Li and Merz proposed to add another term scaling as r -4 to the Lennard-Jones potential and obtained a better estimation of the hydration free energy, ion oxygen distance as well as coordination number in system involving multivalent cations than using empirical force field with regular 6-12 Lennard-Jones potential. Polarizable force field were successfully applied to divalent cations for which the charge and the van der Waals centers are distributed to multiple site represented by dummy atoms. Also, the Electronic Continuum Correction is another approach that takes into account of the polarization of the divalent cation in a mean field approach: the charge of the cation are rescaled by the inverse square root of the electronic part of solvent dielectric constant. In this work, we have made the choice of using the refined empirical force field proposed by Mamatkulov and coworkers, not only because it reproduces empirically experimental energy solvation at infinite dilution for divalent cation electrolytes, but also for the transferability of the force field for monovalent salt, water and later, porous materials.