For the synthesis of PCL, 720 mg (2 mmol) and 200 L of ECL (ca. 2 mmol) were dissolved using 500 L dichloromethane (DCM) solvent inside a Schlenk tube which was previously heated-vacuumed-degassed three times using nitrogen gas. Schlenk tube was then irradiated using a photo-reactor equipped with 3 fluorescent lamp (Crawl Miracle UVB 13W) emitting light nominally at 300 nm with a light intensity ~80 mW/cm 2 (measured using Delta OHM Quantum radio photometer) at reaction flask. After 4 h of irradiation, the solution was precipitated into 10-fold methanol and the resultant white colored solid was dried under vacuum. For the synthesis of PEDOT, 500 L of EDOT (ca. 5 mmol) and 100 mg of PAB (ca. 5 mmol) were dissolved using 500 L dichloromethane (DCM) solvent inside a Schlenk tube which was previously heated-vacuumed-degassed three times using nitrogen gas. Schlenk tube was irradiated inside the photo-reactor used for the scaffold synthesis. The dark-blue colored solution was precipitated into cold methanol and dried under vacuum. IR Measurements. Fourier-transform infrared (FTIR) spectra were recorded on Perkin-Elmer Spectrum One spectrometer with an ATR Accessory (ZnSe, PikeMiracle Accessory) and mercury cadmium telluride (MCT) detector. 32 scans were averaged. GPC Measurements. Gel permeation chromatography measurements were performed on a TOSOH EcoSEC GPC system equipped with an auto sampler system, a temperaturecontrolled pump, a column oven, a refractive index (RI) detector, a purge and degasser unit and TSKgel superhZ2000, 4. 6mm ID x 15 cm x 2cm column. Tetrahydrofuran was used as an eluent at flow rate of 1.0 mL.min -1 at 40 °C. Refractive index detector was calibrated with polystyrene standards having narrow molecular-weight distributions. GPC data were analyzed using Eco-SEC Analysis software. NMR Measurements. H NMR and C NMR spectra were recorded in CDCl3 and DMSO-d6 with tetramethylsilane as an internal standard) at 500 MHz and 125 MHz, respectively on an Agilent VNMRS 500 spectrometer at 25 o C. SEM Measurements. SEM measurements were performed using Zeiss Ultra Plus Field Emission Scanning Electron Microscope with EHT= 5.00 kV and probe at 200 nA.