Table . Electronic energy (a.u.), Gibbs free energy correction (a.u.), relative energy (kcal mol -1 ) and Boltzman distribution (at 298 K) of the various conformers of P/(R)-CSA complex optimized using the BP86-D3BJ/def2-SV(P) level of theory and SMD solvent model (in dichlomethane). Table . Single point calculations of electronic energy using various methods (functionals and basis sets) and Gibbs free energy correction calculated using BP86-D3BJ/cc-pVDZ for two main conformers A and B in dichloromethane. Boltzman distribution calculated at 298 K. Table . In-plane (ip) and out-of-plane (oop) NSD results of conformers 1-7 of P/(R)-CSA complexes in dichloromethane.