Phenol nucleophile scope [B] P(V) electrophile scope reactions were carried out on 0.1 mmol scale; all yields are isolated yields; yields for related products employing our first-generation method are reported in purple under the relevant examples; e.r. determined by HPLC analysis; 2 is a single crystal X-ray structure, H-atoms omitted for clarity; d.r. was determined by P{ 1 H} NMR or 1 H NMR.