Unlike conventional elastomers that are crosslinked by permanent covalent bonds, LAL polymers are a kind of thermoplastic-like elastomer physically crosslinked by nodules of glassy polymers. Similar to the melting of traditional thermoplastics, these nodules easily dissociate at high temperatures. We explore the effects of temperature for two polymers with nearly the same end block volume fraction of 𝑓 ≈ 0.31 but with a fraction of associative groups of 𝜆 = 0 and 𝜆 = 0.25.