The tertiary aliphatic amines were also investigated. DC electrolysis did not furnish any arylation or cyanation products. In contrast, one-electron oxidation arylation product exclusively formed under AC conditions in moderate yields 28-39% (32a-34a). Tertiary amines containing strong electron-withdrawing functional groups such as nitro (39), pyrimidinyl (40), and benzenesulfonyl (41) did not result in any products (Figure ).