were characterized for ODH of ethane at lower temperatures and high WHSVs to evaluate electrochemical processing of ethane to ethylene. This technique differs from prior literature studies that also provide inherent air separation and high ethylene selectivity such as chemical looping , which lacks modularity and membrane reactors , which cannot provide an electric byproduct. Two perovskite-based electrodes were synthesized: LaFeO3 with Gd0.1Ce0.9O1.95 (GDC) denoted as LFO and SrFeO3- with GDC denoted as SFO, with GDC providing enhanced ionic conductivity in combination with the demonstrated olefin yield of the iron-based perovskites .