The Hirshfield charge (Table ) partitioning data reveal subtle variations in charge distribution across the Pt dopant and the surrounding carbon atoms under external pressure. Unlike the Mulliken analysis, which emphasizes localized nucleophilicity, the Hirshfield method provides a broader perspective on how charge is shared across the system. This charge redistribution underscores the adaptability of the platinum-doped graphene to external influences, indicating potential for tunability in its electronic and adsorption properties. These insights further corroborate the material's efficacy in applications requiring precise charge interaction and control.