Storing hydrogen at operational temperatures poses a significant challenge to its commercial viability, particularly in applications such as transportation. The U.S. Department of Energy (DOE) has set ambitious targets for hydrogen storage by 2025, including achieving 5.5 weight percent (wt %) and 40 g L -1 at 233-358 K, with an ultimate target of 6.5 wt % and 50 g L -1 . Additionally, during the DOE's Hydrogen Shot summit in 2021, a further goal was announced: to reduce the cost of clean hydrogen to $1 per 1 kg within the next decade. To achieve these targets, it is evident that materials-based approaches are preferred. Rather than attempting to compress or cryogenically cool hydrogen storage tanks, adsorbents such as Metal-Organic Frameworks (MOFs) and Covalent-Organic Frameworks (COFs) can be introduced to the vessel, improving gas uptakes without incurring high utility costs. Of these adsorbents, COFs show particular promise due to their high surface area and composition of lighter, more abundant elements compared to MOFs. While many MOFs can offer high uptakes, operating at cryogenic temperature (77 K) swings to ambient conditions (298 K) is often prohibitively expensive. To make the process more economical, it is preferable to perform the adsorption process at ambient conditions. However, this is challenging for many MOFs and COFs, as adsorption energies decay at higher temperatures due to entropic changes. As a result, MOFs and COFs can lose their loading capacity at higher temperatures, and those with promising uptakes at 77 K may not perform as well at room temperature.