The functional groups' electron-withdrawing capacities and spatial orientations significantly influence the electronic behavior of these complexes, dictating their reactivity and stability. The strong electron-withdrawing nature of keto groups amplifies the electropositive character of the carbon centers, potentially enhancing electrophilic reactivity. Conversely, the azomethine group's moderate electron-donating tendency introduces a nuanced interplay of electronic effects, stabilizing the coordination environment. These interactions elucidate the intrinsic relationship between ligand architecture and metal center behavior, offering critical insights into their potential applications in catalysis and electronic material design.