In addition to being loss free, CCS is capable of partitioning the sample into a few yet chemically highly distinct fractions, which are amenable 100% qHNMR, separately or after adequate recombination. Figure shows the power of this off-line CCS-qHNMR combination in capturing both major and minor components by assessing the mass proportions of all sample components (via the masses of CCS fractions), providing information about the relative polarity of the constituents (via the CCS K-values), as well as giving details about their chemical constitutions (via the NMR δ scale and dispersion).