Finally, using the weighted populations we can show how we would expect the H adsorption energy to change with temperature Figure : E ads ) for a H atom on a Pt 13 NP using different thermodynamic ensembles generated with pyGlobOpt runs using xTB as the energetic evaluator. all levels of hydrogenation we study. We find the resulting adsorption energies to be similar to those found in the literature (c.f. section S1).