In conclusion, we have developed the first electrochemical method for alkoxy radical generation from alcohols and utilized this for the manganese-catalyzed electrochemical deconstructive chlorination of cycloalkanols. The method is applicable across various cyclopropanols and cyclobutanols, accessing a broad range of synthetically useful β-and γ-chlorinated ketones (40 examples). Furthermore, the combination of recirculating flow electrochemistry and continuous inline purification was employed to access products on gram scale. Ongoing studies are focused on further applications of earth-abundant transition metals in synthetic organic electrochemistry and these results will be reported in due course.