CONTAMINATED CLOTHING BEFORE USE. Supplemental Safety and Health RESP PROT: OSHA 1910.134 & 1915 FOR COATING OPERATIONS; 1910.146 CONFINED SPACES; ANSI Z88.2, PRACTS FOR RESP PROT. VENT: REMOVE WELDING OR FLAME CUTTING DECOMP PRODS; FOLLOW CURRENT ANSI Z49.1, "SFTY IN WELDING & CUTTING." REFER TO 29 CFR 1910 & 1915 FOR COATING OPERATIONS, 1910.146, CONFINED SPACES. ================== Physical/Chemical Properties ================== Boiling Pt:>100.C, 212.F B.P. Text:212-327F Vapor Pres:SEE INGREDS Vapor Density:HVR/AIR Spec Gravity:1.41 Evaporation Rate & Reference:FASTER/BUTYL ACETATE Solubility in Water:NO Appearance and Odor:LIQUID; SOLVENT ODOR. Percent Volatiles by Volume:51.69 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, ACIDS AND ALKALIS. Stability Condition to Avoid:HEAT, OPEN FLAME, ARC OR SPARKS. Hazardous Decomposition Products:(BY FIRE, BURNING OR WELDING): CARBON MONOXIDE, CARBON DIOXIDE, IRON OXIDE FUMES, ACRYLIC MONOMER FUMES. SO*X. TOXIC GASES OR FUMES. =================== Toxicological Information=================== Toxicological Information:SEE SECTION 2 OF MSDS. ===================== Ecological Information ===================== Ecological:NO INFORMATION. ==================== Disposal Considerations ==================== Waste Disposal Methods:EPA WASTE NO: D001, D018. PLACE IN SEPARATE, APPROPRIATE, CLOSED CONTAINER IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS. THIS MATERIAL HAS NOT BEEN TESTED BY TOXICITY CHARACT ERISTIC LEACHING PROCEDURE (TLCP). =================== MSDS Transport Information =================== Transport Information:DOT: FLAMMABLE. DOT PROPER SHIPPING NAME: PAINT. DOT HAZARD CLASS: 3. HAZARD SUBCLASS: NA. DOT UN/NA NUMBER: 1263. IMO: NA. PACKING GROUP: III. ===================== Regulatory Information ===================== SARA Title III Information:(SARA, CERCLA, HAPS) TOXIC CHEMICAL SUBJECT TO REPORTING REQUIREMENTS OF SARA AND CERCLA (40 CFR 302, 355, 372) OR HAPS (40 CFR 63): ACRYLIC RESIN (CERCLA), BUTYL ACETATE (CERCLA), ACRYLIC RESIN (SARA , CERCLA), TOLUENE (HAPS, SARA, CERCLA), XYLENE (HAPS, SARA, CERCLA). Federal Regulatory Information:PIGMENT CONTENT (TITANIUM DIOXIDE, IRON OXIDE) IS DEPENDENT ON COLOR. ALL INGREDIENTS ARE ON TSCA INVENTORY OR ARE EXEMPT. OSHA: HAZARDOUS BY DEFINITION OF HAZARD COMMUNICATION STANDARD (29 CFR 1910.1 200). State Regulatory Information:CALIFORNIA TITLE 26:22-1200 (PROP 65). WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER (SILICA, LEAD, CADMIUM, CHROMIUM, ARSENIC, BENZENE). CALIFORNIA TITLE 26:22-12000 (PROP 65). WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM (LEAD, TOLUENE). ======================= Other Information =======================
1
gloves_mandatory
======================================================= Product ID: RAIN-X ANTI-FOG Cage: GO469 Proprietary Ind: Y ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: GO469 Assigned Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 50159 Cage: GO469 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: YES Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: EYES: IRRITATION. INHALATION: EXCESSIVE VAPORS MAY CAUSE NASAL IRRITATION & A NARCOTIC REACTION. Explanation Of Carcinogenicity: NONE Signs And Symptions Of Overexposure: IRRITATION, DRYNESS, DIZZINESS, WEAKNESS, NAUSEA, HEADACHE, STOMACH CRAMPS, VOMITING, DIARRHEA. First Aid: EYES: FLUSH W/COPIOUS AMOUNTS OF WATER. SKIN: WASH W/SOAP & WATER & APPLY CREAM/LUBRICATING OINTMENT. INHALATION: REMOVE TO FRESH AIR. INGESTION: DRINK WATER & INDUCE VOMITING. OBTAIN MEDICAL ATTENTIO N IN ALL CASE. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: USE APPROPRIATE SAFETY EQUIPMENT. USE ABSORBENT MATERIAL TO COLLECT & CONTAIN FOR DISPOSAL. LARGE: CONTAIN & PUMP INTO A SUITABLE TANK/VESSEL. WASH AREA W/DETERGENT SOLUTION & RINSE THOROUGHLY W/WATER . Waste Disposal Methods: DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. RCRA HAZARD: DOO1, DOO2. Handling And Storage Precautions: STORE IN WELL VENTILATED AREAS AT TEMPS <120F & AWAY FROM IGNITION SOURCES. SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUES. Other Precautions: ALL HAZARD PRECAUTIONS MUST BE OBSERVED. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: TOC Flash Point Text: 65F Lower Limits: 2 Upper Limits: 12.7 @ 200F Extinguishing Media: SMALL: CO2, DRY CHEMICAL. LARGE: FOAM (ALCOHOL, POLYMER/ORDINARY), WATER SPRAY. Fire Fighting Procedures: USE SCBA & PROTECTIVE CLOTHING. KEEP FIRE EXPOSED CONTAINERS COOL W/WATER. Unusual Fire/Explosion Hazard: VAPORS ARE > THAN AIR & MAY TRAVEL ALONG THE GROUND & IGNITE BY AN IGNITION SOURCE AT DISTANT FROM HANDLING POINT. ======================================================= Control Measures ======================================================= Respiratory Protection: USE SCBA WHEN HANDLING/TRANSFERRING LARGE QUANTITIES OF OPEN/BULK MATERIAL IN AN ENCLOSED ROOM. Ventilation: SUFFICIENT AMBIENT/MECHANICAL EXHAUST TO MAINTAIN EXPOSURE < TLV. Other Protective Equipment: CLEAN, BODY-COVERING CLOTHING, EYE FOUNTAIN & SAFETY SHOWER. BOOTS & APRON FOR DRUM QUANTITIES. Work Hygienic Practices: REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: 180F Vapor Pres: 33 @ 25C Vapor Density: >1 Spec Gravity: 0.79 @ 25C Evaporation Rate & Reference: (BU AC = 1): 2.85 Solubility in Water: COMPLETE @ 25C Appearance and Odor: CLEAR, COLORLESS LIQUID W/ALCOHOL ODOR Percent Volatiles by Volume: 98 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: EXCESS HEAT, SPARKS, FLAMES Materials To Avoid: STRONG OXIDIZING MATERIALS, ALDEHYDES, HALOGENS & CONCENTRATED MINERAL ACIDS. Hazardous Decomposition Products: THERMAL/BURNING: SILICONE & CARBON OXIDES. Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: RAIN-X ANTI-FOG Cage: GO469 Assigned IND: Y Company Name: UNELKO CORPORATION Street: 7428 EAST KAREN DRIVE Zipcode: 85260-6923 Label Required IND: Y Date Of Label Review: 12/16/1998 Status Code: C Label Date: 12/16/1998 Origination Code: G Hazard And Precautions: EYES: IRRITATION. INHALATION: EXCESSIVE VAPORS MAY CAUSE NASAL IRRITATION & A NARCOTIC REACTION. IRRITATION, DRYNESS, DIZ ZINESS, WEAKNESS, NAUSEA, HEADACHE, STOMACH CRAMPS, VOMITING, DIARRHEA. =======================================================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:SPRAY FINISH, 2900 GLOSS WHITE CAGE:0NRH3 CAGE:0NRH3 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOL, 2-BUTOXY; (2-BUTOXYETHANOL). VP: 1. LEL: 1%. CAS:111-76-2 RTECS #:KJ8575000 Other REC Limits:PEL: 50 PPM (MFR) OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM; 9293 Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Other REC Limits:PEL: 200 PPM (MFR) OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:NAPHTHA, LIGHT AROMATIC; (AROMATIC PETROLEUM DISTILLATE). VP: 1. LEL: 1%. CAS:64742-95-6 OSHA PEL:100 PPM (MFR) ACGIH TLV:100 PPM (MFR) Ingred Name:N-BUTYL ALCOHOL (SARA III). VP: 4. LEL: 1%. CAS:71-36-3 RTECS #:EO1400000 Other REC Limits:PEL: 100 PPM (MFR) OSHA PEL:100 PPM ACGIH TLV:S, C 50 PPM; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SOLVENT NAPHTHA (PETROLEUM) LIGHT ALIPHATIC; (ALIPHATIC HYDROCARBONS). VP: 42. LEL: 1%. CAS:64742-89-8 OSHA PEL:200 PPM (MFR) ACGIH TLV:100 PPM (MFR) Ingred Name:ACETONE (SARA III). VP: 186. LEL: 3%. CAS:67-64-1 RTECS #:AL3150000 OSHA PEL:1000PPM ACGIH TLV:750PPM/1000STEL;9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 OSHA PEL:1000 PPM ACGIH TLV:SIMPLE ASPHYXIANT Ingred Name:BUTANE CAS:106-97-8 RTECS #:EJ4200000 OSHA PEL:800 PPM ACGIH TLV:800 PPM Ingred Name:VENT: EXPLOSION-PROOF VENTILATION IS RECOMMENDED FOR FLAMMABLE MATERIALS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EXCESSIVE INHAL OF VAPS MAY CAUSE NASAL & RESP IRRIT/DIZZ/LASS/FATG/NAUS/HDACH/POSS UNCON & EVEN ASPHY. SWALLOWING MAY CAUSE GI IRRIT/NAUS/ VOMIT/DIARR. ASPIR OF MATL INTO LUNGS MAY CAUSE CHEM PNEUMONITIS. CHRONIC: RPTS HAVE ASSOC RPTD/ PRLNG OCCUP OVEREXP TO SOLV W/PERM BRAIN/NERVS SYS DMG. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: EXCESSIVE INHAL OF TOLUENE VAP MAY CAUSE BRAIN CELL/LIVER/KIDNEY DMG. RPTD OVEREXP TO 2-BUTOXYETHANOL MAY CAUSE HEMOLYSIS OF RED BLOOD CELLS LEAD TO POSS LIVER/KIDNEY DMG. ANIMAL STUDIES CLE ARLY DEMONSTRATED DOSE-RELATED ADVERSE EFTS ON CNS/HEMATOPOIETIC TISS/BLOOD/KIDNEYS/ LIVER, ASSOC W/ADMIN OF (SUPP DATA) Medical Cond Aggravated by Exposure:TOLUENE, CAS NO. 108-88-3 APPEARS ON THE NAVY LISTING OF OCCUPATIONAL REPRODUCTIVE HAZ.SEEK CONSULT FROM APPROP HEALTH PRO'S CONCERNING THE LATEST HAZ INFO & SAFE HANDLING & EXPOS RECOMMEND . ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR, GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. EYES: FLUSH EXPOSED EYES W/FRESH WATER FOR AT LEAST 15 MINUTES. SKIN: WASH EXPOSED SKIN W/SOAP & WATER. CHANGE CONTAMI NATED CLOTHING. INGEST: DO NOT INDUCE VOMITING. KEEP HEAD LOWER THAN WAIST. ASPIRATION OF VOMITUS MAY CAUSE CHEMICAL PNEUMONITIS. CALL MD. ===================== Fire Fighting Measures ===================== Flash Point:<0F,<-18C Lower Limits:SEE INGRED Extinguishing Media:DRY CHEMICAL, CO*2, OR ALCOHOL FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD POS PRESS SCBA/FULL PROT EQUIP . WATER MAY BE UNSUITABLE AS EXTING MEDIUM, BUT HELPFUL IN COOLING HOT SURF & UNRUPTURED (SUPP DATA) Unusual Fire/Explosion Hazard:EXTREMELY FLAMM. VAPS ARE HEAVIER THAN AIR & MAY ACCUM IN LOW AREAS OF POOR VENT OR TRAVEL ALONG GROUND TO REMOTE IGNIT SITES. CLOSED CONTRS CAN (SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SOURCES OF HEAT, SPARK, OR FLAME. WEAR APPROPRIATE CLOTHING AND GEAR. CLEAN UP SPILLS IMMEDIATELY WITH ABSORBENTS SUCH AS CLAY, SAND OR OTHER SUITABLE MATERIALS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP COOL/DRY & AWAY FROM HEAT/SPARK/FLAME (ALL IGNIT SOURCES). DO NOT STORE IN AREAS ABOVE 120F. STORE IN A WELL VENT AREA & OUT OF DIRECT SUNLIGHT. Other Precautions:AVOID EXCESSIVE PERSONAL EXPOSURE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL. STORE LARGE QUANTITIES AS NFPA CLASS IA FLAMMABLE LIQUIDS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AVOID EXCESSIVE VAPOR INHALATION. IF PEL/TLV IS EXCEEDED, USE NIOSH/MSHA APPROVED RESPIRATOR OR SCBA. USE NIOSH/MSHA APPROVED MECHANICAL FILTER TO REMOVE SOLID AIRBORNE PARTICLES DURING SPRAY APPLICAT ION. Ventilation:GENERAL MECHANICAL VENT MAY PROVIDE SUFFICIENT VOLUME & PATTERN AIR MOVEMENT TO KEEP EXPOSURE BELOW PEL/TLV. (ING 9) Other Protective Equipment:EYE WASHES AND SAFETY SHOWERS, AS NEEDED. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRE FIGHT PROC: CONTRS. IF H*2O MUST BE USED, USE H*2O FOG (NOT DIRECT STREAM OF H*2O) AS BURNING MATL MAY SPREAD/FLOAT ON H*2O SURF. EXPLO HAZ: BUILD UP PRESS & MAY PRDCE AUTO-IGNIT/EXPLOS WHEN EXPO S TO EXTREME HEAT. EFTS OF OVEREXP: ETHYLENE GLYCOL MONOBUTYL ETHER (EGBE).(EXTRACTED FROM DHHS (NIOSH)PUB#90-118. ================== Physical/Chemical Properties ================== HCC:V3 Vapor Pres:SEE INGRED Vapor Density:HVR/AIR Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ACIDS AND BASES, SELECTED AMINES. Stability Condition to Avoid:HEAT, SPARKS OR FLAME. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, UNIDENTIFIED ORGANIC COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:PLACE IN NON-LEAKING CONTAINERS AND DISPOSE OF IN ACCORDANCE WITH APPLICABLE LOCAL, COUNTY, STATE, AND FEDERAL REGULATIONS. BEFORE BEGINNING CLEAN-UP, REFER TO ALL SECTIONS OF MSDS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:VESTAR Q9-6503 PROTECTIVE FINISH CAGE:5D028 CAGE:5D028 CAGE:71984 ============= Composition/Information on Ingredients ============= Ingred Name:2-ETHOXYETHANOL (EGEE) (SARA III) CAS:110-80-5 RTECS #:KK8050000 Fraction by Wt: <25%. OSHA PEL:S,200 PPM ACGIH TLV:S, 5 PPM; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:PROPYLENE GLYCOL MONOMETHYL ETHER CAS:107-98-2 RTECS #:UB7700000 Fraction by Wt: <15%. OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 Ingred Name:N-BUTYL ALCOHOL (SARA III) CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: <15%. OSHA PEL:100 PPM ACGIH TLV:S, C 50 PPM; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:METHYL ALCOHOL (METHANOL) (SARA III) CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 45.0% OSHA PEL:S,200PPM/250STEL ACGIH TLV:S,200PPM/250STEL; 93 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Effects of Overexposure:MAY IRRITATE SKIN(EYES,&CAUSE SLIGHT ANESTHESIA/HEADACHES.MAY CAUSE DEATH OR BLINDNESS IF SWALLOWED. ======================= First Aid Measures ======================= First Aid:SKIN/EYES:FLUSH WITH WATER.INHAL:REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION.IF SWALLOWED INDUCE VOMITING.CALL A PHISICIAN. ===================== Fire Fighting Measures ===================== Flash Point:105F/41C CC Lower Limits:6.0 Upper Limits:36.0 Extinguishing Media:CO*2 OR FOAM Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS & --CONTD--SEE SUPP DATA- ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBENT MATERIAL TO COLLECT & CONTAIN FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:PROPER SAFETY EQUIPMENTS SHOULD BE WORN DURNING HANDLING.SHOULD NOT BE STORED NEAR STRONG OXIDIZERS. Other Precautions:PRODUCT CANNOT BE MADE NON-POISONOUS.SHOULD BE USED IN A WELL VENTILATED AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ORGANIC VAPOR TYPE Ventilation:LOCAL EXHAUST & MECHANICAL(GENERAL) IS RECOMMENDED. Other Protective Equipment:PROTECTIVE CLOTHING & SAFETY SHOES. Supplemental Safety and Health SPEC.FIRE FIGHTING:PROTECTIVE CLOTHING SHOULD BE WORN IN FIGHTING FIRES INVOLVING CHEMICALS. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:150F/66C Vapor Pres:100 Vapor Density:>1.0 Spec Gravity:1.03 Evaporation Rate & Reference:<1.0(ETHER) Solubility in Water:>50% Appearance and Odor:LIQUID,SOME COLOR,ALCOHOL ODOR. Percent Volatiles by Volume:>50 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING MATERIAL Stability Condition to Avoid:OXIDIZERS MAY CAUSE A REACTION. Hazardous Decomposition Products:SIO*2,CO*2 & TRACES OF INCOMPLETELY BURNED CARBON PRODUCTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:REVIEW ALL LOCAL,STATE & FEDERAL REGULATIONS CONCERNING HEALTH/POLLUTION TO DETERMINE APPROVED DISPOSAL PROCEDURES.SPILL RPTG.INFO:DOT(49CFR 171.8)/EPA(40CFR 117).CONTACT DOWCORNING IF THERE ARE ANY D ISPOSAL QUESTIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:2M AMMONIA SULFATE, 478153 CAGE:51404 CAGE:51404 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS INGREDIENTS OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: CONTACT WITH SKIN OR EYES MAY CAUSE SLIGHT IRRITATION. CHRONIC: NONE SPECIFIED BY MANUFACTURER. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARD. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTIFICIAL RESPIRATION) . EYES:IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SK IN:WASH AFFECTED AREAS WITH SOAP AND WATER. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NOT APPLICABLE. ================== Accidental Release Measures ================== Spill Release Procedures:MOP UP AFFECTED AREA. RINSE AREA WITH WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID HIGH TEMPERATURES AND KEEP FROM FREEZING. Other Precautions:NOT APPLICABLE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NOT APPLICABLE. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . LABORATORY PROTECTIVE CLOTHING. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C Spec Gravity:1.02 Solubility in Water:COMPLETE Appearance and Odor:COLORLESS/ODORLESS LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NOT APPLICABLE. Stability Condition to Avoid:NOT APPLICABLE. Hazardous Decomposition Products:NOT APPLICABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE AND LOCAL LAWS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:MIL-L-9000-G GRADE 9250;LUBRICATING OIL CAGE:7A348 CAGE:7A348 ============= Composition/Information on Ingredients ============= Ingred Name:PETROLEUM OIL (80-95%) (TAKE TLV AS OIL MIST) Fraction by Wt: 87.5% ACGIH TLV:5MG/CUM Ingred Name:ADDITIVE PACKAGE (CONTAINING N,ZN,CA,S, P.MG) 5-10% Fraction by Wt: 7.5% ACGIH TLV:NOT SPECIFIED ===================== Hazards Identification ===================== Effects of Overexposure:EYES:IRRITATION;SKIN:DERMAL CONTACT SLIGHT MAY BE IRRITATION;INHAL:IRRITATION TO RESPIRATORY TRACT. ======================= First Aid Measures ======================= First Aid:INHALE:REMOVE TO FRESH AIR, GIVE CPR/O*2 IF NEED;EYES/SKIN:FLUSH W LG AMTS H*2O FOR 15 MIN;INGEST:RINSE MOUTH; GET MEDICAL ATTENTION FOR EYES, BREATHING DIFFICULTY, OR OTHER SYMPTOMS OF OVEREXPOSURE. ===================== Fire Fighting Measures ===================== Flash Point:430F/221C (COC) Extinguishing Media:WATER SPRAY,DRY CHEMICAL,CO*2,FOAM Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA IN CONFINED AREA. Unusual Fire/Explosion Hazard:NONE NOTED ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION;USE SUITABLE ABSORBENT MATERIAL AND RECOVER FOR PROPER DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY AND WELL VENTILATED AREA;KEEP AWAY FROM HEAT,OPEN FLAMES,SPARKS;KEEP CONTAINER CLOSED WHEN NOT IN USE. Other Precautions:AVOID CONTACT WITH SKIN,EYES AND CLOTHES;DO NOT BREATHE VAPORS/MIST;WASH THOROUGHLY AFTER EACH USE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR FOR ORG.VAPORS/MIST IF ABOVE TLV Ventilation:MECH(GEN)OR LOCAL EXHAUST THAT PROVIDES ADEQUATE VENTILATION Other Protective Equipment:FULL PROTECTIVE CLOTHING,SAFETY SHOWER,EYE WASH STATION Supplemental Safety and Health MSDS DATED:11/01/85 ================== Physical/Chemical Properties ================== HCC:V6 Spec Gravity:0.9007 Solubility in Water:NEGLIGIBLE Appearance and Odor:BRIGHT AND CLEAR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS Stability Condition to Avoid:HEAT,OPEN FLAMES. Hazardous Decomposition Products:CO,CO*2,ALDEHYDES+KETONES;COMBUSTION PRODUCTS OF N*2, AND S ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF COLLECTED MATERIAL IN ACCORDANCE WITH LOCAL,STATE AND FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:BROWN, ACRYLIC LACQUER AEROSOL PAINT, 52583 Preparer's Name:BOB BATH CAGE:0A3L4 CAGE:0A3L4 ============= Composition/Information on Ingredients ============= Ingred Name:ACETONE (SARA 313) (CERCLA) CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: <36% OSHA PEL:1000 PPM ACGIH TLV:750 PPM;1000 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA 313) (CERCLA) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: <6% OSHA PEL:200 PPM ACGIH TLV:200 PPM;300 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER; (PROPYLENE GLYCOL METHYL ETHER ACETATE) CAS:108-65-6 RTECS #:AI8925000 Fraction by Wt: <8% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:PHTHALIC ACID, BENZYL BUTYL ESTER; (BUTYL BENZYL PHTHALATE) (SARA 313) (CERCLA) CAS:85-68-7 RTECS #:TH9990000 Fraction by Wt: <2% OSHA PEL:5 MG/M3 (MFR) ACGIH TLV:5 MG/M3 (MFR) EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:TOLUENE (SARA 313) (CERCLA) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: <13% OSHA PEL:200 PPM ACGIH TLV:50 PPM, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ALUMINUM; (ALUMINUM FLAKE)(SARA 313) CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: <2% OSHA PEL:15 MG/M3 DUST ACGIH TLV:10 MG/M3 DUST Ingred Name:ACRYLIC POLYMER CAS:25068-63-7 Fraction by Wt: <13% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:BUTANE; (N-BUTANE) CAS:106-97-8 RTECS #:EJ4200000 Fraction by Wt: <8% OSHA PEL:800 PPM ACGIH TLV:800 PPM Ingred Name:NITROCELLULOSE CAS:9004-70-0 RTECS #:QW0970000 Fraction by Wt: <2% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: <17% OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT Ingred Name:AMORPHOUS SILICA GEL; (AMORPHOUS PRECIPITATED SILICA) CAS:112926-00-8 Fraction by Wt: <5% OSHA PEL:N/K ACGIH TLV:10 MG/M3 (MFR) Ingred Name:STODDARD SOLVENT; (MINERAL SPIRITS) CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: <2% OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:BENZENE, TRIMETHYL-(MIXED ISOMER); (TRIMETHYLBENZENE (MIXED ISOMERS)) CAS:25551-13-7 RTECS #:DC3220000 Fraction by Wt: <2% OSHA PEL:25 PPM ACGIH TLV:25 PPM Ingred Name:BENZENE, 1,2,4-TRIMETHYL-; (1,2,4-TRIMETHYLBENZENE) (SARA 313) CAS:95-63-6 RTECS #:DC3325000 Fraction by Wt: <4% OSHA PEL:25 PPM ACGIH TLV:25 PPM Ingred Name:XYLENE (SARA 313) (CERCLA) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: <2% OSHA PEL:100 PPM ACGIH TLV:100 PPM;150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ORGANIC & ORGANIC ACIDS & SALTS; (ORGANIC & INORGANIC PIGMENTS) Fraction by Wt: <19% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ETHANOL, 2-BUTOXY-; (2-BUTOXYETHANOL) CAS:111-76-2 RTECS #:KJ8575000 OSHA PEL:50 PPM, S ACGIH TLV:25 PPM, S Ingred Name:ISOPROPYL ALCOHOL (SARA 313) CAS:67-63-0 RTECS #:NT8050000 OSHA PEL:400 PPM ACGIH TLV:400 PPM;500 STEL Ingred Name:VOLATILE ORGANIC COMPOUNDS: 5.4 LBS/GAL (647 G/L). RTECS #:9999999VO Ingred Name:SUPDAT:HAVE ASSOC RPTD & PRLNG OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG. ING 2:RPTD BRTHG/SKIN CONT MAY INCR(ING 21) RTECS #:9999999ZZ Ingred Name:ING 20:POTENCY OF NEUROTOXINS (HEXANE), WHEN EXPOS OCCUR AT SAME TIME. ING 5 IS KNOWN TO STATE OF CALIF TO CAUSE(ING 22) RTECS #:9999999ZZ Ingred Name:ING 21:CANCER, BIRTH DEFECTS/OTHER REPRO HARM. NOTE:TOLUENE APPEARS ON NAVY LIST OF OCCUP CHEM REPRO HAZS. SEEK (ING 23) RTECS #:9999999ZZ Ingred Name:ING 22:CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO (ING 24) RTECS #:9999999ZZ Ingred Name:ING 23:. ANIMAL STUDIES CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE EFTS ON CNS, HEMATOPOIETIC TISS, BLOOD, (ING 25) RTECS #:9999999ZZ Ingred Name:ING 24:KIDNEYS & LIVER, ASSOC W/ADMIN OF 2-BUTOXYETHANOL. (EXTRACTED FROM DHHS (NIOSH) PUBLICATION NO.90-118) . RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:EYE:SEV IRRIT/SEV CORNEAL INJURY. SKIN:ALLERGIC DERM & IRRIT. HARMFUL IF ABSORBED. INHAL:IRRIT TO SKIN, EYES, THROAT/LUNGS. NASAL & RESP IRRIT. DIZZ, BRTHG DFCLTY, HDCHS/RESP IRRIT. DROW, STAG, CONFUSN, UNCON, COMA/DEATH. INTENTIONALMISUSE BY DELIB CONC & INHAL CONTENTS CAN BE HARMFUL/FATAL. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:INGEST:MOD TOX. STOM DISCOMFORT, NAUS, VOMIT, DIARR & NARCOS. ASPIR OF MATL CAN CAUSE CHEM PNEUM WHICH CAN BE FATAL. CHRONIC:LAB ANIMAL EFTS:KIDNEY, EYE, LUNG, LIVER, SPLEEN/BRAIN DMG, ANEMIA . ING 4:CANCER. CHRONIC:ING 5:HARMFUL TO FETUS & HIGH FREQUENCY HEARING LOSS-HUMAN CONSEQUENCES UNCERTAIN. HUMAN(SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS. GET MED ATTN, IF IRRIT PERSISTS. SKIN:WASH THORO W/SOAP & WATER & SEEK MED ATTN. REMOVE & LAUNDER CONTAM CLTHG BEFORE REUSE. INHAL:MOVE PERS TO F RESH AIR. IF BRTHG STOPS, APPLY ARTF RESP & SEEK MED ATTN. INGEST:SINCE PROD CAN BE ASPIRATED, DECISION WHETHER TO INDUCE VOMIT/NOT MUST BE MADE BY MD AFTER CAREFUL CONSIDERATION OF ALL INGS INGESTED. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:<-25F,<-32C Lower Limits:0.3% Upper Limits:13.1% Extinguishing Media:DRY CHEMICAL, CO*2, FOAM. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER SPRAY SHOULD NOT BE USED EXCEPT TO KEEP DOWN VAPS/COOL CLSD CNTNRS TO PVNT BUILD-UP OF PRESS. IF (SUPDAT) Unusual Fire/Explosion Hazard:CONTENTS UNDER PRESS. DO NOT PUNCTURE/INCIN. DO NOT CRUSH/PLACE IN GARBAGE CNTNR. AEROSOL CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME HEAT. PROD VAPS ARE (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. AVOID HEAT, SPARKS, FLAMES & ANYTHING WHICH COULD CAUSE FIRE. VENTILATE AREA OF SPILL & ADJACENT LOW LYING AREAS. AVOID BREATHING SOLVENT VAPORS. REMOVE W/INERT ABSORBE NT MATERIALS & NON-SPARKING TOOLS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY AREA W/VENT SUITABLE FOR STORING INGS. DO NOT USE/STORE NEAR SOURCES HEAT, SPARKS & OPEN FLAME. DO NOT STORE AT TEMPERATURES >120F. Other Precautions:KEEP AWAY FROM ANY SOURCE OF HEAT SUCH AS DIRECT SUNLIGHT, HEATERS, STOVES/ANY SOURCE OF IGNIT THAT COULD CAUSE CNTNR TO BURST. EXTREMELY FLAMMABLE LIQUID & VAPOR. VAPORS MAY CAUSE FLASH FIRE OR EXPLO SION. EXTREMELY FLAMMABLE AEROSOL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF WORKPLACE EXPOSURE LIMITS ARE EXCEEDED FOR ANY COMPONENT, A NIOSH APPROVED RESPIRATOR SUITABLE FOR COMPONENTS LISTED IS RECOMMENDED. Ventilation:SUFFICIENT VENT, IN VOL & PATTERN, SHOULD BE PROVIDED TO KEEP AIR CONTAM BELOW CURRENT APPLIC OSHA PEL/ACGIH'S TLV LIM. Other Protective Equipment:ANSI APPRVD EYE WASH FOUNTAIN & DELUGE SHOWER . APPROP IMPERVIOUS CLTHG IS REC IF PRLNG/RPTD CONTACT IS LIKELY. Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE EATING OR DRINKING. SMOKE IN DESIGNATED AREAS ONLY. Supplemental Safety and Health % VOLAT:91-92.2. FIRE FIGHT:WATER IS USED, FOG NOZZ ARE PREF. WHEN FIGHTING FIRE INVOLVING ING 6 PASTE, DO NOT USE WATER STREAM/HALOGENATED EXTING AGENTS. EXPLO HAZ:HVR/AIR & MAY TRAVEL LONG DIST TO S OURCE OF IGNIT & FLASH BACK. EYE PROT:FULL LGTH FCSHLD. EFTS OF OVEREXP:EFTS:LIVER DMG, CARD ABNORMS. RPTS(ING 20) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>-44F,>-42C Vapor Density:HVR/AIR Spec Gravity:0.75-0.78 Evaporation Rate & Reference:FASTER THAN BUTYL ACETATE Appearance and Odor:LIQUID & LIQUIFIED COMPRESSED GAS, OPAQUE LIQUID; SOLVENT ODOR. Percent Volatiles by Volume:SUPDAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ING 6:CAN REACT VIOLENTLY W/HALOGENATED HYDROCARBS INCL HALOGENATED EXTING AGENTS & REACT W/SOME ACIDS, CAUSTIC SOLNS. Stability Condition to Avoid:AVOID CONTACT W/HEAT, SPARKS & OPEN FLAME. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE CARBON DIOXIDE, CARBON MONOXIDE & UNIDENTIFIABLE ORGANIC MATERIALS. ==================== Disposal Considerations ==================== Waste Disposal Methods:PLACE IN CLOSED CONTAINERS. DISPOSE OF PRODUCT I/A/W LOCAL, COUNTY, STATE & FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:SOLVENT 111, GENERAL PURPOSE GRADE, INDUSTR CAGE:1B637 CAGE:4N760 CAGE:1B637 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III) CAS:71-55-6 RTECS #:KJ2975000 Fraction by Wt: 95.5% % Other REC Limits:NONE RECOMMENDED OSHA PEL:350 PPM/450 STEL ACGIH TLV:350 PPM/450STEL;9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ozone Depleting Chemical:1 Ingred Name:1,4-DIOXANE (DIETHYLENE DIOXIDE) (SARA III) CAS:123-91-1 RTECS #:JG8225000 Other REC Limits:NONE RECOMMENDED OSHA PEL:S, 100 PPM ACGIH TLV:S, 25 PPM; 9293 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) = 10300 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: MAY CAUSE EYE & SKIN IRRITATION. MAY CAUSE RESPIRATORY TRACT IRRITATION. CENTRAL NERVOUS SYSTEM DEPRESSANT. LOSS OF CONSCIOUSNESS AND EVEN DEATH CAN OCCUR AT HIGH LEVELS OF EXPOSURE. Explanation of Carcinogenicity:PRODUCT CONTAINS NO INGREDIENTS CURRENTLY CLASSIFIED AS CARCINOGENIC BY NTP, IARC OR OSHA. Effects of Overexposure:ABOVE 1000 PPM: DIZZINESS, DROWSINESS, THROAT IRRITATION. UNCONSCIOUSNESS AND DEATH ABOVE 10000PPM. PROLONGED OR REPEATED SKIN CONTACT CAN CAUSE IRRITATION, DEFATTING OF SKIN AND DERMATITIS. SLIGHT TE MPORARY EYE IRRITATION AND/OR CORNEAL INJURY. ASPIRATION HAZARD; CAN CAUSE CHEMICAL PNEUMONIA. Medical Cond Aggravated by Exposure:ACUTE AND CHRONIC LIVER DISEASE AND RHYTHM DISORDERS OF THE HEART. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. CALL A PHYSICIAN. EYE: FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER PROMPTLY. INGESTION: DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION. NOTE: ADRENALIN SHOULD NEVER BE GIVEN TO PERSONS OVEREXPOSED TO PRODUCT. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:NONFLAMMABLE Lower Limits:7.5 % Upper Limits:15.0 % Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE THE AREA, VENTILATE AND AVOID BREAATHING VAPORS. DIKE AREA TO CONTAIN SPILL. CLEAN UP AREA BY MOPPING OR WITH ABSORBENT MATERIAL AND PLACE IN CLOSED CONTAINERS. AVOID CONTAMINATION OF GROUND AND SURFACE WATERS. DO NOT FLUSH TO SEWEER. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED LOCATION, AWAY FROM ANY AREA WHERE THE FIRE HAZARD MAY BE ACUTE. KEEP CONTAINERS CLOSED WHEN NOT IN USE. Other Precautions:PREVENT WATER OR MOIST AIR FROM ENTERING STORAGE TANKS OR CONTAINERS. DO NOT CUT OR WELD ON EMPTY OR FULL DRUMS. DO NOT USE WITH ALUMINUM. READ AND FOLLOW DIRECTIONS ON LABEL. DO NOT REUSE CONTAINERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE VAPOR CONCENTRATION IS LIKELY TO EXCEED 350 PPM, AN APPROVED ORGANIC VAPOR TYPE RESPIRATOR IS ACCEPTABLE. APPROVED SELF-CONTAINED BREATHING APPARATUS OR AIR LINE RESPIRATOR, WITH FULL FACE PIECE , IS REQUIRED ABOVE 1000 PPM. Ventilation:DO NOT USE IN CLOSED OR CONFINED SPACE. OPEN DOORS AND/OR WINDOWS. USE VENTILATION TO MAINTAIN EXPOSURE LEVELS < 350 PPM Other Protective Equipment:APRON AND WORK CLOTHING TO MINIMIZE EXPOSURE. EYE WASH STATION & SAFETY SHOWER RECOMMENDED. Work Hygienic Practices:WASH THOROUGHLY AFTER USE AND BEFORE EATING, SMOKING OR USING TOILET FACILITIES. DO NOT BREATH VAPORS OR MIST. Supplemental Safety and Health CHRONIC OVEREXPOSURE TO 1,1,1 TRICHLOROETHANE HAS CAUSED LIVER TOXIC EFFECTS IN EXPERIMENTAL ANIMALS. VAPORS ARE HEAVIER THAN AIR AND WILL COLLECT IN LOW AREAS. DO NOT REMOVE OR DEFACE LABEL. DO NOT F LUSH TO SEWER. ================== Physical/Chemical Properties ================== HCC:T4 Boiling Pt:B.P. Text:165F,74C Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Vapor Pres:100 @20C Vapor Density:4.6 Spec Gravity:1.32 Evaporation Rate & Reference:0.4 (ETHER=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR, COLORLESS LIQUID, MILDLY SWEET ODOR Percent Volatiles by Volume:100 % ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ALKALIES, OXIDIZERS AND REACTIVE METALS Stability Condition to Avoid:AVOID CONTACT WITH OPEN FLAME, ELECTRIC ARCS OR OTHER HOT SURFACES WHICH CAN CAUSE THERMAL DECOMPOSITION Hazardous Decomposition Products:WHEN INVOLVED IN FIRE, 1,1,1-TRICHLOROETHANE EMITS HIGHLY TOXIC AND IRRITATING HYDROGEN CHLORIDE, CHLORINE AND PHOSGENE ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:CH3001-1;TEST FOR NO*2 Preparer's Name:DGSC-SHH/HMIS(LEVIEN) CAGE:53833 CAGE:53833 ============= Composition/Information on Ingredients ============= Ingred Name:IODINE PENTOXIDE CAS:12029-98-0 Other REC Limits:NONE RECOMMENDED Ingred Name:SELENIUM DIOXIDE (SARA III) CAS:7446-08-4 RTECS #:VS8575000 Other REC Limits:NONE RECOMMENDED OSHA PEL:0.2 MG(SE)/M3 ACGIH TLV:0.2 MG(SE)/M3; 9394 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:SULFURIC ACID (SARA III) CAS:7664-93-9 RTECS #:WS5600000 Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9394 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ARTICLE.THE HAZARDOUS INGREDIENT IS SULFURIC ACID,ADSORBED ONTO THE BEADS INSIDE OF THE GLASS TUBE.EYES:MAY CAUSE IRRITATION OR BURNS.SKIN:MAY CAUSE IRRITATION OR BURNS.INHAL:MAY CAUSE RESPIRATORY IRR ITATION.INGEST:MAY CAUSE GI TRACT IRRITATION. Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1% WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA. Effects of Overexposure:BURNS OR IRRITATION. Medical Cond Aggravated by Exposure:UNLIKELY TO AGGRIVATE EXISTING CONDITIONS. ======================= First Aid Measures ======================= First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH SOAP AND WATER.EYES:FLUSH WITH WATER FOR 15 MINUTES.INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED.INGEST:DO NOT INDUCE VOMITING. GET PROMPT QUALIFIED MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP OR VACUUM SOLIDS;PLACE IN AN APPROPRIATE CONTAINER FOR DISPOSAL. Neutralizing Agent:SODIUM CARBONATE/SODIUM BISULFITE ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,WELL-VENTILATED PLACE.KEEP CONTAINER CLOSED WHEN NOT IN USE.AVOID PHYSICAL DAMAGE TO THE TUBE. Other Precautions:DO NOT TOUCH THE BEADS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NEEDED IN NORMAL SERVICE. Ventilation:NOT NEEDED IN NORMAL SERVICE. Other Protective Equipment:NONE Work Hygienic Practices:USE REASONABLE CARE IN HANDLING THIS PRODUCT. Supplemental Safety and Health MSDS PREPARED BY SHH USING DRAEGER DISPOSAL DATA. ================== Physical/Chemical Properties ================== HCC:N1 Appearance and Odor:GLASS TUBE FILLED WITH SMALL BEADS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE IN NORMAL SERVICE. Stability Condition to Avoid:NONE IN NORMAL SERVICE.AVOID PHYSICAL DAMAGE TO TUBE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS.
