Regarding the geometric relaxation of the n,* state, there is a tug-of-war between the aromatic -component, which tries to maintain the S0 state geometry, and the antiaromatic component, which seeks to lessen its antiaromaticity through geometric distortions. Here, we identified two possible scenarios. In some systems, the antiaromaticity of the -component and the aromaticity of the -component are reduced significantly, while in others, the aromatic component remains almost unaffected while the antiaromatic -component is reduced only slightly.