In this study, we explore the performance of the CVS-uS approach for computing X2PA cross sections within the EOM-CC singles and doubles framework for electronic excitations (EOM-EE-CCSD). We compare the X2PA spectra computed with the CVS-0 and CVS-uS approaches for small benchmark molecules to highlight the importance of including the valence contribution for modeling X2PA spectra. We also compare these computed X2PA spectra with those from Ref. 63.