1
gloves_mandatory
======================================================= Product ID: SPEEDBALL SUPER BLACK INDIA WATERPROOF INK, 3251 Cage: JO008 ======================================================= Contractor Summary ======================================================= Cage: 08287 Cage: JO008 ======================================================= Ingredients ======================================================= OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: NO Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: CONTACT WITH EYES MAY CAUSE MILD IRRITATION. NOTE:THIS PRODUCT HAS BEEN EVALUATED BY A TOXICOLOGIST ONLY AS PER INTENDED USAGE. DO NOT DEVIATE FROM INTENDED USAGE! Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. First Aid: INGEST:CALL MD IMMEDIATELY (FP N). INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) (FP N). SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD (FP N). EYES:FLUSH W/WATER FOR AT LEAST 15 M INUTES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: FLOOR MAY BE SLIPPERY; USE CARE TO AVOID FALLING. TRANSFER TO CONTAINERS FOR RECOVERY OR DISPOSAL. KEEP OUT OF MUNICIPAL SEWERS & OPEN BODIES OF WATER. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: INCINERATE AT A PERMITTED FACILITY ACCORDING TO CURRENT LOCAL, STATE & FEDERAL REGULATIONS. Handling And Storage Precautions: KEEP FROM FREEZING - PRODUCT MAY COAGULATE. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: MEDIA SUITABLE FOR SURROUNDING FIRE (FP N). Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: MATERIAL CAN SPATTER ABOVE 212F. FILM CAN BURN. ======================================================= Control Measures ======================================================= Respiratory Protection: NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). NONE REQUIRED W/ADEQUATE VENTILATION & NORMAL OPERATING CONDITIONS. Ventilation: LOCAL EXHAUST:ADEQUATE. Other Protective Equipment: ANSI APPROVED EYE WASH FOUNTAIN & DELUGE SHOWER (FP N). USE PROTECTIVE CREAM WHERE EXCESSIVE SKIN CONTACT IS LIKELY. Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: NONE SPECIFIED BY MANUFACTURER. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: >212F,>100C M.P/F.P Text: <32F,<0C Vapor Pres: 17 Vapor Density: <1 Spec Gravity: 1.1 (H*2O=1) Solubility in Water: DILUTABLE Appearance and Odor: BLACK, LOW VISCOSITY W/VERY LITTLE ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: ONSET OF DECOMPOSITION IS 350F. Hazardous Decomposition Products: OXIDES OF CARBON & NITROGEN. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: SPEEDBALL SUPER BLACK INDIA WATERPROOF INK, 3251 Cage: JO008 Assigned IND: Y Company Name: HUNT MFR CO Street: SPEEDBALL RD Zipcode: 28677 Label Required IND: Y Date Of Label Review: 07/09/1998 Status Code: C Label Date: 07/09/1998 Origination Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: None Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE:CONTACT WITH EYES MAY CAUSE MILD IRRITATION. CHRONIC:NONE LISTED BY MANUFACTURER. NOTE:THIS PRODUCT HAS BEEN EVALUATED BY A TOXICOLOGIST ONLY AS PER INTENDED USAGE. DO NOT DEVIATE FROM INTENDED USAGE! =======================================================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:ACS GRADE CAGE:3D869 CAGE:3D869 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM HYDROXIDE (SARA III) CAS:1310-73-2 RTECS #:WB4900000 = Wt:97. OSHA PEL:2 MG/M3 ACGIH TLV:C 2 MG/M3; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Effects of Overexposure:CORROSIVE TO SKIN. CAUSES SEVERE & RAPID BURNS ======================= First Aid Measures ======================= First Aid:REMOVE FROM SKIN AS SOON AS POSSIBLE.WASH AFFECTED AREA WITH WATER FOR AT LEAST 15 MIN. SEEK MEDICAL ATTENTION AT ONCE ===================== Fire Fighting Measures ===================== Fire Fighting Procedures:AVOID WATER UNLESS FLOODING QUANTITIES ARE AVAILABLE Unusual Fire/Explosion Hazard:REACTS WITH WATER TO CREAT HEAT. REACTION WITH SOME METALS WILL CREAT HYDROGEN ================== Accidental Release Measures ================== Spill Release Procedures:SHOVEL UP SPILLAGE. FLOOD WITH WATER. CAN BE NEUTRALIZED WITH ACETIC ACID ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY PLACE. KEEP CONTAINERS CLOSED. KEEP AWAY FROM ACIDS,METALS, EXPLOSIVES. ORGANIC PEROXIDES AND EASILY IGNITIBLE MATERIALS ============= Exposure Controls/Personal Protection ============= Respiratory Protection:US BUREAU OF MINES APPROVED RESPIRATOR Other Protective Equipment:RUBBER PROTECTIVE CLOTHING Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:B1 Spec Gravity:2.13 Solubility in Water:COMPLETE Appearance and Odor:WHITE, DELIQUESCENT BEADS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALUMINUM, MAGNESIUM, ZINC Stability Condition to Avoid:KEEP AWAY FROM FLAMMABLES, ACIDS,METALS & PEROXIDES
1
gloves_mandatory
===================== Product Identification ===================== Product ID:GRAM CRYSTAL VIOLET SOLUTION, 12293, 12297, Preparer's Name:DALE M. OREM CAGE:05545 CAGE:05545 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYL ALCOHOL (ETHANOL) CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: 12% Other REC Limits:NONE SPECIFIED OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9192 Ingred Name:CRYSTAL VIOLET CAS:548-62-9 RTECS #:BO9000000 Other REC Limits:NONE SPECIFIED Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CAN CAUSE BURNING AND STINGING SENSATION TO THE EYES. CAN CAUSE STUPOR AND SLEEPINESS IF INHALED. WHEN INGESTED IT INITIALLY ACTS AS A STIMULANT THEN MENTAL EXCITEMENT AND IMPAIRED VISION. CAN DEFAT A ND CAUSE DERMATITIS TO THE SKIN. Explanation of Carcinogenicity:NONE OF THE COMPOUNDS IN THIS PRODUCT IS LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/WATER 15 MIN, HOLD LIDS OPEN. SKIN:REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. WASH WITH SOAP & WATER. INHALED:REMOVE TO FRESH AIR. RESTORE BREATHING AS NEEDED. INGESTED:WHEN EX CESSIVE, GIVE 2 LARGE GLASSES OF MILK ORWATER AND INDUCE VOMITING. (NOTHING BY MOUTH IF UNCONSCIOUS.) GET IMMEDIATE MEDICAL CARE. IF ANY IRRITATION PERSISTS OR IS SEVERE, SEE A DOCTOR. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:PRODUCT IS NON FLAMMABLE. EXTINGUISH FIRE WITH MEDIA APPROPRIATE FOR SOURCE OF FIRE. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB SPILLS WITH PAPER TOWELS. DISPOSE OF WITH NOMAL LAB TRASH. Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:SUPPLIER DID NOT INCLUDE THIS FIELD OR LEFT IT BLANK. Other Precautions:SUPPLIER DID NOT INCLUDE THIS FIELD OR LEFT IT BLANK. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED UNDER NORMAL PRODUCT USAGE. Ventilation:GENERAL AND/OR LOCAL TO MEET TLV REQUIREMENTS. Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER. Work Hygienic Practices:SUPPLIER DID NOT INCLUDE THIS FIELD OR LEFT IT BLANK. HMIS:PRACTICE GOOD CHEMICAL HYGIENE. AVOID CONTACT. Supplemental Safety and Health MSDS RECEIVED FROM NAVY (FOCAL POINT N). NAVY IDENTIFIED NSN. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:=78.C, 172.4F B.P. Text:172F;78C Vapor Pres:44 Vapor Density:1.59 Spec Gravity:0.7893 Evaporation Rate & Reference:1.4 (BUTYL ACETATE=1) Solubility in Water:COMPLETE Appearance and Odor:DARK PURPLE SOLUTION WITH AROMATIC ODOR. *NOTE: INFO FOR ETHANOL NOT MIXTURE.* ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NOT DETERMINED Stability Condition to Avoid:NOT DETERMINED Hazardous Decomposition Products:NOT DETERMINED ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS. WASTE MATERIAL CAN BE DISPOSED OF WITH NORMAL LAB TRASH.
0
gloves_not_mandatory
===================== Product Identification ===================== Product ID:SINCO SATIN II, TINTABLE WHITE, 1498 Preparer's Name:J G PRINZ CAGE:0U0K0 CAGE:0U0K0 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOL, 2-(2-BUTOXYETHOXY)-; (2-(2-BUTOXYETHOXY) ETHANOL) VP:1.0 @ 68F CAS:112-34-5 RTECS #:KJ9100000 Fraction by Wt: 4% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:VOLATILE ORGANIC COMPOUND (COATING):1.29 LB/GL (155 G/L) RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:MAY CAUSE IRRITATION TO SKIN, EYES AND INTESTINAL SYSTEM. CHRONIC:NONE KNOWN. SIGNS & SYMPS OF OVEREXP:INHAL:ADVERSE HLTH EFTS FROM VAPS/SPRAY MISTS IN POORLY VENT AREAS MAY INCLUDE IRRIT OF MUC OUS MEMBRANES OF NOSE, THROAT & RESP TRACT & SYMPS OF HDCH & NAUS. EYES:INDIRECT CONT MAY CAUSE IRRIT. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZS:SKIN:PROLONGED AND REPEATED CONTACT WITH PRODUCT MAY CAUSE IRRITATION. SKIN ABSORPTION:REDNESS, DRYING OF SKIN, OR OTHER SIGNS OF IRRITATION OR CONTACT DERMATITIS. INGEST:CAN CAUSE GASTROINT ESTINAL IRRITATION, NAUSEA, VOMITING AND DIARRHEA. Medical Cond Aggravated by Exposure:NONE ======================= First Aid Measures ======================= First Aid:SKIN:CLEANSE THOROUGHLY WITH SOAP AND WATER. REMOVE ALL CONTAMINATED CLOTHING. EYES:FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. TAKE TO MD FOR MEDICAL ATTENTION. INHAL:REMOV E TO FRESH AIR. INGEST:DRINK 1-2 GLASSES OF WATER TO DILUTE. DO NOT INDUCE VOMITING. CONSULT MD OR POISON CONTROL CENTER IMMEDIATELY. TREAT SYMPTOMATICALLY. ===================== Fire Fighting Measures ===================== Lower Limits:0.9% Upper Limits:5.9% Extinguishing Media:FOAM, CO*2, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . THIS IS A WATER-BASED COATING. WILL NOT SUPPORT COMBUSTION. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS EXPOSED TO HIGH TEMPERATURES MAY EXPLODE OR BURST DUE TO BUILD UP OF STEAM PRESSURE. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE, CONTAIN OR ABSORB WITH INERT MATERIAL (E.G., SAND, VERMICULATE, ETC.,). TRANSFER TO CONTAINERS FOR RECOVERY OR DISPOSAL. PREVENT RUNOFF INTO SEWERS, STREAMS, OR OTHER BODIES OF WATER. SEE INGRED IENTS AND HEALTH HAZARDS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT EXPOSE TO EXTREMES IN TEMPERATURES. AVOID EXPOSURE TO HIGH TEMPERATURES. DO NOT ALLOW TO FREEZE. Other Precautions:DO NOT TAKE INTERNALLY. AVOID PROLONGED OR REPEATED EXPOSURE TO LEVELS ABOVE TLV. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY REQUIRED. IF TLV IS EXCEEDED USE A NIOSH/MSHA APPROVED ORGANIC VAPOR AND MIST PROTECTION. Ventilation:USE ADEQUATE MECHANICAL (GENERAL AND/OR LOCAL) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV. Other Protective Equipment:WEAR IMPERVIOUS CLOTHING. FURNISH EYEWASH STATIONS. Work Hygienic Practices:WASH HANDS BEFORE EATING OR USING RESTROOMS. REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Vapor Pres:SEE INGS Vapor Density:LTR/AIR Spec Gravity:1.3 (H*2O=1) Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:COMPLETELY Appearance and Odor:TYPICAL FOR WATER BASED LATEX COATING. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE Hazardous Decomposition Products:MAY FORM TOXIC MATERIALS, CARBON DIOXIDE, CARBON MONOXIDE, ETC. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL IN ACCORDANCE WITH ALL LOCAL, STATE OR FEDERAL REGULATIONS.
1
gloves_mandatory
======================================================= NIIN: 00-242-4750 Product ID: KEROSENE (NO. 1 FUEL OIL) Cage: LLEPE Box: 308 ======================================================= Contractor Summary ======================================================= Cage: LLEPE Box: 308 Cage: 0XBZ8 Box: UNKNOW ======================================================= Item Description Information ======================================================= Item Name: KEROSINE ======================================================= Ingredients ======================================================= Cas: 8008-20-6 RTECS #: OA5500000 % Wt: 100 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ ----------------------------- ASPIR OF LIGHT HYDROCARBON LIQ WHICH ----------------------------- CONTAM CLTHG & SHOES. WASH W/SOAP & WATER. ----------------------------- ATTN. ----------------------------- STAY UPWIND & OUT OF LOW AREAS. REMOVE ----------------------------- RESIDUE W/ABSORB MATL. SML SPILLS: SOAK ----------------------------- PROD FOULING TO SHORELINES. MAY BE ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: NO Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: EYES: CAUSES IRRIT. INHAL: CAUSES IRRIT OF MUC MEMB. MAY CAUSE PNEUMIT. IF TAKEN INTO LUNGS, MAY CAUSE COUGHING, DISTRESS & RAPIDLY DEVELOPING PULMONARY EDEMA. MAY ALSO CAUSE DIZZ & UNCON DUE T O ASPHYXIATION & CNS DEPRESS. SKIN: IRRIT & MAY CAUSE SMARTING & REDDENING. INGEST: LIQ IRRIT TO (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: HLTH HAZ: STOMACH, MOUTH & THROAT, & MAY CAUSE NAUS, VOMIT & DROW. CHRONIC: PRLNG/RPTD SKIN CONT MAY CAUSE DEFAT & DRYING OF SKIN. CHRONIC INHAL MAY LEAD TO PNEUMIT & LETHARGY. VAP CAUSES IRRIT OF EYE S, NOSE, & LUNGS, & MAY ALSO CAUSE CNS DEPRESS. Medical Cond Aggravated By Exposure: PREEXISTING EYE, SKIN AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. First Aid: EYES: HOLD EYELIDS OPEN & FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN. GET MD ATTN. INGEST: DO NOT INDUCE VOMIT! IF PROD IS SWALLOWED & VICTIM IS CONSCIOUS, HAVE VICTIM DRINK MILK/WATER. GET MD ATTN. INGEST OF PROD/SUBSEQUENT VOMIT CAN RSLT IN ASPIR OF LIGHT HYDROCARBON LIQ WHICH CAN CAUSE PNEUMIT. INHAL: MOVE TO FRESH AIR. IF BRTHG HAS STOPPED, GIVE ARTF RESP. IF BRTHG DFCLT, GIVE OXYGEN. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: NOTIFY APPROP FEDERAL, STATE & LOC AGENCIES. NO SMKNG, NO FLARES. LGE SPILLS: ISOLATE HAZ AREA & DENY ENTRY TO UNNEC PERS. WEAR RESP & PROT CLTHG. STOP DISCHARGE IF POSS. KEEP FROM ENTERING SURF WATER S & WATER INTAKES. DISPERSE VAPS W/WATER Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: PROD (AS PRESENTLY CONSTITUTED) HAS RCRA CHARACT OF IGNITABILITY & IF DISCARDED IN ITS PURCHASED FORM, WOULD HAVE EPA HAZ WASTE NO. D001. REFER TO LATEST EPA, STATE, LOCAL & FEDERAL REGULATIONS REGARD ING PROPER DISPOSAL. Handling And Storage Precautions: STABLE DURING TRANSPORT. AMBIENT STORAGE TEMPERATURE. NOT REACTIVE WITH WATER. DO NOT HEAT OR DRILL ON/OR NEAR CONTAINER. Other Precautions: AVOID HEAT, FLAME, STRONG OXIDIZERS & OTHER IGNIT SOURCES. NO SMKNG! HARMFUL/FATAL IF SWALLOWED. DO NOT SIPHON. FOR USE AS FUEL ONLY. REMOVE CONTAM CLTHG & SHOES. WASH HANDS BEFORE EATING/DRINKING. EM PTY CONTRS MAY CONTAIN EXPLO VAPS. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: CC Flash Point Text: 100F,38C Lower Limits: 0.7% Upper Limits: 0.5% Extinguishing Media: DRY CHEMICAL, FOAM, WATER SPRAY, HALON/CARBON DIOXIDE FOR SMALL FIRES. EXTINGUISH LARGE FIRES W/WATER SPRAY, FOG/FOAM. Fire Fighting Procedures: CLEAR AREA OF UNPROT PERS & ISOLATE. ELIMINATE ALL IGNIT SOURCES. COOL EXPOSED CONTRS W/WATER. STOP LEAK IF POSS. USE POS PRESS NIOSH/MSHA APPRVD SCBA (SUP DAT) Unusual Fire/Explosion Hazard: VAP MAY EXPLODE IF IGNITED IN ENCLOSED AREA. DO NOT WELD, HEAT/DRILL ON/NEAR CONTR. VAPS ARE HVR/AIR & ACCUMULATE IN LOW AREAS. VAP FORMS EXPLO MIX W/ (SUP DAT) ======================================================= Control Measures ======================================================= Respiratory Protection: USE A POSITIVE PRESSURE NIOSH/MSHA APPROVED SCBA UNDER CONDITIONS OF POTENTIALLY HIGH CONCENTRATIONS. Ventilation: USE EXPLOSION-PROOF VENTILATION TO PREVENT VAPOR ACCUMULATION. Other Protective Equipment: WEAR PROTECTIVE CLOTHING TO MINIMIZE SKIN CONTACT WITH PRODUCT. Work Hygienic Practices: LAUNDER OR DRY CLEAN CLOTHING WHEN SOILED. WASH HANDS WITH SOAP BEFORE EATING, DRINKING OR SMOKING. Supplemental Safety and Health: FIRE FIGHT PROC: & FULL BUNKER GEAR. USE WATER SPRAY TO KNOCK DOWN VAP TO PROT PERS ATTEMPTING TO STOP FLOW & TO COOL EXPOSED CONTRS. WITHDRAW IMMED IN CASE OF RISING SOUND FROM VENTING DEVICE/ANY DIS COLORATION OF TANK DUE TO FIRE. EXPLO HAZ: AIR. PROD WILL FLOAT ON WATER & MAY BECOME REIGNITED ON SURF. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: >392F,>200C Vapor Pres: <0.2 Vapor Density: 5.0 Spec Gravity: 0.81 (H*2O=1) Solubility in Water: INSOLUBLE Appearance and Odor: COLORLESS TO LIGHT STRAW-COLORED WATERY LIQ W/A CHARACTERISTIC HYDROCARBON ODOR Percent Volatiles by Volume: 99 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: AVOID HEAT, FLAMES, FLARES, SPARKS. PREVENT VAPOR ACCUMULATION BY USING EXPLOSION-PROOF VENTILATION. Materials To Avoid: AVOID STRONG OXIDIZERS. Hazardous Decomposition Products: PRODUCT FORMS CARBON MONOXIDE AND CARBON DIOXIDE DURING COMBUSTION. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: KEROSENE (NO. 1 FUEL OIL) Cage: LLEPE Company Name: LL & E PETROLEUM MARKETING INC Street: MOBILE REFINERY PO Box: 308 Zipcode: 36571 Label Required IND: Y Date Of Label Review: 04/10/1995 Status Code: C Label Date: 04/10/1995 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Moderate Fire Hazard: Moderate Reactivity Hazard: None Hazard And Precautions: COMBUSTIBLE LIQUID. ACUTE: EYES: CAUSES IRRIT. INHAL: CAUSES IRRIT OF MUCOUS MEMBRANES. MAY CAUSE PNEUMONITIS. IF TAKEN INTO LUNGS, MAY CAUSE COUGHING, DISTRESS & RAPIDLY DEVELOPING PULMONARY EDEMA. M AY ALSO CAUSE DIZZINESS & UNCONSCIOUSNESS DUE TO ASPHYXIATION & CENTRAL NERVOUS SYSTEM DEPRESSION. SKIN: IRRIT & MAY CAUSE SMARTING & REDDENING. INGEST: LIQUID IRRIT TO STOMACH, MOUTH & THROAT, & MAY CAUSE NAUSEA, VOMITING & DROWSINESS. CHRONIC: PROLONGED/REPEATED SKIN CONTACT MAY CAUSE DEFATTING & DRYING OF SKIN. CHRONIC INHALATION MAY LEAD TO PNEUMONITIS & LETHARGY. VAPOR CAUSES IRRIT OF EYES, N OSE, & LUNGS, & MAY ALSO CAUSE CNS DEPRESSION. =======================================================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:ACETYLENE CAGE:36346 CAGE:7D711 CAGE:36346 ============= Composition/Information on Ingredients ============= Ingred Name:ACETYLENE CAS:74-86-2 Fraction by Wt: 100% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SOME TOXIC GASES ASSOCIATED WITH WELDING AND RELATED PROCESSES MAY CAUSE PULMONARY EDEMA, ASPHYXIATION, AND DEATH. Effects of Overexposure:INHALATION: ASPHYXIATION. MODERATE CONCENTRATIONS OF VAPOR MAY CAUSE HEADACHE, DROWSINESS, DIZZINESS, NAUSEA, VOMITING, EXCITATION, EXCESS SALIVATION, AND UNCONSCIOUSNESS. LIQUID MAY CAUSE FROSTB ITE. ======================= First Aid Measures ======================= First Aid:SKIN: FLUSH FROSTBITE AREA WITH WARM WATER, NOT HOT. IN CASE OF MASSIVE EXPOSUREREMOVE CLOTHING WHILE SHOWERING WITH WARM WATER. CALL A PHYSICIAN. INHALATION: REMOVE TO FRESH AIR. IF BREATHING HAS ST OPPED GIVE CPR AND SUPPLEMENTAL OXYGEN;CALL A PHYSICIAN. EYES: IMMEDIATELY FLUSH EYES THOROUGHLY WITH WATER FOR AT LEAST 15 MIN. SEE OPTHAMOLOGIST. IF SWALLOWED, INDUCE VOMITING. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:-17C/0F Autoignition Temp:Autoignition Temp Text:*BELOW Lower Limits:2.3% Upper Limits:100% Extinguishing Media:EVACUATE AREA. IMMEDIATELY COOL CONTAINERS WITH WATER SPRAY.REMOVE IGNITION SOURCES. ALLOW FIRE TO BURN OUT. Fire Fighting Procedures:IF FLAMES ARE ACCIDENTALLY EXTINGUISHED, EXPLOSIVE RE-IGNITION MAY OCCUR. STOP FLOW OF GAS IF WITHOUT RISK WHILE CONTINUING COOLING WATER SPRAY. Unusual Fire/Explosion Hazard:FORMS EXPLOSIVE MIXTURES WITH AIR AND OXIDIZING AGENTS. CONTAINER MAY RUPTURE DUE TO HEAT OF FIRE. DO NOT EXTINGUISH FLAMES DUE TO EXPLOSIVE RE-IGNITION. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. USE PROTECTIVE EQUIP. REMOVE ALL SOURCES OF IGNITION & SHUT OFF LEAK IF W/O RISK. VENTILATE AREA OF LEAK OR MOVE LEAKING CONTAINER TO WELL-VENTILATED AREA. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE/USE IN COOL, DRY, WELL VENTILATED AREA.STOREAWAY FROM SOURCES OF HEAT/IGNITION. STORE FIRMLY SECURED AND UPRIGHT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE RESPIRABLE FUME RESPIRATOR OR AIR SUPPLIED RESPIRATOR WHEN WORKING IN CONFINED SPACE OR WHERE LOCAL EXHAUST OR VENTILATION DOES NOT KEEP EXPOSURE BELOW TLV. Ventilation:LOCAL EXHAUST- USE ENOUGH VENTILATION TO KEEP THE FUMES AND GASES BELOW THE TLV'S IN THE WORKERS BREATHING ZONE. Other Protective Equipment:AS NEEDED, WEAR HAND, HEAD AND BODY PROTECTION. Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Vapor Pres:635 PSIG Vapor Density:0.91 Solubility in Water:SLIGHT Appearance and Odor:COLORLESS GAS AT NORMAL TEMPERATURE AND PRESSURE; GARLIC-LIKE ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:NO COPPER, SILVER, MERCURY, OR THEIR ALLOYS, OXIDIZING AGENTS, ACIDS, HALOGENS, MOISTURE. Stability Condition to Avoid:STABLE AS SHIPPED. AVOID PRESSURES ABOVE 15 PSIG. Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE. OTHER COMPOSITION PRO- DUCTS ORIGINATE FROM VOLITIZATION, REACTION, & OXIDATION. Conditions to Avoid Polymerization:ELEVATED TEMPERATURE AND PRESSURE AND/OR THE PRESENCE OF A CATALYST. ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. KEEP PERSONNEL AWAY. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER OR LINER INAN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE WITH STATE, FEDERAL & LOCAL REGULATIONS
1
gloves_mandatory
===================== Product Identification ===================== Product ID:SUPER KINCOTE CLEAR LACQUER, 76C-F07 CAGE:GO268 CAGE:33629 CAGE:GO268 ============= Composition/Information on Ingredients ============= Ingred Name:XYLENE; (XYLOL) (SARA 313) (CERCLA). VP:5.1 CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 14% OSHA PEL:100 PPM ACGIH TLV:100 PPM;150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ACETIC ACID, ISOBUTYL ESTER; (ISOBUTYL ACETATE) (CERCLA). VP:12.8. CAS:110-19-0 RTECS #:AI4025000 Fraction by Wt: 38% OSHA PEL:150 PPM ACGIH TLV:150 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER; (PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE) (PM ACETATE). VP:3.7. CAS:108-65-6 RTECS #:AI8925000 Fraction by Wt: 3.4% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ISOPROPYL ALCOHOL; (ISOPROPANOL) (SARA 313). VP:33. CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 7.7% OSHA PEL:400 PPM ACGIH TLV:400 PPM;500 STEL ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SEVERE EYE IRRITATION. AVOID INHALING SOLVENT VAPORS. EXCESSIVE INHALATION MAY CAUSE HEADACHES, DIZZINESS AND/OR NAUSEA. EXCESSIVE SOLVENT VAPOR LEVELS OVER LONG PERIODS OF TIME IN AIR WHERE SOLVENT P AINTS ARE APPLIED MAY LEAD TO NERVE DAMAGE. DEPENDING UPON CONCENTRATION LEVELS OF VAPORS AND EXPOSURE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:DURATIONS. NOTICE:REPORTS HAVE ASSOC RPTD & PRLNG OCCUP OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG. INTENTIONAL MISUSE BY DELIB CONC & INHALING CONTENTS MAY BE HARMFUL/FATAL. SKIN ABSORPTIO N MAY POTNTLY CONTRIBUTE TO OVERALL EXPOS TO PM ACETATE. APPROP MEASURES SHOULD BE TAKEN TO PVNT ABSORPTION SO THAT TLV IS ALWAYS MET. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:IMMEDIATELY FLUSH W/POTABLE WATER FOR A MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM MD. SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . IN ALL CASES, CONTACT MD FOR PROPER MEDICAL ATTENTION & TAKE THIS INFORMATION TO MD. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:53.0F,11.7C Lower Limits:1% Extinguishing Media:FOAM, CARBON DIOXIDE (CO*2), DRY CHEMICAL OR WATER FOG SPRAY. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . STREAMS OF WATER ARE NOT ORDINARILY EFFECTIVE. SOLID HOSE STREAMS TEND TO SCATTER LIQUID & SPREAD FIRE. WATER FOAMS, WATER SPRAYS OR FOG NOZ ZLES COOL BURNING SURFACES & EXCLUDE AIR. Unusual Fire/Explosion Hazard:FLAMMABILITY CLASS: IB. VAPORS MAY FORM EXPLOSIVE MIXTURES W/AIR. ================== Accidental Release Measures ================== Spill Release Procedures:COLLECT IN A RETAINING AREA OR CONTAINER, THEN TRANSFER TO A CLOSED CONTAINER. AVOID EXPOSURE TO HEAT, SPARKS, FIRE OR OPEN FLAME. AVOID HOT METAL SURFACES. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID ANY DIRECT INHAL OF SPRAY MIST IF THIS PROD IS SPRAYED. MAY ADHERE TO SKIN. TRAIN & EDUCATE EMPLOYEES IN SAFE USE OF PROD. USE ONLY W/ADEQ VENT. Other Precautions:KEEP AWAY FROM HEAT, SPKS, FIRE & OPEN FLAME. AVOID PRLNG/RPTD CONT W/SKIN. CLEAN ALL CNTNR OPENINGS & KEEP TIGHTLY SEALED. STORE UPRIGHT & SECURE IN COOL, DRY, APPRVD AREA (40-80F) AVOID INHAL OF DRYOVERSPRAY. EMPTIED CNTNRS MAY RETAIN HAZ RESIDUE & EXPLOS VAPS. KEEP AWAY FROM HEAT, SPKS & FLAMES.DO NOT CUT,(SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH APPROVED SCBA IS REQUIRED, UNLESS PRIOR WORKER MONITORING SPECIFICALLY FOR SOLVENT CONCENTRATION LEVELS HAS INDICATED THAT SAFE EXPOSURE LEVELS EXIST IN THE OPERATION. Ventilation:ADEQ VENT IS NEC WHEN SPRAYING/MIXING & EXHST W/PROPER AIRFLOW IS ALWAYS REC. ALL ELEC EQUIP MUST BE EXPLOSION-PROOF. FACESHIELD . Other Protective Equipment:ANSI APPROVED EYE WASH FOUNTAIN & DELUGE SHOWER . LONG SLEEVES & HATS ARE RECOMMENDED. PROTECTIVE CREAMS MAY Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health OTHER PRECAUTIONS: PUNCTURE OR WELD ON OR NEAR EMPTIED CONTAINERS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>180F,>82C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:0.97 Evaporation Rate & Reference:1.17 X N-BUTYL ACETATE Appearance and Odor:CLEAR HEAVY LIQUID. Percent Volatiles by Volume:71.7 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:AVOID HEAT, SPARKS, FIRE OR OPEN FLAME. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY YIELD CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . MATERIAL SHOULD BE CONSIDERED A HAZARDOUS WASTE & SUBJECT TO HAZARDOUS WASTE REGULATIONS FOR DISPOSAL.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:SCOTCH SPRAY MOUNT ARTIST'S ADHESIVE CAGE:76381 CAGE:04963 CAGE:76381 ============= Composition/Information on Ingredients ============= Ingred Name:ACRYLIC RESIN (SEE SUPPLEMENTAL FOR INGREDIENTS) Fraction by Wt: <8% Ingred Name:TERPENE RESIN BLEND Fraction by Wt: <8% Ingred Name:ISOBUTANE CAS:75-28-5 RTECS #:TZ4300000 Fraction by Wt: 37.0% Ingred Name:METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III) CAS:71-55-6 RTECS #:KJ2975000 Fraction by Wt: 55.0% OSHA PEL:350 PPM/450 STEL ACGIH TLV:350 PPM/450STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ozone Depleting Chemical:1 Ingred Name:1,4-DIOXANE (DIETHYLENE DIOXIDE) (SARA III) CAS:123-91-1 RTECS #:JG8225000 OSHA PEL:S, 100 PPM ACGIH TLV:S, 25 PPM; 9293 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== Effects of Overexposure:DIZZINESS/NAUSEA/HEADACHE/UNCONSCIOUSNESS/DEATH. EYE/SKIN CONTACT: MAY CAUSE IRRITATION. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH W/WATER FOR AT LEAST 15 MINUTES. SKIN: WASH WITH SOAP/WATER. INHALATION: MOVE VICTIM TO FRESH AIR. RESTORE OR SUPPORT BREATHING AS NECESSARY. IF SWALLOWED: DON'T INDUCE VOMITING. DRINK 2 GL ASSES MILK OR WATER. CALL A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:-50F Extinguishing Media:CO2, FOAM, DRY CHEMICAL Fire Fighting Procedures:SCBA WHEN FIGHTING FIRES INVOLVING THIS MATERIAL. Unusual Fire/Explosion Hazard:FLAMMABLE. OVERHEATED, CLOSED CONTAINERS ADJACENT TO FIRE COULD EXPLODE DUE TO PRESSURE BUILDUP. ================== Accidental Release Measures ================== Spill Release Procedures:IF ANY CANS RUPTURE, EXTINGUISH ALL IGNITION SOURCES/VENTILATE THE AREA. USE ABSORBE MATERIAL AS NEEDED IN CLEANUP PROCEDURE. PLACE CAN IN AN APPROVED U.S. PT. OF TRANSPORTATION CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID PROLONGED BREATHING OF VAPORS AND OVERSPRAY DURING APPLICATION. AVOID CONTACT WITH EYE/SN. Other Precautions:AVOID VAPOR CONTACT W/OPEN FLAMES, WELDING ARCS OR HIGH TEMP SOURCES WHICH MIGHT CAUSE VAPOR DECOMPOSITION TO PRODUCE HARMFUGASES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE ONLY IN AREAS ADEQUATELY VENTILATED Ventilation:PROVIDE LOCAL EXHAUST VENTILATION TO KEEP BELOW TLV/LEL Supplemental Safety and Health MSDS DATE: 16 DEC 1985. ALSO CONTAINS: PLASTICIZER (1000264PL) <8.0%. ================== Physical/Chemical Properties ================== Vapor Density:4.6 Evaporation Rate & Reference:(ETHER = 1): .4 Solubility in Water:NIL Appearance and Odor:TRANSLUCENT LIQUID: SWEET ODOR. Percent Volatiles by Volume:92% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES DON'T PUNCTURE OR INCINERATE Stability Condition to Avoid:DON'T STORE AT TEMPERATURES ABOVE 120F. Hazardous Decomposition Products:HCL/CHLORINE/PHOSGENE WHEN SUBJECTED TO EXCESS. HEAT/FLAME ==================== Disposal Considerations ==================== Waste Disposal Methods:DON'T PUNCTURE IN INCINERATE CAN IN HOUSEHOLD INCINERATOR. INCINERATE PROPERLY IN ACCORDANCE W/APPLICABLE REGULATIONS AS THE PRODUCT CONTAINS HALOGENS. EMPTY CONTAINERS MAY BE DISPOSED IN A SANITARY L ANDFILL IN ACCORDANCE W/LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:ENGINE PAINTS-1 1611 UNIVERSAL GRAY CAGE:54626 CAGE:54626 CAGE:09800 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE (DIMETHYLMETHANE)*97-1* CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 20% Other REC Limits:1800 MG/CUM OSHA PEL:1000 PPM ACGIH TLV:SIMPLE ASPHYXIANT Ingred Name:HEXANE, N-HEXANE *97-1* CAS:110-54-3 RTECS #:MN9275000 Fraction by Wt: 12% Other REC Limits:50 PPM OSHA PEL:1800 MG/CUM ACGIH TLV:176 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:2-METHYL PENTANE, ISOHEXANE *97-1* CAS:107-83-5 RTECS #:SA2995000 Fraction by Wt: 8% ACGIH TLV:500 PPM Ingred Name:LIGHT ALIPHATIC NAPHTHA, VM & P NAPHTHA, LACOLENE *97-1* CAS:64742-89-8 Fraction by Wt: 16% OSHA PEL:300 PPM ACGIH TLV:300 PPM Ingred Name:ACETONE; DIMETHYL KETONE; 2-PROPANONE *97-1* CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 20% OSHA PEL:2400 MG/CUM ACGIH TLV:750 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PROPYLENEGLYCOL MONOMETHYL ETHER ACETATE, 1-METHOXY-2-PROPANOL ACETATE CAS:108-65-6 RTECS #:AI8925000 Fraction by Wt: 8% Ingred Name:TITANIUM DIOXIDE, TITANIUM OXIDE (SUSPECTED ANIMAL CARCINOGEN, IARC GROUP 3)*97-1* CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 3% OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM (DUST) ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:IRRITATION OF EYES/SKIN/RESPIRATORY SYSTEM. NERVOUS SYSTEM DEPRESSION/DEATH. PROLONGED/REPEATED OVEREXPOSURE TO HEXANE MAY CAUSE DAMAGE TO NERVE TISSUE OF THE ARMS/LEGS. PROLONGED OVEREXPOSURE TO SOLV ENTS MAY CAUSE ADVERSE EFFECTS TO THE LIVER, URINARY, BLOOD-FORMING, CARDIOVASCULAR & REPRODUCTIVE SYSTEMS. (SEE SUPP) Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, UNCONSCIOUSNESS, HEADACHE, DIZZINESS, NAUSEA, LOSS OF COORDINATION, REDNESS, ITCHING, BURNING, MUSCULAR WEAKNESS, LOSS OF SENSATION ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM & QUIET. SKIN: WASH THOROUGHLY W/SOAP & WATER. EYES: FLUSH W/LARGE AMOUNTS OF WATER FOR 15 MINS. INGESTION: NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. DON'T INDUCE VOMITING. GIVE SEVERAL GLASSES OF WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:<0F Lower Limits:0.9 Upper Limits:13.1 Extinguishing Media:CO2, DRY CHEMICAL, FOAM Fire Fighting Procedures:USE FULL PROTECTIVE EQUIPMENT W/SCBA. WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERRED. WATER MAY BE USED TO COOL CLOSED CONTAINERS. Unusual Fire/Explosion Hazard:ISOLATE FROM HEAT/IGNITION SOURCES. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. APPLICATION TO HOT SURFACES REQUIRES SPECIAL PRECAUTIONS. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE & REMOVE W/INERT ABSORBENT. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP FROM IGNITION SOURCES. USE APPROVED BONDING/GROUNDING PROCEDURES. DURING USE/UNTIL ALL VAPORS ARE GONE, VENTILATE AREA. DON'T TAKE INTERNALLY. Other Precautions:DON'T PUNCTURE, INCINERATE/EXPOSE TO TEMP >120F. HEAT SOURCES MAY CAUSE CONTAINER TO BURST. VAPORS WILL ACCUMULATE READILY & IGNITE EXPLOSIVELY. KEEP OUT OF REACH OF CHILDREN. AVOID BREATHING VAPOR/SP RAY MIST & CONTACT W/SKIN & EYES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURE CAN'T BE CONTROLLED BELOW APPLICABLE LIMITS BY VENTILATION, WEAR A PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA. WHEN SANDING/ABRADING DRIED FILM, WEAR A DUS T/MIST RESPIRATOR NIOSH/MSHA APPROVED. Ventilation:LOCAL EXHAUST: PREFERRED. GENERAL EXHAUST ACCEPTABLE IF EXPOSURE IS MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS. Other Protective Equipment:SAFETY SPECTACLES W/UNPERFORATED Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH HANDS AFTER USING. DO NOT SMOKE. Supplemental Safety and Health REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSE PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE CONTENTS CAN BE HARMFUL/FATAL. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:<0-325F Vapor Density:>1 VOC Grams/Liter:3.93 Evaporation Rate & Reference:FASTER THAN ETHER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:HEAT, ELECTRICAL EQUIPMENT, SPARKS, OPEN FLAMES, HOT SURFACES & OTHER IGNITION SOURCES Hazardous Decomposition Products:BY FIRE: CO2, CO ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE THE APPLICABLE EPA HAZARDOUS WASTE NUMBERS. DON'T INCINERATE. DEPRESSURIZE CONTAINER. DISPOSE OF IAW/LOCAL, STATE & FEDERAL REGULATIONS.
