One promising avenue of investigation has been the synthesis of bio-based polyesters, which has garnered considerable attention in recent years . