Abstract: Accelerated production of recyclable and biodegradable biopolymers is crucial in combating the socio-economic and environmental issues of fossil-based plastics. While renewable diacids have been in the spotlight for the generation of bio-based polyesters with tailored properties by varying the alkyl chain length, capitalizing on diols from biomass for this purpose is underexplored and has mainly focused on linear and branched shorter chain alcohols.