Interestingly, the relevance of both corrections is reversed as the ChCl-LA ratio increases. We observe that both FF1 and FF2 reported similar results in terms of coordination numbers in di↵erent ratios (see Figure ); increasing (decreasing) the value for the Cl -ChOH (Cl -LACOOH) interaction, weakening (strenghtening) it, alters its coordination numbers to Cl only weakly. The influence of the overpolarization, nevertheless, is crucial as the ratio increases. The coordination number in the Cl -ChOH interaction decreases upon the increasing the ratio in FF3, stating, therefore, that the overpolarization remarkably a↵ects the population of the Cl -ChOH interaction. While in ratio 1:1 this has no remarkable influence, as the ratio is increased, the higher availability of the Cl in FF3 induces more probable interactions with the LA, in line with several works that show ChCl-based DES hydrogen bond network to rely on the competition between cation and HBD for the anion .