0
gloves_not_mandatory
===================== Product Identification ===================== Product ID:AWS A5.10 (SEE SUPPLEMENTAL) CAGE:NO119 CAGE:0AZS7 CAGE:NO119 ============= Composition/Information on Ingredients ============= Ingred Name:ALUMINUM (SARA III) CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: BALANCE Other REC Limits:NONE RECOMMENDED OSHA PEL:15MG/M3 DUST/5 FUME ACGIH TLV:10MG/M3 DUST; 9394 Ingred Name:COPPER (SARA III) CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: 3-7% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.1MG/M3 FUME/1 DUST ACGIH TLV:0.2 MG/M3 FUME; 9394 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:MAGNESIUM CAS:7439-95-4 RTECS #:OM2100000 Fraction by Wt: 2-6% Other REC Limits:NONE RECOMMENDED Ingred Name:BERYLLIUM (SARA III) 0.04-0.07%. CAS:7440-41-7 RTECS #:DS1750000 Fraction by Wt: SEE ING Other REC Limits:NONE RECOMMENDED OSHA PEL:0.002 MG/M3; Z-2 ACGIH TLV:0.002MG/M3, A2; 9394 Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 Fraction by Wt: 3-13% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9394 Ingred Name:CHROMIUM (SARA III) CAS:7440-47-3 RTECS #:GB4200000 Fraction by Wt: 0.05-35% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG/M3 ACGIH TLV:0.5 MG/M3; 9394 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:MANGANESE (SARA III) CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: 0.5-1.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:C 5 MG/M3 ACGIH TLV:5 MG/M3, DUST; 9394 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:YES Health Hazards Acute and Chronic:WELD FUMES/GAS DANGEROUS TO HEALTH.MAY RESULT IN DISCOMFORT,DIZZ,NAU,DRYNESS,NOSE/THROAT/EYE IRRIT.CR CMPDS:SEVERE LUNGS/BRONCHIAL TUBES IRRIT,INJURY/DEATH,BURN EYES,CAUSE ALLERGIC RX.NASAL SEPTUM ULC ERATION/PERFORATION,LIVER/KID DAMAGE.BE:HIGHLY TOXIC,PNEUITIS,BERYLLIOSIS,BE DISEASE.PB:SIDEROSIS,AFFECT (SUPPLEMENTAL) Explanation of Carcinogenicity:PER MSDS:CHROMIUM & BERYLLIUM COMPOUNDS ARE ON IARC. Effects of Overexposure:DISCOMFORT, DIZZINESS, NAUSEA, DRYNESS, NOSE/THROAT/EYE IRRIT. LUNGS/BRONCHIAL TUBES IRRIT, INJURY, DEATH, BURN EYES, ALLERGIC RXS. NASA SEPTUM ULCERATION/PERFORATION, LIVER/KIDNEY DAMAGE, PNEUITIS, B ERYLLIOSIS, BERYLLIUM DEISEASE, SIDEROSIS, AFFECT PULM FUNCTION. EYE INJURY. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:CALL FOR MEDICAL ASSISTANCE. USE FIRST AID PROCEDURES RECOMMENDED BY AMERICAN RED CROSS. IF BREATHING IS DIFFICULT GIVE OXYGEN. IF NOT BREATHIN USE CPR. CONSULT PHYSICIAN IF IRRIT OF EYES & SKIN OR FL ASH BURNS DEVELOP AFATER EXPOSURE. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:NONE SPECIFIED BY MANUFACTURER. HOWEVER USE APPROPRIATE EXTINGUISHING MEDIA FOR SURROUNDING FIRE & MATLS. Fire Fighting Procedures:NONE SPECIFIED BY MANUFACTURER. Unusual Fire/Explosion Hazard:WEDLING ARC AND SPARKS CAN IGNITE COMBUSTIBLES. ================== Accidental Release Measures ================== Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:READ/UNDERSTAND MFG'S INSTRUCTIONS/PRECAUTIONARY LABEL ON PROD.SEE AMER STD Z49.1 SAF IN WELD/CUT PUBLISHED BY AMER WELD SOC 550 NW LEJUNE RD,MIA,FL33126 & OSHA PUBLICATION 2206,US GOVT,WASHINGTON DC2 0402. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE RESPIRABLE FUME RESP OR AIR SUPPLIED RESP WHEN WELDING IN CONFINED SPACE OF GENERAL WORK AREA WHERE LOCAL EXHAUST &/OR VENTILATION DOES NOT KEEP EXPOSURE BELOW THRESHOLD LIMIT VALUE. Ventilation:USE PLENTY OF VENTI &/OR LOCA EXH @ARC,KEEP FUME/GAS BELOW TLV W/IN WORKER'S BREATH ZONE & GEN WORK AREA. Other Protective Equipment:APPROVED HEAD/HAND/BODY PROT FROM RADIATION/SPARKS/ELECTR SHOCK.SHIELD OTHER WORKERS/SCREENS/FLASH GOG.INSULATE WELDERS. Work Hygienic Practices:ADVICE WELDERS KEEP HEAD OUT OF FUMES.TRAIN Supplemental Safety and Health ER4043;ER5356;ER110;ER2319;ER4047;ER4145;ER5183;ER4643. DECOMP PROD:ATM CONTAMINANTS.REASONABLE EXPECTED CONSTITUENTS:COMPLEX OXIDES OF AL,FE,MN,SI,TI,CR,MG,ZM,BE,CU. HEALTH HAZ:PULM FUNCTION.ARC RAYS :EYE INJURY,BURN SKIN.ELECTRIC SHOCK CAN KILL. ================== Physical/Chemical Properties ================== HCC:N1 Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:WELD FUMES/GAS CAN'T BE CLASSIFIED SIMPLY;DEPENDS ON METAL,PROCEDURE,ELECTRODE,METAL COATING,#OF WELDERS,VENTI,(SUPPLEN) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCARD ANY PRODUCT, RESIDUE CONTAINER, OR LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER APPROVED BY LOCAL, STATE AND FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:HEMATOXYLIN, H345100 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:HEMATOXYLIN; (BENZBINDENOL,2-DPYRAN-3,4,6A,9,10(6H)-PENTOL,7,11B-DIHYDRO-, CIS-(+)-) CAS:517-28-2 RTECS #:MH7875000 Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE: MAY CAUSE EYE IRRITATION. SKIN: MAY CAUSE SKIN IRRITATION. INGESTION: MAY CAUSE GASTROINTESTINAL IRRITATION WITH NAUSEA, VOMITING AND DIARRHEA. LOW HAZARD FOR USUAL INDUSTRIAL HANDLING. IN HALATION: MAY CAUSE RESPIRATORY TRACT IRRITATION. LOW HAZARD FOR USUAL INDUSTRIAL HANDLING. CHRONIC: NO INFO FOUND. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF H*2O FOR AT LEAST 15 MIN, OCCAS LIFTING UPPER & LOWER LIDS. GET MED AID. SKIN: GET MED AID. FLUSH SKIN W/PLENTY OF SOAP & H*2O. INGEST: IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERSON. GET MED AID. INGEST: REMOVE FROM EXPOS TO FRESH AIR IMMED. IF NOT BRTHG GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE (SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:USE ALCOHOL FOAM, CARBON DIOXIDE, OR WATER SPRAY WHEN FIGHTING FIRES INVOLVING THIS MATERIAL. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP SPILLS IMMEDIATELY, OBSERVING PRECAUTIONS IN THE PROTECTIVE EQUIPMENT SECTION. SWEEP UP, THEN PLACE INTO A SUITABLE CLEAN, DRY CONTAINER FOR DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE WITH ADEQUATE VENTILATION. STORE IN A COOL, DRY PLACE. KEEP CONTAINERS TIGHTLY CLOSED. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. Ventilation:USE ADEQUATE VENTILATION TO KEEP AIRBORNE CONCENTRATIONS LOW. Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. Supplemental Safety and Health FIRST AID PROC: OXYGEN. GET MEDICAL AID. NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY AND SUPPORTIVELY. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:DECOMPOSES Vapor Pres:NEGLIGIBLE Evaporation Rate & Reference:NEGLIGIBLE Solubility in Water:SOLUBLE IN HOT WATER Appearance and Odor:SOLID ORANGE-BROWN POWDER; ODOR: NOT AVAILABLE. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES LIGHT, STRONG OXIDIZING AGENTS. Stability Condition to Avoid:INCOMPATIBLE MATERIALS. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, HYDROCARBONS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE, AND LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:HYSOL PC 18M Resp. Party Other MSDS Num.:PRODUCT: PO0011 CAGE:04347 CAGE:04347 CAGE:6S222 ============= Composition/Information on Ingredients ============= Ingred Name:2-PROPANOL, 1-METHOXY-, ACETATE CAS:108-65-6 RTECS #:AI8925000 Minumum % Wt:10. Maxumum % Wt:30. Other REC Limits:NOT PROVIDED. OSHA PEL:NOT DETERMINED. ACGIH TLV:NOT DETERMINED. Ingred Name:XYLENE CAS:1330-20-7 RTECS #:ZE2100000 Minumum % Wt:10. Maxumum % Wt:30. OSHA PEL:435 MG/M3 ACGIH TLV:434 MG/M3;100 PPM ACGIH STEL:651 MG/M3;150 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BENZENE, ETHYL- CAS:100-41-4 RTECS #:DA0700000 Minumum % Wt:1. Maxumum % Wt:5. Other REC Limits:NOT PROVIDED. OSHA PEL:435 MG/M3;100 PPM ACGIH TLV:434 MG/M3;100 PPM ACGIH STEL:543 MG/M3;125 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TOLUENE CAS:108-88-3 RTECS #:XS5250000 = Wt:.2 Other REC Limits:754 MG/M3 (MSDS) OSHA PEL:200 PPM Code:F ACGIH TLV:188 MG/M3;50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BENZENE, 1,3-DIISOCYANATOMETHYL- CAS:26471-62-5 RTECS #:NQ9490000 = Wt:1. Other REC Limits:OSHA CEIL 0.14MG/M3 OSHA PEL:NOT DETERMINED. ACGIH TLV:NOT DETERMINED. EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS: EYES, SKIN, RESPIRATORY TRACT. EYE: MAY CAUSE IRRITATION. SKIN: PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE IRRITATION. CONTACT WITH PRODUCT AT ELEVATED TEMPERATURES (>150C) CAN RESULT IN THERMAL BURNS. INHALATION: HARMFUL IF INHALED, MAY CAUSE ALLERGIC RESPIRATORY REACTION SUCH AS ASTHMA. INGESTION: MODERATELY TOXIC, MAY CAUSE VOMITING. Explanation of Carcinogenicity:TOLUENE DIISOCYANTE(CAS 26471-62-5) IS LISTED BY NTP AS GP 2 (REASONABLY ANTICIPATED) AND BY IARC AS GP 2A (PROBABLE) CARCINOGEN. NOT LISTED BY OSHA. Effects of Overexposure:IRRITATION OF EYES AND SKIN. CONTACT WITH PRODUCT AT ELEVATED TEMPERATURES (>150C) CAN RESULT IN THERMAL BURNS. HARMFUL IF INHALED, MAY CAUSE ALLERGIC RESPIRATORY REACTION SUCH AS ASTHMA. INGESTION: MAY CAUSE VOMITING. Medical Cond Aggravated by Exposure:PREEXISTING SKIN AND EYE DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. PRE-EXISTING SKIN OR LUNG ALLERGIES MAY INCREASE THE CHANCE OF DEVELOPING INCREASED ALLERGIC SYMPTOMS TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:EYE: IMMEDIATELY FLUSH EYES WITH WATER FOR MINUMUM 10 MINUTES. SEEK MEDICAL ATTENTION. SKIN: WASH OFF IN FLOWING WATER OR SHOWER. REMOVE CONTAMINATED CLOTHING AND SHOES. SEEK MEDICAL ATTENTION, IF IRR ITATION DEVELOPS. INHALATION: MOVE TO FRESH AIR. IF NOT BREATHING, GIVE MOUTH TO MOUTH RESUSCITATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. SEEK MEDICAL ATTENTION. INGESTION: IF SWALLOWED, DO NOT IN DUCE VOMITING. SEEK PROMPT MEDICAL ATTENTION. NOTE TO PHYSICIAN: TREATMENT SHOULD BE DIRECTED AT THE CONTROL OF SYMPTOMS AND THE CLINICAL CONDITIONS. THERE ARE NO SPECIFIC ANTIDOTES. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:=31.7C, 89.F Lower Limits:NONE PROVIDE Upper Limits:NONE PROVIDE Extinguishing Media:WATER FOG, CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:RECOMMENDED USE OF SELF CONTAINED BREATHING APPARATUS (SCBA). Unusual Fire/Explosion Hazard:NO UNUSUAL FIRE OR EXPLOSION HAZARDS. ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN-UP: CONTAIN SPILL IN NATURAL FORM OR WITH SAND OR DIRT. ELIMINATE ALL IGNITION SOURCES. PREVENT RUNOFF TO STORM SEWERS, DITCHES AND WATERWAYS. SHOVEL OR SCRAPE (NON-METALLIC) ABSORBED WASTE MATE RIAL INTO DISPOSAL CONTAINER. SEAL LID TIGHTLY WITH TAPE AND LABEL PROPERLY. CLEAN UP SPILL IMMEDIATELY. OBSERVE PRECAUTIONS INCLUDING VENTILATION AND/ OR PERSONAL PROTECTIVE EQUIPMENT. Neutralizing Agent:NONE PROVIDED BY MFR. ======================Handling and Storage ====================== Handling and Storage Precautions:HANDLING: PLASTIC CONTAINERS MAY BE SLIPPERY WHEN HANDLING. STORAGE: LESS THAN TWENTY FIVE DEGREE CENTIGRADE (<25C/ 77F) FOR OPTIMUM SHELF LIFE. DRY ATMOSPHERIC CONDITIONS. KEEP CONTAINERS CLOSED AND TIGHTLY SEALED. Other Precautions:DO NOT EXPOSE TO DIRECT SUNLIGHT. ONCE CONTAINER IS OPEN, USE NITROGEN BLANKET ON MATERIAL AND RESEAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO RESPIRATOR IS REQUIRED IF INGREDIENT EXPOSURE LIMITS ARE NOT EXCEEDED. AN OSHA APPROVED (29 CFR 1910.134 USA DEPT. OF LABOR), AIR-PURIFYING RESPIRATOR WITH APPROPRIATE CARTRIDGE SHOULD BE USED IF E XPOSURE LIMITS ARE EXCEEDED. Ventilation:USE LOCAL EXHAUST VENTILATION NEAR THE SOURCE. Other Protective Equipment:A SAFETY SHOWER AND EYE WASH STATION SHOULD BE WITHIN REASONABLE DISTANCE OF THE WORK AREA. Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING, DRINKING, SMOKING OR USING TOILET. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE (HMIS). Supplemental Safety and Health NONE PROVIDED BY MFR. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:NONE PROVIDED BY MFR. Melt/Freeze Pt:M.P/F.P Text:NONE PROVIDED BY MFR. Decomp Temp:Decomp Text:NONE PROVIDED BY MFR. Vapor Pres:9.5 (MM HG) Vapor Density:3.7(AIR=1) Spec Gravity:1.0 VOC Pounds/Gallon:550 pH:NONE PROVIDED VOC Grams/Liter:4.6 Viscosity:NONE PROVIDED BY MFR. Evaporation Rate & Reference:0.5 Solubility in Water:SOLUBLE Appearance and Odor:LIQUID, MEDIUM VISCOSITY, AMBER COLOR, AROMATIC ODOR. Percent Volatiles by Volume:NOT PROVIDED Corrosion Rate:NONE PROVIDED BY MFR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE IDENTIFIED. Stability Condition to Avoid:HIGH TEMPERATURE, OPEN FLAMES. Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, POSSIBLE ORGANICS. Conditions to Avoid Polymerization:EXOTHERMIC =================== Toxicological Information=================== Toxicological Information:TESTING HAS NOT BEEN PERFORMED ON THIS ===================== Ecological Information ===================== Ecological:NO SPECIFIC STUDIES HAVE BEEN CODUCTED BY DEXTER ON THE ECOTOXICITY OR ENVIRONMENTAL FATE OF THIS MATERIAL. HOWEVER, COMMONLY AVAILABLE DATA ON SOME OF THE CONSTITUENTS OF THIS MATERIAL INDICATE THAT UNCONTROLLED RELEASES TO SOIL, GROUND OR SURFACE WATERS COULD ENTAIL ACUTE AND/OR CHRONIC ECOLOGICAL EFFECTS, DEPENDING ON THE QUANTITY AND CONCENTRATION OF SUCH RELEASES. RELEASE OF VOLATILE COMPONE NTS TO THE ATMOSPHERE ARE NOT BELIEVED TO ENTAIL SIGNIFICANT ECOLOGICAL CONSEQUENCES PROVIDE SUCH RELEASES ARE WITHIN THE EXPOSURE LEVELS. ==================== Disposal Considerations ==================== Waste Disposal Methods:LEGAL DISPOSTION OF WASTE IS THE RESPONSIBILITY OF THE OWNER/ GENERATOR OF THE WASTE. APPLICABLE FEDERAL, STATE, AND/ OR LOCAL REGULATIONS MUST BE FOLLOWED DURING TREATMENT, STORAGE, OR DISPOSAL OF WA STE CONTAINING THIS PRODUCT. DO NOT DISPOSE OF IN AN UNCONTROLLED MANNER. =================== MSDS Transport Information =================== Transport Information:PSN: RESIN SOLUTION, 3, UN1866. ===================== Regulatory Information ===================== SARA Title III Information:THIS PRODUCT IS CLASSIFIED AS A RCRA HAZARDOUS WASTE. COMPONENT 2-PROPANOL, 1-METHOX IS SUBJECT TO THE FOLLOWING ENVIRONMENTAL LIST: SARA SEC 311/312. COMPENENT BENZENE, DIMETHYL- IS SUBJECT TO THE FO LLOWING ENVIRONMENTAL LIST: CERCLA HAZARDOUS SUBSTANCE; SEC 311/312 & 313. COMPENENT BENZENE, ETHYL- IS SUBJECT TO THE FOLLOWING ENVIRONMENTAL LIST: CERCLA HAZARDOUS SUBSTANCE; SEC 311/312 & 313. COMP ENENT BENZENE IS SUBJECT TO THE FOLLOWING ENVIRONMENTAL LIST: CA PROP 65 REPRODUCTIVE TOXIN, SEC 302 CERCLA LISTS; SEC 311/312 & 313. Federal Regulatory Information:COMPENENT BENZENE, 1,3 DIISOCY IS SUBJECT TO THE FOLLOWING ENVIRONMENTAL LIST: CERCLA HAZARDOUS SUBSTANCE; CA PROP 65 CARCINOGEN, SEC 302 & CERCLA LISTS, SEC 311/312 & 313. OSHA STATUS: THIS PRODUCT IS HAZARDOUS UNDER OSHA HAZ COM STANDARD 29CFR 1910.1200. State Regulatory Information:CALIFORNIA PROPOSITION 65: COMPENENT BENZENE IS LISTED ON CA PROP 65 AS REPRODUCTIVE TOXIN. COMPENENT BENZENE, 1,3 DIISOCYANTOMETHY (TDI) IS LISTED ON CA PROP 65 AS CARCINOGEN. ======================= Other Information =======================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:153-2323 MINERAL SPIRITS CAGE:54636 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:KEROSENE (PETROLEUM), HYDROTREATED (C10-C15 SATURATED HYDROCARBONS 97%, C10 AROMATICS 3%) *96-2* CAS:64742-47-8 RTECS #:OA5504000 Fraction by Wt: 100% Other REC Limits:200 PPM EXXON OSHA PEL:100 PPM ACGIH TLV:100 PPM Ingred Name:VOLATILE ORGANIC CONTENT: (THEORETICAL) 6.35 LB/GAL RTECS #:9999999VO ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:IRRITATION OF EYES, SKIN & RESPIRATORY SYSTEM, MAY CAUSE NERVOUS SYSTEM DEPRESSION & POSSIBLY DEATH. REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSE PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, UNCONSCIOUSNESS, HEADACHE, DIZZINESS, NAUSEA, LOSS OF COORDINATION, REDNESS, ITCHING, BURNING SENSATION. Medical Cond Aggravated by Exposure:NONE ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. KEEP WARM & QUIET. SKIN: WASH AREA THOROUGHLY W/SOAP & WATER. EYES: FLUSH W/LARGE AMOUNTS OF WATER FOR 15 MINS. INGESTION: NEVER GIVE ANYTHING BY MO UTH TO AN UNCONSCIOUS PERSON. DON'T INDUCE VOMITING. GIVE SEVERAL GLASSES OF WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:105F Lower Limits:1 Upper Limits:6 Extinguishing Media:CO2, DRY CHEMICAL, FOAM Fire Fighting Procedures:WEAR FULL PROTECTIVE EQUIPMENT & SCBA. WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. APPLICATION TO HOT SURFACES REQUIRES SPECIAL PRECAUTIONS. OVEREXPOSURE MAY CAUSE A HEALTH HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SOURCES OF IGNITION. VENTILATE & REMOVE W/INERT ABSORBENT. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & FLAME. USE APPROVED BONDING & GROUNDING PROCEDURES. KEEP CONTAINER CLOSED WHEN NOT IN USE. USE ADEQUATE VENTILATION. Other Precautions:TRANSFER TO CONTAINERS W/COMPLETE & APPROVED LABELING. DON'T TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE CONTENTS CAN BE HARMFUL/FAT AL. CONTENTS ARE COMBUSTIBLE.(SEE SUPP) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOSURE CAN'T BE CONTROLLED BELOW APPLICABLE LIMITS, WEAR A PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA FOR PROTECTION AGAINST MATERIALS. Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS. Other Protective Equipment:PERSONAL PROTECTIVE EQUIPMENT TO MINIMIZE EXPOSURE. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH HANDS AFTER USING. Supplemental Safety and Health KEEP CONTAINERS TIGHTLY CLOSED. AVOID BREATHING VAPOR & SPRAY MIST. AVOID CONTACT W/SKIN & EYES. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:300-395F Vapor Pres:2 Vapor Density:>1 Spec Gravity:0.76 Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME, HOT SURFACES & SOURCES OF IGNITION. Hazardous Decomposition Products:BY FIRE: CO2, CO ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE/DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. DON'T INCINERATE CLOSED CONTAINERS. WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS DEFINED UNDER THE RCRA & MUST BE TESTED FOR IGNITABILITY T O DETERMINE APPLICABLE EPA HAZARDOUS WASTE.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:CW1479 TEMPERATURE INDICATING CRAYONS Preparer's Name:KEN HEARREAN CAGE:67292 CAGE:67292 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS INGREDIENTS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:SHORT TERM EXPOSURE TO WELDING FUMES: DIZZINESS, NAUSEA, DRYNESS/IRRITATION OF NOSE/THROAT/LUNGS/EYES. LONG TERM EXPOSURE TO WELDING FUMES: RESPIRATORY PROBLEMS, IRON BUILDUP IN THE LUNGS, BONE EROSIO N, REDUCED PULMONARY FUNCTIONS, NERVOUSDISORDERS. Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:SHORT TERM EXPOSURE TO WELDING FUMES: DIZZINESS, NAUSEA, DRYNESS/IRRITATION OF NOSE/THROAT/LUNGS/EYES. LONG TERM EXPOSURE TO WELDING FUMES: RESPIRATORY PROBLEMS, IRON BUILDUP IN THE LUNGS, BONE EROSIO N, REDUCED PULMONARY FUNCTIONS, NERVOUSSYSTEM DISORDERS. Medical Cond Aggravated by Exposure:PRE-EXISTING RESPIRATORY/ALLERGIC CONDITIONS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM EXPOSURE TO FRESH AIR. SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/WATER FOR 15 MINS. INGESTION: DON'T INDUCE VOMITING. EMPLOY FIRST AID TECHNIQUES RECOMMENDED BY THE RED CROSS. O BTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Unusual Fire/Explosion Hazard:WELDING ARCS, SPARKS, FUEL GAS TORCHES & SOLDERING IRONS USED FOR WELDING, BRAZING & SOLDERING OPERATIONS CAN IGNITE COMBUSTIBLES. (SEE SUPPLEMENTAL DATA) ================== Accidental Release Measures ================== Spill Release Procedures:COLLECT MATERIAL FOR RECLAMATION & REUSE/DISPOSE IN SEALED CONTAINERS. KEEP AIRBORNE DUST AT A MINIMUM WHEN CLEANING UP. ======================Handling and Storage ====================== Handling and Storage Precautions:MONITOR THE AIR TO ENSURE THE LEVELS ARE <THE RECOMMENDED LIMITS. WEAR APPROPRIATE EQUIPMENT TO PREVENT INJURY FROM RADIATION, SPARKS/ELECTRIC SHOCK. Other Precautions:TRAIN WELDER NOT TO TOUCH LIVE ELECTRICAL PARTS & INSULATE THEMSELVES FROM WORK & GROUND. AVOID CONTACT W/EYES, SKIN/CLOTHING. TRAIN WELDER TO KEEP HIS HEAD OUT OF THE FUMES. READ & UNDERSTAND INSTRUC TIONS & LABEL ON THIS PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE RESPIRABLE FUME DUST RESPIRATOR/AIR SUPPLIED RESPIRATOR WHEN USING PRODUCTS IN CONFINED SPACE/WHEN WELDING , BRAZING/SOLDERING IN CONFINED SPACE/WHERE LOCAL EXHAUST/VENTILATION DOESN'T KEEP EXPOSU RE BELOW TLV. Ventilation:LOCAL EXHAUST AT ARC TO KEEP FUMES/GASES <TLV IN WORKER'S BREATHING ZONE & GENERAL AREA. Other Protective Equipment:ARM PROTECTOR, APRON, HAT, SHOULDER PROTECTION, DARK SUBSTANTIAL CLOTHING Work Hygienic Practices:WASH HANDS AFTER HANDLING. DON'T SMOKE, EAT/DRINK IN WORK AREA. USE GOOD HOUSEKEEPING PRACTICES. Supplemental Safety and Health AVOID ACCUMULATION OF DUST/FUMES. PRODUCT IS NONHAZARDOUS UNTIL USED AS IN WELDING PURPOSES. THE COMPOSITION & QUANTITY OF FUMES/GASES DEPENDS ON METAL BEING WELDED, PROCESS, PROCEDURES, ELECTRODES US ED, COATINGS, POSITION OF WELDERS HEAD W/RESPECT TO THE PLUME & AS THE PRESENCE OF CONTAMINANTS IN THE ATMOSPHERE. ================== Physical/Chemical Properties ================== Appearance and Odor:CRAYON-LIKE PRODUCT W/NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, ALKALIS, OXIDIZERS, CHLORINE TRIFLUORIDE, POTASSIUM, SODIUM, MOLTEN MAGNESIUM, ALUMINUM, LITHIUM & SILICON Stability Condition to Avoid:(SEE SUPP) Hazardous Decomposition Products:COMPLEX OXIDES OF IRON, MANGANESE, SILICON, CHROMIUM, NICKEL, MOLYBDENUM, CALCIUM, MAGNESIUM, TITANIUM (SEE SUPP) ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER/LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER IAW/LOCAL, STATE & FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:65104 OMALA OIL 150 Preparer's Name:J C WILLETT CAGE:SHELO CAGE:SHELO CAGE:54527 ============= Composition/Information on Ingredients ============= Ingred Name:ADDITIVES Fraction by Wt: <3% Ingred Name:SOLVENT REFINED HYDROTREATED HEAVY PARAFFINIC DISTILLATE, HYDROTREATED HEAVY PARAFFINIC DISTILLATE, LUBRICATING OIL. CAS:64742-54-7 RTECS #:PY8035500 Fraction by Wt: 40-50% OSHA PEL:5 MG/CUM (MIST) Ingred Name:RESIDUAL OILS (PETROLEUM), HYDROTREATED *95-1* CAS:64742-57-0 Fraction by Wt: 40-50% ACGIH TLV:5 MG/CUM ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): >5 G/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: MINIMAL IRRITATION. SKIN: MILDLY IRRITATION. PROLONGED/REPEATED CONTACT CAN RESULT IN VARIOUS DISORDERS SUCH AS DERMATITIS, FOLLICULITIS/OIL ACNE. INHALATION: VAPORS/OIL MIST MAY CAUSE MILD IRRI TATION OF THE UPPER RESPIRATORY TRACT. INGESTION: SLIGHTLY TOXIC. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN & RESPIRATORY DISORDERS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR 15 MINS. SKIN: FLUSH W/WATER. FOLLOW BY WASHING W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR & GIVE OXYGEN IF NEEDED. INGESTION: DON'T INDUCE VOMITING. IF VOMITING OCCURS SPONTANEOUSLY, KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION OF LIQUID INTO THE LUNGS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:360F Extinguishing Media:USE WATER FOG/FOAM/DRY CHEMICAL/CO2. Fire Fighting Procedures:DON'T ENTER CONFINED FIRE-SPACE W/OUT FULL BOOTS) & APPROVED SCBA. COOL FIRE CONTAINERS W/WATER Unusual Fire/Explosion Hazard:PRODUCT WILL FLOAT & CAN BE REIGNITED ON SURFACE OF WATER. MATERIAL WILL NOT BURN UNLESS PREHEATED. ================== Accidental Release Measures ================== Spill Release Procedures:LARGE: WEAR RESPIRATOR & PROTECTIVE CLOTHING AS APPROPRIATE. SHUT OFF SOURCE OF LEAK. DIKE & CONTAIN. REMOVE W/VACUUM TRUCKS/PUMP TO STORAGE SALVAGE VESSELS. SOAK UP RESIDUE W/AN ABSORBENT SUCH AS CLA Y, SAND/OTHER SUITABLE MATERIALS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE W/ADEQUATE VENTILATION. KEEP AWAY FROM OPEN FLAMES & HIGH TEMPS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE A NIOSH-APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. USE EITHER AN ATMOSPHERE SUPPLYING RESPIRATOR/AN AIR-PURIFYING RESPIRATOR FOR ORGANIC VAPORS & PARTICULATES. Ventilation:ADEQUATE Other Protective Equipment:PROTECTIVE CLOTHING. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH W/SOAP & WATER BEFORE EATING, DRINKING, SMOKING/TOILET FACILITYS Supplemental Safety and Health NOTE TO PHYSC: IF MORE THAN 2 ML PER KG HAS BEEN INGESTED & VOMITING HASN'T OCCURED, EMESIS SHOULD BE INDUCED W/SUPERVISION. KEEP VICTIMS HEAD BELOW HIPS TO PREVENT ASPIRATION. IF SYMPTOMS SUCH AS LOS S OF GAG REFLEX, CONVULSIONS/UNCONSCIOUSNESS OCCUR BEFORE EMESIS, CAST ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:-10F Vapor Pres:<0.1 Spec Gravity:0.8973 Solubility in Water:NEGLIGIBLE Appearance and Odor:AMBER OIL W/SLIGHT HYDROCARBON ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING MATERIALS Stability Condition to Avoid:HEAT, OPEN FLAMES Hazardous Decomposition Products:CO & OTHER UNIDENTIFIED ORGANIC COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:FLUSH AREA W/WATER TO REMOVE TRACE RESIDUE. DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:WEDJETS (ALL COLORS) CAGE:30047 CAGE:30047 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS INGREDIENTS Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT KNOWN Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE - NOT EXPECTED TO BE A HEALTH HAZARD. CHRONIC- NOT KNOWN. Effects of Overexposure:NONE Medical Cond Aggravated by Exposure:NONE ======================= First Aid Measures ======================= First Aid:IN CASE OF EYE CONTACT, FLUSH EYE WITH WATER. IN CASE OF SKIN CONTACT, WASH SKIN WITH SOAP AND WATER. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:CO2, FOAM OR DRY CHEMICAL Fire Fighting Procedures:FIRE FIGHTERS MUST USE SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:SHOVEL UP AND DISPERSE OF IN APPROVED WASTE DISPOSAL FACILITY. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:NONE Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO SPECIAL REQUIREMENTS Ventilation:NONE REQUIRED IF USED AS INTENDED Other Protective Equipment:NONE Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:NONE Decomp Temp:Decomp Text:NOT KNOWN Vapor Pres:NONE Spec Gravity:0.9 - 1.0 Evaporation Rate & Reference:NOT RELEVANT Solubility in Water:INSOLUBLE Appearance and Odor:RUBBER CORD OF VARIOUS COLORS WITH SLIGHT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:EXCESSIVE HEAT Hazardous Decomposition Products:MAY FORM SMOKE, TOXIC FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:MAY BE INCINERATED IN COMPLIANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS.
0
gloves_not_mandatory
===================== Product Identification ===================== Product ID:WEED PRO, 4 LB, LOW VOLUME Kit Part:Y CAGE:0AGD9 CAGE:0AGD9 ============= Composition/Information on Ingredients ============= Ingred Name:2,4-D ISOOCTYL ESTER (CERCLA)(LIMITS FOR FREE ACID PEL/TLV 10 MG/M3)(2,4-D ACID EQUIV + 42.8%--3.8 LB/GL) CAS:25168-26-7 RTECS #:AG8575000 Fraction by Wt: 64.5% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:KEROSENE (TOTAL PERCENT OF INGREDIENTS OTHER THAN 2,4-D = 35.5) CAS:8008-20-6 RTECS #:OA5500000 Other REC Limits:NONE RECOMMENDED Ingred Name:ISOOCTYL ALCOHOL (TOTAL PERCENT OF INGREDIENTS OTHER THAN 2,4-D = 35.5) CAS:26952-21-6 RTECS #:NS7700000 Other REC Limits:NONE RECOMMENDED Ingred Name:INERT INGREDIENTS (NONHAZ)(TOTAL PERCENT OF INGREDIENTS OTHER THAN 2,4-D = 35.5) Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 RAT 1792MG/KG INGEST/SKIN 200MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL: AVOID BREATHING SPRAY MISTS/VAPORS.CHLOROPHENOXY COMPOUNDS ABSORBED THROUGH LUNGS. EXCESS EXPOSURE MAY IRRIT UPPER RESP TRACT. MAY CAUSE MYOTONIA/MUSCLE WEAKNESS/FALLING BP.MAY CAUSE EYE IRRIT/ CORNEAL INJURY. SKIN: ABSORPTION OF HARMFUL AMTS. CAUSES ALLERG REACT IN SUSCEPTIBLE PEOPLE. MAY CAUSE NAUSEA/DIARRHEA/* Effects of Overexposure:*STOMACH CRAMPS/GI DISTRESS/MYOTONIA/MUSCLE WEAKNESS/FALLING BP. INGEST:NAUSEA/ABDOMIN PAIN/DIARRHEA/STOMACH CRAMPS/GI DISTRESS/MYTONIA/MUSCLE WEAKNESS/FALLING BP. CONTAINS PETROLEUM DISTILLATES. ASPI RATION MAY RESULT IN CHEMICAL PNEUMONIA. ======================= First Aid Measures ======================= First Aid:INHALATION: GET FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESP. GIVE OXYGEN IF NEEDED. GET MED AID. EYE: HOLD LIDS OPEN. FLUSH W/STEADY GENTLE STREAM WATER >15 MIN. GET MED AID IF IRRIT PERSISTS. SK IN: IMMED WASH W/LOTS SOAP & WATER. REMOVE CONTAM CLOTHES/SHOES/WASH BEFORE REUSE. IF IRRIT PERSISTS GET MED AID. INGEST: IF CONSCIOUS/ALLERT GIVE 2-3 GLASSES WATER. DON'T INDUCE VOMITING. GET MED AID ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:150F,66C Lower Limits:NOT AVAIL Upper Limits:NOT AVAIL Extinguishing Media:DRY CHEMICAL, FOAM, CO2, WATER SPRAY, FOG. Fire Fighting Procedures:USE PROTECTIVE CLOTHES/SCBA. DIKE TO PREVENT RUN-OFF/CONTAM WATER SOURCES. SMOKE/FUMES MAY CONTAIN HAZARDOUS COMPONENTS. Unusual Fire/Explosion Hazard:NOXIOUS FUMES (HYDROGEN CHLORIDE/OTHERS) MAY BE FORMED. CONTAINERS MAY RUPTURE VIOLENTLY WHEN OVERHEATED. AFTER FIRE CONTROLLED DON'T HANDLE CNTNRS UNTIL COOL. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE LARGE SPILLS. ABSORB SMALL SPILL ON INERT ABSORBANT (SAND/VERMICULITE). IF SPILLED ON GROUND REMOVE TO DEPTH OF 1-2 INCHES/PLACE IN APPROP DISPOSAL CNTNR. USE PERSONAL PROTEC EQUIP. DON'T CONTAM PUBLIC WATER SOURCES. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID INGESTION OR INHALATION. DON'T GET IN EYES ON SKIN OR CLOTHES. DON'T CONTAMINATE WATER/FOOD/FEED BY STORAGE/DISPOSAL. Other Precautions:KEEP AWAY FROM HEAT, SPARKS, OPEN FLAME, OTHER IGNIT SOURCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR FOR PESTICIDE MIST. Ventilation:LOCAL EXHAUST PREFERRABLE IN PLANTS/CONFINED AREAS. Other Protective Equipment:FULL BODY PROTECTIVE CLOTHES. WASH BEFORE GLASSES, EYEBATH. Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:300F,149C Melt/Freeze Pt:M.P/F.P Text:-6F,-21C Vapor Pres:<1 @ 20C Vapor Density:NA Spec Gravity:1.03 @ 20C pH:7.5-10 Evaporation Rate & Reference:LOWER THAN BUAC Solubility in Water:100%EMULSIFIABLE@25C Appearance and Odor:AMBER LIQUID, PHENOLIC-LIKE ODOR Percent Volatiles by Volume:30-35 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS, ACIDS. Stability Condition to Avoid:EXCESSIVE HEAT. Hazardous Decomposition Products:HYDROGEN CHLORIDE/NITROGEN OXIDES MAY BE PRODUCED ON COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:IF CAN'T BE USED ACCORDING TO LABEL DISPOSE OF IN APPROVED LANDFILL OR INCINERATOR ACCORDING TO ALL APPLICABLE STATE, FEDERAL, LOCAL REGS. TRIPPLE RINSE ALL CONTAINERS. PUNCTURE/CRUSH/OFFER FOR RECYCL ING/RECONDITIONING IF POSSIBLE.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:TEXACO UNLEADED, PRODUCT CODE:00385 Preparer's Name:MANAGER, PRODUCT SAFETY CAGE:2R503 CAGE:2R503 ============= Composition/Information on Ingredients ============= Ingred Name:GASOLINE (STRAING CHAIN/BRANCHED PARAFFINIC HYDROCARBONS,OLEFINS,CYCLOPEARAFFINS,AROMATIC) Fraction by Wt: 95-99.9% Other REC Limits:NONE RECOMMENDED Ingred Name:CUMENE (SARA III) CAS:98-82-8 RTECS #:GR8575000 Fraction by Wt: <160%PPM Other REC Limits:NONE RECOMMENDED OSHA PEL:S, 50 PPM ACGIH TLV:S, 50 PPM; 9394 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BENZENE (SARA III) CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: 1-3.99% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE 1910.1028 ACGIH TLV:10 PPM; A2; 9394 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 4-10.99% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM; Z-2 ACGIH TLV:S, 50 PPM; 9394 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYL BENZENE (SARA III) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 1-3.99% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM/125STEL;9394 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 4-10.99% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM/150STEL;9394 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:1,2,4-TRIMETHYLBENZENE (SARA III) CAS:95-63-6 RTECS #:DC3325000 Fraction by Wt: 1-3.99% Other REC Limits:NONE RECOMMENDED OSHA PEL:25 PPM ACGIH TLV:25 PPM; 9394 Ingred Name:METHYL TERT-BUTYL ETHER (SARA III) (VOL%) CAS:1634-04-4 RTECS #:KN5250000 Fraction by Wt: 0-15% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50,ORAL,RAT >5G/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:EYE:IRRIT, MILD DISCOMFORT, SLIGHT EXCESS REDNESS. SKIN:PROLONG/WIDESPREAD CONTACT MAY RESULT IN ABSORPTIN OF POTENTIALLY HARMFUL AMTS.SLIGHT IRRIT. INHAL:IRRIT OF NOSE/THROAT, CNS DEPRESSION, UNCONSC /ASPHYXIATION. INGEST:ABDOMINAL DISCOMFORT, GI DISTURBANCES, ASPIRATION. CONTAINS BENZENE & ASSOCIATED W/ANEMIA/LEUKEMIA Explanation of Carcinogenicity:POSSIBLE CANCER HAZARD BASED ON ANIMAL DATA. Effects of Overexposure:SKIN:DISCOMFORT, LOCAL REDNESS, SWELLING. INHAL:HEADACHE, NAUSEA, VOMITING, DIZZINESS, DROWSINESS, EUPHORIA, LOSS OF COORDINATION, DISORIENTATION, UNCONSC/ASPHYXIATION. INGEST:NAUSEA, DIARRHEA, LUNG D AMAGE FROM ASPIRATION. Medical Cond Aggravated by Exposure:BECAUSE OF ITS IRRITATING PROTPERITES REPEATED SKIN CONTACT MAY AGGRAVATE AN EXISTING DERMATITIS (SKIN CONDITION). ======================= First Aid Measures ======================= First Aid:EYE:IMMED FLUSH W/PLENTY OF WATER FOR @ LEAST 15MINS OPENING EYELIDS.GET MED ATTN. SKIN:WASH W/PLENTY OF SOAP & WATER.REMOVE CONTAMIN CLOTH.GET MED ATTN IF IRRIT PERSIST/CONTACT HAS BEEN PROLONGED. IN GEST:GET IMMED MED ATTN.ONLY INDUCE VOMIT AS DIRECTED BY DR. INHAL:REOVE TO FRESH AIR.NOT BREATH GIVE ART RESP.DIFF BREATH GIVE OXY BY QUALIFIED PERSONNEL.GET IMMED MED ATTN. (SEE SUPPLEM) ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:-40F,-40C Autoignition Temp:Autoignition Temp Text:850F Lower Limits:1.4 Upper Limits:7.6 Extinguishing Media:IAW NFPA GUIDE USE DRY CHEM, FOA, OR CARBON DIOXIDE. WATER MAY BE INEFFECTIVE ON FLAMES. Fire Fighting Procedures:WATER SHOULD BE USED TO COOL FIRE-EXPOSED CNTNR.IF LEAK/SPILL USE WATERSPRAY TO DISPERSE VAP & PROVIDED PROTECTION FOR PERSONNEL ATTEMPTING TO STOP LEAK. Unusual Fire/Explosion Hazard:USE NON-SPARKING TOOLS,GROUND/BOND ALL CNTNR.VAP HEAVIER THAN AIR,TRAVEL DISTANCE & FLASHBACK.CAN GENERATE STATIC ELECT & CAUSE FIRE EXPLOSION. