Tetrahydrofuran (THF) is a good solvent for dissolving substrate and LiBr, and charge transformation. Anode and cathode use bulk metal without any heterogeneous catalyst loading. However, such a combination is completely incapable of transforming nitrobenzene. To make the reaction possible, tripyrolidinophosphine (TPPA) is added to form a solid electrolyte interphase (SEI) for promoting Li + transfer, inspired by Peter's previous work accomplishing an electrochemical Birch reaction. Adding TPPA triggered the transformation of nitrobenzene and a 47.73% aniline yield was obtained.