The main purpose of the data collection here was to analyze the constituents rather than to solve the structures, which is why a short rotation range of only 50° per crystal was used instead of the typical larger rotation range that would be more appropriate for structure determination. This decision facilitated the collection of more data sets within the same time frame, increasing the statistical significance of the analysis. Attempts to use much shorter rotation wedges underlined the difficulties to index the data sets reliably due to the flatness of the Ewald sphere. As an example at the extreme end, no rotation was used in another study were instead prior knowledge of the unit cell parameters was used to compensate for the lack of rotation data . Our approach which involved continuous rotation of at least 20° per crystal) allows unit cell determination without any a priori knowledge 1,2 which is more suitable for analytical purposes. Our study also demonstrates that it is not necessary to solve the structures for compositional analysis, as proper unit cell parameters are sufficient to distinguish between the compounds in the mixtures. This approach also allows for a more comprehensive analysis of the sample when the structures of the constituents are already known, as indexing a data set is typically easier than solving the structure ab initio.