On the application level, the ease of excellent solution processability confers to the possibilities to be explored in biological applications, including trans-membrane transport, biological imaging and drug delivery. Overcoming biocompatibility, water solubility, and retention of structural integrity in a complex biological environment are the major obstacles, though. On the other hand, manipulations at the molecular level to tune the emissive properties and their effect on the enantiopure environment is a compelling way to address the challenges related to the development of chiroptical materials in the field of circularly polarised luminescence. In a more ambitious manner, it would be utterly captivating to explore the molecularly dispersed materials in order to fabricate chiral MOC-embedded membranes or thin films, with the ultimate objective of tackling the formidable task of enantio-separation through membrane-based techniques. It is foreseen that endeavors shall persist in the intensification of exploration into the vast expanse and aesthetic allure of metallo-supramolecular chemistry, thereby enabling synthetic chemists to fabricate materials of heightened utility for practical applications.