To underscore the extensive applicability of this method in the synthesis of diverse organosulfur compounds, various post-functionalization procedures were applied to ethane sulfinate (Scheme 2). Our mild protocol facilitated straightforward follow-up functionalization through an operationally-simple fed-batch process. One-pot protocols enabled the synthesis of heteroaryl sulfones via aromatic nucleophilic substitution reactions (SNAr), yielding benzothiazole derivative 26 and thiophene derivative 27 in 76% and 63% yields, respectively.