Benefiting from the widespread commercial availability, lower toxicity, and stability of aliphatic acids, the past decades have witnessed a wealth of transition-metal-catalyzed decarboxylative cross-coupling to forge new C-C and C-X bonds. The high levels of chemoselectivity and functional group tolerance exhibited by these reactions have enabled the late-stage C(sp )-enriched functional group modification and spatial diversification of bioactive molecules and natural products . A great progress has been made in efficiently constructing racemic C(sp )-C(sp ) bonds via transition metal catalyzed decarboxylative cross-coupling of aliphatic acids. Various strategies have been developed by groups led by MacMillan , Baran , Fu , Weix , and Cernak 22 etc., encompassing diverse crosscoupling partners such as alkyl halides, alkenes, alcohols, amines, and even carboxylic acids. Despite these advancements, achieving asymmetric decarboxylative couplings with C(sp³) partners remains a formidable challenge .