This section presents the rovibrational kinetic database generated through SurQCT and compares it against the results from complete QCT calculations. The section is divided into two parts: the first part discusses the direct comparison of state-specific energy transfer and dissociation reaction rate coefficients at different translational temperatures; the second part contrasts the results of the master equation analysis based on the two databases. Several observables are calculated and discussed, including the thermal and quasi-steady state dissociation rates, internal energy relaxation times, and the evolution of macroscopic observables.