Remarkably, the latter electrocatalytic C-H chlorination step was found to proceed with high efficiency at room temperature with a variety of acid chloride and chloroformate reagents, when using a carbon cloth anode and a platinum cathode without the need of any additional metal catalysts, additives or electrolytes. Another elegant feature of this electrochemistry-enabled cascade protocol is that it can be performed efficiently with near-equimolar ratios of acid chloride or chloroformate and aromatic amine reagents (1.05 equiv. vs 1.0 equiv.), making the overall transformation highly atom-economical. Moreover, as shown by the present work, the resource efficiency of the cascade protocol combined with its excellent chemo-and regioselectivity allow for very clean reactions with minimal formation of undesired byproducts and waste.