However, studies involving structural transitions in n-type counterparts (necessary for full logic design) have severely lagged behind. N-type semiconductors require relatively low lying LUMO levels for efficient electron transport, which are difficult to stabilize under ambient conditions . One route to design stable n-type molecules involves forming a quinoidal structure using strong electron withdrawing groups such as cyano groups and attaching long alkyl chains to the core. The cyano groups break the aromaticity of the conjugated core and planarize the molecule by stabilizing the quinoidal resonance structure that exhibits double bonds between the rings. On the other hand, alkyl chains are widely used to impart solution processability and helps prevent reactions with water and oxygen in the solid state . At the same time, these quinoidal cores stabilize an exotic biradical ground state that exists in equilibrium with the quinoidal form . The presence of biradicals results in interesting spin-spin interactions between the conjugated cores and, in extreme cases, results in formation of "pancake" bonding . These unique interactions are also tunable through slight changes in environment (concentration, temperature etc.). Along with intermolecular interactions, biradical formation appears to have self-doping effects capable of tuning the charge carrier densities and the resulting electronic properties . While both the quinoidal core and alkyl chains are key to engineering n-type semiconductor molecules, the effect on structural transitions is still unexplored.