Reaction discovery and optimization. The widespread nature of C(sp 3 )-C(sp 3 ) structures makes it essential for organic synthetic chemists to improve the construction of these common bonds. The developments in pharmaceutical chemistry also create a need for new synthetic methods that facilitate alkyl carbon centres. The utilization of regiodivergent alkene hydroalkylation to access the C(sp 3 )-C(sp 3 ) bond was highly desired.