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE IGN SOURCES.VNETILATE AREA.ISOLATE.STAY UPWIND.AVOID BREATH VAP.WEAR SCBA OR SUPPLIED AIR MASK FOR LG SPILLS/CONFINED AREAS.AVOID CONTACT W/SKIN/EYE/CLOTH.CONTAIN SPILL.REMOVE W/INERT ABSORBENT .PREVENT ENTRY INTO SEWERS/WATERWAYS. Neutralizing Agent:NONE SPECIFIED BY MFG. ======================Handling and Storage ====================== Handling and Storage Precautions:TRANS/HANDLE/STORE IAW OSHA REG 1910.106 & APPLICABLE DOT REGS.GROUND/BOND SHIPPPING CNTNR/TRANS LINE/REC CNTNR.USE SPARK-PROOF TOOLS. Other Precautions:KEEP AWAY FROM HEAT/SPARKS/ETC.MATL MAY BE AT ELEVATED TEMPS &/OR PRESSURES.EXERCISE DUE CARE WHEN OPENING BLEEDERS & SAMPLING PORTS.CONSULT NFPA 77 FOR PROPER HANDLING PRECAUTIONS.INTENDED FOR USE AS MOTOR FUEL ONLY.CONTAINS REPORTABLE QTY ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AIRBORNE CONCEN SHOULD BE KEPT TO LOWEST LEVELS POSSIBLE.IF VAP/MIST/DUST GENERATED USE RESP APPROVED BY MSHA/NIOSH AS APPROPRIATE.SUPPLIED AIR RESP PROTECTION SHOULD BE USED FOR CLEANING LG SPILLS/UP ON ENTRY INTO TANKS/VESS/CONFINED SPACES Ventilation:ADEQUATE TO MEET RECOMMENDED OCCUPATINAL EXPOSURE LIMITS. Other Protective Equipment:PROTECTIVE CLOTHING SUCH AS UNIFORMS, COVERALLS, BOOTS. Work Hygienic Practices:LAUNDER (DRYCLEAN MORE EFFECTIVE;INFORM THEM OF HAZ)CONTAMIN CLOTH PRIOR TO REUSE.DESTROY NON-RESISTANT FOOTWEAR. Supplemental Safety and Health 1STAID:DR-ASPIRATION DURING INDUCED EMESIS CAN RESULT IN LUNG INJURY.IF EVACUATION OF STOMACH CONTENTS IS CONSIDERED NECESSARY USE METHOD LEAST LIKELY TO CAUSE ASPIRATION (GASTRIC LAVAGE AFT ENDOTRAC HEAL INTUBATION). CONTAINS SUBSTANCES KNOWN TO STATE OF CA AS CANCER CAUSING. ================== Physical/Chemical Properties ================== HCC:F1 Boiling Pt:B.P. Text:>90F,>32C Vapor Pres:465 @100F Vapor Density:3-4 Spec Gravity:0.7-0.77 Viscosity:<1.4CST @100F Solubility in Water:SLIGHT. Appearance and Odor:LIGHT STRAW TO LIGHT RED LIQUID. ================= Stability and Reactivity Data ================= STRONG OXIDIZERS. Stability Condition to Avoid:HEAT, SOURCES OF IGNITION. Hazardous Decomposition Products:TOXIC LEVELS OF CARBON MONOXIDE, CARBON DIOXIDE, IRRITATING ALDEHYDES AND KETONES. ==================== Disposal Considerations ==================== Waste Disposal Methods:MATL HAS RCRA CLASSIFICATION OF BENZENE TOXICITY & IGNITABILITY.IF DISCARD IN PRESENT FORM IT WOULD HAVE HAZ WASTE NOS:D018 & D001.PER RCRA USER RESPONSIBILITY TO DEREMINE AT TIME OF DISPOSAL WHETHER MATL MEETS RCRA CRITERIA FOR HAZ WASTE.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:DEVRAN, DV201 BASE Kit Part:Y Preparer's Name:H KLINE CAGE:NO217 CAGE:55849 CAGE:NO217 ============= Composition/Information on Ingredients ============= Ingred Name:TITANIUM DIOXIDE (CONTAINING INGS 2 & 3). LD50: (ORAL,RAT) 10 G/KG CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: <15% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:ALUMINUM HYDROXIDE CAS:21645-51-2 RTECS #:BD0940000 Fraction by Wt: 2.5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:AMORPHOUS SILICA Fraction by Wt: 3% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:BARIUM SULFATE (CONTAINING ING 5) CAS:7727-43-7 RTECS #:CR0600000 Fraction by Wt: <10% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (SILICA). % WT: 100 PPM CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: <0.1% OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST Ingred Name:SILICA, CRYSTALLINE - QUARTZ CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: <10% OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST Ingred Name:TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (TALC(ASBESTOS FREE)) (CONTAINING ING 8) CAS:14807-96-6 Fraction by Wt: <15% OSHA PEL:0.2 FIBERS/CC ACGIH TLV:0.2 FIBER/CC, A1 Ingred Name:SILICA, CRYSTALLINE - QUARTZ CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: <1% OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST Ingred Name:SILICATE, MICA; (MICA) (CONTAINING ING 10) CAS:12001-26-2 RTECS #:VV8760000 Fraction by Wt: <10% OSHA PEL:20 MPPCF; Z-3 ACGIH TLV:3 MG/M3 RDUST Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (CRYSTALLINE SILICA) CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: >5% OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST Ingred Name:XYLENE (SARA 313) (CERCLA) (CONTAINING ING 12). VP: 6.6 @ 68F. LD50: (ORAL,RAT) 3.9 G/KG CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 7.31% OSHA PEL:100 PPM ACGIH TLV:100 PPM/150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BENZENE (SARA 313) (CERCLA). % WT: 5 PPM CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: <0.1% OSHA PEL:SEE 1910.1028 ACGIH TLV:10 PPM; A2 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:ETHYL BENZENE (SARA 313). VP: 7.1 @ 68F CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 1.77% OSHA PEL:100 PPM ACGIH TLV:100 PPM/125 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BUTYL ALCOHOL (SARA 313) (CERCLA). VP: 4.3 @ 68F. LD50:(ORAL,RAT) 4.2 G/KG CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: 9.21% OSHA PEL:100 PPM ACGIH TLV:S, C 50 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:2-HEPTANONE; (METHYL N-AMYL KETONE). VP: 2.1 @ 68F. LD50:(ORAL,RAT) 12 G/KG CAS:110-43-0 RTECS #:MJ5075000 Fraction by Wt: 11.50% OSHA PEL:100 PPM ACGIH TLV:50 PPM Ingred Name:BISPHENOL A EPOXY RESIN; (EPOXY RESIN) (CONTAINING INGS 17, 18 & 19). LD50: (ORAL,RAT) 3 G/KG CAS:25036-25-3 Fraction by Wt: <25% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:4-(1,1-DIMETHYL)PHENYL POLYMER W/ CHLOROMETHYL OXIRANE & BISPHENL CAS:67924-34-9 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:BENZENE (SARA 313) (CERCLA). % WT: <80 PPM CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: <0.1% OSHA PEL:SEE 1910.1028 ACGIH TLV:10 PPM; A2 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:PROPANE, 1-CHLORO-2,3-EPOXY-; (EPCH). % WT: <1 PPM CAS:106-89-8 RTECS #:TX4900000 Fraction by Wt: <0.1% OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:MIXED VOLATILE ORGANIC COMPOUND: 432 G/L (EPA) RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT: OR TOLUENE MAY CAUSE IRREGULAR HEART BEAT. EYES: IRRITANT. CORNEAL INJURY. FOR MORE INFO CONT NEHC . RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. TRAT SYMPTOMATICALLY. RTECS #:9999999ZZ Ingred Name:SPILL PROC: NOTIFY LOCAL AUTHORITIES. RTECS #:9999999ZZ Ingred Name:RESP PROT: HAZARDS." FOR MORE INFORMATION CONT NEHC . RTECS #:9999999ZZ Ingred Name:VENT: CONTAMINANT CONCS BELOW TLV LIMITS. FOR MORE INFORAMTION CONT NEHC . RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: VAP/SPRAY MIST/SPATTERED MATL CAN BE HARMFUL. IRRIT TO EYES, SKIN, & IF INHALED, TO NOSE & THROAT. EXCESS/PRLNGD INHAL CAN CAUSE HDCH, NAUS/DIZZ. RPTD & PRLNGD OCCUP OVREXP TO SOLVS IS ASSOC W/ PERM BRAIN & NERV SYS DMG. INTENTIONAL ABUSE, MISUSE/OTHER MASSIVE EXPOS TO SOLVS MAY CAUSE MULTIPLE (EFTS OF OVEREXP) Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ: IARC MONO, VOL 68, 1987: GROUP 1. NTP 7TH ANNUAL RPT ON CARCIN, 1994: ANTIC TO BE (SUPDAT) Effects of Overexposure:HLTH HAZ: ORGAN DMG &/OR DEATH. OVEREXP (PRLNGD/RPTD USE) CAN AGGRAVATE/ACCENTUATE ANY OF THESE EFTS. SKIN: IRRITANT. SENSIT. CAN BE ABSORBED THRU SKIN. CAN CAUSE DEFAT & DRYING. INHAL: IRRITANT. DELA YED LUNG INJURY CNS DMG. RPTD EXPOS TO SILICA DUST CAN CAUSE SILICOSIS. CRYSTALLINE SILICA MAY CAUSE CANCER. (SUPDAT) Medical Cond Aggravated by Exposure:KIDNEYS, LIVER, SKIN, EYES, RESPIRATORY, ALLERGIES, LUNGS. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. RESTORE NORM BRTHG. TREAT SYMPTOMATICALLY. SEE PHYS. SKIN: WASH THORO W/SOAP & WATER. REMOVE CONTAMD CLTHG. CONSULT PHYS IF IRRIT PERSISTS. EYES: FLUSH IMMED W/PLENTY OF WA TER FOR @ LST 15 MINS & GET MED ATTN. INGEST: DRINK 1-2 GLASSES OF WATER TO DILUTE. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON. DO NOT INDUCE VOMIT (UNLESS METHANOL LISTED IN INGREDS). CONT(ING 22) ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:95.0F,35.0C Lower Limits:1.0% Upper Limits:11.20% Extinguishing Media:FOAM, CARBON DIXOIDE, DRY CHEMICAL. Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROTECTIVE EQUIPMENT . WATER MAY BE USED TO COOL CLOSED CNTNRS TO PREVENT PRESS BUILD/EXPLOSION WHEN EXPOSED TO EXTREME HEAT. Unusual Fire/Explosion Hazard:CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME HEAT & PRESS BUILDUP. MAY PRDCE FLOATING FIRE HAZ. ISOLATE ELEC EQUIP, SPKS, HEAT & OPEN FLAME. VAPS MAY (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT. AVOID BRTHG VAPS. VENTILATE AREA. USE ABSORB, INERT, CLEANUP MATLS. (DO NOT USE SAWDUST). REMOVE ABSORB MATL W/NON-SPK TOOLS. PLACE IN SEPARATE CNTNR. KEEP OUT OF SEWERS & WATERWAYS. IF ENTRY IS THREATENED/OCCURS,(ING 23) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED, UPRIGHT WHEN NOT IN USE. STORE IN COOL, DRY, WELL-VENTILATED AREA. AVOID PROLONGED STORAGE TEMPERATUES ABOVE 100F. Other Precautions:USE CAUTION WHEN POURING. AVOID BREATHING SANDING DUST. DO NOT WELD/FLAME CUT ON EMPTY CONTAINER. DESTROY CONTAMINATED LEATHER AND ABSORBENT SHOES WHICH CANNOT BE DECONTAMINATED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH CERTIFIED RESP DESIGNED TO REMOVE COMBINATION OF PARTICULATES(DUST/SPRAY MIST) & VAP. WHEN BRUSHING, ROLLING/SPREADING SELECT APPROP RESP PROT FOR CNDTNS. FOR SPECIFIC CNDTNS, REFER TO CURRENT " NIOSH POCKET GUIDE TO CHEM (ING 24) Ventilation:IMPLEMENT ADMIN & ENGINEERING CTLS TO REDUCE EXPOS. PROVIDE SUFFICIENT VENT IN VOL & PATTERN TO KEEP AIR (ING 25) Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . RESIST COVERALLS & SHOE COVERINGS. USE EXPLOSION & SPARK-PROOF EQUIP. Work Hygienic Practices:WASH THORO AFTER HNDLG & BEFORE EATING, SMKNG OR USING TOILET. LAUNDER CONTAMD CLTHG BEFORE REUSE. Supplemental Safety and Health EVAP RATE: 0.34. HIGH: 0.87 (BUTYL ACETATE=1). EXPLO HAZ: SPREAD LONG DIST, CAUSE FLASH FIRE/IGNITE EXPLOSIVELY. EXPLAN OF CARCIN: CARCIN. EFTS OF OVEREXP: RISK OF CANCER DEPENDS ON DURATION & LEVEL O F EXPOSURE TO DUST FROM SANDING SURFACES OR SPRAY MIST. SMOKING AGGRAVATES PROBLEMS. CHEMICAL PNEUMONIA. XYLENE (ING 21) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>244F,>118C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:1.45 Evaporation Rate & Reference:SUPP DATA Appearance and Odor:LIQUID, SOLVENT ODOR. Percent Volatiles by Volume:52.1 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, ACIDS, ALKALIES. Stability Condition to Avoid:HEAT, OPEN FLAME, ARC OR SPARKS. AMINES UNDER UNCONTROLLED CONDITION. Hazardous Decomposition Products:BY FIRE, BURNING/WELDING: CO, CO*2, ALDEHYDES, SO*X. TOXIC GASES/FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:PLACE IN SEPARATE, APPROPRIATE, CLOSED CONTAINER I/A/W ALL APPLICABLE LOCAL, STATE, AND FEDERAL REGULATIONS. THIS MATERIAL HAS NOT BEEN TESTED BY TOX CHARACT LEACHING PROC (TCLP). EPA WASTE NO: D001.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:SOLUTION S0726 HYDROCHLORIC AC Preparer's Name:RICKY A. STACKHOUSE CAGE:89524 CAGE:89524 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROCHLORIC ACID, HYDROGEN CHLORIDE, MURIATIC ACID CAS:7647-01-0 RTECS #:MW4025000 Fraction by Wt: 10-20% Other REC Limits:7 PPM OSHA PEL:5 PPM ACGIH TLV:C 11 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(ALBINO RATS): 900 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: CORROSIVE W/POSSIBLE PERMANENT DAMAGE. SKIN: CORROSIVE W/POSSIBLY THIRD DEGREE BURNS. INGESTION: HARMFUL. INHALATION: CAN BE CORROSIVE TO THE MUCOUS MEMBRANES & THE LUNGS. Explanation of Carcinogenicity:NONE Effects of Overexposure:BURNS ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH FOR 15 MINS. SKIN: IMMEDIATELY FLUSH W/WATER FOR 15 MINS. FOR A LARGE SPLASH, FLOOD BODY UNDER A SHOWER. INGESTION: DON'T INDUCE VOMITING. GIVE WATER. INHALATION: REMOVE TO FRE SH AIR. TREAT SYMPTOMS. IF UNCONSCIOUS,HAVING TROUBLE BREATHING/IN CONVULSIONS, DON'T INDUCE VOMITING/GIVE WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. (SEE SUPP) ===================== Fire Fighting Measures ===================== Flash Point:NONE Unusual Fire/Explosion Hazard:ACID REACTS W/MOST METALS TO RELEASE HYDROGEN GAS WHICH CAN FORM EXPLOSIVE MIXTURES W/AIR. ================== Accidental Release Measures ================== Spill Release Procedures:COVER W/SODIUM BICARBONATE/SODA ASH/LIME MIXTURE. MIX & ADD WATER TO FORM A SLURRY. FLUSH DOWN DRAIN W/LARGE AMOUNTS OF WATER. ACID SOLUTION SHOULD BE NEUTRALIZED BEFORE BEING DISCHARGED TO A SANITARY SEWER. ======================Handling and Storage ====================== Other Precautions:CAUSES BURNS TO SKIN & EYES. DON'T GET IN EYES, ON SKIN/ON CLOTHING. AVOID BREATHING VAPORS. DON'T TAKE INTERNALLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY NEEDED. Ventilation:GENERAL VENTILATION IS RECOMMENDED Other Protective Equipment:EYE WASH FOUNTAIN & SAFETY SHOWER Supplemental Safety and Health INCOMPATIBILITIES CONT'D: SULFIDES, HYPOCHLORITES, CHLORITES. FIRST AID CONT'D-NOTE TO PHYSICIAN: PROBABLE MUCOSAL DAMAGE MAY CONTRAINDICATE THE USE OF GASTRIC LAVAGE. MEASURES AGAINST CIRCULATORY SHO CK, RESPIRATORY DEPRESSION & CONVULSIONS MAY BE NEEDED. ================== Physical/Chemical Properties ================== Spec Gravity:1.08 pH:<1 Solubility in Water:COMPLETE Appearance and Odor:COLORLESS LIQUID W/PUNGENT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALINE MATERIALS; AMMONIA, CARBONATES, SODIUM HYDROXIDE, POTASSIUM HYDROXIDE, CALCIUM HYDROXIDE, CYANIDES (SEE SUPP) Hazardous Decomposition Products:HYDROGEN CHLORIDE, SMOKE/FUMES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS. DOO2. EMPTY CONTAINERS SHOULD BE PUNCTURED, IF PLASTIC & PLACED IN GARBAGE COLLECTION CONTAINER.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:INNERBOND HZ-15 HYDRAZINE CAGE:66172 CAGE:66172 ============= Composition/Information on Ingredients ============= Ingred Name:HYDRAZINE (SARA III) CAS:302-01-2 RTECS #:MU7175000 Fraction by Wt: 15% OSHA PEL:S, 1 PPM ACGIH TLV:S, 0.1 PPM, A2; 9293 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:WATER CAS 7732-18-5 CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 85% ===================== Hazards Identification ===================== Effects of Overexposure:INHAL/INGEST:PUNG,SORE THROAT,COUGH,SHORTNESS OF BREATH,LABORED BRTHG; SKIN/EYES:CORR,RED,PAIN,BURNS ======================= First Aid Measures ======================= First Aid:INHAL:RMV TO FRESH AIR. IF NOT BRTHNG GIVE CPR; IF BRTHNG DIFF GIVE OXYGEN. EYE:IMMED FLUSH W/PLENTY OF WATER. SKIN:WASH W/SOAP&WATER. RMV CONTAM CLTHG&SHOES. INGEST:INDUCE VOMIT. RPT UNTIL VOMIT IS C LEAR. NOTHG BY MOUTH IF UNCONSC. GET MEDICAL ATTN. ===================== Fire Fighting Measures ===================== Lower Limits:4.7 Upper Limits:99.0 Extinguishing Media:WATER FOG CONTRS W/H*20. Unusual Fire/Explosion Hazard:HYDRAZINE VAPOR CAN IGNITE EXPLOSIVELY AND SPONTANEOUSLY IN AIR OR ABSORBED IN POROUS MATERIAL ================== Accidental Release Measures ================== Spill Release Procedures:WEAR FULL PROTECTIVE CLOTHING AND SCBA. SMALL SPILLS MAY BE DILUTED WITH WATER AND HELD IN A WELL VENTILATED AREA FOR DISPOSAL ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL AREA-COVERED AREA OUTSIDE PREFERRED-INDOOR SHOULD BE POSITIVELY VENTILATED. MAJOR STORAGE AREAS SHOULD BE DIKED. Other Precautions:OBSERVE ALL PRECAUTIONS WITH EMPTY CONTAINERS INCLUDING ELIMINATION OF SOURCES OF IGNITION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SCBA, SUPPLIED AIR RESPIRATOR Ventilation:PROVIDE MECHAN(GEN/LOCAL EXHAUST)VENT TO MAINTN <TLV Other Protective Equipment:WEAR IMPERVIOUS CLOTHING/BOOTS. Supplemental Safety and Health MSDS 05-13-87 HYDRAZINE IS LISTED AS A CARCINOGEN BY NTP & IARC ================== Physical/Chemical Properties ================== HCC:B2 Boiling Pt:B.P. Text:212F/100C Vapor Pres:17 Spec Gravity:1.15 Evaporation Rate &amp; Reference:SLOWER THAN ETHER Appearance and Odor:WHITE TO PALE YELLOW LIQUID Percent Volatiles by Volume:<95% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS,ORGANICS,MINERAL ACIDS,LEAD,COPPER Stability Condition to Avoid:EXCESSIVE HEAT Hazardous Decomposition Products:CO*2, CO, NH*3.TOXIC NITROGEN COMPOUNDS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT MFR FOR NEUTRALIZATION INSTRUCTIONS. DISPOSE OF IAW FEDERAL,STATE, LOCAL REGULATIONS
1
gloves_mandatory
===================== Product Identification ===================== Product ID:ISO-BUTYLENE CAGE:54262 CAGE:57631 CAGE:54262 ============= Composition/Information on Ingredients ============= Ingred Name:ISOBUTYLENE O.O1 % IN AIR CAS:115-11-7 RTECS #:UD0890000 Fraction by Wt: 0.01% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LC50: 620 MG/M3, RAT 4 HOURS Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES- CONTACT WITH THE LIQUID MAY CAUSE FROSTBITE. SKIN- CONTACT WITH THE LIQUID MAY CAUSE FROSTBITE.INHALATION- MAY CAUSE ASPHYXIATION DUE TO DILUTION OF AVAILABLE OXYGEN IN AIR. CHRONIC:NONE KNOWN. Effects of Overexposure:INHALATION- RAPID RESPIRATION, MUSCULAR INCOORDINATION. FATIGUE, NAUSE, AND VOMITING. LOSS OF CONSCIOUSNESS AND DEATH MAY OCCUR. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:INHALATION- IMMEDIATELY REMOVE VICTIM TO FRESH AIR. IF BREATHING HAS STOPPED, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. SKIN- IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR 15 MIN. WHILE REMOVING CONTAMINATED CLOTHING. EYES AND INGESTION- N/P. ===================== Fire Fighting Measures ===================== Autoignition Temp:Autoignition Temp Text:465C Extinguishing Media:CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. FLAMMABLE. HIGH PRESSURE LIQUID AND GAS. KEEP FIRE EXPOSED CONTAINERS COOL W/ WATER SPRAY. Unusual Fire/Explosion Hazard:VAPORS MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND FLASH BACK. CYLINDER RUTPURE MAY OCCUR UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AND VENTILATE AREA. REMOVE LEAKING CYLINDER TO EXHAUST HOOD OR SAFE OUTDOOR AREA. SHUT OFF SOURCE IF POSSIBLE AND REMOVE SOURCE OF HEAT. ALLOW GAS TO DISSIPATE. ======================Handling and Storage ====================== Handling and Storage Precautions:SECURE CYLINDER WHEN USING TO PROTECT FROM FALLING. USE SUITABLE HND TRUCK TO MOVE CYLINDERS. Other Precautions:STORE IN WELL VENTILATED AREAS. KEEP VALVE PROTECTION CAP ON CYLINDERS WHEN NOT IN USE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN CASE OF LEAK, USE SELF-CONTAINED BREATHING APPARATUS. Ventilation:GENERAL & LOCAL EXHAUST VENTILATION TO MINTAIN CONCENTRATIONS BELOW FLAMMABLE LIMITS & AVOID ASPHYXIATION. Other Protective Equipment:SAFETY SHOES WHEN HANDLING CYLINDERS. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:G3 Boiling Pt:B.P. Text:19.6F,-6.9C Vapor Pres:39 PSIG Vapor Density:1.98 Spec Gravity:GAS Evaporation Rate & Reference:GAS Solubility in Water:INSOLUBLE Appearance and Odor:COLORLESS AS WITH AN UNPLEASANT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS. Stability Condition to Avoid:STORAGE IN POORLY VENTILATED AREAS. STORAGE NEAR A HEAT SOURCE. Hazardous Decomposition Products:TOXIC CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:RETURN CYLINDERS TO SUPPLIER WITH ANY VALVE OUTLET PLUGS OR CAPS SECURED AND VALVE PROTECTION CAP IN PLACE. EMPTY CYLINDERS WILL CONTAIN HAZARDOUS RESIDUE.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:CARBON DIOXIDE (SOLID) DRY ICE CAGE:AMDRY CAGE:AMDRY ============= Composition/Information on Ingredients ============= Ingred Name:CARBON DIOXIDE; (DRY ICE) CAS:124-38-9 RTECS #:FF6400000 OSHA PEL:5000 PPM ACGIH TLV:5000 PPM;30000 STEL Ingred Name:SUPDAT:SODIUM PEROXIDE:EXPLO HAZ. AZIRIDINE:VIOLENT POLYMERIZATION. BARIUM PEROXIDE:INCANDESCENT RXN. BERYLLIUM (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2:(PWDR) & NITROGEN:IGNIT ON HEATING. CERIUM (PWDR) & NITROGEN:IGNIT ON HEATING. CESIUM OXIDE:IGNIT. CHROMIUM(ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:(HEATED):IGNIT & EXPLO. DIETHYL MAGNESIUM & AIR:IGNIT. DIMETHYL ETHER & ALUMINUM HYDRIDE:VIOLENT DECOMP. (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:LITHIUM:VIGOROUS RXN. LITHIUM & OXYG:IGNIT. LITHIUM & WATER:IGNIT. LITHIUM ACETYLENE CARBIDE DIAMMINO: (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:IGNIT. MAGNESIUM(DUST):IGNIT & EXPLO. MAGNESIUM ALUMINUM ALLOYS:IGNIT & EXPLO. MAGNESIUM & SODIUM PEROXIDE:(ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:EXPLO HAZ. MANGANESE(HEATED):IGNIT & EXPLO. MONOLITHIUM ACETYLIDE:IGNIT. POTASSIUM:EXPLO HAZ WHEN SUBJECTED(ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:TO SHOCK. POTASSIUM ACETYLENE CARBIDE:INCANDESCENT RXN. POTASSIUM-SODIUM ALLOY:MIXT W/SOLID CARBON DIOXIDE (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:IS EXPLO. RUBIDIUM ACETYLIDE:IGNIT ON HEATING. SODIUM:IGNIT. SODIUM ACETYLIDE:INCANDESCENT RXN. SODIUM (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:CARBIDE:INCANDESCENT RXN. SODIUM PEROXIDE:HIGHLY EXOTHERMIC RXN. SODIUM PEROXIDE & ALUMINUM(PWDR) & WATER:(ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:IGNIT. SODIUM PEROXIDE & COTTON WOOL:IGNIT. SODIUM PEROXIDE & MAGNESIUM (PWDR) & WATER:IGNIT. SODIUM (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:PEROXIDE & TIN (PWDR) & WATER:IGNIT. THORIUM (PWDR) & NITROGEN:IGNIT ON HEATING. TITANIUM:BURNS >550C. (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:URANIUM:FINELY DIVIDED METAL IGNITES AT 750C; MASSIVE METAL IGNITES AT 800C. URANIUM (PWDR) & NITROGEN: (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:IGNIT ON HEATING. ZIRCONIUM & NITROGEN:IGNIT ON HEATING. ZIRCONIUM:IGNITION & EXPLOSION. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:NO ADVERSE EFTS FROM GAS. VAPORS MAY CAUSE DIZZINESS OR SUFFOCATION. CONTACT W/LIQUID MAY CAUSE FROSTBITE. IN VAPOR FORM:MAY CAUSE FROSTBITE, SAME AS SKIN. LIQUID OR SOLID MAY CAUSE FROSTBITE. C HRONIC:IF ENVIRON CONTAINS 0.03-0.06% CARBON DIOXIDE GAS & NO ADVERSE EFTS ARE EXPECTED FROM PRLNG EXPOS AS THIS LEVEL. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HEADACHE, INCREASED BREATHING RATE, DIFFICULT BREATHING, PERSPIRATION, DIZZINESS, RINGING IN EAR, LIPS BLUE, TREMORS & WEAKNESS, VISUAL DISTURBANCE, DROWSINESS, UNCONSCIOUSNESS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD IMMEDIATELY . EYES:IMMEDIATELY FLUSH W/POTABLE WATER FOR A MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM MD . SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . INHAL:REMO VE FROM EXPOSURE AREA TO FRESH AIR IMMEDIATELY. IF BREATHING HAS STOPPED GIVE ARTF RESP. MAINTAIN AIRWAY & BLOOD PRESSURE. GET MEDICAL ATTENTION IMMEDIATELY. ===================== Fire Fighting Measures ===================== Extinguishing Media:CARBON DIOXIDE CANNOT CATCH FIRE. USE MEDIA FOR SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . EVACUATE ALL PERS FROM DANGER AREA. MOVE CNTNR FROM FIRE AREA IF POSS. STAY AWAY FROM STOR TANK (SUPDAT) Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:DO NOT TOUCH SPILLED MATERIAL. STOP LEAK IF YOU CAN DO SO W/OUT RISK. KEEP UNNECESSARY PEOPLE AWAY! ISOLATE HAZARD AREA & DENY ENTRY. VENTILATE CLOSED SPACES BEFORE ENTERING. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:IF CONTACT W/LIQ OR SOLID, WEAR COLD Other Precautions:FOR GAS FORM, NO PROTECTIVE CLOTHING REQUIRED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL EXHST/GENERAL DILUTION VENT TO MEET PELS. MECHANICAL (GENERAL):EXHAUST FANS WHERE NECESSARY. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . USE LONG SLEEVE SHIRTS/CLTHG APPROP TO(SUPDAT) Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRE FIGHT PROC:ENDS. COOL FIRE-EXPOS CNTNRS FROM SIDE UNTIL WELL AFTER FIRE IS OUT. EYE PROT:& FULL LGTH FCSHLD . OTHER PROT EQUIP:PVNT SKIN FROM FREEZING. MATLS TO AVOID:IODIDE/ALUMINUM CHLORI DE ACCELERATES RXN TO INCANDESCENCE. ALUMINUM HYDRIDE & BIS(2-METHOXYETHYL)ETHER: VIOLENT DECOMP. ALUMINUM & (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:-109F,-78C Melt/Freeze Pt:M.P/F.P Text:-94F,-70C Vapor Pres:569 @ -82C Vapor Density:1.5 Spec Gravity:1.56 (H*2O=1) Evaporation Rate & Reference:HIGH (BUTYL ACETATE=1) Solubility in Water:1.6% Appearance and Odor:EXTREMELY COLD, WHITE SNOW-LIKE FLAKES OR CUBES WHICH SUBLIME AT ROOM TEMP. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACRYLALDEHYDE:EXOTHERMIC RXN & VIOLENT POLYMERIZATION. ALUMINUM(PWDR):IGNITES WHEN HEATED; PRESENCE OF ALUMINUM (SUPDAT) Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES & PRESSURES. CONTAINER MAY EXPLODE IN HEAT OF FIRE. Hazardous Decomposition Products:TEMPERATURES >1700C MAY CAUSE DECOMPOSITION & RELEASE OF OXYGEN & CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . PROVIDE LOCAL EXHAUST VENTILATION &/OR GENERAL DILUTION VENTILATION TO MEET PELS. SLOWLY RELEASE INTO ATMOSPHERE OUTDOORS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:TONER FOR DPC LZR 1200 CAGE:19790 CAGE:19790 ============= Composition/Information on Ingredients ============= Ingred Name:STYRENE ACRYLIC RESIN CAS:26655-10-7 Fraction by Wt: 80-90% Other REC Limits:NONE RECOMMENDED Ingred Name:POLYOXYPROPYLENE GLYCOL CAS:25322-69-4 RTECS #:TR5250000 Fraction by Wt: 5-10% Other REC Limits:NONE RECOMMENDED Ingred Name:DYE CAS:84179-66-8 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: 5-10% Other REC Limits:NONE RECOMMENDED OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3; 9394 Ingred Name:TRIMETHYLATED SILICA CAS:68909-20-6 Fraction by Wt: 0-1% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ACUTE: LDLO VALUE IS OVER 10.0 G/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:NONE SPECIFIED BY MANUFACTURER. Explanation of Carcinogenicity:CARBON BLACK IS LISTED BY IARC AS A SUSPECTED CARCINOGEN. Effects of Overexposure:MINIMAL IRRITATION MAY OCCUR AS WITH EXPOSURE TO ANY NON-TOXIC DUST. Medical Cond Aggravated by Exposure:ACCUMULATION OF DUST IN THE RESPIRATORY SYSTEM. ======================= First Aid Measures ======================= First Aid:INGESTION- RINSE MOUTH WITH WATER. CALL A PHYSICIAN. INHALATION- REMOVE TO FRESH AIR. IF EFFECTS OCCUR, CONSULT LOCAL MEDICAL PERSONNEL.EYES- IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH WATER A ND SEEK MEDICAL TREATMENT. SKIN- WASH WITH SOAP AND WATER. ===================== Fire Fighting Measures ===================== Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM OR WATER. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:TONER IS A COMBUSTIBLE POWDER. WHEN DISPERSED IN AIR, IT FORMS EXPLOSIVE MIXTURES. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP OR CLEAN UP WITH A VACUUM CLEANER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL DRY PLACE. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. Ventilation:NONE NORMALLY REQUIRED. Other Protective Equipment:NONE NORMALLY REQUIRED. Work Hygienic Practices:INHALATION SHOULD BE AVOIDED. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:1.2 Solubility in Water:NEGLIGABLE Appearance and Odor:FINE BLACK POWDER, PRACTICALLY ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:NONE Hazardous Decomposition Products:CARBON MONOXIDE AND OTHER DECOMPOSITION PRODUCTS IN CASE OF INCOMPLETE COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE MATERIAL SHOULD BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. DO NOT INCINERATE.
0
gloves_not_mandatory
===================== Product Identification ===================== Product ID:235801 BOSCODUR 4 Kit Part:Y Preparer's Name:D.C. MOLBERG CAGE:MO931 CAGE:MO931 CAGE:70707 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 31% OSHA PEL:200 PPM/300 STEL ACGIH TLV:200 PPM/300STEL 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:METHYLENE BISPHENYL ISOCYANATE (MDI) (SARA III) CAS:101-68-8 RTECS #:NQ9350000 Fraction by Wt: 69% OSHA PEL:C, 0.02 PPM ACGIH TLV:0.005 PPM; 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:UNKNOWN Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PRODUCT IS IRRITATING TO SKIN,CORROSIVE TO EYES AND HARMFUL IF INGESTED OR INHALED. CHRONIC EXPOSURE MAY PRODUCE ASTHMA,CENTRAL NERVOUS SYSTEM EFFECTS,LUNG IMPAIRMENT. Effects of Overexposure:EYE:BURNS,POSSIBLY IRREVERSABLE. SKIN:IRRITATION. INGESTION/INHALATION:IRRITATION,BREATHLESSNESS,CHEST PAIN,COUGHING,NAUSEA,DIARRHEA,VOMITING,NARCOSIS. PRODUCT MAY ALSO SENSITIZE INDIVIDUALS PRODUCING ASTHMA. Medical Cond Aggravated by Exposure:BRONCHIAL HYPERACTIVITY,ASTHMA. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH WITH WATER 15 MIN. SKIN:WASH WITH SOAP & WATER. INHALED:REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION OR OXYGEN AS NEEDED. INGESTED:DO NOT INDUCE VOMITING. GIVE LARGE QUANTITY OF MILK OR WATER.(NOTHING BY MOUTH IF UNCONSCIOUS).GET IMMEDIATE MEDICAL ATTENTION. IF ANY IRRITATION PERSISTS OR IS SEVERE,GET PROMPT MEDICAL CARE. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:28F/-2C Autoignition Temp:Autoignition Temp Text:959F Lower Limits:1.8(CALC) Upper Limits:11.4(CALC) Extinguishing Media:CARBON DIOXIDE,DRY CHEMICAL,FOAM,WATER FOG,OR SPRAY. Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS.PRODUCT FOAMS WITH WATER WHEN HEATED. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE SOURCES OF IGNITION. ADSORB WITH SAND,SWEEPING COMPOUND,ETC. PACKAGE IN CLOSED STEEL CONTAINERS. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,WELL VENTILATED AREA. STORE AT 6-77F. KEEP TIGHTLY CLOSED. Other Precautions:WARNING-HARMFUL WHEN INHALED;AVOID BREATHING VAP/MIST.USE W/ADEQUATE VENT.AVOID SKIN,EYE,CLOTHG CONTCT;CAUSES SKIN IRRITATION;MAY CAUSE ALLERGIC RESPIRATORY REACTION.AVOID MOISTURE CONTAMINAT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR EQUIPPED WITH CARTRIDGE FOR ORGANIC VAPORS/MISTS OR SUPPLIED AIR RESPIRATOR IF EXPOSED ABOVE TLV/PEL. Ventilation:USE NORMAL ROOM VENTILATION. IF PEL/TLV IS EXCEEDED,PROVIDE LOCAL EXHAUST TO RETURN EXPOSURE TO SAFE/LEGAL LEVELS. Other Protective Equipment:SAFETY SHOWER,EYE WASH. Work Hygienic Practices:USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID ALL UNNECESSARY CONTACT. Supplemental Safety and Health MSDS FM MFR DATED: 3/20/85; THIS IS PART B OF 2 PART KIT; SEE P/N IND A, SAME NSN, FOR PART A (BOSTIK 7132) DATA; PER MFR, MSDS CONFORMS TO OSHA STD; CALL PHYSICIAN IN CASE OF ANY OVEREXPSR EFFECTS. K EY1:F3 ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:176F/80C Vapor Pres:74 MM Vapor Density:2.49 Spec Gravity:1.05 Evaporation Rate & Reference:5.7 BUAC:2.7 ETHER Solubility in Water:8.4% Appearance and Odor:BROWN LIQUID,KETONE ODOR. Percent Volatiles by Volume:40.4 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS,HALOGENS,ALKALIS,MINERAL ACIDS,ALCOHOLS,AMINES,DETERGENTS,AMMONIA,WATER. Stability Condition to Avoid:SUNLIGHT,HEAT,IGNITION SOURCES. Hazardous Decomposition Products:MISCELLANEOUS INNOCUOUS AND TOXIC PRODUCTS OF COMBUSTION.INCLUDING CO,CO*2,HCN,H*2O,NO*X. Conditions to Avoid Polymerization:CONTACT WITH WATER & OTHER ISOCYANATES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W FEDERAL,STATE,LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:A-162, LG-34 (LIQUID GREASE) CAGE:0FWB4 CAGE:0FWB4 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE;(PROPANE PROPELLANT) CAS:74-98-6 RTECS #:TX2275000 OSHA PEL:1000 PPM ACGIH TLV:SIMPLE ASPHYXIANT Ingred Name:BENZIN;(MINERAL SPIRITS) CAS:8030-30-6 RTECS #:DE3030000 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:DIZZINESS. PROLONGED EXPOSURE MAY LEAD TO UNCONSCIOUSNESS. INHALATION MAY CAUSE NASAL IRRITATION. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN:WASH THOROUGHLY WITH SOAP & WATER. EYE: FLUSH WITH WATER FOR AT LEAST 15 MINUTES AND CALL MD. INHAL:PROVIDE OXYGEN. MOVE TO FRESH AIR. INGEST:CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:193F,89C CONC Extinguishing Media:FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN WITH SAFETY ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY AREA. Other Precautions:AEROSOL UNDER PRESSURE AT 40 PSI @ 75F. DO NOT USE OR STORE ABOVE 120F. OBSERVE WARNING LABEL PRECAUTIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:GENERALLY NOT NEEDED. NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL EXHAUST IS ADEQUATE. Other Protective Equipment:NONE NEEDED. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:V4 Boiling Pt:B.P. Text:104F,40C Spec Gravity:1.03 (AS WATER) Solubility in Water:INSOLUBLE Appearance and Odor:LIGHT RED COLOR WITH CHLORINATED SOLVENT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CO, CO2, HCL, PHOSGENE. ==================== Disposal Considerations ==================== Waste Disposal Methods:LANDFILL. DISPOSAL MUST BE IN ACCORDANCE WITH ALL LOCAL, STATE, AND FEDERAL REGULATIONS .
