Returning to the S66 data set, examination of the DFT dispersion corrections for individual systems illuminates an additional layer of consistency that cannot be gleaned from mere histograms of errors; see Fig. . Comparing D3, D4, XDM, and MBD, as parameterized for the PBE functional in each case, we find that all four methods afford very similar corrections on a system-bysystem basis. The largest differences are observed for the dispersion-dominated systems, whereas for the hydrogen-bonded dimers the variations are 0.5 kcal/mol; see Fig. ). The XDM approach affords dispersion corrections at most variance to the other corrections but even so, these differences are no larger than 1.4 kcal/mol for any of the S66 dimers. The MAE between XDM and D3 is 0.4 kcal/mol, in systems where the magnitude of the total correction ranges up to 7 kcal/mol. This level of consistency is reassuring although perhaps not surprising, as the description of these models in Section 2.1.2 emphasized similarities in the construction of each. In the next section, however, we will find that this consistency does not extend to larger vdW complexes.