In summary, zigzag-type heterocyclic aromatic belts have been synthesized by means of an effective fjord-stitching strategy through multiple intramolecular Caryl-Caryl homocoupling reactions from easily accessible polybrominated azacalix [n]pyridine derivatives. The acquired belt [n]pyrrole [n]pyridines (n = 6 -8) have globally -conjugated belt structures and exhibit unique photophysical and electrochemical properties. The application of belt of a spherical frustum shaped cavity as a powerful receptor for C60 has also been demonstrated. We believe the present work would inspire people to design and construct a diversity of novel aromatic belts of distinct topological structures and tailormade properties, leading to significant breakthroughs and advances in practical applications of zigzag aromatic belts in science and high technology.