Recently, König reported universal conditions for the coupling of aryl bromides and various nucleophiles, including sulfinates, using nickel and the photocatalyst 4CzIPN. SMOPS, PMB-R, and SES sulfinate were effectively coupled with aryl bromides using NiBr2(DME), 4CzIPN, and DABCO in 66%, 82%, and 62% yield, respectively (Figure ). The PMB-R sulfinate coupling required airfree conditions while both SMOPS and SES required the presence of oxygen (air). oNB-R sulfinate failed to engage and Rongacyl degraded. This photocatalytic method provides a straightforward method to access protected sulfinates from the much more readily accessible aryl bromide. Efforts are ongoing to further the utility of this reaction.