New 𝑘 liq predictions are made based on the solvation parameters computed using the ab initio methods described in Section 2.3. In this approach, the solvation energies and enthalpies of reactants and TS are calculated at 298 K and combined together to get the ΔΔ𝐺 ‡ solv (298 K) and ΔΔ𝐻 ‡ solv (298 K) of a reaction. Then we applied our method to extrapolate ΔΔ𝐺 ‡ solv (𝑇 ) from ΔΔ𝐺 ‡ solv (298 K) and ΔΔ𝐻 ‡ solv (298 K) and combined it with the literature 𝑘 gas data to make 𝑘 liq predictions. The solvation parameters, however, could be only calculated for the reaction that has a TS and has literature gas phase kinetic parameters. Only Reaction 5 matched this criteria, and thus the new predictions were made for only one reaction.