First, a strong reduction in the DRT signal related to solid-state diffusion of Li + within the TiS2 lattice (P1) in the low frequency range is observed when transitioning to the pseudocapacitive potential region (Fig. ), which is consistent with the general assumption about non-diffusion limited behavior of pseudocapacitive charge storage phenomena and with previous reports on reduced diffusion limitation in TiS2 in this potential region. It is also consistent with the higher slope observed in the Warburg region of the Nyquist plot (Fig. ). In the midfrequency range, DRT signals related to interfacial ion adsorption and transport also strongly decrease in the pseudocapacitive region, with the intensity of P2 and P3 strongly reducing, resulting in P2* (Fig. ). However, the DRT signal we assign to ion desolvation (P4) increases in intensity in the pseudocapacitive region, including contributions from P3 from the batterylike region (Fig. ). This behavior is in line with experimentally measured solvent accumulation at the interface in the pseudocapacitive region. Consequently, when transitioning from battery-like to pseudocapacitive lithiation in bulk-TiS2, kinetic limitations of solid-state diffusion and surface adsorption diminish, while ion desolvation now poses a more severe impedance to the charge storage process. This nuanced behavior is not easily visible from the Nyquist plots alone.