3.4 Low Gamma Catalytic Kinetics. The dynamic kinetics of high gamma (γ B-A ~ 2.0) catalytic systems were previously evaluated and shown to exhibit significant rate enhancement (1,000-10,000x above the Sabatier maximum) in the resonant frequency range . Under optimal conditions, the surface coverage of high γ chemistries oscillate between high coverage in A* and high coverage in B*, ultimately yielding a turnover frequency about equal to the imposed surface oscillation frequency. As these dynamic catalytic systems modulated into the strong binding state, the heat of the surface reaction was at its most negative condition leading to the lowest energy transition state; this permitted A* to readily convert to B*. When the surface binding energy then converted to weaker overall binding, the binding energy of B* decreased thereby decreasing the desorption barrier. Additionally, the high energy binding state inhibited the reverse surface reaction (B* to A*) due to a high transition state energy. This behavior held for multiple waveform types (e.g. square, sinusoidal) over a range of linear transition state scaling relationships (0 < α < 1.0), making these types of reactions amenable to dynamic rate enhancement.