Since the main contribution to entropy arises from the lowfrequency translational and rotational modes, we focus on these modes only. The DoS features for water shown in Figures 5 and 6 were discussed above. Also here, we quantify the corresponding entropy by separately examining the metal surface, 1WL, and IBL contributions (see Figure ). The entropies of water components are collected in Table II such that the water molecules which stay in the 1WL region for 80 % of the simulation time are included as the 1WL contribution. The number of such molecules in the simulation box was of the order of 20. While the chosen residence time impacts the absolute local entropy values (see Table ), the trends of the absolute 1WL and IBL entropies are robust enough for a qualitative discussion.