The increasing current energy crisis and the environmental pollution are key challenges of modern societies, calling for new approaches for a sustainable future.(1) A decentralized green hydrogen economy (GHE) with electrolytically generated hydrogen as an energy carrier represents an attractive alternative to the predominant use of fossil fuels,(2) thereby providing a viable tool for the reduction of greenhouse gas emissions. In the past decade, the organic electrochemistry has re-emerged as an increasingly-viable, environmentally-friendly platform for molecular synthesis, among others allowing novel mechanistic pathways and replacing cost-intensive redox agents by renewable forms of energy. Pairing electrooxidative C-H activations to the hydrogen evolution reaction (HER) thus bears potential for late-stage upgrading of organic compounds and decentralized hydrogen production, rendering this approach attractive compared to traditional methods that rely on multi-step functional group interconversion with stoichiometric reagents (Fig. ). However, efforts towards the development of full selectivity control in electrocatalysis have thus far met with limited success. The merger of enantioselective catalyzed C-H activation with electrosynthesis has only very recently been realized, being severely limited to expensive 4dtransition-metal catalysis, namely with cost-intensive palladium and rhodium catalysts through two electron transfer processes (Fig. ). In sharp contrast, the use of Earth-abundant 3d transition metals in enantioselective electrocatalytic C-H activation has thus far unfortunately proven elusive. Given these major restrictions, we questioned whether enantioselective electrocatalytic C-H activation could be accomplished with 3d transition metal catalysts which typically proceed via single electron transfer (SET) elementary steps.