The qualitative insight provided by simulation snapshots (Figures and) indicate that the localization of the citrates for the two limiting cases of field amplitude (E = 0 and E = 0.11) is substantially the same as in the T = 300 K case. Also at this temperature, the population of the three molecular motifs depends very weakly on the applied field, with the blue state being dominant. The "blue" CIT ions persist even in the conductive regime (diagonal entry converging to ∼ 0.58), which is fundamental to preserve the FCC lattice integrity. Also in this case, we observe the same features in the characteristic supramolecular ionic semiconductivity of the superlattice, with the conductive regime originating from the emergence of direct ionic gates allowing the diffusion and transport of CIT ions (EAs) throughout the tetrahedral and octahedral cavities present in the TMA-NP (AAs) lattice. As a unique difference, in this case we note that activating the CIT conduction requires slightly weaker values of applied electric field (E = 0.03 Vnm -1 ) than at T = 300 K, in line with the data of Figure . This result suggests that in this case, crossing the supramolecular "band gap" requires a lower electric stimulus, as the breakage of the CIT-NPs interactions is facilitated by the increased thermal agitation.