The agreement of the rheology kinetic measurement curves of P_T and P_pMeOx corroborates that the thermogelation is largely unaffected by the synthesis protocol, i.e., the triazole linker between the blocks. However, µDSC thermograms indicate the absence of the secondary peak at lower temperature present for P_T. So far, we were unable to hypothesize on the molecular origin of this second transition. Hence, at this point it remains unclear how the additional triazole linkers lead to the diminution of this second peak. Interestingly, for the PEG-based triblock P_PEG the gelation is much faster compared to the pMeOx-based counterparts. Incubation at 5 °C leads to an immediate increase in complex viscosity, with the gelation process being completed within 30 minutes. The rapid gelation of P_PEG is consistent with the faster attainment of the peak equilibrium in the µDSC thermograms compared to P_pMeOx (Fig. ). This indicates that the hydrophilic PEG blocks enable efficient transition from spherical to worm-like micelles and hence are convenient for the coolinginduced thermogelation.