The synthesis of novel complexes from different metal centers with so far non-investigated ligands is a promising option to develop new functional materials such as (photo)catalysts, 1 materials for organic light-emitting diodes , and biomedical probes . It may also support the search for new bioactive compounds such as antimicrobial agents . Still, promising strategies for predicting and rapidly detecting complexation processes are rare, and the systematic access to new complexes is difficult. Developing new complexes often relies on coincidental observation or crystallization experiments performed in batch mode. Reported screening methods often use HPLC and LC-MS to detect complexation and are therefore limited to soluble and stable complexes. Moreover, these methods usually focus on synthesizing libraries for an already established type of complex, making them interesting for in-depth biological screenings but not the systematic exploration of complexation properties of new ligands. Due to the lack of techniques for the easy screening of ligands for their potential to form complexes, many combinations of known ligands and metals are probably unknown, and their benefits have not been explored yet. Organic chemistry and especially methodological approaches to new heterocycles give access to many potential ligands for complexation experiments. Considering the techniques available in standard organic chemistry labs, we were searching for solutions for the current limitation of fast access to new complexes.