We have shown that the use of GEOR in conjunction with a bipolar membrane can effectively replace OER as an anodic reaction in a variety of electrolysis cells, even those with significantly different electrochemical environments. GEOR can be paired with HER, both in concentrated acid solutions and seawater, and with CO2RR in bicarbonate buffered solution. We showed that a load-line analysis can be used as a method for predicting the overall cell potential in a twoelectrode electrochemical setup. The overall cell potential of the GEOR-BPM electrochemical cell paired with HER and CO2RR was 1 V less that of a conventional OER-membrane cell at -10.0 mA cm -2 . The Au-Pt-Bi-coated Ni foam electrocatalyst was shown to be stable for greater than 20 h periods at -10.0 mA cm -2 during GEOR. Minimal glycerol migration through the BPM was observed. This device design may help to facilitate PEC solar fuels systems that rely on alternative oxidation reactions.