If the fluoride anions are bonded to the same Si atom over extended periods of time, i.e., if there is static disorder (or no disorder at all), the Si NMR spectra show a sharp resonance with an isotropic chemical shift δiso of -140 to -150 ppm. In the case of dynamic disorder, the local environment of the participating Si atoms changes between tetrahedral and trigonal-bipyramidal coordination over time, which leads to a broad Si NMR signal in the chemical shift range of δiso = -115 to -150 ppm. NMR evidence for dynamic disorder at room temperature (RT) has been presented for ZSM-5/Silicalite-1 (MFI framework), ITQ-4 (IFR), and SSZ-23 (STT), among other systems. The dynamic disorder can be frozen out by cooling to ~140 K, and, in the case of Silicalite-1, by varying the OSDA. The frequent occurrence of static or dynamic disorder also leads to difficulties in the accurate determination of F-Si bond distances with crystallographic methods. They tend to overestimate the bond length, typically delivering values between 1.8 and 2.0 Å. More accurate distances can be obtained with NMR methods, which give F-Si distances between 1.72 and 1.79 Å. The dynamic behavior of fluoride anions in all-silica zeolites and other neutral-framework zeotypes has been studied with DFT-based ab-initio molecular dynamics (AIMD) calculations in a series of recent publications. Two of these studies focused on zeolites and zeotypes with the AST topology, where the fluoride anions are occluded in d4r cages, investigating the role of the local environment (in other words, the atomic species occupying the corners of the cage) in determining their equilibrium location and dynamic behavior. The third study addressed the impact of the OSDA on the dynamic disorder of fluoride anions in Silicalite-1, which contains [SiO4F] -units. It was found that the dynamic disorder is visible through distinct discontinuities ("jumps") in the time evolution of the coordinates of some fluoride anions, especially when performing AIMD simulations for temperatures above RT (373 K, 473 K). In addition, the drastic reduction of the dynamic disorder when incorporating methyl-or ethyltributylammonium instead of tetrapropylammonium cations as OSDA, previously observed in NMR experiments, could be reproduced and rationalized on the basis of the calculations. Building upon these previous studies, the present works compares a set of five structurally different zeolites with NON, STF, IFR, STT, and CHA topologies, which are also known to differ in the dynamic behavior of fluoride. In the first part, DFT optimizations are employed to study the preferred fluoride locations in these zeolites, using crystal structure data of the as-synthesized forms as starting point. For each zeolite, information about the cage that hosts the fluoride anions is taken from experiment, and different positions within that cage are then compared in a systematic fashion in order to discern different factors that govern the energetically favored fluoride position. Second, DFTbased AIMD calculations are used to study the dynamic behavior of the fluoride anions at temperatures of 298 K, 373 K, and 473 K. In addition to evaluating whether the fluoride anions remain bonded to the same Si atom during the simulation time or "jump" between different sites, a further analysis of the role of F-Si and F-OSDA interactions is carried out. While the occurrence of dynamic disorder can be probed experimentally, the computations provide a unique possibility to better understand its origins, thereby helping to explain why fluoride anions are dynamically disordered in some zeolites, but not in others.