In conclusion, we report the direct electrochemical arylation of benzylic C(sp 3 )-H bonds via a convergent-paired electrolysis. We merged anodic benzylic C-H bond oxidation and cathodic reduction of dicyanobenzenes to produce two radical species that can merge to form the desired biarylmethane derivatives 4 over hydroxyl-biarylmethanes 5 or biarylketones 6 as in previous works.