Regarding the overpolarization correction, it does not significantly alter the short-range structure of the 1:1 system. The Cl -LAOH interactions seem to be more a↵ected by the contribution to the interaction than the Cl -LACOOH interactions; nevertheless, we observe that the overpolarization correction alters the mediumlong range structure by tuning the Cl -ChOH and Cl -LACOOH competition. This results in a better mixing of the HBD and HBA molecules, resulting in structural changes that become more relevant as the ChCl:LA ratio increases. The maleability of the Cl -ChOH interaction is evidenced and its coordination number becomes lower as the LA content increases. This is due to the screening of the charge-induced dipole interactions, that have as a consequence the better availability of Cl and therefore, the competition and interplay between the intra HBA and inter HBA-HBD interactions.