1
gloves_mandatory
===================== Product Identification ===================== Product ID:2452 LIGHTWEIGHT BODY FILLER Preparer's Name:S ABDUL RAZZAK CAGE:16522 CAGE:16522 ============= Composition/Information on Ingredients ============= Ingred Name:DIETHYLENE GLYCOL, MALEIC ANHYDRIDE, PHTHALIC ANHYDRIDE POLYMER*97-1* CAS:26123-45-5 Fraction by Wt: <35% Ingred Name:STYRENE, STYRENE MONOMER (SUSPECTED ANIMAL/HUMAN CARCINOGEN BY IARC GROUP 2B) *97-1* CAS:100-42-5 RTECS #:WL3675000 Fraction by Wt: <18% EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TALC (POWDER), (ASBESTOS FREE), TALCUM; HYDROUS MAGNESIUM SILICATE (SUSP ANIMAL CARC BY IARC; NTP)* 97-1 * CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: <50% OSHA PEL:2 MG/CUM (RESP DUST) ACGIH TLV:2 MG/CUM (RESP DUST) Ingred Name:SODA LIME BOROSILICATE GLASS (AMORPHOUS SILICATE) Fraction by Wt: <50% Ingred Name:TITANIUM DIOXIDE, TITANIUM OXIDE (SUSPECTED ANIMAL CARCINOGEN, IARC GROUP 3)*97-1* CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: <50% OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM (DUST) Ingred Name:VOLATILE ORGANIC CONTENT: MATERIAL 216 G/L RTECS #:9999999VO ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION. INHALATION: UPPER RESPIRATORY IRRITATION. SKIN: IRRITATION & DERMATITIS. IF ECZEMATOUS DEVELOPS, MOST OFTEN OCCURS ON THE BACK OF HANDS, WRISTS & FOREARMS. Explanation of Carcinogenicity:STYRENE IS A SUSPECTED 2B ANIMAL CARCINOGEN BY IARC. Effects of Overexposure:IRRITATION, DRUGGED, SLEEPY, UNCONSCIOUSNESS, RASH. Medical Cond Aggravated by Exposure:RESPIRATORY CONDITIONS SUCH AS ASTHMA, CHRONIC BRONCHITIS, EMPHYSEMA. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER. SKIN: WASH THOROUGHLY W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES . ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:(SEE SUPP) Lower Limits:1.1 Upper Limits:6.1 Extinguishing Media:CO2, DRY CHEMICAL (SMALL FIRES), FOAM & WATER FOG (LARGE FIRES). Fire Fighting Procedures:VENT SMOKE & USE GAS MASK/REMOTE AIR SUPPLY. WEAR A MSHA/NIOSH APPROVED SCBA W/PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:DENSE SMOKE SERIOUSLY LIMITS VISIBILITY. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SOURCES OF IGNITION. INCREASE VENTILATION TO MAXIMIZE VAPOR DISPERSAL. LARGE SPILL: DIKE TO PREVENT RUNOFF INTO SEWERS/WATERWAYS. SHOVEL/WIPE. SWEEP/CLEAN W/INERT MATERIAL SUCH AS SAND, VERMICU LITE & PLACE IN CLOSED CONTAINER FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY AREA. DON'T STORE IN DIRECT SUNLIGHT. BOND/GROUND CONTAINERS FOR TRANSFER TO PREVENT STATIC SPARKS. AVOID CONTACT W/SKIN & EYES. Other Precautions:STYRENE VAPORS ARE UNINHIBITED & MAY CAUSE BLOCKAGE OF VENTILATION VENTS DUE TO POLYMERIZATION. PERIODIC INSPECTION MAY BE NECESSARY TO PREVENT BLOCKAGE. AVOID IMPROPER ADDITION OF PROMOTERS & OXIDIZI NG AGENTS. AVOID ELECTRICAL EQUIPMENT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE A NIOSH/MSHA APPROVED ORGANIC VAPOR/DUST RESPIRATOR. Ventilation:LOCAL EXHAUST: CONTROL THE EMISSION OF AIR CONTAMINANTS. GENERAL: ASSIST W/THE REDUCTION OF AIR CONTAMINANTS. Other Protective Equipment:SAFETY SHOWERS & EYE WASH STATIONS Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. CLEAN HANDS W/SOAP & WATER AFTER EVERY USAGE. Supplemental Safety and Health INFORMATION IS FOR STYRENE: FLASH POINT 90F (TCC); BOILING POINT 293F; VAPOR DENSITY 3.6. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:(SEE SUPP) Vapor Density:(SEE SUPP) Spec Gravity:1.05-1.35 Evaporation Rate & Reference:LESS THAN ETHER Solubility in Water:NEGLIGIBLE Appearance and Odor:WHITE PASTE W/STYRENE ODOR. Percent Volatiles by Volume:18%/WT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, PEROXIDES & OTHER OXIDIZING AGENTS. Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME, DIRECT SUNLIGHT/OTHER SOURCES OF IGNITION. Hazardous Decomposition Products:CO, CO2, LOW MOLECULAR WEIGHT HYDROCARBONS & ORGANIC ACIDS. Conditions to Avoid Polymerization:UNREGULATED CONTACT W/ORGANIC PEROXIDES, EXPOSURE TO HEAT, OPEN FLAME, & STORAGE >100F. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF AS SOLID WASTE IAW/FEDERAL, STATE & LOCAL REGULATIONS. IF DISCARDED, THIS MATERIAL & CONTAINERS ARE CONSIDERED RCRA HAZARDOUS WASTES BASED ON THE CHARACTERISTIC OF IGNITABILITY.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:MA336-7166 CAGE:LO787 CAGE:96341 CAGE:LO787 ============= Composition/Information on Ingredients ============= Ingred Name:COBALT 60 CAS:8000-29-1 RTECS #:GE8750000 ===================== Hazards Identification ===================== Effects of Overexposure:HAZ DEGREE DEPENDS ON TYPE/QUANT OF RADIATION. LATENT EFFECTS:SOMATIC/GENETIC DAMAGE. ======================= First Aid Measures ======================= First Aid:USE FIRST AID. CALL MEDICAL EMERGENCY CARE. REMOVE/ISOLATE COMTAMINATED CLOTHING.SHOWER VICTIM(S) W. SOAP & H*2O. DETAIN PERSONNEL/EQUIPMENT EXPOSED. ADVISE MEDICAL PERSONNEL THAT VICTIM(S) MAY BE CON TAMINATED. ===================== Fire Fighting Measures ===================== Extinguishing Media:EXTINQUISH W. AGENT SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR CHEMICAL PROTECTIVE SUIT WITH SELF CONTD BRTHG APP. Unusual Fire/Explosion Hazard:SOME OF MATL MAY BURN. CONT MAY EXPLODE IN HEAT OF FIRE. ================== Accidental Release Measures ================== ======================Handling and Storage ====================== Handling and Storage Precautions:SHIELD ACCORDING TO EMITTED RADIATION. PROTECT FROM FILM/FILM PLATES. KEEP CONTAINERS CLOSED. STORE IN AREA FOR RADIOACTIVE MATERIALS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SCBA IF INVOLVED IN FIRE, OTHERWISE GAS MASK. Ventilation:PROVIDE MECHAN(GEN/LOCAL EXHAUST)VENT TO MAINTN <TLV Other Protective Equipment:EYE WASH STATION. APRONS. SPECIAL IMPERVIOUS CLOTHING. Supplemental Safety and Health SOURCE OF DATA-MIL HANDBOOK 600-1 SEP 76.SAFETY & HEALTH DATA DEVELOPED BY DGSC-STF. ================== Physical/Chemical Properties ================== HCC:A2 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ISOLATE,SEGREGATE FROM MOST OTHER TYPE MATERIAL Hazardous Decomposition Products:DEPENDS ON CHEMICAL COMPOSITION; FISSION PRODUCTS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-IN ACCORDANCE WITH DOD REGULATIONS AND FEDERAL,STATE & LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:LECOSORB, 502-174 CAGE:FO436 CAGE:94174 CAGE:FO436 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM HYDROXIDE; (SODIUM HYDROXIDE, CAUSTIC SODA)(SARA III) CAS:1310-73-2 RTECS #:WB4900000 Fraction by Wt: 99.2% OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3, C EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:COATED ON SILICATE CAS:1318-00-9 OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CORROSIVE TO ALL BODY TISSUES WHICH IT COMES IN CONTACT. CHRONIC LOCAL EFFECT MAY CONSIST OF MULTIPLE AREAS OF SUPERFICIAL DESTRUCTION OF SKIN. INHALATION OF DUST MAY CAUSE VARYING DEGREES OF IRRITATI ON. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:ITCHING, BURNING OF SKIN OR EYES. TEMPORARY DISCOMFORT OF BREATHING PASSAGES. Medical Cond Aggravated by Exposure:INCREASED SUSCEPTIBILITY TO RESPIRATORY ILLNESSES. ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . SKIN:FLUSH W/WATER. SEEK MEDICAL ATTENTION. EYES:FLUSH W/LARGE AMOUNTS OF CLEAN WATER FOR A T LEAST 15 MINUTES, FOLLOWED BY BORIC ACID EYE WASH SOLUTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:>550F,>288C Extinguishing Media:PRODUCT NOT COMBUSTIBLE, FOAM, CO*2 OR DRY CHEMICAL CAN BE USED. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . ================== Accidental Release Measures ================== Spill Release Procedures:WASH AREA W/1 MOLAR HYDROCHLORIC ACID OR USE CAUSTIC SPILL KIT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:WEAR PROTECTIVE CLOTHING, USE ADEQUATE VENTILATION WHERE DUST MAY BE GENERATED. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED MSA DUST FOE 77 OR RESPIRATOR. Ventilation:LOCAL EXHAUST: EXHAUST FAN. Other Protective Equipment:COVERALLS, CHEMICALLY RESISTANT SHOES. EMERG EYE WASH AND DELUGE SHOWER WHICH MEETS ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH CONTAMINATED CLOTHES. Supplemental Safety and Health EYE PROT:FULL LENGTH FACESHIELD . ================== Physical/Chemical Properties ================== HCC:C2 Boiling Pt:B.P. Text:2530F,1388C Vapor Pres:42 @ 1000C Spec Gravity:2.13 (H*2O=1) Solubility in Water:COMPLETELY SOLUBLE Appearance and Odor:LIGHT GREEN; NO DISTINCT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONT W/WATER CAUSES STRONG EXOTHERMIC RXN. AVOID STRONG ACIDS CONT, ALUMINUM, TIN & ZINC. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:EXPOSURE TO AIR RESULTS IN FORMATION OF H*2O & CARBONATE. ==================== Disposal Considerations ==================== Waste Disposal Methods:APPROPRIATE DISPOSAL SHOULD CONFORM W/LOCAL, STATE & FEDERAL HEALTH REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:LECTRA CLEAN II Preparer's Name:JON BROWN CAGE:10136 CAGE:10136 ============= Composition/Information on Ingredients ============= Ingred Name:PARAFFINIC HYDROCARBONS Other REC Limits:NONE RECOMMENDED Ingred Name:PROPYLENE GLYCOL CAS:57-55-6 RTECS #:TY2000000 Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL:MAY CAUSE IRRITATION AND CNS EFFECTS.SKIN/EYES:MAY CAUSE IRRITATION.INGEST:MAY CAUSE LUNG DAMAGE IF VOMITED AFTER SWALLOWING. Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1% WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA. Effects of Overexposure:INHAL:MAY CAUSE CNS DEPRESSION(HEADACHE,NAUSEA,FATIGUE...). Medical Cond Aggravated by Exposure:MANUFACTURER STATES NONE. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR.GIVE ARTIFICIAL RESPIRATION IF NEEDED.EYES:FLUSH WITH WATER FOR 15 MINUTES.SKIN:DO NOT INDUCE VOMITING.GET PROMPT QUALIFIED MEDICAL ASSISTANCE.SKIN:WASH WITH SOAP AND WATER. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:219F,104C Lower Limits:0.6@145C Upper Limits:20.4@180C Extinguishing Media:WATER FOG,FOAM,CARBON DIOXIDE,DRY CHEMICAL. Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR,CAN TRAVEL DISTANCES ALONG THE GROUND,AND FLASHBACK AT THE SOURCE. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE SOURCES OF IGNITION.SOAK UP WITH A NON-COMBUSTIBLE ABSORBANT;PLACE IN SUITABLE CONTAINERS FOR DISPOSAL.DO NOT RELEASE INTO SEWER OR WATERWAYS. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID MISTING(A FIRE HAZARD).AVOID SPILLING THIS MATERIEL ON FIBROUS INSULATION(A SPONTANEOUS COMBUSTION HAZARD). Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN ENCLOSED SPACES USE A SELF-CONTAINED BREATHING APPARATUS. Ventilation:USE LOCAL OR GENERAL MECHANICAL DILUTION VENTILATION. Other Protective Equipment:CLOTHING TO PREVENT BODY CONTACT,AS NEEDED. Work Hygienic Practices:WASH HANDS.SEPERATE WORK CLOTHES FROM STREET CLOTHES.LAUNDER WORK CLOTHES BEFORE REUSE.KEEP FOOD OUT OF THE WORK AREA. Supplemental Safety and Health HMIS SPOKE TO MICHELLE WEISSMULLER AND LEARNED THAT AN INGREDIENT DESCRIBED AS A "P-SERIES ALKYL GLYCOL ETHER" IS PROPLYENE GLYCOL. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>400F,>204C Melt/Freeze Pt:M.P/F.P Text:33.8F,1.0C Vapor Pres:<1 Vapor Density:>5 AIR=1 Spec Gravity:0.81 Evaporation Rate & Reference:SLOW Solubility in Water:NEGLIGIBLE Appearance and Odor:COLORLESS LIQUID;ODOR NOT REPORTED ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:HIGH HEAT,SOURCES OF IGNITION. Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:DIRT FIGHTER INTERIOR LATEX SEMI-GLOSS,73-1 CAGE:85231 CAGE:59019 CAGE:85231 ============= Composition/Information on Ingredients ============= Ingred Name:NO INGREDIENT FOR THIS FORMULATION_INGREDIENT ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:IRRIT OF EYES, SKIN & UPPER RESP SYS. IN A CONFINED AREA VAPORS IN HIGH CONC MAY CAUSE HDCH, NAUS OR DIZZ. REDNESS & ITCHING OR BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN EXPOS. CHRONI C:ETHYLENE GLYCOL IS CONSIDERED AN ANIMAL TERATOGEN. IT HAS BEEN SHOWN TO CAUSE BIRTH DEFECTS IN RATS &(EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:MICE AT HIGH DOSES WHEN GIVEN IN DRINKING WATER OR BY GAVAGE. THERE IS NO EVIDENCE TO INDICATE IT CAUSES BIRTH DEFECTS IN HUMANS. PRLNGD OVEREXP TO SOLV INGREDS MAY CAUSE ADVERSE EFTS TO LIVE R & URINARY SYS. RATS EXPOSED TO TITANIUM DIOXIDE DUST AT 250 MG/M3 DEVELOPED LUNG CANCER BUT SUCH EXPOSURE (SUPP DATA) Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM & QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY WITH SOAP & WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. EYE:FLUSH WITH LARGE AMOU NTS OF WATER FOR AT LEAST 15 MINUTES. GET MD. INGEST:CALL MD IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>199F,>93C Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZ ARE PREF. WATER MAY BE USED TO COOL (SUPP DATA) Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE ONLY WITH ADEQUATE VENTILATION. AVOID BREATHING VAPOR AND SPRAY MIST. AVOID CONTACT WITH SKIN AND EYES. KEEP CONTAINER CLOSED WHEN NOT IN USE. Other Precautions:THIS COATING MAY CNTN MATLS CLASSIFIED AS NUISANCE PARTICULATES, SUCH AS TITANIUM DIOXIDE OR CALCIUM CARBONATE, WHICH MAY BE PRESENT AT HAZ LEVELS ONLY DURING SANDING/ABRADING DRIED FILM. TRANSFER ONL Y TO APPRVD CNTNRS W/COMPLETE(SUPP DATA) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ALL RESPS MUST BE NIOSH/MSHA APPRVD. IF PERSONAL EXPOS CANNOT BE CNTRLS BELOW APPLIC LIMITS BY VENT, WEAR PROPERLY FITTED ORGANIC VAP/PARTICULATE RESP FOR PROT. WHEN SANDING/ABRADING DRIED FILM, WEAR DUST/MIST RESP FOR DUST WHICH (ING 4) Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS TO INGREDS IS MAINTAINED BELOW APPLIC EXPOS LIMITS. REFER TO (ING 5) Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health MFR PT#/TRADE NAME:OFF-WHITE. FIRE FIGHT PROC:CLOSED CONTAINERS TO PREVENT PRESSURE BUILDUP/POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. EFTS OF OVEREXP:LEVELS NOT ATTAINABLE IN WO RKPLACE. OTHER PREC:& APPROPRIATE LABELING. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:212F,100C Vapor Pres:SEE ING Vapor Density:HVR/AIR Spec Gravity:1.04-1.23 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:66-75 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:BY FIRE:CO, CO*2. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM PRODUCT IS NOT HAZARDOUS AS DEFINED UNDER RCRA 40 CFR 261. INCINERATE IN APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINER. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGUL ATIONS REGARDING POLLUTION.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:CAT, 1-COAT, TT-P-2756, 36081 PC 03GY373CAT Kit Part:Y CAGE:33461 CAGE:33461 ============= Composition/Information on Ingredients ============= Ingred Name:ALIPHATIC ISOCYANATE (HEXAMETHYLENE DIISOCYANATE [HDI] CAS: 822-06-0; FREE MONOMER CONTENT LESS THAN 0.5%) CAS:28182-81-2 RTECS #:HQ9170000 Fraction by Wt: 60% Other REC Limits:MOBAY CEILING.02 PPM ACGIH TLV:TWA 0.005 PPM Ingred Name:ETHYL 3-ETHOXYPROPIONATE (VAPOR PRESSURE .7 MM HG @ 68F) CAS:763-69-9 RTECS #:UF3325000 Fraction by Wt: 25% Other REC Limits:50 PPM;STEL 100 PPM Ingred Name:N-BUTYL ACETATE (VAPOR PRESSURE 13 MM HG @ 68F) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 15% Other REC Limits:NONE SPECIFIED OSHA PEL:150 PPM/STEL 200 PPM ACGIH TLV:150 PPM/STEL 200 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:VOC: 320 G/L RTECS #:9999999VO Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE; EYES, NOSE, THROAT IRRIT & ACUTE NERV SYS DEPRESSN. INHAL:HEADACHES, DIZZINESS, STAGGERING, DIFFICULT BREATHING, CONFUSION, UNCONSCIOUSNESS, COMA. SKIN: IRRIT (SWELLING, REDNESS, RASH). EYES: I RRIT (TEARING, REDNESS, SWELLING W/STINGING). INGEST: IRRIT, CORROSIVE TO GI TRACT. ASPIRATION (VOMIT)-CHEM PNEUMONITIS. Effects of Overexposure:CHRONIC; AS A RESULT OF PREVIOUS REPEATED OVEREXPOSURE OR A SINGLE LARGE DOSE, CERTAIN INDIVIDUALS WILL DEVELOP ISOCYANATE SENSITIZATION WHICH WILL CAUSE THEM TO REACT TO A LATER EXPOSURE OF ISOCYANAT E LEVELS WELL BELOW THE TLV VALUE OF ISOCYANATES. Medical Cond Aggravated by Exposure:ASTHMA AND ANY OTHER RESPIRATORY DISORDERS. SKIN ALLERGIES, ECZEMA AND DERMATITIS. ISOCYANATE SENSITIZATION. ======================= First Aid Measures ======================= First Aid:INHAL: MOVE TO FRESH AIR. RESTORE BREATHING. ASTHMATIC TYPE SYMPTOMS MAY DEVELOP (IMMED/DELAYED). GET MED AID. SKIN: REMOVE CONTAMINATED CLOTHING. WASH AFFECTED AREAS WITH SOAP & WATER. WASH CONTAMINA TED CLOTHES BEFORE REUSE. EYES: FLUSH WITH LUKEWARM WATER (LOW PRESSURE) 15 MIN, LIFTING EYELIDS. GET MED AID. INGEST: DONT INDUCE VOMITING. DO NOT GIVE ANYTHING TO AN UNCONSCIOUS PERSON. GET MED AID. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:76.0F,24.4C Lower Limits:1.05 Upper Limits:7.60 Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG Fire Fighting Procedures:USE FULL PROTECT CLOTH/FIREFIGHT EQUIP W/SCBA. WATER MAY BE USED TO COOL CLSD CNTNRS (PREVENT PRESS BLDUP/AUTOIGNIT/EXPLOS). HDI/IRRIT VAPOR GENERATED BY FIRE. Unusual Fire/Explosion Hazard:KEEP CNTNR CLSD. KEEP FROM HEAT/IGNIT SOURCE. CLSD CNTNR MAY EXPLODE W/HEAT. APPLIC TO HOT SURFACE REQ SPECIAL PRECAUTION. OVEREXPOSURE TO DECOMP PROD-HLTH HZD. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE ALL NON-ESSENTIAL PERSONNEL. REMOVE ALL SOURCES OF IGNITION (FLAME, SPARK SOURCES, HOT SURFACES). VENTILATE AREA. CONTAIN AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN BUILDINGS IN COMPLIANCE WITH OSHA 1910.106. AVOID STORING NEAR HIGH TEMPS/IGNITION SOURCE. STORE IN CLOSED CONTAINER IN WELL VENTILATED AREA. Other Precautions:KEEP CNTNR TIGHT/UPRIGHT (PREVENT LEAK). PREVENT PROLONGD VAPOR BREATHING. PROLONGD OVEREXPOSURE MAY CAUSE ALLERGIC REACTION. AVOID SKIN/EYE CONTACT. DONT INGEST.DONT HANDLE TILL MFR PRECAUTIONS READ/ UNDERSTOOD. SMOKE IN SMOKING AREAS ONLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE RESPIRATOR RECOMMENDED FOR USE IN ORGANIC VAPOR ENVIRONMENT (AIR PURIFYING/FRESH AIR SUPPLIED). OBSERVE OSHA RESPIRATOR REGULATIONS. VAPOR PARTIC RESPIRATOR (TC23C) MAY BE USED WHEN AIR MONITORING SHOWS VAPOR LEVELS BELOW 10X TLV/PEL. Ventilation:EXHAUST VENTILATION TO KEEP AIRBORNE CONCENTRATION (HDI, POLYISOCYANATES, SOLVENT) BELOW TLVS. REMOVE IGNITION SOURCES. Other Protective Equipment:THE USE OF LONG SLEEVE AND LONG LEG CLOTHING RECOMMENDED. REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE. Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING OR USING WASHROOM. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:260 TO 460F Vapor Density:> AIR Spec Gravity:1.02521 Evaporation Rate & Reference:0.44 X N-BUTYL ACETATE Solubility in Water:INSOLUBLE Appearance and Odor:AMBER LIQUID WITH SOLVENT ODOR Percent Volatiles by Volume:45.0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS AND SURFACE ACTIVE MATERIALS. Stability Condition to Avoid:CONTACT WITH MOISTURE, MATERIAL WHICH REACT WITH ISOCYANATES AND HIGH TEMPERATURES. Hazardous Decomposition Products:BY HIGH HEAT/TEMPERATURE: CARBON MONOXIDE, CARBON DIOXIDE, AND OXIDES OF NITROGEN, TRACES OF HCN AND HDI. Conditions to Avoid Polymerization:CONTACT WITH MOISTURE, MATERIALS WHICH REACT WITH ISOCYANATES AND HIGH TEMPERATURES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE & LOCAL ENVIRONMENTAL CONTROL REGULATIONS. EMPTY CONTAINERS MUST BE HANDLED WITH CARE, DUE TO PRODUCT RESIDUE & FLAMMABLE VAPOR. DONT INCINERATE CLOSED CONTAI NER. EPA HZD WASTE #: D001, F003, F005,IGNITABLE.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:STAINLESS STEEL 2XX TO 5XX SERIES CAGE:72113 CAGE:72113 ============= Composition/Information on Ingredients ============= Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 Fraction by Wt: 0-90% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 ACGIH TLV:10 MG/M3 AS FE2O3 Ingred Name:CHROMIUM (SARA III) CAS:7440-47-3 RTECS #:GB4200000 Fraction by Wt: 0-30% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG/M3 ACGIH TLV:0.5 MG/M3; 9293 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:NICKEL (SARA III) CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: 0-999.5% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9293 Ingred Name:MANGANESE (SARA III) CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: 0-15% Other REC Limits:NONE RECOMMENDED OSHA PEL:(C) 5 MG/M3 DUST ACGIH TLV:5 MG/M3 DUST 9293 Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 Fraction by Wt: 0-3% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:MOLYBDENUM CAS:7439-98-7 RTECS #:QA4680000 Fraction by Wt: 0-5% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3; 9293 Ingred Name:SELENIUM (SARA III) CAS:7782-49-2 RTECS #:VS7700000 Fraction by Wt: 0-1% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.2 MG/M3 ACGIH TLV:0.2 MG/M3; 9293 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:COBALT (SARA III) CAS:7440-48-4 RTECS #:GF8750000 Fraction by Wt: 0-1% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.1 MG/M3;AS CO ACGIH TLV:0.05 MG/M3;DUST 9293 Ingred Name:COPPER (SARA III) CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: 0-5% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.1MG/M3 FUME/1 DUST ACGIH TLV:0.2MG/M3 FUME; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TITANIUM, METAL CAS:7440-32-6 RTECS #:XR1700000 Fraction by Wt: 0-6% Other REC Limits:NONE RECOMMENDED Ingred Name:ALUMINUM (SARA III) CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: 0-4.25% Other REC Limits:NONE RECOMMENDED OSHA PEL:15MG/M3 DUST/5 FUME ACGIH TLV:10MG/M3 DUST; 9293 Ingred Name:VANADIUM (SARA III) CAS:7440-62-2 RTECS #:YW1355000 Fraction by Wt: 0-1.1% Other REC Limits:NONE RECOMMENDED OSHA PEL:C,0.5 MG V2O5/M3 RD ACGIH TLV:0.05 MG V205/M3;9293 Ingred Name:TUNGSTEN CAS:7440-33-7 RTECS #:YO7175000 Fraction by Wt: 0-2% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3/ 10 STEL ACGIH TLV:5 MG/M3/10 STEL;9293 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:IN THE NATURAL STATE, STEEL PRODUCT DO NO PRESENT INHALATION, INGESTION OR CONTACT HEALTH HAZARDS. HOWEVER, WELDING, BURNING, GRINDING, BRAZING, SAWING OR MACHINING CAN RESULT IN THE GENERATION OF FUM ES & DUST PARTICULATES. IRRITATION OF EYES, NOSE, & THROAT MAY RESULT FROM EXCESSIVE EXPOSURE TO METAL FUMES & DUST. Explanation of Carcinogenicity:CHROMIUM, VANADIUM AND NICKEL ARE CONSIDERED AS CARCINOGEN OR POTENTIAL HUMAN CARCINOGENS. Effects of Overexposure:METAL FUME FEVER MAY-A METALLIC TASTE IN MOUTH, IRRITATION AND DRYNESS OF MUCOUS MEMBRANES, FEVER AND CHILLS USUALLY LASTING 12 TO 48 HOURS ARE TYPICAL SYMPTOMS COMMONLY ASSOCIATED WITH METAL FUME FEV ER. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION-IF IRRITATION OR PULMONARY SYMPTOMS DEVELOP, CONSULT A PHYSICIAN. EYE/SKIN-IF IRRITATION DEVELOPS, CONSULT A PHYSICIAN. INGESTION-IF CONSUMED WATER CONTAINING METAL PARTICULES, CONSULT A PH YSICAIN. ===================== Fire Fighting Measures ===================== Extinguishing Media:NO FIRE OR EXPLOSION HAZARD. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED PARTICULATE AND/OR ACID FUME RESPIRATOR IF THE CONCENTRATION OF ACTUAL OR POTENTIAL AIRBORNE CONTAMINANTS EXCEEDS, OR IS ANTICIPATED TO EXCEED, THE EXPOSURE LIMITS. Ventilation:FUMES & WASTE GASES SHOULD BE REMOVED BY LOCAL EXHAUST VENTILATION. IF NOT ADEQUATE, USE A HIGH LEVEL POWER VENTILATION. HELMET, HAND SHIELD, EARPLUGS & MUFFS AS NEEDED TO PROTECT WORKERS. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING, DRINKING OR SMOKING. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:7 Appearance and Odor:ODORLESS SOLID WITH METALLIC LUSTRE. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:NONE Hazardous Decomposition Products:FUMES AND DUSTS OF IRON OXIDE AND MANGANESE.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:RHODANILE BLUE, 12149-5 CAGE:60928 CAGE:60928 ============= Composition/Information on Ingredients ============= Ingred Name:RHODANILE BLUE CAS:14969-56-3 Code:F RTECS #:BP6700000 Code:F Other REC Limits:N/K OSHA PEL:N/K OSHA STEL:N/K ACGIH TLV:N/K ACGIH STEL:N/K ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: MAY BE HARMFUL BY INHALATION, INGESTION, OR SKIN ABSORPTION. MAY CAUSE EYE AND SKIN IRRITATION. CHRONIC: POSSIBLE CARCINOGEN. LABORATORY EXPERIMENTS HAVE SHOWN MUTAGENIC EFFECTS. Explanation of Carcinogenicity:POSSIBLE CARCINOGEN. A COMPLEX OF NILE BLUE AND RHODAMINE B. RHODAMINE B IS A CARCINOGEN. Effects of Overexposure:SEE HEALTH HAZARDS. ======================= First Aid Measures ======================= First Aid:EYES: CONTAMINATION OF THE EYES SHOULD BE TREATED BY IMMEDIATE AND PROLONGED IRRIGATION WITH COPIOUS AMOUNTS OF WATER, FOR AT LEAST 15 MINUTES. SKIN: IMMEDIATELY WASH WITH SOAP AND COPIOUS AMOUNTS OFWATER. INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. INGESTION: WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN. DISCARD CONTAMINATED CLOTHING AND SHOES. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. WEAR NIOSH APPROVED SCBA, DISCARD THEM AFTER USE. SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT BREATHE DUST. AVOID ALL CONTACT. AVOID PROLONGED OR REPEATED EXPOSURE. KEEP TIGHTLY CLOSED. STRONG DYE. STORE IN A COOL DRY PLACE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR. Ventilation:USE ONLY IN A CHEMICAL FUME HOOD. Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . PROTECTIVE CLOTHING. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Appearance and Odor:PURPLE CRYSTALLINE POWDER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE, AND NITROGEN OXIDES. =================== Toxicological Information=================== Toxicological Information:SEE HEALTH HAZARDS. POSSIBLE CARCINOGEN. LABORATORY EXPERIMENTS HAVE SHOWN MUTAGENIC EFFECTS. RTECS #: BP6700000 AMMONIUM, (6-(DIETHYLAMINO)-9-(0-((9-(DIETHYLAMINO)-5H-BENZO(A)PHENOXAZIN-5-Y LIDECARBAM OYL)PHENYL)-3H-XANTHEN-3-YLIDENE)DIETHYL-, CHLORIDE. ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR COMPLETE INFORMATION. ===================== Ecological Information ===================== Ecological:DATA NOT YET AVAILABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:CONTACT ALDRICH CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION. ===================== Regulatory Information ===================== Federal Regulatory Information:REVIEWS, STANDARDS, AND REGULATIONS: NOES 1983: HZD X1534; NIS 1; TNF 10; NOS 1; TNE 40; TFE 40. State Regulatory Information: ======================= Other Information =======================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:ORANGE ESSENCE #2 Preparer's Name:JERRY SENN CAGE:04A57 CAGE:04A57 CAGE:02TC4 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 60-100% Other REC Limits:NONE RECOMMENDED Ingred Name:D-LIMONENE CAS:5989-27-5 RTECS #:GW6360000 Fraction by Wt: 5-10% Other REC Limits:NONE RECOMMENDED Ingred Name:ALKANEMMIDE Fraction by Wt: 10-30% Other REC Limits:NONE RECOMMENDED Ingred Name:NONIONIC SURFACTANTS Fraction by Wt: 5-10% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: IRRITATION. SKIN: IRRITATION. INHAL: IRRITATION TO NOSE/MUCOUS MEMBRANE. INGEST: GI IRRITATION, NAUSEA, DYSENTERY. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH W/WATER FOR 15 MINUTES, LIFTING LIDS. SKIN: WASH W/MILD SOAP & WATER. INGEST: DRINK 20 LARGE GLASSES OF WATER. GET MED AID. INHAL: GET FRESH AIR & REST. GET MED AID. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:124F,51C Autoignition Temp:Autoignition Temp Text:NA Lower Limits:NE Upper Limits:NE Extinguishing Media:USE MEDIA PROPER TO THE PRIMARY CAUSE OF FIRE. Fire Fighting Procedures:USE PROPER PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:AVOID IGNIT SOURCES. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH W/WATER. MOP UP. USE SAND. DONT LET FLOW INTO PUBLIC WATERWAYS. Neutralizing Agent:WATER ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL DRY PLACE. AVOID ANY SOURCES OF IGNITION. Other Precautions:AVOID OXIDIZERS. KEEP AWAY FROM CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. W/GOOD VENTILATION. Ventilation:ADEQUATE ROOM VENTILATION Supplemental Safety and Health *PH ADDITIONAL: 7.4 TO 9.0 ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:220F,104C Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C Vapor Pres:NE Vapor Density:<1.0 Spec Gravity:0.995 pH:* Viscosity:NA Evaporation Rate & Reference:<1.0 Solubility in Water:100 Appearance and Odor:LIGHT YELLOW, CITRUS ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:STRONG OXIDIZERS & SOURCES OF IGNITION. ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT FROM GOING INTO PUBLIC WATERWAYS. TRY TO REUSE, WHATEVER THE ACCEPTED METHOD IN LOCAL, STATE OR FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:EPOXY PRIMERS,ENAMELS & ACTIVATORS, 823Y67632 CAGE:18873 CAGE:18873 ============= Composition/Information on Ingredients ============= Ingred Name:VOLITILE ORGANIC CONTENT AS LISTED ON MSDS, 3.8. RTECS #:9999999VC Fraction by Wt: NA Other REC Limits:NONE RECOMMENDED Ingred Name:BARIUM SULFATE CAS:7727-43-7 RTECS #:CR0600000 Fraction by Wt: 9.73% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9596 Ingred Name:BISPHENOL-EPICHLOROHYDRIN POLYMER CAS:25036-25-3 Fraction by Wt: 25.33% Other REC Limits:NONE RECOMMENDED Ingred Name:ETHYL ACETATE (CERCLA) CAS:141-78-6 RTECS #:AH5425000 Fraction by Wt: 6.61% Other REC Limits:NONE RECOMMENDED OSHA PEL:400 PPM ACGIH TLV:400 PPM; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:MAGNESIUM SILICATE Fraction by Wt: 13.89% Other REC Limits:NONE RECOMMENDED Ingred Name:ISOPROPYL ALCOHOL (SARA 313) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 3.47% Other REC Limits:NONE RECOMMENDED OSHA PEL:400 PPM ACGIH TLV:400 PPM/500STEL;9596 Ingred Name:N-BUTYL ALCOHOL (SARA 313) (CERCLA) CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: 5.57% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:S, C 50 PPM; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PROPYLENEGLYCOL MONOMETHYL ETHER ACETATE CAS:108-65-6 RTECS #:AI8295000 Fraction by Wt: 10.39% Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT ESTABLISHED. ACGIH TLV:NOT ESTABLISHED. Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 18.07% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9596 Ingred Name:TOLUENE (SARA 313) (CERCLA) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 4.93% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM; Z-2 ACGIH TLV:S, 50 PPM; 9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGEST:GI DISTRESS.INHAL:MAY CAUSE NOSE/THROAT IRRIT.REP/PROL OVEREXPO TO SOLVTS MAY LEAD TO PERM BRAIN/NERV SYS DMG.EYE WATERING,HEAD,NAU,DIZZ,LOSS OF COORDINATION ARE SIGNS OF TOO HIGH SOLVT LEVELS. SKIN/EYE:MAY CAUSE IRRIT/BURNING OF EYES.REP/PROL LIQ CONTACT CAN CAUSE SKIN IRRIT W/DISCOMFT/DERM. Effects of Overexposure:SEE HEALTH HAZ ABOVE.ADDN:N-BUTYL ALCOHOL:CHEM EYE BURNS,ABDNOR BLOOD FORMING FUNCTION W/ANEMIA,RECURRENT OVEREXPO-LIV/KID INJURY,ABSORBED THRU SKIN IN HARMFUL AMTS.TOLUENE:RECURRENT OVEREXPO-LIV/KID INJURY,PALP.PROPYLENE GLYCOL MONOMETHYLETHER ACETATE:MOD EYE BURN,RECURRENT OVEREXPO LIV/KID INJURY.BISPHENOL(SUPPLEME) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:IN THE UNLIKELY EVENT OF INGEST CALL PHYSICIAN IMMED.HAVE NAMES OF INGREDS AVAILABLE.INHAL:REMOVE TO FRESH AIR.BREATH DIFFICULTY PERSISTS/OCCURS LATER CONSULT PHYSICIAN.EYE:IMMED FLUSH W/PLENTYOF WATER FOR @LEAST 15MINS.CALL PHYSICIAN.SKIN:WASH W/SOAP/WATER.IRRIT OCCURS CONTACT PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:20.0F,-6.7C Autoignition Temp:Autoignition Temp Text:NP Lower Limits:0.8 Upper Limits:16 Extinguishing Media:WATER SPRAY, FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:FULL PROTECTIVE EQPMT INCLUDING SELF-CONTAINED BREATHING APPARATUS RECOMMENDED.WATER FROM FOG NOZZ MAY BE USED TO COOL CLSD CNTNR TO PREVENT PRESSURE BUILDUP. Unusual Fire/Explosion Hazard:WHEN HEATED >FLASH PT EMITS FLAMM VAP WHICH WHEN MIXED W/AIR CAN BURN/EXPLO.FINE MSITS/SPRAY MAY BE FLAMM @TEMPS BELOW FLASH PT. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA.REMOVE SOURCES OF IGN.PREVENT SKIN CONTACT/BREATH VAP.CONFINE/REMOVE W/INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:OBSERVE LABEL PRECAUT.KEEP AWAY FROM HEAT/SPARKS/FLAME.CLOSE CONTAINER AFT EACH USE.GROUND CNTNRS WHEN POURING.DON'T STORE >120F. Other Precautions:DON'T SAND/FLAME CUT/BRAZE/WELD DRY COATING W/O NIOSH/MSHA APPROVED RESPIRATOR/APPROPRIATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DON'T BREATH VAPMIST.WEAR PROPERLY FITTED VAP/PARTICLUATE RESP APPROVED BY NIOSH/MSHA FOR USE W/PAINT DURING APPLICATION & TIL VAP/SPRAY MIST EXHAUST.IN ALL CASES FOLLOW RESP MFG DIRECTIONS FOR RESP U SE.DON'T PERMIT ANYONE W/O PROT(SUPPLE) Ventilation:PROVIDE SUFFICIENT VENTI IN VOLUME/PATTERN TO KEEP CONTAMIN BELOW APPLICABLE OSHA REQMTS. Other Protective Equipment:NEOPRENE COVERALLS.INCLUDE SPLASH GUARDS/SIDE SHIELDS. Work Hygienic Practices:WASH THROUGHLY AFT HNDLG & BEF EATING/SMOKING. Supplemental Safety and Health OVEREXPO:A/EPICHLORHYDRIN POLYMER:ALLERGIC SKIN RASH,ITCH,SWELL. RESP:IN PAINTING AREA. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:169F,76C Melt/Freeze Pt:M.P/F.P Text:NP Decomp Temp:Decomp Text:NP Vapor Pres:NP Vapor Density:>AIR Spec Gravity:NP pH:NP Viscosity:NP Evaporation Rate & Reference:SLOWER THAN ETHER. Solubility in Water:MISCIBLE. Appearance and Odor:NP Percent Volatiles by Volume:28-64 Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE REASONABLY FORESEEABLE. Stability Condition to Avoid:KEEP AWAY FROM HEAT/SPAKRS/FLAME. Hazardous Decomposition Products:CO,CO2,SMOKE,OXIDES OF HEAVY METALS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DON'T ALLOW MATL TO CONTAMIN GROUND WATER SYSTEMS.SEND TO HAZ WASTE WATER TREATMENT/INCINERATE ABSORBED MATL IAW LOCAL, STATE AND FEDERAL REQMTS.DON'T INCINERATE IN CLOSED CNTNR.CONTAINS CHEMS SUBJ TO REPORTING REQMTS (SEC 313).
1
gloves_mandatory
===================== Product Identification ===================== Product ID:RUSTCO R-300-1 CAGE:01VK0 CAGE:01VK0 ============= Composition/Information on Ingredients ============= Ingred Name:MADE FROM INGREDIENTS PERMISSIBLE PER CFR 21/178.1010, CFR 21/182. ORAL LD50=RAT 1.26G/KG.SKIN=MILD.EYE=MODERATE. Fraction by Wt: NA Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN: MILDLY IRRITATING. EYES: MODERATELY IRRITATING. POSSIBLE CORNEAL DAMAGE. INGESTION: SLIGHTLY TOXIC. INHALATION: LOW VOLATILITY MAKES VAPOR INHALATION UNLIKELY. AEROSOL MAY BE IRRITATING. Effects of Overexposure:SWEATING, BURNING SENSATION, VOMITING, NAUSEA, SHORTNESS OF BREATH. Medical Cond Aggravated by Exposure:MIST MAY CAUSE EYE/RESPIRATORY IRRITATION W/COUGHING. ======================= First Aid Measures ======================= First Aid:EYE: IMMEDIATELY FLUSH W/PLENTY OF WATER 30 MIN OCCASIONALLY LIFTING LIDS. CALL DR. SKIN: REMOVE CONTAM CLOTHES. WASH W/SOAP & WATER 15 MIN. IF IRRITATION PERSISTS GET MED AID. WASH CLOTHES BEFORE REU SE. INGESTION: IF APPRECIABLE AMTS SWALLOWED CALL DR/POISON CONTROL CENTER. DRINK 1-2 GLASSES WATER. DON'T INDUCE VOMITING OR GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point:NA Fire Fighting Procedures:WEAR SCBA & FULL PROTECTIVE GEAR WHEN ENTERING CONFINED AREAS. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN TO PREVENT DISCHARGE TO ENVIRONMENT. REMOVE FREE LIQUID. SOAK UP W/INERT ABSORBENT/PLACE IN SUITABLE CONTAINER FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL DRY AREA IN ACID RESISTANT CONTAINERS BETWEEN 10F-122F. ALWAYS KEEP IN CLOSED CONTAINER WHEN NOT IN USE. DON'T GET ON SKIN/EYES/CLOTHES. Other Precautions:USE W/ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR PROPERLY FITTING NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:LOCAL EXHAUST PREFERRED. Other Protective Equipment:WEAR IMPERVIOUS APRON WHEN SPLASHING. Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:220F,104C Melt/Freeze Pt:M.P/F.P Text:NA Vapor Pres:NA Vapor Density:NA Spec Gravity:1.04 pH:5-7 Evaporation Rate & Reference:<1.0 (BUAC=1) Solubility in Water:COMPLETE Appearance and Odor:AMBER LIQUID, NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NA Stability Condition to Avoid:EXCESSIVE HEAT. Hazardous Decomposition Products:CO, CO2, HYDROGEN SULFIDE, OXIDES OF SULFUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF ABSORBED MATERIAL IN ACCORDANCE W/ALL FEDERAL, STATE, LOCAL REGULATIONS. DISPOSE OF WATER IN CONTAINED WASTE TREATMENT SYSTEM.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:CARBON MONOXIDE (6%), OXYGEN (1%) IN NITROGEN CAGE:51906 CAGE:2P651 CAGE:51906 ============= Composition/Information on Ingredients ============= Ingred Name:CARBON MONOXIDE CAS:630-08-0 RTECS #:FG3500000 Fraction by Wt: 6% Other REC Limits:NONE RECOMMENDED OSHA PEL:50 PPM/C, 200 ACGIH TLV:25 PPM; 9394 Ingred Name:OXYGEN CAS:7782-44-7 RTECS #:RS2060000 Fraction by Wt: 1% Other REC Limits:NONE RECOMMENDED Ingred Name:NITROGEN CAS:7727-37-9 RTECS #:QW9700000 Fraction by Wt: 93% Other REC Limits:NONE RECOMMENDED ACGIH TLV:ASPHYXIANT; 9394 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT KNOWN. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:HEADACHE, TACHYPNEA, NAUSEA, WEAKNESS, DIZZINESS, CONFUSION, HALUCINATIONS, CYANOSIS, ABNORMAL ELECTROCARDIOGRAM, ANGINA, SYNCOPE. CHRONIC:SOME ACUTE EFFECTS IDENTIFIED MAY BECOME CHROMIC. NITRO GEN IS A SIMPLE ASPHYXIANT WITHOUT OTHER ADVERSE EFFECTS. Effects of Overexposure:HEADACHE, TACHYPNEA, NAUSEA, WEAKNESS, DIZZINESS, CONFUSION, HALUCINATINS, CYANOSIS, ABNORMAL ELECTROCARDIOGRAM, ANGINA, SYNCOPE. Medical Cond Aggravated by Exposure:CHRONIC RESPIRATORY PROBLEMS, C0RONARY ARTERY DISEASE OR HEART DISEASE. ======================= First Aid Measures ======================= First Aid:RESPIRATORY:PROVIDE FRESH AIR OR OXYGEN AND CONSULT PHYSICIAN. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE METHODS APPROPRIATE TO SURROUNDING FIRE. Fire Fighting Procedures:NONE. Unusual Fire/Explosion Hazard:COMPRESSED GAS CYLINDERS MAY EXPLODE IN HEAT OF FIRE. WITHDRAW IMMED IN CASE OF RISING SOUND FROM VENTING SAFETY DEVICE. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AND VENTILATE AREA. Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:USE SAFE HANDLING PRACTICES FOR THE HANDLING OF COMPRESSED GAS CYLINDERS. DO NOT PUNCTURE. STORE IN COOL, DRY AREA. Other Precautions:USE SAFE STORAGE PRACTICES FOR THE STORAGE OF COMPRESSED GAS CYLINDERS. EXPOSURE TO TEMP ABOVE 150F MAY OPERATE EXCESS-PRESSURE VALVE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NECESSARY. Ventilation:RECOMMENDED. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:G3 Vapor Density:1 Solubility in Water:SLIGHT Appearance and Odor:GAS, COLORLESS, ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, BROMINE TRIFLUORIDE, CHLORINE TRIFLUORIDE,LITHIUM, NICKEL, AND OIL IN HIGH PRESSURE EQUIPMENT. Stability Condition to Avoid:NONE IDENTIFIED. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:EMPTY CONTAINERS MAY BE DISCARDED AS METAL REFUSE, OBSERVING LOCAL, STATE AND FEDERAL REGULATIONS. DO NOT INCINERATE.
0
gloves_not_mandatory
===================== Product Identification ===================== Product ID:MOBILTEMP 78 CAGE:3U728 CAGE:3U728 CAGE:0T5C6 ============= Composition/Information on Ingredients ============= Ingred Name:LUBRICATING OILS (PETROLEUM),C>25 HYDROTREATED BRIGHT STOCK-BASED; ING 1 AND 2: >90 % CAS:72623-83-7 Fraction by Wt: SEE ING Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 (OIL MIST) ACGIH TLV:5 MG/M3 (OIL MIST) Ingred Name:MINERAL OIL, PETROLEUM DISTILLATE, SOLVENT DEWAXED (MILD), HEAVY PARAFFINIC CAS:64742-65-0 RTECS #:PY8038500 Fraction by Wt: SEE # 1% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 AS OIL MIST ACGIH TLV:5 MG/M3 AS OIL MIST Ingred Name:QUATERNARY AMMONIUM COMPOUNDS, BIS(HYDROGENATED TALLOW ALKYL) DIMETHYL, SALTS WITH BENTONITE/BENTONITE CLAY 27 CAS:68953-58-2 RTECS #:UZ2996400 Fraction by Wt: <7% Other REC Limits:NONE RECOMMENDED Ingred Name:1,2,3-PROPANETRIOL/GLYCERIN (GLYCEROL) CAS:56-81-5 RTECS #:MA8050000 Fraction by Wt: 1.25% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 (MIST) ACGIH TLV:10 MG/M3 (MIST);9596 Ingred Name:MOLYBDENUM DISULFIDE CAS:1317-33-5 RTECS #:QA4697000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MG MO/M3 ACGIH TLV:10 MG MO/M3 Ingred Name:ZINC DIAMYLDITHIOCARBAMATE CAS:15337-18-5 Fraction by Wt: 0.25% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG ZN/M3 ACGIH TLV:5 MG ZN/M3 Ingred Name:SODIUM PHOSPHATE, TRIBASIC (CERCLA) CAS:7601-54-9 RTECS #:TC9490000 Fraction by Wt: 0.16% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS >5,000 MG/KG. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:NONE. ACUTE- EYES/SKIN: NOT EXPECTED TO BE A PROBLEM. INHALATION: HARMFUL CONCENTRATIONS OF MISTS AND/OR VAPORS ARE UNLIKELY TO BE ENCOUNTERED THROUGH ANY CUSTOMARY OR REASONABLY FORESEE ABLE HANDLING, USE OR MISUSE OF THIS PRODUCT. ORAL: NOT EXPECTED TO BE A PROBLEM. CHRONIC- NONE. Explanation of Carcinogenicity:NONE Effects of Overexposure:NONE ======================= First Aid Measures ======================= First Aid:CALL PHYSICIAN IF SYMPTOMS PERSIST. EYE:FLUSH WITH WATER. HOLD EYELIDS OPEN. SKIN:WIPE EXCESS OFF. WASH SKIN WITH SOAP & WATER. IF MATERIAL IS INJECTED UNDER SKIN, REGARDLESS OF APPEARANCE/SIZE, GET M EDICAL ATTENTION PROMPTLY. DO NOT WAIT FOR SYMPTOMS TO DEVELOP. INHALED:NOT EXPECTED TO BE A PROBLEM. IF GREATER THAN 1/2 LITER (PINT) INGESTED, DRINK 1-2 GLASSES OF WATER. CALL PHYSICIAN IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:>400F,>204C Extinguishing Media:WATER FOG, CARBON DIOXIDE, FOAM/DRY CHEMICAL. DIRECTLY SPRAYING WATER/FOAM ONTO BURNING OIL MAY CAUSE FROTHING. Fire Fighting Procedures:DO NOT ENTER ANY ENCLOSED OR CONFINED AREA WITHOUT PROPER PROTECTIVE EQUIPMENT AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:PICK UP SPILL WITH INERT MATERIAL SUCH AS SAND, CLAY, EARTH. SHOVEL INTO CONTAINERS FOR DISPOSAL. PREVENT RUN-OFF TO ENTER WATERWAYS, SEWERS. REPORT TO COAST GUARD AT 800-424-8802 IF SPILLS COULD REAC H ANY WATERWAYS INCLUDING DRY CREEKS. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY, VENTILATED PLACE AWAY FROM STRONG OXIDIZERS. KEEP OUT OF REACH OF CHILDREN. Other Precautions:AVOID CONTACT WITH EYES AND SKIN. WASH THOROUGHLY AFTER HANDLING. LAUNDER CLOTHING BEFORE REUSE. AVOID INHALING MISTS. DO NOT TAKE INTERNALLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. Ventilation:GENERAL ROOM VENTILATION SHOULD BE SUFFICIENT. Other Protective Equipment:EYEBATH, WASHING FACILITY Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND SHOES. Supplemental Safety and Health DIFFERENT FORMULA. MOBIL PRODUCTS ARE NOT FORMULATED TO CONTAIN PCBS. ================== Physical/Chemical Properties ================== HCC:V6 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:>600F,>316C Vapor Pres:<0.1 @ 68F Spec Gravity:0.9 Viscosity:2448SUS @100F Solubility in Water:NEGLIGIBLE Appearance and Odor:GRAY-BLACK GREASE, MILD ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:EXTREME HEAT Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, SILICON DIOXIDE, NITROGEN OXIDES, SULFUR OXIDES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN AN APPROPRIATE DISPOSAL FACILITY IN COMPLIANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. INCINERATION OR RECYCLING IS RECOMMENDED.
