In this work we show an order of magnitude improvement in sensitivity, and demonstrate hyperpolarization and zero-field detection of multi-component sample mixtures. We demonstrate fine experimental control over the process, coupling the hyperpolarization apparatus with the ZULF spectrometer. We obtain spin polarization of the order of tens of percent and therefore sensitivity enhancements of 11000 with respect to a conventional ZULF-NMR experiment with sample prepolarization at 2 T.