For the outer position, it can be noted that all occurrences have overall less high or low values, staying within the range of 8 to 30 %. This can be interpreted in the sense, that the center position is in general more susceptible for tuning the considered 𝑆 1 excitation energy. Further, comparing with the center position, it can be found that some trends are seemingly reversed for the outer position -as, for example, the prevalence of cyano groups is favored for high wavelengths at the outer position, but disfavored at the center position. This hints at a structural role of these regions in the sense of push-pull directionality. Seeing how the cyano group can be considered a strong electron withdrawing group, high wavelengths seem to favor excitations with electron withdrawal towards the outside positions, while the opposite seems to be true for low wavelengths.