0
gloves_not_mandatory
===================== Product Identification ===================== Product ID:MERCURY (METAL) CAGE:DO870 CAGE:DO870 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:MERCURY (SARA III) CAS:7439-97-6 RTECS #:OV4550000 Fraction by Wt: 90-100% Other REC Limits:NONE RECOMMENDED OSHA PEL:C 0.1 MG/M3; Z-2 ACGIH TLV:S, 0.05 MG/M3; 9394 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CHRONIC EFFECTS: KIDNEY DAMAGE, LIVER DAMAGE, CENTRAL NERVOUS SYSTEM DEPRESSION, HEADACHE, SHAKES, LOOSE TEETH, IMPAIRED MEMORY, LOSS OF APETITE, SKIN ULCERATION, MERCURY BUILD-UP IN THE BRAIN, LIVER AND LIDNEYS. Explanation of Carcinogenicity:NONE SPECIFIED BY MANUFACTURER. Effects of Overexposure:INHALATION-COUGHING, CHEST PAIN, HEADACHE, NAUSEA, VOMITING, DIARRHEA, PULMONARY EDEMA, KIDNEY DAMAGE. SKIN-IRRITATION, DERMATITIS. EYE-IRRITATION. INGESTION-CORROSION OF MOUTH, THROAT AND STOMACH, GA STROINTESTINAL PAIN, GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING. Medical Cond Aggravated by Exposure:ALCOHOLISM, KIDNEY DISORDERS. ======================= First Aid Measures ======================= First Aid:INGESTION-CALL A PHYSICIAN. IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING. INHALATION-REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE CPR. IF BREATHING IS HARD, GIVE OXYGEN. SKIN-IMMEDIATELY FLU SH SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MIN. EYE-IN CASE OF CONTACT, IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE EXTINGUISHING MEDIA APPROPIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT & SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:NONE IDENTIFIED. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. CLEAN UP SPILL IMMEDIATELY. COLLECT AND STORE USING A SUCTION PUMP WITH A CAPILLARY TUBE. CALCIUM POLYSULFIDE WITH EXCESS SULFUR S HOULD BE SPRINKLED INTO CRACKS. KEEP INA BOTTLE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE IN SECURE POISON AREA. Other Precautions:RQ=1 LB. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENTILATION CONDITIONS EXIST. IF AIRBORNE CONCENTRATIONS EXCEED TLV, A SELF-CONTAINED BREATHING APPARATUS IS ADVISED. Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. Other Protective Equipment:UNIFORM, PROTECTIVE SUIT RECOMMENDED. Work Hygienic Practices:WASH AFTER HANDLING. Supplemental Safety and Health STORAGE COLOR CODE: BLUE (HEALTH) ================== Physical/Chemical Properties ================== HCC:T6 Boiling Pt:B.P. Text:675F,357C Melt/Freeze Pt:M.P/F.P Text:-38F,-39C Vapor Pres:.001 Vapor Density:7.0 Spec Gravity:13.5 Evaporation Rate & Reference:4 (N-BUTYL ACETATE=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:SILVERY-WHIE LIQUID METAL. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, AZIDES, AMMONIA, ALKALI METALS, ALUMINUM, STRONG OXIDIZING AGENTS, ACETYLENE. Stability Condition to Avoid:HEAT. Hazardous Decomposition Products:NONE IDENTIFIED. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:WHITE LEAD BASIC CARBONATE PASTE IN OIL CAGE:33151 CAGE:33151 ============= Composition/Information on Ingredients ============= Ingred Name:LEAD CARBONATE (OSHA PEL FROM 29CFR 1910.1025) CAS:598-63-0 RTECS #:OF9275000 Fraction by Wt: 89.1% OSHA PEL:0.05 MG/M3 (PB) ACGIH TLV:0.15 MG/M3 (PB);8990 Ingred Name:RAW LINSEED OIL CAS:8001-26-1 RTECS #:QI9690000 Fraction by Wt: 10.9% OSHA PEL:NA ACGIH TLV:NA ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Health Hazards Acute and Chronic:EXCESSIVE INGESTION MAY AFFECT BLOOD, NERVOUS(BRAIN); DIGESTIVE(STOMACH); RENAL (KIDNEYS), OR REPRODUCTIVE SYSTEM. SYNTHESIS OF HEMOGLOBIN IS INHABITED, & WILL RESULT IN ANEMIA. IF SYMPTOMS ARE LEFT U NTREATED, NEURO MUSCULAR DISFUNCTION,POSSIBLE PARALYSIS, AND ENCEPHALOPATHY CAN RESULT. Effects of Overexposure:SYMPTOMS INCLUDE PERSISTENT FATIGUE, SLEEP DISTURBANCE, HEADACHE, ACHING BONES &MUSCLES, CONSTIPATION, ABDOMINAL PAINS & LOSS OF APPETITE. PROLONGED INGESTION MAY BE INDICATED BY INTENSE CRAMPS, & CO NSTIPATION, NAUSEA, & VOMITING. WORSTCASE SITUATION COULD RESULT IN CONVULSION,STUPOR,COMA, & ENCEPHALOPATHY. Medical Cond Aggravated by Exposure:COLIC, ANEMIA, & NEURITIS. APATHY, & DEPRESSION MAY BE SYMPTOMS, & COULD LEAD TO NEURO MUSCULAR DISFUNCTIONS. ======================= First Aid Measures ======================= First Aid:INGESTION: GET IMMEDIATE MEDICAL ATTENTION. CALL A PHYSICIAN. SKIN: WASH THOROUGHLY WITH SOAP AND WATER. EYE: FLUSH WITH COPIOUS QUANTITIES OF WA TER. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:615F/ 324C Extinguishing Media:WATER SPRAY, DRY CHEMICAL, FOAM, CO2 Fire Fighting Procedures:WEAR FULL BODY PROTECTIVE CLOTHING & FULL FACE PIECE. S.C.B.A. OPERATED IN POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:FUME,VAPOR, AND/OR DUST MAY OCCUR, & ARE CONSIDERED TOXIC, & RESPIRATORY IRRITANTS. THE PRODUCT, OR DUST REACT VIGOROUSLY W/STRONG OXIDIZING AGENTS. ================== Accidental Release Measures ================== Spill Release Procedures:SPILLS MAY BE PICKED UP WITH SCOOPS, AND ABSORBENTMATERIALS, & TRANSFERRED TO CONTAINERS. SAFELY DISPOSE OF SATURATED ABSORBENT MATERIALS BY IMMER-SING IN WATER. WEAR PROTECTIVE CLOTHING DURING CLEAN UP. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM HIGH TEMPERATURES, & OPEN FLAMES. STORE IN DRY AREA WHERE ACCIDENTAL CONTACT WITH ACIDS OR BASES IS NOT POSSIBLE. AVOID SKIN CONTACT Other Precautions:KEEP LEAD MATERIALS AWAY FROM FEED, OR FOOD PRODUCTS. DO NOT REUSE CONTAINERS. KEEP AWAY FROM CHILDREN. THIS PRODUCT IS INTENDED FOR INDUSTRIAL USE ONLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NA Ventilation:NA Other Protective Equipment:FULL BODY CLOTHING SHOULD BE WORN DURING PRODUCT HANDLING, AND SHOULD BE LEFT AT WORK SITE.LAUNDER CLOTHING AFTER USE. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT SMOKE,EAT OR APPLY COSMETICS IN WORK AREA. Supplemental Safety and Health DO NOT WEAR ANY PART OF WORK CLOTHING HOME, THIS INCLUDES SHOES. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:NA Vapor Pres:NA Vapor Density:NA Spec Gravity:4.03 Evaporation Rate & Reference:NA Solubility in Water:INSOLUBLE Appearance and Odor:WHITE PASTE. VEGETABLE OIL ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, REACTS WITH HYDROGEN PEROXIDE. Stability Condition to Avoid:DO NOT HEAT IN THE PRESENCE OF AL, NA, TI. STABLE TO 200F; LOSES CO2 @ 375F; DECOMPOSES TO PBO AT 750F. Hazardous Decomposition Products:CO, CO2, AND POSSIBLY A CROLEIN. HIGH TEMP. OR FIRE MAY PRODUCE FUME, VAPOR OR DUST. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, ANDLOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:ZP-9C ZYGLO DEVELOPER 1 GALLON CAN CAGE:37141 CAGE:37676 CAGE:37141 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANE, 1,1,1-TRICHLORO-; (1,1,1-TRICHLOROETHANE) (SARA III) CAS:71-55-6 RTECS #:KJ2975000 Fraction by Wt: 95% OSHA PEL:350 PPM;450 STEL ACGIH TLV:350 PPM;450 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ozone Depleting Chemical:1 Ingred Name:CARBON DIOXIDE CAS:124-38-9 RTECS #:FF6400000 Fraction by Wt: 5% OSHA PEL:5000 PPM ACGIH TLV:5000 PPM;30000 STEL ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL: DIZZINESS, DROWSINESS, NAUSEA. SKIN: IRRITATING. DISSOLVE SKIN OILS. EYE: IRRITAING. CHLOROCARBON MATLS HAVE PRODUCED SENSITIZATION OF THE MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS AND COULD HAV E A SIMILAR EFFECT IN HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE CONTRAINDICATED EXCEPT FOR (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: LIFE-SUSTAINING USES IN HUMANS ACUTELY OR CHRONICALLY EXPOSED TO CHLOROCARBONS . Medical Cond Aggravated by Exposure:NONE. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. SKIN: USE SOOTHING LOTION. EYE: RINSE EYES COPIOUSLY WITH WATER FOR AT LEAST 15 MIN. INGEST: GET MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:10% Upper Limits:15% Extinguishing Media:EXTINGUISHING MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:AEROSOL CANS MAY BURST AT TEMPERATURES OVER 130F. VAPORS PARTIALLY DECOMPOSE TO TOXIC GASES WHEN EXPOSED TO FLAME, ARCS, RED HOT SURFACES. THERMAL (SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:LESS THAN ONE GALLON, WIPE UP, BEING CAREFUL NOT TO BREATHE VAPORS. ONE GALLON OR MORE, EVACUATE AREA. HAVE CLEANUP CREW WEAR NIOSH/MSHA APPROVED RESPIRATORY PROTECTION. MOP UP AND STORE IN CLOSED CON TAINER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT BREATHE VAPORS. AVOID FREQUENT OR PROLONGED EXPOSURE TO SKIN. DO NOT USE AROUND FLAMES, ARCS, OR RED HOT SURFACES. Other Precautions:DO NOT HEAT AEROSOL CNTNRS >130F. STORE AWAY FROM HEAT SOURCES. NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICINITY OF ARC WELING, OPEN FLAME OR HOT SURFACES. HEAT AND/OR UV RADIATION MAY CAUSE THE FORMATION OF HCL AND/OR PHOSGENE . ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR WITH CHEMICAL CARTRIDGE IF USING IN POORLY VENTILATED AREA. FULL MASK WITH SEPARATE AIR SUPPLY IF USING IN CONFINED, UNVENTILATED SPACE. Ventilation:USE IN SPRAY BOOTH WHERE VENTILATION IS ADEQUATE TO CARRY VAPORS FROM OCCUPIED AREAS. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXPLO HAZ: DECOMP PRODS MAY INCLUDE HCL, PHOSGENE . ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:162F,72C Vapor Pres:230 @ 100F Vapor Density:4 Spec Gravity:1.35 pH:NEUT Evaporation Rate & Reference:0.7 THAT OF ETHER Solubility in Water:PARTIAL Appearance and Odor:CLOUDY, COLORLESS LIQUID. Percent Volatiles by Volume:94 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI METALS. Stability Condition to Avoid:PARTIALLY DECOMPOSES IN FLAME, ARCS OR ON RED HOT SURFACES. Hazardous Decomposition Products:PHOSGENE AND HYDROCHLORIC ACID. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF AS EPA HAZARDOUS WASTE #F002. MAKE SURE AEROSOL CANS ARE EMPTY BEFORE DISCARDING. PRESSURIZED AEROSOL CANS ARE NOT ACCEPTABLE WASTE. DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND L OCAL REGULATIONS .
1
gloves_mandatory
===================== Product Identification ===================== Product ID:PRO-SEAL 870 CLASS A, ACCELERATOR Kit Part:Y Preparer's Name:AFS CAGE:83574 CAGE:83574 ============= Composition/Information on Ingredients ============= Ingred Name:MAGNESIUM CHROMATE CAS:13423-61-5 Fraction by Wt: 25% Other REC Limits:NONE SPECIFIED OSHA PEL:.05MG/M3C.1MG/M3STEL ACGIH TLV:0.05 MG/M3 Ingred Name:1,3-DIPHENYL GUANADINE CAS:102-06-7 RTECS #:MF0875000 Fraction by Wt: < 5% Other REC Limits:NONE SPECIFIED Ingred Name:MANGANESE DIOXIDE CAS:1313-13-9 RTECS #:OP0350000 Fraction by Wt: 40% Other REC Limits:NONE SPECIFIED OSHA PEL:5 MG/M3 CEILING ACGIH TLV:5 MG/M3 Ingred Name:HYDROGENATED TERPHENYLS CAS:61788-32-7 Fraction by Wt: 30% Other REC Limits:NONE SPECIFIED OSHA PEL:0.5 PPM ACGIH TLV:0.5 PPM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: STRONG IRRITANT. MAY CAUSE EYE DAMAGE. SKIN: IRRITATION. MAY CAUSE ALLERGIC SKIN RASH IN SENSITIZED INDIVIDUALS. INHALATION & INGESTION: ALTHOUGH THE MAIN HAZARD OF MANGANESE COMPOUNDS IS BY BRE ATHING DUST, INGESTION SHOULD BE AVOIDED AS PRECAUTION AGAIN. MANGANESE POISONING. Effects of Overexposure:SKIN: PROLONGED EXPOSURE TO HEXAVALENT CHROMIUM COMPOUNDS OVER THE PEL MAY CAUSE PAINLESS PENETRATING ULCERS OF THE SKIN. INHALATION & INGESTION: PROLONGED EXPOSURE TO HEXAVALENT CHROMIUM COMPOUNDS OV ER THE PEL MAY CAUSE PENETRATING ULCERSOF THE MUCOUS MEMBRANES OF THE NOSE & PERFORATION OF THE CARTILAG. NASAL SEPTUM ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH LUKE WARM WATER FOR 15 MINUTES. IF SYMPTOMS PERSIST, CONSULT A PHYSICIAN. SKIN: WASH WITH SOAP & WATER. IF SYMPTOMS PERSIST, CONSULT A PHYSICIAN. INHALATION: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION. INGESTION: CONSULT APHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:CO2, DRY CHEMICAL, FOAM, WATER FOG. Fire Fighting Procedures:USE AIR SUPPLIED RESPIRATOR. USE WATER TO COOL HEAT EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:NONE KNOWN. ================== Accidental Release Measures ================== Spill Release Procedures:SCOOP INTO CONTAINERS. CLEAN-UP RESIDUE WITH 1,1,1-TRICHLOROETHANE. ======================Handling and Storage ====================== Handling and Storage Precautions:WASH THOROUGHLY AFTER HANDLING & BEFORE SMOKING OR EATING. AVOID INGESTION. Other Precautions:THIS PRODUCT CONTAINS A TOXIC CHEMICAL OR CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372. ============= Exposure Controls/Personal Protection ============= Ventilation:GENERAL VENTILATION. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F3 Spec Gravity:1.8 Solubility in Water:NEGLIGIBLE Appearance and Odor:BLACK LIQUID Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES EASILY OXIDIZABLE MATERIALS Hazardous Decomposition Products:OXIDES OF CARBON, CHROMIUM COMPOUNDS ==================== Disposal Considerations ==================== Waste Disposal Methods:EPA WASTE NO. D-007. DISPOSE OF SPILLAGE IN COMPLIANCE WITH LOCAL, STATE & FEDERAL REGULATIONS.
1
gloves_mandatory
======================================================= Product ID: 52693, DERUSTO RUST PREVENTATIVE ENAMEL (SUPP DATA) Cage: 90300 Box: 277 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 90300 Box: 277 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE:EYE CONT:MAY CAUSE IRRIT. SKIN CONT:COMPONENT OF THIS PROD IN ITS CONCENTRATED STATE IS KNOWN TO CAUSE MOD IRRIT AFTER PRLNG &/OR RPTD CONT. INHAL:VAP HARMFUL. VAP MAY IRRIT NOSE & UPPER RESP TR ACT. VAP INHAL MAY AFFECT BRAIN/NERV SYS CAUSING DIZZ, HDCH/NAUS. INGEST:THIS MATL MAY BE HARMFUL/FATAL(EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: HLTH HAZ:IF SWALLOWED. IF INGESTED THIS PROD MAY CAUSE VOMIT, DIARR & DEPRESSED RESP. ASPIR OF MATL INTO LUNGS DUE TO VOMIT CAN CAUSE CHEM PNEUM WHICH CAN BE FATAL. CHRONIC:RPTS HAVE ASSOC PERM BRAIN & NERV SYS DMG W/PRLNG & RPTD OCCUP OVEREXP TO SOLVS. PRLNG/RPTD CONT W/SKIN CAN CAUSE DEFAT WHICH MAY LEAD TO Medical Cond Aggravated By Exposure: NONE KNOWN. First Aid: EYES:FLUSH W/LARGE QUANTITIES OF WATER UNTIL IRRITATION SUBSIDES (FOR AT LEAST 15 MINUTES). SKIN:IMMEDIATELY WASH W/SOAP & WATER. CONTACT MD IF IRRITATION DEVELOPS. INHAL:REMOVE TO FRESH AIR. CONTACT MD IMMEDIATELY. INGEST:DO NOT INDUCE VOMITING. CONTACT MD OR REGIONAL POISON CONTROL CENTER IMMEDIATELY. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: DIKE SPILL AREA. ABSORB REMAINING LIQUID W/ABSORBENT MATERIAL & PLACE INTO CONTAINERS. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISP OF ACCORDING TO FED, STATE & LOC STDS. DISCARDED MATL SHOULD BE INCIN AT PERMITTED FACILITY. LIQS CANNOT BE DISPOSED OF IN A LANDFILL. DO NOT REUSE EMPTY CNTNR. STATE & LOC REGS/RESTRICTIONS ARE COMPLEX & MAY DIFFER FROM FED REGS. (SUPP DATA) Handling And Storage Precautions: KEEP OUT OF REACH OF CHILDREN. AVOID SKIN & EYE CONTACT. AVOID BREATHING VAPORS. USE ONLY IN A WELL VENTILATED AREA. Other Precautions: STORE AWAY FROM CAUSTICS & OXIDIZERS. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. KEEP CONTAINERS FROM EXCESSIVE HEAT & FREEZING. DO NOT STORE AT TEMPERATURES >120F. DO NOT TAKE INTERNALLY. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: SCC Flash Point Text: 105F,41C Extinguishing Media: CO*2, DRY CHEMICAL, FOAM. Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). COOL EXPOSED CONTAINERS W/WATER. Unusual Fire/Explosion Hazard: COMBUST LIQ. CAN FORM EXPLO MIXTS AT TEMPS AT/ABOVE FLASHPOINT. CNTNRS MAY EXPLODE IF EXPOS TO EXTREME HEAT. ELIM SOURCES OF IGNIT:HEAT, ELEC EQUIP, (SUPP DATA) ======================================================= Control Measures ======================================================= Respiratory Protection: IF 8 HR EXPOS LIM/VALUE IS EXCEEDED FOR ANY COMPONENT, USE A NIOSH APPRVD RESP. CONSULT YOUR SAFETY EQUIP SUPPLIER & OSHA REG, 29 CFR 1910.134 FOR RESP REQUIREMENTS. A RESP PROT PROGRAM THAT MEETS OSH A 1910.134 & ANSI Z88.2 Ventilation: PROVIDE SUFFICIENT MECH VENT (LOC/GEN EXHST) TO MAINTAIN EXPOS BELOW PEL & TLV. VAPS ARE HVR/AIR & WILL COLLECT Other Protective Equipment: ANSI APPROVED EYE WASH FOUNTAIN & DELUGE SHOWER (FP N). PROVIDE IMPERVIOUS APRON IF BODY CONTACT W/PRODUCT IS EXPECTED. Work Hygienic Practices: WASH CONTAMINATED CLOTHING BEFORE REUSE. AVOID PROLONGED OR REPEATED CONTACT W/SKIN. Supplemental Safety and Health: NOTE:USER'S OF "L" VERSION SHOULD CONSULT "LR" VERSION FOR ADDNL INFO (FP N). MFR'S TRADE NAME/PART NO:VOC BRUSH GRADE. EXPLO HAZ:SPKS & FLAMES. DO NOT PUT IN CONT W/OXIDIZING OR CAUSTIC MATLS. WASTE DISP METH:RESPONSIBILITY FOR PROPER WASTE DISP IS W/OWNER OF WASTE. EPA WASTE CODE-IF DISCARDED (40 CFR 261): IGNITABLE. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: >240F,>116C Vapor Pres: 15 @ 38C Vapor Density: HVR/AIR Spec Gravity: 0.94-1.14 VOC Grams/Liter: 340 Evaporation Rate & Reference: FASTER THAN BUTYL ACETATE Solubility in Water: NEGLIGIBLE Appearance and Odor: LIQUID, VARIOUS COLORS; PETROLEUM ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: EXCESSIVE HEAT & FREEZING. Materials To Avoid: STRONG OXIDIZERS & CAUSTICS. Hazardous Decomposition Products: NORMAL DECOMPOSITION PRODUCTS, I.E., CO*X, NO*X. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= Other Information: VOLATILE ORGANIC COMPOUNDS:330-340 G/L (29-36%) - LESS WATER, LESS EXEMPT SOLVENT & MATERIAL. ======================================================= HAZCOM Label ======================================================= Product ID: 52693, DERUSTO RUST PREVENTATIVE ENAMEL (SUPP DATA) Cage: 90300 Company Name: DAP INC. PO Box: 277 Zipcode: 45401-0277 Label Required IND: Y Date Of Label Review: 08/13/1998 Status Code: C Label Date: 08/13/1998 Origination Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: Moderate Reactivity Hazard: None Hazard And Precautions: COMBUST. ACUTE:EYE CONT:MAY CAUSE IRRIT. SKIN CONT:COMPONENT OF THIS PROD IN ITS CONCENTRATED STATE IS KNOWN TO CAUSE MOD IRRIT AFTER PRLNG &/OR RPTD CONT. INHAL:VAP HARMFUL. VAP MAY IRRITATE NOSE & U PPER RESP TRACT. VAP INHAL MAY AFFECT BRAIN/NERV SYS CAUSING DIZZ, HDCH/NAUS. INGEST:THIS MATL MAY BE HARMFUL/FATAL IF SWALLOWED. MAY CAUSE VOMIT, DIARR & DEPRESSED RESPIRATION. ASPIR HAZ - MAY BE FAT AL. CHRONIC:ANIMAL STUDIES CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE EFTS ON CNS, BLOOD-FORMING TISSUES, BLOOD, KIDNEYS & LIVER, ASSOC W/ADMIN OF 2-BUTOXYETHANOL (FP N). POSS PERM BRAIN & NERV SYS DMG . SKIN DEFAT, DERM. MISUSE MAY BE HARMFUL/FATAL. =======================================================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:165 1900 INDUSTREX DEVELOPER REPLENISHER, PART A Kit Part:Y CAGE:19139 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 60-65% Other REC Limits:NONE SPECIFIED Ingred Name:POTASSIUM SULFITE CAS:10117-38-1 RTECS #:WT3530000 Fraction by Wt: 20-25% Other REC Limits:NONE SPECIFIED Ingred Name:HYDROQUINONE (SARA III) CAS:123-31-9 RTECS #:MX3500000 Fraction by Wt: 6% Other REC Limits:NONE SPECIFIED OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3; 9394 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:POTASSIUM HYDROXIDE (SARA III) CAS:1310-58-3 RTECS #:TT2100000 Fraction by Wt: 1-5% Other REC Limits:NONE SPECIFIED OSHA PEL:C, 2 MG/M3 ACGIH TLV:C 2 MG/M3; 9394 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:POTASSIUM CARBONATE CAS:584-08-7 RTECS #:TS7750000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE:CAUSES BURNS. SKIN:CAUSES IRRITATION. MAY CAUSE ALLERGIC REACTION. INHALED:LOW HAZARD FOR RECOMMENDED HANDLING. INGESTED:HARMFUL IF SWALLOWED. CAUSES BURNS TO G/I TRACT IF SWALLOWED. Explanation of Carcinogenicity:MFR LISTED NO INFORMATION ABOUT THE CARCINOGENICITY OF THIS MATERIAL. HMIS DOES NOT EXPECT IT TO BE CARCINOGENIC. Effects of Overexposure:EYE:BURNS. SKIN:IRRITATION, POSSIBLE ALLERGIC REACTION. INHALED:LOW HAZARD FOR RECOMMENDED HANDLING. INGESTED:BURNS TO G/I TRACT IF SWALLOWED. Medical Cond Aggravated by Exposure:NO INFORMATION GIVEN BY MFR ON MSDS. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/WATER 15 MIN, HOLD LIDS OPEN. GET IMMEDIATE MEDICAL ATTENTION. SKIN:WASH WITH SOAP & WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. GET MEDICAL CARE FOR ANY SKIN REACTION. I NHALED:REMOVE TO FRESH AIR. IF SYMPTOMSPERSIST, GET MEDICAL CARE. INGESTED:DO NOT INDUCE VOMITING. GIVE LARGE GLASS OF WATER. NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:NOT RELEVANT Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY CAUSE PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. LARGE SPILL:ABSORB W/VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. Neutralizing Agent:NO INFORMATION GIVEN BY MFR ON MSDS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED.KEEP AWAY FROM INCOMPAITBLE SUBSTANCES.DO NOT GET IN EYES & AVOID CONTACT W/SKIN & CLOTHING. USE W/ADEQUATE VENTILATION. Other Precautions:WASH THOROUGHLY AFTER HANDLING. USE OF NONALKALINE (ACID) TYPE HAND CLEANER I REGULAR CLEANING OF WORKING SURFACES, KEEP FROM CONTACT WITH OXIDIZING MATERIALS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. Ventilation:GOOD GENERAL VENTILATION (10 AIR CHANGES PER HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. Other Protective Equipment:WEAR PROTECTIVE CLOTHING APPROPRIATE FOR THE RISK OF EXPOSURE. EYE BATH, WASHING FACILITIES & SAFETY SHOWER. Work Hygienic Practices:MFR: ? HMIS:USE STRICT CHEMICAL HYGIENE PRACTICE. AVOID UNNECESSARY EXPOSURE. WASH THOROUGHLY BEFORE EATING OR DRINKING. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:B1 NRC/State Lic Num:NONE Boiling Pt:>100.C, 212.F Vapor Pres:18 MM Vapor Density:0.6 Spec Gravity:1.31 pH:12.0 Solubility in Water:COMPLETE Appearance and Odor:OFF-WHITE LIQUID, ODORLESS Percent Volatiles by Volume:65 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ACIDS Stability Condition to Avoid:HIGH TEMPERATURES AND FLAMES Hazardous Decomposition Products:SULFUR DIOXIDE Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE OR LOCAL LAWS. SMALL AMOUNTS:FLUSH TO SEWER W/LARGE AMOUNTS OF WATER. LARGE AMOUNTS:CONTRACT W/A LICENSED CHEMICAL DISPOSAL COMPANY.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:CLEANING CMPND, SOLVNT - DET (CONC ALKALINE CAGE:0FMP6 CAGE:0FMP6 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 78% Other REC Limits:NONE SPECIFIED Ingred Name:SODIUM METASILICATE PENTAHYDRATE CAS:10213-79-9 Fraction by Wt: 3% Other REC Limits:NONE SPECIFIED Ingred Name:SODIUM TRIPOLYPHOSPHATE (STPP) (SARA 313) CAS:7758-29-4 RTECS #:YK4570000 Fraction by Wt: 5% Other REC Limits:NONE SPECIFIED EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:POTASSIUM HYDROXIDE (KOH) (SARA 313) CAS:1310-58-3 RTECS #:TT2100000 Fraction by Wt: 1% Other REC Limits:NONE SPECIFIED EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TRITON X-100 CAS:9036-19-5 RTECS #:MD0907600 Fraction by Wt: 3% Other REC Limits:NONE SPECIFIED Ingred Name:ETHYLENE GLYCOL MONOBUTYL ETHER (BUTYL CELLOSOLVE) CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 5% Other REC Limits:NONE SPECIFIED OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM; 9293 Ingred Name:SODIUM XYLENE SULFONATE CAS:1300-72-7 Fraction by Wt: 5% Other REC Limits:NONE SPECIFIED Ingred Name:BLUE DYE Fraction by Wt: TRACE Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:UNKNOWN Skin:YES Ingestion:YES Effects of Overexposure:100% CONCENTRATION - PRODUCT WILL DEFAT SKIN AFTER 3 MINUTES OF CONTACT. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS CALL A PHYSICIAN. SKIN: WASH WITH COLD RUNNING WATER. INHALATION: NO HAZARDOUS FUMES. INGESTION: DRINK LARGE AMOUNTS OF WAT ER - DO NOT INDUCE VOMITING, THEN DRINKVINEGAR SOLUTION OR LEMON JUICE. SEE PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BETWEEN 25 - 120 F. ============= Exposure Controls/Personal Protection ============= Ventilation:LOCAL EXHAUST: ADEQUATE Other Protective Equipment:CAN USE SAFETY APRON Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212(+) pH:12.5-* Solubility in Water:COMPLETE Appearance and Odor:BLUE WATER LIKE FLUID; BUTYL ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES DO NOT MIX WITH ACIDS OR OXIDIZERS. ==================== Disposal Considerations ==================== Waste Disposal Methods:BIODEGRADABLE MATERIAL (PH TO 13.5) WET VACUUM PICKUP OR WATER FLUSH TO DRAIN.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:TEMPILSTIK 306F CAGE:49851 CAGE:49851 CAGE:82682 ============= Composition/Information on Ingredients ============= Ingred Name:PHENOL, 4,4'-ISOPROPYLIDENEDI-; (BISPHENOL A) CAS:80-05-7 RTECS #:SL6300000 Fraction by Wt: 70-80% Ingred Name:NON-HAZARDOUS INGREDIENTS Fraction by Wt: 20-30% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION OR SKIN OR EYE CONTACT MAY CAUSE IRRITATION. CHRONIC: MAY CAUSE GREATER IRRITATION. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:IRRITATION OF CONTACT AREA. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. IF PAIN OR IRRITATION PERSISTS, OBTAIN MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER. IF PAIN OR IRRITATION PERSISTS, OBTAIN MEDICAL ATTENTION. INHAL : REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, OBTAIN MEDICAL ATTENTION. INGEST: OBTAIN IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:400F,204C Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE KNOWN ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP AND HOLD UNUSABLE PRODUCT FOR DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. STORE IN DRY AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR TO REMOVE VAPORS. Ventilation:LOCAL EXHAUST SUFFICIENT TO REMOVE VAPORS. MECHANICAL (GENERAL) IF USED IN CLOSED AREA. Other Protective Equipment:NOT NORMALLY REQUIRED. Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USING PRODUCT. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:N1 Solubility in Water:SLIGHT Appearance and Odor:SOLID STICK; NO ODOR. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:UNKNOWN. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE CARBON DIOXIDE AND CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF UNUSABLE PRODUCT IN A CHEMICAL LANDFILL I/A/W ALL FEDERAL, STATE AND LOCAL LAWS CONCERNING HEALTH AND ENVIRONMENT.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:BRAKE SHOE SET Preparer's Name:HMIS TECHNICIAN CAGE:JO760 CAGE:7R834 CAGE:18113 CAGE:0S074 CAGE:05074 CAGE:JO760 ============= Composition/Information on Ingredients ============= Ingred Name:ASBESTOS, CHRYSOTILE CAS:12001-29-5 RTECS #:CI6478500 Other REC Limits:NONE SPECIFIED OSHA PEL:0.2 FIBERS/CC ACGIH TLV:2 FIBERS/CC; A1;9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE:MINOR EYS/SKIN IRRITATION. INGESTION- IRRITATION OF GI TRACT. INHALATION-IRRITATION OF RESPIRATORY TRACT. CHRONIC: ASBESTOSIS, LUNG CANCER, & MESOTHELIOMA, ALL OF WHICH ARE DISABLING AND FATAL D ISEASES OF THE LUNG. INHALATION AND INGESTION OF ASBESTOS FIBERS MAY CAUSE CANCER OF THE BOWEL. Explanation of Carcinogenicity:ASBESTOS IS A KNOWN HUMAN CARCINOGEN. Effects of Overexposure:INHALATION: FATIGUE AND SHORTNESS OF BREATH THAT GETS WORSE WITH TIME AND EVENTUALLY BECOMES DISABLING. EYES: IRRITATION. SKIN: IRRITATION. INGESTION: MILD STOMACH DISTRESS. DIARRHEA, VOMITING, AND NA USEA. Medical Cond Aggravated by Exposure:ASTHMA, EMPHYSEMA, AND TUBERCULOSIS ARE ALL GENERALLY AGGRAVATED BY EXPOSURE TO ASBESTOS FIBERS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. SEE DOCTOR. EYES: RINSE THOROUGHLY WITH WATER FOR 15 MINUTES. SEE DOCTOR. SKIN: WASH THOROUGHLY WITH SOAP AND WATER. IF IRRITATION PERSISTS, SEE DOCTOR. INGESTION: DIL UTE WITH WATER. DO NOT INDUCE VOMITING.SEE DOCTOR. ===================== Fire Fighting Measures ===================== Flash Point:NOT REQUIRED Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. ================== Accidental Release Measures ================== Spill Release Procedures:VACUUM THE MATERIAL WITH A HEPA FILTERED VACUUM. THE EQUIPMENT SHALL BE USED & EMPTIED SO AS TO MINIMIZE THE RE-ENTRY OF ASBESTOS INTO THE WORKPLACE. OTHERWISE, WET THE MATERIAL WITH WATER & SURFACTAN T AND THEN SHOVEL OR MOP UP CONTAMINATION. ======================Handling and Storage ====================== Handling and Storage Precautions:GASKET IS NONFRIABLE & WILL NOT SHED FIBERS IN NORMAL USE AND STORAGE. USED GASKETS SHALL BE WETTED BEFORE, DURING & AFTER DISASSEMBLY FROM AN ENGINE. Other Precautions:IF IT IS NECESSARY TO CUT OR IMPACT THE GASKET WHILE INSTALLING IT, WEAR A RESPIRATOR AND PROTECTIVE CLOTHING. USED GASKETS SHALL BE IDENTIFIED AND DISPOSED OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A NIOSH/MSHA APPROVED HEPA RESPIRATOR IF REQUIRED. WEAR SELF-CONTAINED BREATHING APPARATUS IF REQUIRED FOR HIGH LEVELS OF CONTAMINATES. Ventilation:LOCAL EXHAUST SUFFICIENT TO ENTRAIN ALL PARTICULATE EMISSIONS. HEPA FILTER REQUIRED. NO LEAKS ON PRESSURE SIDE OF FAN. Other Protective Equipment:USE COVERALLS OR DISPOSABLE CLOTHING. Work Hygienic Practices:WET WORK TO THE DEGREE POSSIBLE. WASH HANDS AFTER HANDLING GASKET. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health MSDS GENERATED BY HMIS TECHNICIAN. MANUFACTURER IS UNKNOWN OR OUT OF BUSINESS. ================== Physical/Chemical Properties ================== HCC:T6 Solubility in Water:INSOLUBLE Appearance and Odor:BRAKE SHOE SET Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG MINERAL ACIDS, AND STRONG ALKALIS Stability Condition to Avoid:ACCUMULATIONS OF DUST Hazardous Decomposition Products:ASBESTOS DUST ==================== Disposal Considerations ==================== Waste Disposal Methods:WET THE MATERIAL WITH WATER AND SURFACTANT. PLACE IN 6 MIL THICK POLYETHYLENE PLASTIC BAG. PLACE THESE BAGS INTO ANOTHER POLY BAG OR A SAFE PLACE UNTIL IT CAN BE SHIPPED TO AN APPROVED DISPOSAL SITE. IDENTIFY WITH ASBESTOS CANCER WARNING LABEL.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:HC 200/45330 1 GAL HISTOPREP BUFFERED 10% FORMALIN CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:FORMALDEHYDE, FORMALIN (SUSPECTED HUMAN CARCINOGEN BY IARC; ACGIH; SUSPECTED CARCINOGEN BY NTP; IARC - GROUP 2A) *97-4* CAS:50-00-0 RTECS #:LP8925000 Fraction by Wt: 4% ACGIH TLV:0.37 MG/CUM IC (2A) EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:METHANOL (METHYL ALCOHOL), COLUMBIAN SPIRITS *97-4* CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 1% Other REC Limits:200 PPM OSHA PEL:200 PPM ACGIH TLV:200 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SODIUM PHOSPHATE, DIBASIC, ANHYDROUS, DISODIUM PHOSPHATE CAS:7558-79-4 RTECS #:WC4500000 Fraction by Wt: 0.65% EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 90% Ingred Name:PHOSPHORIC ACID, MONOSODIUM SALT, MONOHYDRATE *97-3* CAS:10049-21-5 Fraction by Wt: 0.4% ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT):5628 MG/KG METHYL ALCOHOL Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION. SKIN: IRRITATION, MAY CAUSE SENSITIZATION, AN ALLERGIC REACTION. INGESTION: FATAL, CAUSES GI IRRITATION, LIVER & KIDNEY DAMAGE, CNS DEPRESSION & DEATH. INHALATION: MAY CAUSE CNS EFFE CTS, RESPIRATORY TRACT IRRITATION, ALLERGIC SENSITIZATION. Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:IRRITATION, BLINDNESS, NAUSEA, VOMITING, DIARRHEA, HEADACHE, DIZZINESS, DROWSINESS, COLLAPSE, UNCONSCIOUSNESS, COMA, RESPIRATORY FAILURE, ASTHMATIC ATTACKS, DISCOLORATION, THICKENING & NAIL DECAY. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR 15 MINS. DON'T ALLOW VICTIM TO RUB/CLOSE. SKIN: FLUSH W/PLENTY OF SOAP & WATER FOR 15 MINS. INGESTION: DON'T INDUCE VOMITING. IF CONSCIOUS & ALERT GIVE 2-4 CUPFULS OFMILK/WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN. TREAT SYMPTOMATICALLY & SUPPORTIVELY. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:185F Lower Limits:7 Upper Limits:73 Extinguishing Media:SMALL: DRY CHEMICAL, CO2, WATER SPRAY/ALCOHOL-RESISTANT FOAM. Fire Fighting Procedures:WEAR SCBA IN PRESSURE DEMAND MSHA/NIOSH APPROVED/EQUIVALENT & FULL PROTECTIVE GEAR. USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL. Unusual Fire/Explosion Hazard:COMBUSTIBLE LIQUID. VAPORS CAN TRAVEL TO A SOURCE OF IGNITION & FLASH BACK. CAN FORM EXPLOSIVE MIXTURES AT TEMPS ABOVE THE FLASHPOINT. AUTOIGNITION TEMP: 806F. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT. REMOVE SOURCES OF IGNITION. ABSORB USING AN ABSORBENT, NON-COMBUSTIBLE MATERIAL SUCH AS EARTH, SAND/VERMICULITE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY WELL VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES. KEEP CONTAINER TIGHTLY CLOSED. USE ONLY IN A WELL VENTILATED AREA. Other Precautions:AVOID CONTACT W/EYES, SKIN/CLOTHING. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE & CAN BE DANGEROUS. DON'T PRESSURIZE/CUT/WELD/BRAZE/SOLDER/DRILL/GRIND/EXPOSE SUCH CONTAINERS TO HEAT, SPARKS/OPEN FLAMES. AVOID INGESTION & INHALATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE A NIOSH APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:ADEQUATE GENERAL/LOCAL EXHAUST TO KEEP AIRBORNE CONCENTRATIONS BELOW THE EXPOSURE LIMITS. Other Protective Equipment:PROTECTIVE CLOTHING. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. DESTROY CONTAMINATED SHOES. Supplemental Safety and Health PH: 6.8-7.2. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F Vapor Pres:25 Spec Gravity:1.02 pH:(SUPP) Solubility in Water:COMPLETE Appearance and Odor:COLORLESS LIQUID W/PUNGENT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAMES/SOURCES OF IGNITION. Hazardous Decomposition Products:CO, OXIDES OF PHOSPHORUS, IRRITATING & TOXIC FUMES & GASES, CO2, TOXIC FUMES OF SODIUM OXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:CAAPCOAT AS-P108 BLACK ANTISTATIC POLYURETHANE RAIN EROSION- Preparer's Name:CHRISTINE L SLEDGE CAGE:60922 CAGE:60922 ============= Composition/Information on Ingredients ============= Ingred Name:XYLENE, DIMETHYLBENZENE, XYLOL (IARC - GROUP 3) *96-3* CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 54.7% Other REC Limits:100 PPM OSHA PEL:100 PPM ACGIH TLV:100 PPM, SKIN EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:COLUMBIA CARBON, CARBON BLACK, LAMPBLACK, BLACK PEARLS (IARC CARC GROUP 3) - *96-3* CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: 1.6% Other REC Limits:3.5 MG/CUM (NIOSH) OSHA PEL:3.5 MG/CUM ACGIH TLV:3.5 MG/CUM Ingred Name:1,3-DIISOCYANATOMETHYL-BENZENE, DIISOCYANATOTOLUENE, (IARC GROUP2B,NTP SUSPECTED CARCINOGEN,IARC ANIMAL SUFFICIENT*96-3* CAS:26471-62-5 RTECS #:HQ9490000 Fraction by Wt: 0-0.5% EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:POLYPROPYLENE GLYCOL, POLY(1,4-BUTYLENE)GLYCOL, TOLUENE DIISOCYANATE POLYMER CAS:65636-36-4 Fraction by Wt: 43.7% Ingred Name:VOLATILE ORGANIC CONTENT: 471 GM/L; (3.93 LBS/GAL) RTECS #:9999999VO ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: MAY CAUSE IRRITATION & BURNING. MAY CAUSE DAMAGE. SKIN: IRRITATION, BURNING. REPEATED/PROLONGED EXPOSURE MAY CAUSE DERMATITIS, POSSIBLE SENSITIZATION. INHALATION: MAY CAUSE THROAT & RESPIRATORY IRRITATION. MAY CAUSE NEURAL IMPAIRMENT. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, DEFATTING, BURNING, HEADACHE, DIZZINESS, LOSS OF APPETITE, NAUSEA Medical Cond Aggravated by Exposure:PRE-EXISTING ALLERGIES, EYE, SKIN & RESPIRATORY DISORDERS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER. SKIN: WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR, GIVE CPR IF NECESSARY. INGESTION: DON'T INDUCE VOMITING. IF VOMITING OCCURS SPONTANEOUSLY, KEEP HEAD BELOW HIS HIPS TO PREVENT BREATHING VOMITUS INTO LUNGS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:80F Lower Limits:1 Upper Limits:7 Extinguishing Media:CO2, FOAM, DRY CHEMICAL Fire Fighting Procedures:WATER MAY BE USED TO COOL FIRE EXPOSED CONTAINERS. WEAR SELF CONTAINED BREATHING APPARATUS & PROTECTIVE ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE IGNITION SOURCES. WEAR SOLVENT PRESSURE AIR-SUPPLIED RESPIRATOR. CONTAIN W/DIKES OF ABSORBENT & SOAK UP. CLEAN UP & CONTAIN. SWEEP& WET MOP AREA W/SOAP & WATER. VENTILATE AREA. ======================Handling and Storage ====================== Other Precautions:ONLY PROPERLY TRAINED & PROTECTED PERSONNEL SHOULD BE IN THE IMMEDIATE SPRAY AREA. VENTILATION SYSTEMS SHOULD BE DESIGNED TO DRAW AIR PAST THE OPERATOR, THEN PAST THE SOURCE OF VAPOR & THEN TO THE EXH AUST., NOT THE REVERSE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF USE CONDITIONS GENERATE VAPORS/MISTS, WEAR A NIOSH APPROVED RESPIRATOR FOR THOSE EMISSION LEVELS AT POINT OF USE. OTHER RESPIRATORS: A FULL FACEPIECE/A PURIFYING CARTRIDGE RESPIRATOR EQUIPPED FOR O RGANIC VAPORS/MISTS, SCBA. Ventilation:SPRAY BOOTH FOR SPRAY APPLICATIONS. EXHAUST: SUFFICIENT TO KEEP AIRBORNE CONCENTRATIONS 100F, HOT SURFACES & ALL IGNITION SOURCES Hazardous Decomposition Products:BY COMBUSTION: CO, CO2, OXIDES OF NITROGEN, TRACES OF HYDROGEN CYANIDE & UNIDENTIFIED COMPOUNDS IN BLACK SMOKE ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE IN A LICENSED INCINERATOR. WHEN THE AS-P108 & CATALYST ARE MIXED TOGETHER & THE SOLVENT IS EVAPORATED, THE SOLID END PRODUCT IS A NON-HAZARDOUS LANDFILL ITEM. DISPOSE OF IAW/LOCAL, STATE &FEDERAL REGULATIONS. FLAMMABLE LIQUID UN1263.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:SODIUM-P-TOLUENE SULFON CHLORAMIDE, 0177925 Preparer's Name:GASTON L PILLORI CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:P-TOLUENE SULFONAMIDE, N-CHLORO-, SODIUM SALT; (CHLORAMINE T) CAS:127-65-1 RTECS #:XT5616800 Fraction by Wt: 100% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL: IRRITANT. (ACUTE) MAY CAUSE MUC MEMB IRRIT, RHINITIS, AND OCCASIONAL ALLERGIC RESPIRATORY RXNS. SKIN: IRRITANT. MAY CAUSE MILD IRRIT. EYE: IRRITANT. CONTACT WITH DUST, MIST, OR SOLUTIONS MAY CA USE REDNESS, PAIN OR IRRITATION. INGEST: INGEST OF TOXIC AMTS MAY CAUSE NAUSEA, ABDOM PAIN, VOMIT, (SEE EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: FROTHING AT MOUTH, COLLAPSE, CIRCULATORY AND/OR RESPIRATORY FAILURE, CYANOSIS, AND DEATH. (CHRONIC) INHALE: RPTD/PRLNGD CONT TO DUST MAY CAUSE ASTHMA & MUC MEMB IRRIT. SKIN: NO DATA AVAILABL E. EYE: RPTD/PRLNGD CONT MAY CAUSE CONJUNCTIVITIS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE FROM EXPOS AREA TO FRESH AIR IMMED. IF BRTHG STOPS, PERFORM ARTF RESP. KEEP PERSON WARM & AT REST. GET MD IMMED. SKIN:REMOVE CONTAM CLTHG & SHOES. WASH AFFECTED AREA W/SOAP/MILD DETERGENT & LRG AMTS OF WATER UNTIL NO EVIDENCE OF CHEM REMAINS (APPROX 10- 20 MIN). GET MD IF NEEDED. EYE:WASH IMMED W/LRG AMTS OF WATER, OCCASNLY LIFTING UPPER & LOWER LIDS, UNTIL NO EVIDENCE OF (SUPP DATA) ===================== Fire Fighting Measures ===================== Flash Point:378F,192C Extinguishing Media:DRY CHEMICAL OR CARBON DIOXIDE. FOR LRG FIRES, USE WATER SPRAY, FOG OR ALCOHOL FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA W/FULL FACEPIECE OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE.MOVE CNTNR BRTHG VAPOR/DUST. KEEP UPWIND. Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE AND EXPLOSION HAZARD WHEN EXPOSED TO HEAT OR FLAME. SEE HAZARDOUS DECOMP PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP AND PLACE IN SUITABLE (FIBERBOARD) CONTAINERS FOR LATER DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN TIGHTLY CAPPED CONTAINERS BELOW 95F (35C). KEEP AWAY FROM HEAT. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:EXPOS LIMIT TO 1000 MG/M3(TDUST)-NIOSH/MSHA APPRVD HEPA FILTER W/FULL FACEPIECE. 10,000 MG/M3(TDUST)-NIOSH/MSHA APPRVD SUPPLIED-AIR RESP W/FULL FACEPIECE, HELMET, OR HOOD. NIOSH/MSHA APPRVD SCBA W/FUL L FACEPIECE. Ventilation:PROVIDE LOCAL EXHAUST OR GENERAL DILUTION VENTILATION SYSTEM. Other Protective Equipment:PROTECTIVE CLOTHING NOT REQUIRED. AVOID REPEATED OR PROLONGED CONTACT WITH THIS SUBSTANCE. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRST AID PROC:CHEM REMAINS(APPROX 15-20 MIN). GET MD IMMED. INGEST:IF VICTIM IS CONSCIOUS, IMMED GIVE 2 TO 4 GLASSES OF WATER & INDUCE VOMIT BY TOUCHING FINGER TO BACK OF THROAT. IF BRTHG STOPS, GIVE ARTF RESP. IF BRTHG DFCLT, GIVE OXYGEN. GET MD IMMED. NIOSH/MSHA APPRVD SCBA W/FULL FACEPIECE OPER(SEE ING 2) ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:M.P/F.P Text:266F,130C pH:NEUT Solubility in Water:15% Appearance and Odor:WHITE TO YELLOW POWDER WITH SLIGHT ODOR OF CHLORINE. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MAY REACT VIGOROUSLY WITH ACIDS, AND CHLORINE. Stability Condition to Avoid:KEEP AWAY FROM HEAT. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RELEASE TOXIC NOX AND SOX. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS .
