Increases in structural order observed by NMR again led to decreases in the capacitance, although less significantly than for ACS-PC, suggesting a limit of lowering the capacitance by increasing the ordered domain sizes for this connected pore system. The consistent observations on annealed carbons further support the hypothesis that it is the local structural disorder that governs the 160 capacitance, rather than pore size (Fig. vs. Fig. ), with more disordered carbons with smaller ordered domains having higher capacitance.