In the kinetic-energy resolved IY of the monocationic fragments (Figure and "Peak 1" in Figure ), we see the same channels as in the XUV experiments, namely (1,0)→(1,1) and (1,1)→(2,1) (Figure and ESI). However, because the low-energy IR pump photons do not necessarily ionize the molecule, a new channel was observed, namely (0,0)→(1,0), similar to that in the parent monocations (see Figure ). This channel has a much shorter lifetime on the order of a few fs to 10 fs than the analogous process in the parent ions (FLU 0 --→ FLU + ) with a lifetime of 62 ± 1 fs (see Table and Figure ). Similar to the FLU 0 --→ FLU + and FLU + --→ FLU 2+ channels (Table ), we see shorter lifetimes of metastable species in (0,0)→(1,0) channels compared to (1,0)→(1,1) channels (Figure ). This trend can be again explained by the decreased density of states in the neutral metastable species with respect to their monocationic analogs. The additional decrease in lifetimes of (0,0)→(1,0) compared to the parent species (FLU 0 --→ FLU + channel) can be explained in the same fashion: the smaller the molecular species, the smaller the near-ionization threshold density of states.