Bond Length and Bond Angle: Table reveals how the platinum atom is bonded to specific carbon atoms (C2, C6, and C8) which significantly redefines the electronic environment of the. The interaction between platinum and the graphitic carbon lattice induces charge redistribution, due to the delocalized π-electron system of graphite interacts with the d-orbitals of platinum . This charge transfer modifies the electronic states of both the platinum atom and the carbon atoms it is bonded to, potentially shifting the d-band center of platinum. Such a shift has critical implications for the material's catalytic and electronic properties, influencing its ability to facilitate reactions or conduct electricity.