1
gloves_mandatory
===================== Product Identification ===================== Product ID:8278178 KODAK 24 FIXER 1/2 GAL READY TO USE CAGE:19139 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 60-70% Ingred Name:THIOCYANIC ACID, AMMONIUM SALT, AMMONIUM THIOCYANATE CAS:1762-95-4 RTECS #:XK7875000 Fraction by Wt: 10-15% EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:AMMONIUM THIOSULFATE CAS:7783-18-8 RTECS #:XN6465000 Fraction by Wt: 10-15% Ingred Name:SODIUM SULFITE CAS:7757-83-7 RTECS #:WE2150000 Fraction by Wt: 5-10% Other REC Limits:5 MG/CUM (DUST) Ingred Name:POTASSIUM SULFITE CAS:10117-38-1 RTECS #:WT3530000 Fraction by Wt: 5-10% Ingred Name:ACETIC ACID (GLACIAL), ETHANOIC ACID *96-3* CAS:64-19-7 RTECS #:AF1225000 Fraction by Wt: <5% OSHA PEL:25 MG/CUM ACGIH TLV:25 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: MAY BE IRRITATING. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. EYES: WASH OUT IMMEDIATELY W/WATER. SKIN: WASH AFTER EACH CONTACT. INGESTION: DRINK 1-2 GLASSES OF WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CO2. Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:FIRE/EXCESSIVE HEAT MAY CAUSE PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH MATERIAL TO SEWER W/LARGE AMOUNTS OF WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP FROM CONTACT W/OXIDIZING MATERIALS. Other Precautions:AVOID MINERAL ACIDS, ALKALIS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:MAY BE NEEDED IN SPECIAL CIRCUMSTANCES. Ventilation:GOOD: SHOULD BE SUFFICIENT. Other Protective Equipment:MAY BE REQUIRED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F Vapor Pres:18 Vapor Density:0.6 Spec Gravity:1.16 pH:5 Solubility in Water:COMPLETE Appearance and Odor:COLORLESS TO SLIGHTLY PINK SOLUTION W/VINEGAR ODOR Percent Volatiles by Volume:70/WT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI, MINERAL, ACIDS, STRONG OXIDIZERS. Hazardous Decomposition Products:AMMONIA, SULFUR DIOXIDE, CARBON, CO2. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE TREATMENT/DISPOSE IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:91901 REGAL BLUE, VOC COMPLIANT INDUSTRIAL (SUPDAT) CAGE:DO934 CAGE:DO934 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE (PROPELLANT). VP:760. CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 13% OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT Ingred Name:PROPANE, 2-METHYL-; (2-METHYLPROPANE (PROPELLANT)). VP:760. CAS:75-28-5 RTECS #:TZ4300000 Fraction by Wt: 13% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:XYLENE (SARA 313) (CERCLA). VP:5.9. CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 15% OSHA PEL:100 PPM ACGIH TLV:100 PPM;150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ACETONE (SARA 313) (CERCLA). VP:180. CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 19% OSHA PEL:1000 PPM ACGIH TLV:750 PPM;1000 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA 313) (CERCLA). VP:70. CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 2% OSHA PEL:200 PPM ACGIH TLV:200 PPM;300 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BARIUM SULFATE CAS:7727-43-7 RTECS #:CR0600000 Fraction by Wt: 16% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:VOLATILE ORGANIC COMPOUNDS (BAAQMD RULE 49): 62% BY WT. RTECS #:9999999VO Ingred Name:SUPDAT:SOLVS W/PERM BRAIN & NERV SYS DMG. INTENTIONAL MISUSE BY DELIB CONC & INHALING CONTENTS CAN BE HARMFUL/FATAL. RTECS #:9999999ZZ Ingred Name:WASTE DISP METH:DEPRESSURIZE CONTAINER. DISPOSE OF I/A/W FEDERAL, STATE & LOCAL REGULATIONS REGARDING POLLUTION. RTECS #:9999999ZZ Ingred Name:OTHER PREC:GROUNDING PROCS. CONTENTS UNDER PRESS. DO NOT PUNCTURE, INCIN/EXPOSE TO TEMP >120F. HEAT FROM (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:SUNLIGHT, RADIATORS, STOVES, HOT WATER & OTHER HEAT SOURCES COULD CAUSE CNTNR TO BURST. DO NOT TAKE (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:INTERNALLY. KEEP OUT OF REACH OF CHILDREN. USE ONLY W/ADEQ VENT. AVOID CONT W/SKIN & EYES. THIS COATING (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:MAY CONTAIN MATLS CLASSIFIED AS NUISANCE PARTICULATES WHICH MAY BE PRESENT AT HAZ LEVELS ONLY DURING (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:SANDING/ABRADING OF DRIED FILM. IF NO SPECIFIC DUSTS ARE LISTED, APPLIC LIMS FOR NUISANCE DUSTS ARE ACGIH(ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:TLV 10 MG/M3 TDUST, OSHA PEL 15 MG/M3 TDUST, 5 MG/M3 RESPIRABLE FRACTION. RTECS #:9999999ZZ Ingred Name:RESP PROT:DUST WHICH MAY BE GENERATED FROM THIS PRODUCT, UNDERLYING PAINT OR THE ABRASIVE. RTECS #:9999999ZZ Ingred Name:VENT:1910.94, 1910.107, 1910.108. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EXPOS MAY BE BY INHAL &/OR SKIN/EYE CONT, DEPENDING ON CNDTNS OF USE. TO MIN EXPOS, FOLLOW RECS FOR PROPER USE, VENT & PERSONAL PROT EQUIP. ACUTE:IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERV SYS DEP RESS. EXTREME OVEREXP MAY RSLT IN UNCON& POSS DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:OF EXCESSIVE EXPOS TO VAPS/SPRAY MISTS. REDNESS & ITCH/BURNING SENSATION MAY INDICATE EYE/EXCESSIVE SKIN EXPOS. CHRONIC:PRLNG OVEREXP TO SOLV INGS MAY CAUSE ADVERSE EFTS TO LIVER, URINARY, BL OOD FORMING, CVS & REPRO SYS. METHYL ETHYL KETONE MAY INCR NERV SYS EFTS OF OTHER SOLVS. REPORTS HAVE ASSOC RPTD(SUPDAT) Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM & QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE RE-USE. EYES:FLUSH W/LARGE AMOUNTS OFWATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGEST:GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:<0F,<-18C Lower Limits:0.9% Upper Limits:12.8% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. WATER SPRAY MAY BE INEFT. IF WATER IS USED, FOG NOZZ ARE PREF. WATER MAY BE USED TO COOL CLSD CNTNRS(SUPDAT) Unusual Fire/Explosion Hazard:EXTREMELY FLAMM. ISOLATE FROM HEAT, ELEC EQUIP, SPKS & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME HEAT. APPLICATION TO HOT SURFS REQS (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE & REMOVE W/INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DOL STOR CATEGORY - 1A. KEEP AWAY FROM HEAT, SPKS & OPEN FLAME. VAPS WILL ACCUM READILY & MAY IGNITE EXPLOSIVELY. AVOID BRTHG VAP & SPRAY MIST. Other Precautions:DURING USE & UNTIL ALL VAPS ARE GONE - KEEP AREA VENTILATED; DO NOT SMOKE; EXTING ALL FLAMES, PILOT LIGHTS & HEATERS; TURN OFF STOVES, ELEC TOOLS & APPLIANCES & ANY OTHER SOURCES OF IGNIT. CONSULT NFP A CODE. USE APPRVD BONDING & (ING 10) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIMS BY VENT, WEAR PROPERLY FITTED NIOSH/MSHA APPRVD ORG VAP/PARTICULATE RESP FOR PROT AGAINST INGS. WHEN SANDING/ABRADING DRIED FILM, WEAR NIOSH/MS HA APPRVD DUST/MIST RESP FOR (ING 16) Ventilation:LOC EXHST PREF. GEN EXHST ACCEPT IF EXPOS TO INGS IS MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS (ING 17) Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH HANDS AFTER USING. Supplemental Safety and Health MFR'S TRADE NAME/PART NO:MAINTENANCE COLORS - 2. FIRE FIGHT PROC:TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOS TO EXTREME HEAT. EXPLO HAZ:SPECIAL PRECS. DURING EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN. EFTS OF OVEREXP:& PRLNG OVEREXP TO (ING 8) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:<395F,<202C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Evaporation Rate & Reference:FASTER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:>65 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF METALS IN INGREDIENTS SECTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM THIS PROD MAY BE HAZ AS DEFINED UNDER RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE APPLIC EPA HAZ WASTE NUMBERS. WASTE FROM PROD CNTNG METHYL ETHYL KETONE MAY REQ TES TING FOR EXTRACTABILITY. DO NOT INCIN. (ING 9)
1
gloves_mandatory
======================================================= Product ID: DUCT SEAL, 31-601, 31-605 Cage: 30119 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 30119 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: NO Skin: YES Ingestion: NO Carcinogenicity Inds - NTP: YES IARC: YES OSHA: NO Explanation Of Carcinogenicity: Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: IF TOO SENSITIVE, SEEK MEDICAL ATTENTION. EYES:DO NOT REMOVE, SEEK MEDICAL ATTENTION. FLUSH EYES WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES (FP N). SKIN:FLUSH WITH COPIOUS AMOUNTS OF WATER. CALL MD IMMEDIATELY (FP N). INGEST:NOTLIKELY. IF INGESTED, CONSTIPATION OR BLOCKAGE MAY OCCUR. SEEK MED ATTENTION. INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTIFICIAL RESP) (FP N). ======================================================= Handling and Disposal ======================================================= Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: COMPLY WITH FEDERAL, STATE AND LOCAL REGULATIONS FOR SOLID LANDFILL. Handling And Storage Precautions: STORE IN A COOL, DRY PLACE. Other Precautions: NONE SPECIFIED BY MANUFACTURER. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: COC Flash Point Text: 1094F,590C Extinguishing Media: USE WATER, FOAM, CARBON DIOXIDE OR DRY CHEMICAL Fire Fighting Procedures: NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). OXIDES OF NITROGEN AND CARBON MAY EVOLVE. Unusual Fire/Explosion Hazard: NONE KNOWN ======================================================= Control Measures ======================================================= Other Protective Equipment: FOR SENSITIVE INDIVIDUALS, PROTECT SKIN FROM CONTACT. Work Hygienic Practices: WASH HANDS WITH SOAP AND WATER BEFORE EATING. Supplemental Safety and Health: NONE SPECIFIED BY MANUFACTURER. ======================================================= Physical/Chemical Properties ======================================================= HCC: N1 B.P. Text: NONE Spec Gravity: 1.65 (H*2O=1) Solubility in Water: NEGLIGIBLE Appearance and Odor: DARK GRAY PUTTY, MILD RUBBER ODOR. Percent Volatiles by Volume: 2 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Materials To Avoid: STRONG OXIDIZERS, ACIDS, BASES. Hazardous Decomposition Products: OXIDES OF NITROGEN AND CARBON MAY EVOLVE Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: DUCT SEAL, 31-601, 31-605 Cage: 30119 Company Name: IDEAL INDUSTRIES INC Street: BECKER PL Zipcode: 60178 Label Required IND: Y Date Of Label Review: 11/22/1994 Status Code: C Label Date: 11/22/1994 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: None Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: ACUTE:NONE LISTED BY MANUFACTURER. CHRONIC:CANCER HAZARD. CONTAINS A MATERIAL WHICH IS LISTED AS A LUNG CARCINOGEN (FP N). =======================================================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:ALUMINUM PHOSPHIDE, PHOSTOXIN CAGE:59471 CAGE:59471 CAGE:8C885 ============= Composition/Information on Ingredients ============= Ingred Name:ALUMINUM PHOSPHIDE (SARA 302) (CERCLA) CAS:20859-73-8 RTECS #:BD1400000 Fraction by Wt: 55% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:INERT INGREDIENTS (INCLUDING INGREDIENT # 3) Fraction by Wt: 45% Other REC Limits:NONE RECOMMENDED Ingred Name:AMMONIUM CARBAMATE (CERCLA) CAS:1111-78-0 RTECS #:EY8575000 Fraction by Wt: SEE # 2% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT) = 11.5 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PHOSTOXIN IS A HIGHLY ACUTE TOXIC SUBSTANCE. PHOSTOXIN IS NOT KNOWN TO CAUSE CHRONIC POISONING. Explanation of Carcinogenicity:PHOSTOXIN IS NOT KNOWN TO BE CARCINOGENIC AND IS NOT LISTED AS SUCH BY NTP, IARC OR OSHA. Effects of Overexposure:ALUMINUM PHOSPHIDE TABLETS, PELLETS OR DUST REACTS WITH AIR MOISTURE, ACIDS & MANY OTHER LIQUIDS TO RELEASE HYDROGEN PHOSPHIDE GAS. INHALING GAS MAY CAUSE MALAISE, RINGING IN EARS, FATIGUE, NAUSEA, VO MITING, DIARRHEA, WEAKNESS, PAIN JUST ABOVE STOMACH, CHEST PAIN, DYSPNEA, PULMONARY EDEMA, DIZZINESS, COMA & DEATH. Medical Cond Aggravated by Exposure:MFR GAVE NO INFORMATION OF MSDS. ======================= First Aid Measures ======================= First Aid:IF ANY IRRITATION PERSISTS OR SEVERE, GET MEDICAL ATTENTION. EYE:FLUSH W/WATER FOR 15 MIN. SKIN:WASH W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. (DO NOT LEAVE CONTAMINATED CLO THING IN UNVENTILATED AREA.) INHALED:REMOVE FROM EXPOSURE. AID OR RESTORE BREATHING AS NEEDED. INGESTED:IF CONSCIOUS, GIVE 2 GLASSES OF WATER & INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:SUFFOCATE FLAMES WITH SAND, CARBON DIOXIDE OR DRY EXTINGUISHING CHEMICALS. Fire Fighting Procedures:DO NOT USE WATER ON METAL PHOSPHIDE FIRES. WEAR NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING APPARATUS OR EQUIVALENT RESPIRATORY PROTECTION. Unusual Fire/Explosion Hazard:READILY REACTS WITH WATER TO PRODUCE HYDROGEN PHOSPHIDE GAS WHICH MAY IGNITE SPONTANEOUSLY IN AIR AT CONCENTRATIONS ABOVE ITS LEL OF 1.8%. ================== Accidental Release Measures ================== Spill Release Procedures:FRESHLY SPILLED MATERIAL THATS NOT CONTAMINATED MAY BE REPLACED INTO ORIGINAL CONTAINER. PUNCTURED FLASKS OR CONTAINERS MAY BE TEMPORARILY REPAIRED USING ALUMINUM TAPE. IF AGE OF SPILL IS UNKNOWN, GAT HER UP IN SMALL OPEN BUCKET (1-1.5 KG PER BUCKET.) Neutralizing Agent:SEE SUPP DATA FOR WET DEACTIVATION PROCEDURE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A LOCKED, DRY, WELL VENTILATED AREA AWAY FROM HEAT.POST AS A PESTICIDE STORAGE AREA. DO NOT STORE IN BUILDING INHABITED BY MAN OR ANIMALS. Other Precautions:OPEN CONTAINERS ONLY IN OPEN AIR. DO NOT ALLOW WATER OR OTHER LIQUIDS TO CONTACT PRODUCT. ONCE EXPOSED, DO NOT CONFINE. DO NOT OPEN IN FLAMMABLE ATMOSPHERE. INHALATION TOXICITY IS HIGH. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED FULL FACE MASK WITH APPROVED CANISTER FOR PHOSPHINE MAY BE WORN AT CONCENTRATIONS UP TO 15 PPM. AT LEVELS ABOVE THIS OR WHEN THE HYDROGEN PHOSPHIDE CONCENTRATIONS IS UNKNOWN, NIOSH /MSHA APPROVED SCBA MUST BE WORN. Ventilation:LOCAL VENTILATION IS ADEQUATE. EXHAUST FANS MAY BE USED TO SPEED THE AERATION OF SILOS, WAREHOUSES, SHIPHOLDS,CONTAINERS Other Protective Equipment:MFR GAVE NO INFORMATION OF MSDS. Work Hygienic Practices:MFR GAVE NO INFORMATION OF MSDS. Supplemental Safety and Health PERFORM WET DEACTIVATION OUTSIDE & W/SCBA. PREPARE 2% SOLUTION OF LOW SUDS DETERGENT (DEACTIVATE NO MORE THAT 45 LB/15 GAL SOLUTION.) SLOWLY & W/STIRRING, ADD PHOSTOXIN. ALLOWE TO STAND (W/INTERMITTAN T STIRRING) FOR 36 HOURS. MAY THEN BE LANDFILLED OR SEWERED IF W/I LOCAL REGULATIONS. CALL DEGESH FOR ASSISTANCE. ================== Physical/Chemical Properties ================== HCC:R2 NRC/State Lic Num:NONE pH:UNKNON Appearance and Odor:GREENISH GRAY COLOR. HYDROGEN PHOSPHIDE HAS GARLIC OR DECAYING FISH ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH WATER AND OXIDIZING AGENTS. Stability Condition to Avoid:THEY WILL REACT WITH MOIST AIR, LIQUID WATER, ACIDS & SOME OTHER LIQUIDS TO PRODUCE TOXIC & FLAMMABLE HYDROGEN GASES. Hazardous Decomposition Products:HYDROGEN PHOSPHIDE (PHOSPHINE) GAS UPON CONTACT WITH WATER OR MOISTURE. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:SMALL AMOUNTS OF SPILLAGE, FROM ABOUT 4 TO 8 KG MAY BE SPREAD OUT OVER THE GROUND IN AN OPEN AREA TO BE DEACTIVATED BY ATMOSPHERIC MOISTURE.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:RT FILM DEVELOPER, PART B CAGE:40003 CAGE:0TR15 CAGE:40003 CAGE:40023 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 85-90% Other REC Limits:NONE RECOMMENDED Ingred Name:SODIUM METABISULFITE CAS:7681-57-4 RTECS #:UX8225000 Fraction by Wt: 10-15% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3; 9394 Ingred Name:SODIUM GLUTARALDEHYDE BISULFITE CAS:28959-35-5 Fraction by Wt: 5-10% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE:VAPOR MAY CAUSE IRRITATION, CONTACT MAY CAUSE BURNS. SKIN:PROLONGED/REPEATED SKIN CONTACT MAY CAUSE IRRITATION. INHALED:LOW HAZARD FOR ORDINARY INDUSTRIAL HANDLING. INGESTED:DO NOT TAKE INTERNALLY . MAY CAUSE NAUSEA. Explanation of Carcinogenicity:THIS PRODUCT CONTAINS NO INGREDIENT AT 0.1% OR GREATER THAT IS LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN. Effects of Overexposure:EYE:VAPOR MAY CAUSE IRRITATION, CONTACT MAY CAUSE BURNS. SKIN:PROLONGED/REPEATED SKIN CONTACT MAY CAUSE IRRITATION. INHALED:LOW HAZARD FOR ORDINARY INDUSTRIAL HANDLING. INGESTED:DO NOT TAKE INTERNALLY . MAY CAUSE NAUSEA. Medical Cond Aggravated by Exposure:NO INFORMATION GIVEN ON MSDS BY MFR. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/WATER 15 MIN, SEEK MEDICAL ATTENTION. SKIN:WASH SKIN WITH SOAP AND WATER. IF IRRITATION OCCURS, SEEK MEDICAL ATTENTION. INHALED:MOVE TO FRESH AIR. INGESTED:INDUCE VOMITING. SEEK MEDICAL A TTENTION IMMEDIATELY GIVING FULL DETAILS OF AMOUNT INGESTED AND TOXICITY. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:PRODUCT IS NON FLAMMABLE. EXTINGUISH FIRE WITH MEDIA APPROPRIATE FOR SOURCE OF FIRE. Fire Fighting Procedures:USE PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES. Unusual Fire/Explosion Hazard:WHEN HEATED TO DECOMPOSITION, IT CAN EMIT TOXIC FUMES OF SO2. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE CLOTHING AS SPECIFIED. NEUTRALIZE WITH SODIUM BICARBONATE. IF FEDERAL, STATE & LOCAL REGULATIONS PERMIT. FLUSH TO SEWER WITN LARGE AMOUNTS OF WATER. Neutralizing Agent:SODIUM BICARBONATE ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE OR CONSUME FOOD, DRINK OR TOBACCO IN SURROUNDING AREA. WASH THOROUGHLY AFTER USE. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SHOULD NOT BE NECESSARY UNDER NORMAL CONDITIONS. IF EXPOSED TO VAPORS THAT EXCEED THE TLV OR PEL, WEAR AN APPROVED VAPOR RESPIRATOR. Ventilation:GOOD LOCAL MECHANICAL VENTILATION SHOULD BE SUFFICIENT. Other Protective Equipment:AS NECESSARY TO PREVENT SKIN CONTACT. EYE WASH STATION IN VICINITY OF USE. Work Hygienic Practices:MFR: ?HMIS:USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID UNNECESSARY CONTACT. WASH THOROUGHLY BEFORE EATING OR DRINKING. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NONE Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:17 MM Vapor Density:0.6 Spec Gravity:1.23 pH:6.0 Solubility in Water:COMPLETE Appearance and Odor:YELLOWISH, ODORLESS Percent Volatiles by Volume:90 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MINERAL ACIDS Stability Condition to Avoid:NONE KNOWN Hazardous Decomposition Products:WHEN HEATED TO DECOMPOSITION, IT CAN EMIT TOXIC FUMES OS SO2. Conditions to Avoid Polymerization:WILL NOT OCCUR ==================== Disposal Considerations ==================== Waste Disposal Methods:IF FEDERAL, STATE & LOCAL REGULATIONS PERMIT, FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. OTHERWISE DISPOSE OF IN MANNER APPROVED FOR THIS MATERIAL. CONSULT PROPER FEDERAL, STATE & LOCAL REGULATORY AG ENCIES TO ASCERTAIN PROPER DISPOSAL PROCEDURES.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:SODA ASH CAGE:64713 CAGE:64713 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM CARBONATE CAS:497-19-8 RTECS #:VZ4050000 Fraction by Wt: 99% OSHA PEL:UNK ACGIH TLV:UNK ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Effects of Overexposure:TOPICAL SENSITIVITY;INGESTION MAY INDUCE CORROSION OF GI TRACT;VOMIT,DIARRHEA,CIRCULATORY COLLAPSE & DEATH. ======================= First Aid Measures ======================= First Aid:WASH AFFECTED AREA W/WATER. ===================== Fire Fighting Measures ===================== Flash Point:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP & DISPOSE OF IN AN ENVIRONMENTALLY ACCEPTABLE MANNER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE Ventilation:MECHANICAL EXHAUST Other Protective Equipment:COVERALLS Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:B3 NRC/State Lic Num:NOT RELEVANT Spec Gravity:2.53 Solubility in Water:APPRECIABLE Appearance and Odor:ODORLESS,WHITE POWDER OR CRYSTALS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS Hazardous Decomposition Products:CARBON DIOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:IAW LOCAL,STATE & FED REGS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:APPROXIMATE JIM, PR-2 CLEAR CAGE:60150 CAGE:60150 ============= Composition/Information on Ingredients ============= Ingred Name:2-BUTANONE; (METHYL ETHYL KETONE)(MEK) (SARA 313) (CERCLA) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 80% OSHA PEL:200 PPM ACGIH TLV:200 PPM;300 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:FURAN, TETRAHYDRO-; (TETRAHYDROFURAN) (CERCLA) CAS:109-99-9 RTECS #:LU5950000 OSHA PEL:200 PPM ACGIH TLV:200 PPM; 250 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CYCLOHEXANONE (CERCLA) CAS:108-94-1 RTECS #:GW1050000 OSHA PEL:50 PPM, S ACGIH TLV:25 PPM, S EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SUPP DATA: IGNITE FLAMMABLE VAPORS. RTECS #:9999999ZZ Ingred Name:EYE PROT: (ANSI Z 87.1 OR EQUIVALENT) RTECS #:9999999ZZ Ingred Name:HYGIENE PROC: LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. RTECS #:9999999ZZ Ingred Name:CNDTNS TO AVOID: STANDING IN AIR. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:IRRIT OF EYES, NOSE & THROAT; DROWSINESS, NARCOSIS, TREMORS & OTHER CNS EFFECTS AT HIGH CONC. SKIN IRRIT, DERM & DEFATT. POSS LIVER & KIDNEY DMG. NOTICE: REPORTS HAVE ASSOC RPTD & PLNGD OCCUP OVEREXP TO SOLVS W/PERM BRAIN & CNS DMG. INTENTIONAL MISUSE BY DELIB CONC & INHAL CONTENTS OF PROD MAY BE HARMFUL/FATAL. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:EYES: WATERING, BLURRED VISION, INFLAMM & IRRIT WHICH CAN RSLT IN CORNEAL INJURY. INHAL: NASAL & RESP IRRIT, DIZZ, NARCOSIS, HDCH, NAUS, CNS DEPRESS & UNCON. INGEST: NAUS, VOMIT; CNS DEPRESS, IRRIT OF GI TRACT, LIVER & PERITONEAL WALL, LUNG CONGESTION. SKIN: IRRIT, DERMATITIS. Medical Cond Aggravated by Exposure:INDIVIDUALS W/PRE-EXISTING OR CHRONIC DISEASES OF EYES, SKIN, RESP SYSTEM, CARDIOVASCULAR SYSTEM, GI SYSTEM, LIVER/KIDNEYS MAY HAVE INCREASED SUSCEPTABILITY TO EXCESSIVE EXPOSURE. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/LGE AMOUNTS OF WATER FOR AT LEAST 15 MINS. SEEK IMMED MED ATTN. INHAL: REMOVE TO FRESH AIR. ADMIN O*2/ARTF RESP IF NEEDED. SEEK IMMED MED ATTN. INGEST: DO NOT INDUCE VOMITING. GIVE LARGE AMOUNTS OF WATER ONLY IF CONSCIOUS. SEEK IMMED MED ATTN. SKIN: WASH W/SOAP & WATER. IF IRRIT OCCURS, SEEK MED ATTN. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:17F,-8.3C Lower Limits:2% Upper Limits:11.8% Extinguishing Media:FOAM, DRY CHEMICAL, CO*2 OR WATER FOG. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. HAZ DECOMP PRODS POSS. EVAC IMMED AREA. DIKE FIRE CONTROL AREA AS RUN-OFF MAY CREATE ADDTNL FIRE(SUPDAT) Unusual Fire/Explosion Hazard:EXTREMELY FLAMM-VERY LOW FLASH PT. VAPS ARE HVR/AIR & MAY TRAVEL ALONG GROUND/TO LOW SPOTS AT CONSIDERABLE DISTANCE TO SOURCE OF IGNIT RSLTG IN POTNTL(SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT. USE ABSORB MATLS TO PVNT FOOTING HAZ & TO CONTAIN. VENT AREA W/NATURAL/EXPLOS PROOF, FORCED AIR VENT. AVOID FLUSHING INTO SEWERS, DRAINS, WATERWAYS & SOIL. WEAR PROT CLTHG & NIOSH/MSHA APPRVD RESP DURING CLEAN-UP. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CNTNR CLSD & UPRIGHT WHEN NOT IN USE. DO NOT STORE NEAR HEAT, SPARKS/OPEN FLAMES. IF TRANSFERRING LIQUID MATL TO OTHER CNTNRS, GROUND(SUPDAT) Other Precautions:AVOID PROLONGED & REPEATED CONTACT WITH SKIN OR CLOTHING. EMPTY CONTAINERS MAY CONTAIN RESIDUES & VAPORS; TREAT AS IF FULL AND OBSERVE ALL PRODUCT PRECAUTIONS. DO NOT REUSE EMPTY CONTAINERS. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN CONFINED, POORLY VENT AREAS, USE NIOSH/MSHA APPROVED AIR PURIFYING OR SUPPLIED AIR RESPIRATORS. Ventilation:LOCAL EXHST: ACCEPTABLE. MECH(GENL): PREFERABLE. SPECIAL: EXPLOSION-PROOF EQUIPMENT. Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA. COVERALLS RECOMMENDED. Work Hygienic Practices:WHERE USE CAN RSLT IN SKIN CONTACT, WASH EXPOSED AREAS THORO BEFORE EATING, DRINKING, SMOKING/LEAVING WORK AREA.(ING 6) Supplemental Safety and Health FIRE FIGHT PROC: HAZ & ENVIRON CONTAM. COOL HEAT EXPOSED CNTNRS W/WATER. IF SPILL/LEAK HAS NOT IGNITED, USE WATER SPRAY TO DISPERSE VAPS. EXPLO HAZ: FLASHBACK. BURNING LIQ MAY FLOAT ON WATER. HEAT MAY BUILD UP PRESS & RUPTURE CLSD CNTNRS. STOR/HNDLG: ALL CNTNRS TO AVOID STATIC ELEC BUILDUP & DISCHARGE WHICH MAY (ING 4) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:151F,66C Vapor Pres:140 @ 68F Vapor Density:2.5 Spec Gravity:0.91 (H*20=1) Evaporation Rate & Reference:6 (ETHYL ACETATE=1) Solubility in Water:90% Appearance and Odor:CLEAR OR PURPLE LIQUID/ PUNGENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS, ACIDS AND BASES. Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAMES & STRONG OXIDIZING, ACIDIC & BASIC CNDTNS. CAN FORM POTNTLY EXPLOS PEROXIDES UPON LONG(ING 7) Hazardous Decomposition Products:CO, CO*2 AND FRAGMENTED HYDROCARBONS. Conditions to Avoid Polymerization:PRESENCE OF CATIONIC INITIATORS SUCH AS SELECTED LEWIS ACIDS/STRONG PROTON ACIDS. KEEP AWAY FROM CATIONIC INITIATORS. ==================== Disposal Considerations ==================== Waste Disposal Methods:RCRA CLASSIFIED HAZARDOUS WASTE. DISPOSE OF ABSORBED MATLS & LIQUID WASTES IN APPROVED, CONTROLLED INCINERATION FACILITY IN ACCORDANCE W/ALL LOCAL, STATE & FEDERAL REGULATIONS.
