) within 1h at room temperature in the presence of a 2.5 wt% solution of 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) in THF. We also recently determined the reactivity ratio of DOT (rDOT = 1.6) and methyl acrylate (rMA = 0.2) during the copolymerizaton of these two monomers in anisole at 70 °C in the presence of 1 mol% of AIBN as radical initiator. Additionally, DOT was recently extended to dispersed media, 23, 24 network 25 and 3D printing