The overview of our approach is illustrated in Figure . Our method uses the previously developed correlation to approximate the temperature dependence of ΔΔ𝐺 ‡ solv and subsequently employs eq 3 to express the liquid phase rate constant as a function of Arrhenius parameters and ΔΔ𝐺 ‡ solv . Eq 3 is derived based on the assumption that the same reaction occurs in both gas and liquid phases , which allows the liquid phase rate constant to be expressed in terms of the corresponding gas phase rate constant (𝑘 gas ) and solvation correction :