0
gloves_not_mandatory
===================== Product Identification ===================== Product ID:887 7482 FLEXICOLOR DEVELOPER REPLENISHER LORR, PART A Kit Part:Y CAGE:19139 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 65-70% Other REC Limits:NONE RECOMMENDED Ingred Name:POTASSIUM CARBONATE CAS:584-08-7 RTECS #:TS7750000 Fraction by Wt: 25-30% Other REC Limits:NONE RECOMMENDED Ingred Name:POTASSIUM SULFITE CAS:10117-38-1 RTECS #:WT3530000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED Ingred Name:PENIETIC ACID, PENTA SODIUM SALT CAS:140-01-2 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED Ingred Name:SODIUM SULFITE CAS:7757-83-7 RTECS #:WE2150000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): NOT GIVEN Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EXPECTED TO BE A LOW INHALATION HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL HANDLING BY TRAINED PERSONNEL. MAY LIBERATE SULFUR DIOXIDE GAS WHICH IS IRRITATING TO RESPIRATORY TRACT. EYE CONTACT CAUSES IR RITATION. SKIN CONTACT MAY CAUSE SKIN SENSITIZATION. HARMFUL IF SWALLOWED. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:RESPIRATORY TRACT IRRITATION, EYE IRRITATION, SKIN SENSITIZATION, DIFFICULT BREATHING. Medical Cond Aggravated by Exposure:SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING. ======================= First Aid Measures ======================= First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: WASH OUT IMMEDIATELY WITH WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN: WASH WITH SOAP AND WATER . GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGESTION: DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Lower Limits:NOT GIVEN Upper Limits:NOT GIVEN Extinguishing Media:NONFLAMMABLE. USE EXTINGUISHING MEDIA SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER IF ALLOWABLE WITH LARGE AMOUNTS OF WATER. OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE TO REMOVE RESIDUA L CONTAMINATION. Neutralizing Agent:NEUTRALIZATION AND SEWERING MAY NOT BE ALLOWED IN SOME STATES AND MUNICIPALITIES ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID BREATHING MIST. AVOID CONTACT WITH EYES & PROLONGED OR REPEATED CONTACT WITH SKIN. USE WITH ADEQUATE VENTILATION. KEEP CONTAINER CLOSED. Other Precautions:KEEP AWAY FROM INCOMPATIBLE SUBSTANCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. Ventilation:GOOD GENERAL VENTILATION, TYPICALLY 10 AIR CHANGES PER HOUR, SHOULD BE USED. RATES SHOULD MATCH CONDITIONS. Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE AVAILABLE. Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES. Supplemental Safety and Health KEY1:B1. REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE. ================== Physical/Chemical Properties ================== HCC:C2 Boiling Pt:B.P. Text:>212F,>100C Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Decomp Temp:Decomp Text:NOT GIVEN Vapor Pres:18 Vapor Density:0.6 Spec Gravity:1.39 pH:12.3 Viscosity:NOT GIVEN Evaporation Rate & Reference:NOT GIVEN Solubility in Water:COMPLETE Appearance and Odor:COLORLESS LIQUID, NO ODOR Percent Volatiles by Volume:65-70% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE OR LOCAL LAWS. MAY REQUIRE NEUTRALIZATION IF PH < 2.0 OR PH > 12.5. DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE ANDLOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:CEE BEE A-491 INHIBITOR CAGE:71361 CAGE:71361 ============= Composition/Information on Ingredients ============= Ingred Name:TETRAETHYL SILICATE CAS:78-10-4 RTECS #:VV9450000 Fraction by Wt: 20-40% Other REC Limits:NONE RECOMMENDED OSHA PEL:85 MG/M3 Ingred Name:ETHYL ALCOHOL (ETHANOL) CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED OSHA PEL:1900 MG/M3 Ingred Name:VOC = 21 G/L RTECS #:9999999VO Fraction by Wt: NA Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: IRRITATION. CHRONIC: MAY EFFECT LIVER/KIDNEYS. Effects of Overexposure:EYE: SLIGHT IRRITATION/TEARS. SKIN: MODERATE IRRIT W/CHRONIC CONTACT. INHALATION: IRRIT/DIZZINESS/HEADACHE/NAUSEA/VOMITING. INGESTION: SLIGHTLY TOXIC. NAUSEA. TARGET ORGANS: SKIN/EYES/RESPIRATORY SYST EM/KIDNEYS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER >15 MIN. IF IRRIT PERSISTS GET MED AID. SKIN: FLUSH W/WATER THEN WASH W/SOAP & WATER. INHALATION: GET FRESH AIR. IF TROUBLE BREATHING GIVE OXYGEN. GET MED AID. INGESTION: IF CONSCI OUS GIVE 2 GLASSES WATER. INDUCE VOMITING. GET MEDICAL AID. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:91.0F,32.8C Lower Limits:3.3 Upper Limits:19.0 Extinguishing Media:WATER SPRAY, CO2, DRY CHEMICAL, FOAM. Fire Fighting Procedures:USE SCBA & FULL PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:VAPORS MAY TRAVEL & IGNITE AT DISTANT POINT. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE IGNIT SOURCES. VENTILATE AREA. FLUSH AREA W/WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, FLAME. KEEP CLOSED. STORE IN WELL-VENTILATED AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR IF TWA EXCEEDED. Ventilation:SUFFICIENT TO KEEP BELOW TWA LIMIT Other Protective Equipment:SUFFICIENT TO PREVENT SKIN CONTACT. EYEWASH STATION, SAFETY SHOWER. Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:244F,118C Melt/Freeze Pt:M.P/F.P Text:-130F,-90C Vapor Pres:0.24 @ 20C Vapor Density:>1.0 Spec Gravity:1.06 pH:NA Solubility in Water:DECOMPOSES Appearance and Odor:COLORLESS LIQUID, SLIGHT ALCOHOL ODOR Percent Volatiles by Volume:2.0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACTS SLOWLY W/WATER, MINERAL ACIDS, ALKALIES. Stability Condition to Avoid:NA Hazardous Decomposition Products:OXIDES OF CARBON ==================== Disposal Considerations ==================== Waste Disposal Methods:SEND TO EPA APPROVED WASTE DISPOSAL FACILITY FOR INCINERATION. #D001.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:ERBIUM 10,000 UG/ML (1.0% W/V) CAGE:0EK28 CAGE:0EK28 ============= Composition/Information on Ingredients ============= Ingred Name:NITRIC ACID, HYDROGEN NITRATE CAS:7697-37-2 RTECS #:QU5775000 Fraction by Wt: 0-5% OSHA PEL:5 MG/CUM ACGIH TLV:5.2 MG/CUM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ERBIUM OXIDE *92-2* CAS:12061-16-4 Fraction by Wt: 0-1% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES/SKIN: BURNS. INHALATION: COUGHING, DIFFICULTY BREATHING. INGESTION: NAUSEA, VOMITING, UNCONSCIOUSNESS. Effects of Overexposure:EYES/SKIN: BURNS. INHALATION: COUGHING, DIFFICULTY BREATHING. INGESTION: NAUSEA, VOMITING, UNCONSCIOUSNESS. ======================= First Aid Measures ======================= First Aid:INGESTION: DON'T INDUCE VOMITING. IF CONSCIOUS, GIVE WATER, MILK, OR MILK OF MAGNESIA. EYES/SKIN: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE APPROPRIATE EXTINGUISHING MEDIA. Fire Fighting Procedures:WEAR PROPER PROTECTIVE EQUIPMENT & SELF-CONTAINED BREATHING APPARATUS W/FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. STOP LEAK SAFELY. USE WATER SPRAY TO REDUCE VAPORS. TAKE UP W/SAND OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL & PLACE INTO CONTAINER FOR LATER DISPOSAL. FLUSH SPILL AREA W/ WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE IN CORROSION PROOF AREA. AVOID INHALATION OF VAPORS & CONTACT W/EYES & SKIN. ============= Exposure Controls/Personal Protection ============= Ventilation:LOCAL EXHAUST, VENT HOOD Other Protective Equipment:LAB COAT, APRON Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES BEFORE REUSE. Supplemental Safety and Health FOR USE ONLY BY QUALIFIED INDIVIDUALS, TRAINED & FAMILIAR W/PROCEDURES SUITABLE TO THIS PRODUCT. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F Spec Gravity:1 Solubility in Water:COMPLETE Appearance and Odor:CLEAR, COLORLESS, ODORLESS SOLUTION. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ORGANIC MATERIALS, STRONG REDUCING AGENTS Hazardous Decomposition Products:OXIDES OF NITROGEN ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS. D002 (CORROSIVE WASTE)
1
gloves_mandatory
===================== Product Identification ===================== Product ID:CREATINE KINASE VERIFIER (CK-V) CAGE:18873 CAGE:18873 ============= Composition/Information on Ingredients ============= Ingred Name:HUMAN SERUM (CKMM CONCENTRATE) Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NO INFORMATION GIVEN ON MSDS BY MFR. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PRODUCT MAY CAUSE SENSITIZATION IN SOME IN SOME INDIVIDUALS. INFECTION WITH AN INFECTIOUS DISEASE IS ALSO POSSIBLE. Explanation of Carcinogenicity:THE PRODUCT CONTAINS NO INGREDIENT THAT IS LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN. Effects of Overexposure:EYE:MECHANICAL SENSITIZATION, REDNESS. SKIN:ALLERGIC CONTACT DERMATITIS. INHALED:RESPIRATORY ALLERGY. INGESTED:BIOLOGICAL INFECTION, ALLERGIC RASH. Medical Cond Aggravated by Exposure:NO INFORMATION FOUND. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/WATER 15 MIN, HOLD LIDS OPEN. SKIN:WASH WITH SOAP & WATER. INHALED:REMOVE TO FRESH AIR. RESTORE/AID BREATHING AS NEEDED. INGESTED:NO SPECIFIC INTERVENTION IS INDICATED. CONSULT YOUR SITE M EDICAL. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE WATER, WATER SPRAY, WATER FOG, CARBON DIOXIDE, FOAM, OR DRY POWDER SAND OR METAL-X. Fire Fighting Procedures:MFR: "NO INFORMATION AVAILABLE". HMIS:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:MFR: NO INFORMATION AVAILALE ================== Accidental Release Measures ================== Spill Release Procedures:REVIEW MSDS BEFORE PROCEEDING. USE APPROPRIATE PROTECTIVE EQUIPMENT. PUR IN BIOHAZARD BAG. WIPE UP RESIDUE WITH PAPER TOWELLS AND A 20% CHLOROX SOLUTION. PLACE TOWELS IN BIOHAZARD BAG. AUTOCLAVE. Neutralizing Agent:NO INFORMATION GIVEN ON MSDS BY MFR. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE PER PRODUCT INSERT SHEET. Other Precautions:KEEP AWAY FROM HEAT, SPARKS, AND FLAMES. IF LYOPHILIZED PRODUCT IS REMOVER FROM VIAL, AVOID DUST GENERATION AND TREAT AS A RESPIRATORY SENSITIZATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO INFORMATION GIVEN ON MSDS BY MFR. Ventilation:NO INFORMATION GIVEN ON MSDS BY MFR. Other Protective Equipment:NO INFORMATION GIVEN ON MSDS BY MFR. Work Hygienic Practices:MFR: ?HMIS:USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID UNNECESSARY CONTACT. WASH THOROUGHLY BEFORE EATING OR DRINKING. Supplemental Safety and Health KEY2:KT MSDS RECEIVED FROM NAVY (FOCAL POINT N). CAGE CODE AND NSN IDENTIFIED BY THEM. ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NONE pH:* Solubility in Water:SOLUBLE Appearance and Odor:WHITE POWDER, NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NO INFORMATION GIVEN ON MSDS BY MFR. Stability Condition to Avoid:NO INFORMATION GIVEN ON MSDS BY MFR. Hazardous Decomposition Products:"DECOMPOSES WITH HEAT." Conditions to Avoid Polymerization:WILL NOT OCCUR ==================== Disposal Considerations ==================== Waste Disposal Methods:PLACE IN BIOHAZARD BAG AND AUTOCLAVE. DISPOSE BY LOCAL GUIDELINES.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:2100 QC SHIGELLA ANTIGENS CAGE:04487 CAGE:15481 CAGE:04487 ============= Composition/Information on Ingredients ============= Ingred Name:FORMALDEHYDE, FORMALIN (2A CARCINOGEN BY NTP, IARC, OSHA) INTENDED CHANGE CAS:50-00-0 RTECS #:LP8925000 Fraction by Wt: 0.19% OSHA PEL:SEE 1910.1048 ACGIH TLV:C 0.3 PPM; A2; 9293 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): 420 MG/KG FORMALDEHYDE Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:SKIN/INHALATION: MAY CAUSE CANCER. Explanation of Carcinogenicity:SEE INGREDIENTS Effects of Overexposure:SKIN/INHALATION: MAY CAUSE CANCER. ======================= First Aid Measures ======================= First Aid:EYES/SKIN: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ================== Accidental Release Measures ================== Spill Release Procedures:WIPE UP SPILL W/DAMP SPONGE OR MOP. FLUSH DOWN DRAIN W/PLENTY OF WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. USE ONLY IN ADEQUATE VENTILATION. Other Precautions:DON'T GET IN EYES, ON SKIN OR ON CLOTHING. ============= Exposure Controls/Personal Protection ============= Ventilation:MECHANICAL Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Solubility in Water:SLIGHT Appearance and Odor:LIGHT GREY TO WHITE SUSPENSION ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:40 36204 800 SYN/GARD ENAM DE CAGE:13374 CAGE:13374 CAGE:23526 ============= Composition/Information on Ingredients ============= Ingred Name:LIGROINE; (VM & P NAPHTHA) CAS:8032-32-4 RTECS #:OI6180000 Fraction by Wt: 30% OSHA PEL:300 PPM;400 PPM STEL ACGIH TLV:300 PPM Ingred Name:XYLENE CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 1% OSHA PEL:100 PPM;150 PPM STEL ACGIH TLV:100 PPM;150 PPM STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:LIGROINE; (VM&P NAPHTHA) CAS:8032-32-4 RTECS #:OI6180000 Fraction by Wt: 5% OSHA PEL:300 PPM;400 STEL ACGIH TLV:300 PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:HARMFUL IF INHALED. MAY AFFECT BRAIN, NERVOUS SYSTEM OR RESPIRATORY SYSTEM, CAUSING DIZZINESS, HEADACHE, NAUSEA OR RESPIRATORY IRRITATION. OVEREXPOSURE TO INGREDIENTS MAY CAUSE NOSE AND THROAT I RRITATION, EYE IRRITATION, SKIN IRRITATION. CHRONIC: NOTICE: REPORTS HAVE ASSOCIATED REPEATED AND (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING CONTENTS MAY BE HARMFUL OR FATAL . Medical Cond Aggravated by Exposure:ANY RESPIRATORY OR SKIN CONDITION. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE PERSON FROM EXPOSURE AREA. IF BREATHING HAS STOPPED, USE MOUTH-TO-MOUTH RESUSCITATION AND GET MEDICAL ATTENTION. EYE: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SKIN: WASH WITH SOAP AND WATER. INGESTION: CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:102F,39C Lower Limits:1% Upper Limits:6% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, AND/OR WATER FOG. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . CONTAINERS EXPOSED TO FIRE SHOULD BE KEPT COOL WITH WATER SPRAY. Unusual Fire/Explosion Hazard:CONTAINS OXIDIZING MATLS.CONTAM RAGS, WIPES, SAWDUST,ETC. MAY CATCH FIRE SPONT. STORE WASTE UNDER H*2O IN CLSD METAL CNTNRS UNTIL DISP OF IN COMPLIANCE (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. AVOID BREATHING OF VAPORS. USE NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING APPARATUS OR AIRMASK FOR LARGE SPILLS IN CONFINED AREA. WIPE UP OR ABSORB ON SUITABLE MATERIAL AND SHOVEL UP . AVOID CONTACT WITH EYES. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAMES. KEEP CONTAINER CLOSED WHEN NOT IN USE. DO NOT STORE ABOVE 120F. Other Precautions:BASED ON PROD FL PT & VAP PRESS, SUITABLE STORAGE SHOULD BE PROVIDED I/A/W OSHA REG 1910.106. EMPTY CNTNRS MAY CONTAIN PROD RESIDUE, INCL FLAM/EXPLO VAPS. DO NOT CUT, PUNCTURE/WELD ON/NEAR CNTNR. ALL LBL WARNINGS MUST BE OBSERVED (SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH/MSHA APPROPRIATE, PROPERLY FITTED RESPIRATOR DURING AND AFTER APPLICATION UNLESS AIR MONITORING VAPOR/MIST LEVELS ARE BELOW APPLICABLE LIMITS. FOLLOW RESPIRATOR MANUFACTURERS DIRECTIONS FOR RESPIRATOR USE. Ventilation:REQUIRED FOR SPRAYING OR IN A CONFINED AREA, VENTILATION EQUIPMENT SHOULD BE EXPLOSION PROOF. Other Protective Equipment:USUAL CLOTHING FOR PAINTING OPERATIONS. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXPLOSION HAZARDS: WITH ALL APPLICABLE REGULATIONS. OTHER PRECAUTIONS: UNTIL THE CONTAINER HAS BEEN CLEANED OR RECONDITIONED. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:282F,139C Vapor Pres:6 @ 68F Vapor Density:5.5 Spec Gravity:1.07 Evaporation Rate & Reference:0.6 (BUTYL ACETATE=1) Solubility in Water:NO Appearance and Odor:NORMAL FOR A COATINGS PRODUCT. Percent Volatiles by Volume:55.30 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NOT APPLICABLE. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:NITROGEN OXIDES, CARBON DIOXIDE, CARBON MONOXIDE, METAL OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN CHEMICAL DISPOSAL AREA OR IN A MANNER THAT COMPLIES WITH LOCAL, STATE, AND FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:JP-8 JET FUEL, JET 1A, 4140 CAGE:4L196 CAGE:4L196 ============= Composition/Information on Ingredients ============= Ingred Name:KEROSENE, HYDRODESULFURIZED. LEL:0.7%. UEL:5.0% CAS:64742-81-0 RTECS #:OA5510000 Fraction by Wt: BALANCE Ingred Name:SULFUR CAS:7704-34-9 RTECS #:WS4250000 Fraction by Wt: <0.3% Ingred Name:TOLUENE (SARA 313) (CERCLA) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 0.05% OSHA PEL:200 PPM; Z-2 ACGIH TLV:S, 50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENE (SARA 313) (CERCLA) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 1.17% OSHA PEL:100 PPM ACGIH TLV:100 PPM/150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BENZENE, ETHYL-; (ETHYL BENZENE) (SARA 313) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 0.17% OSHA PEL:100 PPM ACGIH TLV:100 PPM/125 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BENZENE, 1,2,4-TRIMETHYL-; (1,2,4-TRIMETHYLBENZENE) (SARA 313) CAS:95-63-6 RTECS #:DC3325000 Fraction by Wt: 1.64% OSHA PEL:25 PPM ACGIH TLV:25 PPM Ingred Name:CUMENE (SARA 313) (CERCLA) CAS:98-82-8 RTECS #:GR8575000 Fraction by Wt: 0.07% OSHA PEL:S, 50 PPM ACGIH TLV:S, 50 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ANTIFREEZE (ANTI-ICING). % (WT):0.10-0.15. Fraction by Wt: <0.15% Ingred Name:ANTI-OXIDANT. % (WT):6.0-8.4 LBS/M BBL Fraction by Wt: <0.1% Ingred Name:CORROSION INHIBITOR. % (WT):9.4-22.5 MG/L Fraction by Wt: <0.1% Ingred Name:CONDUCTIVITY IMPROVER. % (WT):1.5-2.5 PPM Fraction by Wt: <0.1% Ingred Name:SUPDAT:INTRAVENOUS & INTRAPERITONEAL ROUTES. HUMAN EYE IRRITANT. FUNGICIDE. CHRONIC INHAL CAN CAUSE IRRIT OF MUC(ING 13) Ingred Name:ING 12:MEMB. TOLUENE: POIS BY INTRAPERITONEAL ROUTE. MOD TOX BY INTRAVENOUS & SUBCUTANEOUS ROUTES. MILDLY TOXIC (ING 14) Ingred Name:ING 13:BY INHAL. HUMAN SYSTEMIC EFTS BY INHAL: CNS RECORDING CHANGES, HALLUCINATIONS/DISTORTED PERCEPTIONS, (ING 15) Ingred Name:ING 14:MOTOR ACTIVITY CHANGES, ANTIPSYCHOTIC, PSYCHOPHYSIOLOGICAL TEST CHANGES & BONE MARROW CHANGES. MUTATION (ING 16) Ingred Name:ING 15:DATA RTPD. HUMAN EYE IRRITANT. EXPERIMENTAL SKIN & SEV EYE IRRITANT. XYLENE MOD TOX BY INTRAPERITONEAL & (ING 17) Ingred Name:ING 16:SUBCUTANEOUS ROUTES. MILDLY TOX BY INGEST & INHAL. HUMAN SYSTEMIC EFTS BY INHAL: OLFACTORY CHANGES, (ING 18) Ingred Name:ING 17:CONJUNCTIVA IRRIT & PULM CHANGES. EXPERIMENTAL REPROD EFTS. HUMAN EYE IRRITANT. EXPERIMENTAL SKIN & SEV (ING 19) Ingred Name:ING 18:EYE IRRITANT. ETHYLBENZENE:MOD TOX BY INGEST, INTRAPERITONEAL ROUTE, & INHAL & SKIN CONT. EXPERIMENTAL (ING 20) Ingred Name:ING 19:TERATOGEN. EYE & SKIN IRRITANT. 1,2,4-TRIMETHYLBENZENE: MOD TOX BY INTRAPERITONEAL ROUTE & INHAL. CAN (ING 21) Ingred Name:ING 20:CAUSE CNS DEPRESS, ANEMIA, BRONCH. CUMENE:MOD TOX BY INGEST, INHAL & SKIN CONT. EYE & SKIN IRRITANT. (ING 22) Ingred Name:ING 21:POTNTL NARC ACTION CNS DEPRESSANT. ANTI-ICING:SLIGHTLY TOX BY INGEST. MAY PRDCE SIGNS OF INTOXICATION. (ING 23) Ingred Name:ING 22:EXCESS REDNESS & SWELL OF CONJ MAY OCCUR. CAUSES IRRIT. ANTI-OXIDANT:SYMPS OF OVEREXP TO INHAL OF VAPS (ING 24) Ingred Name:ING 23:INCL DROW, WEAK, HDCH, DIZZ & NAUS. EXPECTED TO BE EYE IRRITANT. RPTD/PRLNGD SKIN CONT MAY CAUSE DERM & DEFAT. ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TOLUENE APPEARS ON NAVY LISTING OF OCCUP CHEM REPROD HAZS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO . ACUTE: MAY BE POISONOUS IF INHALED/ABSORBED THRU SKIN. VAPS MAY CAUSE DIZZ/SUFFOCATION. CONT MAY IRRITATE/BURN SKIN & EYES. FIRE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: MAY PRDCE IRRITATING/POISONOUS GASES. RUNOFF FROM FIRE CTL/DILUTION WATER MAY CAUSE POLLUTION. KEROSENE:POIS BY INTRAVENOUS & INTRATRACHEAL ROUTES. MOD TOX TO ANIMALS BY INGEST. SEV SKIN IRR ITANT. MUTATION DATA RPTD. HUMAN SYSTEMIC EFTS BY INGEST & INTRAVENOUS ROUTES: SOMNOLENCE, HALLUCINATIONS AND (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: MOVE TO FRESH AIR & CALL EMER MEDICAL CARE. IF NOT BRTHG, GIVE ARTF RESP; IF BRTHG IS DFCLT, GIVE OXYG. SKIN CONT: WASH W/SOAP & WATER. REMOVE & ISOLATE CONTAMD CLTHG & SHOES AT SITE. EYE CONT: IMMED FLUSH W/RUNNING WATER FOR @ LST 15 MINUTES. GET MED ATTN. INGEST: DO NOT GIVE ANYTHING BY MOUTH TO UNCONSCIOUS VICTIM. DO NOT INDUCE VOMITING. GET MED ATTN. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:>104F,>40C Lower Limits:SEE ING 1 Upper Limits:SEE ING 1 Extinguishing Media:USE WATER SPRAY, DRY CHEMICAL, FOAM OR CARBON DIOXIDE. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. Unusual Fire/Explosion Hazard:MAY BE IGNITED BY HEAT, SPKS/FLAMES. VAPS MAY TRAVEL TO SOURCE OF IGNIT & FLASH BACK. CNTNR MAY EXPLODE IN HEAT/FIRE. RUNOFF TO SEWER MAY CREATE FIRE/ (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:SHUT OFF IGNIT SOURCES; NO FLARES, SMKNG/FLAMES IN HAZARD AREA. STOP LEAK IF CAN DO W/OUT RISK. SM SPILL, TAKE UP W/SAND/OTHER NONCOMBUT ABSORB MATL & PLACE INTO CNTNS FOR LATER DISP. LG SPILLS, DIKE FAR AHEAD OF LIQUID SPILL FOR LATER DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT USE OR HANDLE NEAR IGNITION SOURCES. PROVIDE ADEQUATE VENTILATION. Other Precautions:CARCIN:FOLLOWING COMPONENTS ARE CONSIDERED TO BE CARCIN BY NATIONAL TOXICOLOGY PROGRAM, INTERNATIONAL AGENCY FOR RESEARCH ON CANCER, AND/OR OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION: KEROSENE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED BREATHING PROTECTION. Ventilation:RECOMMENDED. USE EXPLOSION-PROOF TYPE. Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . AVOID BREATHING VAPORS, SKIN CONTACT OR INGESTION. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXPLO HAZ:EXPLO HAZ. VAP EXPLO HAZ INDOORS, OUTDOORS/IN SEWERS. HAZ DECOMP PROD:AS ASPHYXIANT. WHEN HEATED TO DECOMP IT EMITS ACRID SMOKE & FUMES. EFTS OF OVEREXP:DISTORTED PERCEPTIONS, COUGH, NAUS/VO MIT, & FEVER. ASPIR OF VOMITUS CAN CAUSE SERIOUS PNEUM, PARTICULARLY IN YOUNG CHILDREN. SULFUR:POIS BY INGEST, (ING 12) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>322F,>161C Evaporation Rate & Reference:NOT KNOWN Solubility in Water:NEGLIGIBLE Appearance and Odor:WATER WHITE WITH HYDROCARBON ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CAN REACT WITH OXIDIZING MATERIALS. Stability Condition to Avoid:MODERATELY EXPLOSIVE IN THE FORM OF VAPOR WHEN EXPOSED TO HEAT OR FLAME. Hazardous Decomposition Products:BURNING CAN PRDCE CO & CO*2. CO IS HIGHLY TOX IF INHALED(200 PPM OSHA CEILING). CO*2 IN SUFFICIENT QTYS CAN ACT (SUPDAT) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF AS SPECIFIED BY EPA FEDERAL, STATE AND LOCAL REGULATIONS FOR HAZARDOUS WASTE. ======================================================================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:LEAD/ACID BATTERY,26/26 R-6000 CAGE:63432 CAGE:64812 CAGE:1U269 CAGE:63432 ============= Composition/Information on Ingredients ============= Ingred Name:LEAD (SARA III) CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: 60% Other REC Limits:NONE SPECIFIED OSHA PEL:0.05 MG/M3;1910.1025 ACGIH TLV:0.15 MG/M3;DUST 9293 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ANTIMONY (SARA III) CAS:7440-36-0 RTECS #:CC4025000 Fraction by Wt: 1-5% Other REC Limits:NONE SPECIFIED OSHA PEL:0.5 MG/M3 ACGIH TLV:0.5 MG SB/M3; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ARSENIC (SARA III) CAS:7440-38-2 RTECS #:CG0525000 Fraction by Wt: <1% Other REC Limits:NONE SPECIFIED OSHA PEL:0.5 MG/M3 (AS) ACGIH TLV:0.01,A1 MG/M3; 9394 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:SULFURIC ACID (SARA III) CAS:7664-93-9 RTECS #:WS5600000 Fraction by Wt: 10-38% Other REC Limits:NONE SPECIFIED OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CALCIUM, METAL CAS:7440-70-2 RTECS #:EV8040000 Fraction by Wt: <0.15% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV FOR SULFURIC ACID IS 1 MG/M3. Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE- IF BATTERY LEAKING: LEAD MAY CAUSE GI UPSET, DIARRHEA, CRAMPING & FATIGUE. ELECTROLYTE MAY CAUSE EYE, SKIN & RESPIRATORY TRACT IRRITATION, BURNS, CORNEAL & LUNG DAMAGE. CHRONIC- LEAD MAY CAUSE ANEMIA, KIDNEY & CNS DAMAGE. ACID CAN CAUSE BRONCHITIS, EROSION OF TOOTH ENAMEL. TARGET ORGANS:EYES, SKIN, LUNGS, KIDNEY Explanation of Carcinogenicity:CONTAINS ARSENIC AND LEAD Effects of Overexposure:IF BATTERY IS LEAKING, BROKEN OR IN FIRE: GI UPSET, LOSS OF APPETITE, DIARRHEA, CONSTIPATION, CRAMPING, LACK OF SLEEP, FATIGUE, EYE, SKIN & RESPIRATORY TRACT IRRITATION, BURNS, CORNEAL & LUNG DAMAGE Medical Cond Aggravated by Exposure:INORGANIC LEAD AND ITS COMPOUNDS CAN AGGRAVATE CHRONIC FORMS OF KIDNEY, LIVER AND NEUROLOGIC DISEASES. CONTACT OF SULFURIC ACID WITH THE SKIN MAY AGGRAVATE SKIN DISEASES SUCH AS ECZEMA AND DERMATITIS. ======================= First Aid Measures ======================= First Aid:IF BATTERY LEAKING:OBTAIN MEDICAL ATTENTION IN ALL CASES OF EXPOSURE. EYES/SKIN:FLUSH WITH WATER FOR 15 MINUTES. KEEP EYELIDS OPEN. INHALATION:MOVE TO FRESH AIR. INGESTION:DO NOT INDUCE VOMITING. IF C ONSCIOUS, DRINK LARGE AMOUNT OF MILK ORWATER. CALL PHYSICIAN IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Lower Limits:4.1 (H2) Upper Limits:74.2 (H2) Extinguishing Media:MULTI-PURPOSE DRY CHEMICAL OR MULTI-PURPOSE CO2. WATER SPRAY MAY BE USED TO COOL FIRE-EXPOSED CONTAINER & DECREASE VAPOR Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:HYDROGEN GAS AND SULFURIC ACID VAPORS ARE GENERATED UPON OVERCHARGE. HYDROGEN GAS IS FLAMMABLE AND EXPLOSIVE WHEN MIXED WITH AIR, OXYGEN OR CHLORINE. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENTS. REMOVE COMBUSTIBLES & IGNITION SOURCES (H2 MAY BE PRESENT). CONTAIN BY DIKING AND COVER SPILL WITH SODA ASH OR QUICKLIME. MIX WELL. CHECK THAT MIXTURE IS NEUTRAL. COLLECT A ND PLACE IN A DRUM. DO NOT FLUSH TO SEWER. Neutralizing Agent:SODA ASH (SODIUM CARBONATE), QUICKLIME (CALCIUM OXIDE) ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENTILATED AREA. STORAGE AREA SHOULD BE EQUIPPED WITH A DRAIN WHICH CAPTURES SPILLS OF ACID FOR PROPER DISPOSAL. Other Precautions:KEEP TERMINALS COVERED IN PLASTIC CASE. AVOID SHORTING BATTERIES. DO NOT CRACK OR OVERCHARGE BATTERIES. KEEP LIGHTED CIGARETTES, SPARKS, AND FLAMES AWAY FROM CHARGING BATTERIES. KEEP OUT OF REACH OF C HILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED UNDER NORMAL USE. USE NIOSH-APPROVED ACID-MIST FILTER RESPIRATOR IF 1 MG/M3 TWA IS EXCEEDED (ACID). Ventilation:ADEQUATE GENERAL VENTILATION Other Protective Equipment:RUBBER APRON AND BOOTS IF SPILLED. EYES WASH STATION AND SAFETY SHOWER. USE ACID-PROOF CLOTHING FOR MAJOR SPILLS. Work Hygienic Practices:REMOVE METALLIC JEWELRY-SHOCK POTENTIAL. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING AND DRINKING. Supplemental Safety and Health WARNING! COMBUSTION OR OVERCHARGING MAY CREATE OR LIBERATE TOXIC AND HAZARDOUS GASES AND LIQUIDS INCLUDING HYDROGEN, SULFURIC ACID MIST, SULFUR DIOXIDE, SULFUR TRIOXIDE, ARSINE. DO NOT SHORT CIRCUIT B ATTERY TERMINAL OR REMOVE VENT CAPS DURING STORAGE OR RECHARGING. ================== Physical/Chemical Properties ================== HCC:C1 NRC/State Lic Num:NOT RELEVANT Spec Gravity:NOT RELEVANT Evaporation Rate & Reference:NOT RELEVANT Solubility in Water:NOT RELEVANT Appearance and Odor:BATTERY. RECTANGULAR OR SQUARE IN SHAPE - NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES, OVERCHARGING, SMOKING, SPARKS, SHORTING Hazardous Decomposition Products:OXIDES OF LEAD AND SULFUR, HYDROGEN, SULFUR DIOXIDE AND SULFUR TRIOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE AS HAZARDOUS WASTE. OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS FOR ACID OR LEAD SCRAP. SEND BATTERIES TO LEAD SMELTER FOR RECLAMATION FOLLOWING APPLICABLE FEDERAL, STATE AN D LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:BRULIN 1990 GD Preparer's Name:NOT PROVIDED CAGE:94058 Contract Num:SP0450-01-M-ZE86 CAGE:94058 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS INGREDIENT(S) = Wt:100. Other REC Limits:NOT PROVIDED OSHA PEL:NOT PROVIDED ACGIH TLV:NOT PROVIDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT PROVIDED Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:DIRECT EYE CONTACT AND PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE IRRITATION SEEN AS REDNESS. Explanation of Carcinogenicity:THIS PRODUCT CONTAINS NO CARCINOGENS AT 0.1% OR MORE LISTED IN NTP ANNUAL REPORT ON CARCINOGENS, IARC MONOGRAPHS, OR 29 CFR 1810 SUBPART Z. Effects of Overexposure:DIRECT EYE CONTACT AND PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE IRRITATION SEEN AS REDNESS. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:EYE CONTACT: FLUSH WITH LARGE AMOUNT OF WATER FOR 15 MIN. LIFTING UPPER & LOWER LIDS OCASSIONALLY. GET MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR. SKIN CONTACT: WASH WITH MILD SOAP AND WATER.REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. IF IRRITATION PERSISTS, CONSULT A PHYSICIAN. INGESTION: IF CONSCIOUS, DILUTE BY GIVING 2 GLASSES OF WATER. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:NONE Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS SHOULD BE USED. DURING EMERGENCY CONDITIONS, OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD. SYMPTOMS MAY NOT B E IMMEDIATELY APPARENT. GET MEDICAL ATTENTION. WATER MAY BE USED TO COOL CLOSED CONTAINERS EXPOSED TO EXTREME HEAT. Unusual Fire/Explosion Hazard:NONE KNOWN. CLOSED CONTAINERS MAY EXPLODE (DUE TO BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB ON SOLID ABSORBENT AND SHOVEL INTO CONTAINERS FOR DISPOSAL. Neutralizing Agent:NOT PROVIDED ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BETWEEN 40 AND 110 F. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY REQUIRED. HOWEVER, IF POTENTIAL, FOR OVEREXPOSURE EXISTS, WEAR A NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:MECHANICAL (GENERAL): SUFFICIENT RECOMMENDED. Other Protective Equipment:SUFFICIENT TO MINIMIZE SKIN CONTACT. Work Hygienic Practices:USE ONLY WITH ADEQUATE VENTILATION. AVOID BREATHING VAPOR AND MIST. AVOID CONTACT WITH SKIN AND EYES. DO NOT TAKE INTERNALLY. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health ABBREVIATION: N/A = NOT APPLICABLE. N/AV = NOT AVAILABLE. N/K = UNKNOWN. N/P = NOT PROVIDED. N/R = NOT RELEVANT. N/D = NOT DETERMINED. N/E = NOT ESTABLISHED. CNS = CENTRAL NERVOUS SYSTEM. GI = GASTROI NTESTINAL. SCBA = SELF CONTAINED BREATHING APPARATUS. ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NOT RELEVANT Boiling Pt:=100.C, 212.F Melt/Freeze Pt:=-1.1C, 30.F M.P/F.P Text:APPROX. Decomp Temp:Decomp Text:NOT PROVIDED Vapor Pres:APPROX. 17 @68F. Vapor Density:APPROX.06 Spec Gravity:1.068 pH:NOT PROVIDED Viscosity:NOT PROVIDED Evaporation Rate & Reference:1.0 (WATER=1) Solubility in Water:COMPLETE Appearance and Odor:WATER WHITE, MILD ODOR. Percent Volatiles by Volume:NOT PROVIDED Corrosion Rate:NOT PROVIDED ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS AND OXIDIZERS. Stability Condition to Avoid:FREEZING Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, AND OXIDES OF SULFUR. =================== Toxicological Information=================== Toxicological Information:NOT PROVIDED ===================== Ecological Information ===================== Ecological:NOT PROVIDED ==================== Disposal Considerations ==================== Waste Disposal Methods:NOT PROVIDED =================== MSDS Transport Information =================== Transport Information:NOT PROVIDED ===================== Regulatory Information ===================== SARA Title III Information:NOT PROVIDED Federal Regulatory Information:NOT PROVIDED State Regulatory Information:NOT PROVIDED ======================= Other Information =======================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:SPEC MIL-A-178A CAGE:16486 CAGE:16486 ============= Composition/Information on Ingredients ============= Ingred Name:VEHICLE Ingred Name:SOLVENTS ===================== Hazards Identification ===================== Effects of Overexposure:EYE,THROAT,SKIN,LUNG IRRITANT,DROWSINESS. ======================= First Aid Measures ======================= First Aid:SKIN:WASH WELL W/WATER.EYES:FLUSH W/WATER. INHAL:MOVE TO FRESH AIR.GIVE ARTIF.RESP.IF NEEDED.CALL DR. REMOVE CONTAMINATED CLOTHING. ===================== Fire Fighting Measures ===================== Flash Point:52F,10C TCC Fire Fighting Procedures:FOAM,DRY CHEM.,FOG,CARBON DIOXIDE,DOSPERSE W/WATER/SAND Unusual Fire/Explosion Hazard:AVOID FIRE,HEAT,SPARKS,IGNITION SOURCES,DIRECT SUNLIGHT ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA,KEEP FROM FLAME,FIRE,SPARKS,IGNITION SOURCES.DO NOT BREATHE VAPORS.MECHANICALLY VENTILATE;CLEAN UP WITH ABSORBENT MATERIAL ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS CLOSED,UPRIGHT,AWAY FROM FIRE,FLAME,SPARKS,IGNITION SOURCES,DIRECT SUNLIGHT;STORE IN COOL DRY PLACE. ============= Exposure Controls/Personal Protection ============= Ventilation:LOCAL EXHAUST(FRESH AIR) Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F2 Solubility in Water:NEGLIGIBLE Appearance and Odor:ALCOHOL AND TOLUENE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES
1
gloves_mandatory
===================== Product Identification ===================== Product ID:7819 COMPRESSED ASBESTOS SHEETS CAGE:LO637 CAGE:73680 CAGE:LO637 ============= Composition/Information on Ingredients ============= Ingred Name:ASBESTOS, CHRYSOTILE CAS:12001-29-5 RTECS #:CI6478500 Fraction by Wt: 80-90% Other REC Limits:NONE SPECIFIED OSHA PEL:0.2 FIBERS/CC ACGIH TLV:2 FIBERS/CC; A1;9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:INHALATION OF AIRBORNE FIBERS CAN CAUSE THE WELL-KNOWN LONG TERM EFFECTS OF ASBESTOSIS, LUNG CANCER AND MESOTHELIOMA. INGESTION OF FREE ASBESTOS FIBERS MAY BE A FACTOR IN CANCERS OF THE GI TRACT AND L ARNYX. SUCH CANCERS ARE BELIEVED TO BE SMOKING RELATED. Explanation of Carcinogenicity:ASBESTOS IS CONSIDERED BY NTP, IARC, AND OSHA AS A CARCINOGEN. Effects of Overexposure:THESE PRODUCTS DO NOT POSE A HEALTH HAZARD UNDER ORDINARY CONDITIONS OF USE. A HAZARD WOULD ARISE ONLY IF THE PRODUCTS WERE SUBJECTED TO MECHANICAL ACTIONS THAT WOULD CAUSE THE ASBESTOS FIBERS TO BE R ELEASED FROM THE ELASTOMER COMPOUND MATRIX. SIMPLE IRRITATION WHEN CONTACTING THE SKIN AND EYES. Medical Cond Aggravated by Exposure:INHALING FREE ASBESTOS FIBERS MAY AGGRAVATE ANY LUNG CONDITIONS AND RESPIRATORY TRACT IRRITATIONS. ======================= First Aid Measures ======================= First Aid:INHALATION OF FIBER: REMOVE VICTIM FROM CONTAMINATED AREA. REPORT EXPOSURE TO MEDICAL PERSONNEL. INGESTION OF FIBER: NO SPECIFIC ACTION. REPORT EXPOSURE TO MEDICAL PERSONNEL. WASH SKIN THOROUGHLY WITH SOAP AND WATER. CONTACT PHYSICIAN IF IRRITATION PERSISTS. IF PARTICLES GET IN THE EYES IRRIGATE WELL WITH WATER. CONTACT A PHYSICIAN AS A PRECAUTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT IF FIRE INVOLVES SUBSTANTIAL QUANTITIES OF PRODUCT. POSSIBLE RELEASE OF FIBERS. Unusual Fire/Explosion Hazard:PRODUCES SMOKE, SOME FUMES AND POSSIBLY SOME FREE ASBESTOS FIBERS WHEN BURNED AND BINDER IS BURNED. ================== Accidental Release Measures ================== Spill Release Procedures:WET WASTE. VACUUM UP ANY WASTE WITH HEPA FILTERED VACUUM CLEANER. WEAR PROTECTIVE EQUIPMENT AND HALF FACE RESPIRATOR WITH HEPA FILTERS. Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN CLEAN, DRY PLACE AWAY FROM STRONG OXIDIZING AGENTS. NORMAL WASH UP AFTER HANDLING IS RECOMMENDED. Other Precautions:ASBESTOS BONDED BY AN ELASTOMER COMPOUND HOWEVER, DO NOT MISUSE BY IMPROPER CUTTING OR HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. IF ANY OPERATIONS ARE PERFORMED ON THE PRODUCT THAT MAY RELEASE ASBESTOS FIBERS, USE A NIOSH APPROVED HALF FACE RESPIRATOR WITH HEPA FILTERS. Ventilation:NONE NORMALLY. SUFFICIENT VENTILATION TO KEEP FIBER LEVEL BELOW 0.2 FIBERS PER CC IF FIBERS RELEASES. Other Protective Equipment:NONE NORMALLY REQUIRED. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health AVOID PRODUCTION OF AIRBORNE FIBERS. ================== Physical/Chemical Properties ================== HCC:T6 Solubility in Water:NEGLIGIBLE Appearance and Odor:GREY-BLACK TO BLACK SHEET OR GASKET. SLIGHT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. DIRECT FLAME WILL IGNITE BINDER. Stability Condition to Avoid:NONE Hazardous Decomposition Products:IN A FIRE: SMOKE, POSSIBLY CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:SINCE THE ASBESTOS IN THE PRODUCT IS SECURED WITH A BINDER AND IS NOT FRIABLE OR LOOSE, THE PRODUCT CAN BE DISPOSED OF WITH OTHER INERT MATERIALS IN A NORMAL LANDFILL.
0
gloves_not_mandatory
===================== Product Identification ===================== Product ID:CUSTOM INORGANIC MIX, IS-2818A Kit Part:Y CAGE:0U4A8 CAGE:0U4A8 ============= Composition/Information on Ingredients ============= Ingred Name:NITRIC ACID (SARA 302/313) (CERCLA) CAS:7697-37-2 RTECS #:QU5775000 Fraction by Wt: 5% OSHA PEL:2 PPM ACGIH TLV:2 PPM; 4 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 94-95% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:CADMIUM (SARA 313) (CERCLA) CAS:7440-43-9 RTECS #:EU9800000 Fraction by Wt: 0.1% OSHA PEL:0.2 MG/M3 DUST ACGIH TLV:0.01 MG/M3 DUST EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:LEAD (II) NITRATE (1:2); (PB AS LEAD NITRATE) (SARA 313) CAS:10099-74-8 RTECS #:OG2100000 Fraction by Wt: 0.1% OSHA PEL:N/K ACGIH TLV:0.15 MG/M3 (PB) EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:ZINC (SARA 313) (CERCLA) CAS:7440-66-6 RTECS #:ZG8600000 Fraction by Wt: 0.1% OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:IRRITATING TO EYES AND MUCOUS MEMBRANES. MAY CAUSE EYE INJURY. MAY BE HARMFUL IF SWALLOWED. MAY BE IRRITATING ON CONTACT WITH SKIN, EYES OR MUCOUS MEMBRANES. VAPOR IRRITATING TO EYES AND RESPIRATORY P ASSAGES. CHRONIC: LEAD APPEARS ON THE NAVY LIST OF OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS. SEEK (EFTS OF OVEREXP) Explanation of Carcinogenicity:CADMIUM: IARC MONOGRAPHS ON THE EVAL OF CARCIN RISK OF CHEMS TO MAN, VOL 58, PG 119, 1993:GROUP 1. NTP 7TH (SUPDAT) Effects of Overexposure:HLTH HAZ: CONSULTATION FROM APPROPRIATE HEALTH PROFESSIONALS CONCERNING LATEST HAZARD LIST INFO AND SAFE HANDLING AND EXPOSURE INFO . Medical Cond Aggravated by Exposure:RESPIRATORY CONDITIONS. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE. SKIN: IMMEDIATELY FLUSH THOROUGHLY WITH LARGE AMOUNTS OF WATER. EYES: IMMEDIATELY FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. INHAL: REMO VE TO FRESH AIR; GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. INGEST: GET IMMEDIATE MEDICAL ATTENTION; IF CONSCIOUS, GIVE WATER FREELY. ===================== Fire Fighting Measures ===================== Flash Point:NONCOMBUSTIBLE Extinguishing Media:USE ANY SUITABLE FOR ADJACENT MATERIAL. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCES TOXIC FUMES. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA OF ALL UNNEC PERS. WEAR SUITABLE PROT EQUIP AS LISTED. ELIM ANY IGNIT SOURCES UNTIL AREA IS DETERMD TO BE FREE FROM EXPLO/FIRE HAZS. CNTN RELS & ELIM ITS SOURCE IF IT CAN BE DONE W/OUT R ISK. TAKE UP & CONTAINERIZE FOR PROPER DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. STORE AT CONTROLLED ROOM TEMPERATURE. Other Precautions:DO NOT BREATHE VAPOR. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:MATERIAL SHOULD BE HANDLED OR TRANSFERRED IN AN APPROVED FUME HOOD OR WITH ADEQUATE VENTILATION. Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT TAKE INTERNALLY. Supplemental Safety and Health EXPLAN OF CARCIN: ANNUAL REPORT ON CARCINS, 1994:ANTIC TO BE CARCIN. HUMAN:LUNG, PROSTATE, RENAL SYS EFTS. OSHA REGULATED CFR 29 1910.1018. ================== Physical/Chemical Properties ================== Solubility in Water:SOLUBLE Appearance and Odor:LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE INDICATED. Stability Condition to Avoid:EXTREME HEAT. Hazardous Decomposition Products:OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:COMPLY WITH WITH FEDERAL, STATE AND LOCAL REGULATIONS.
1
gloves_mandatory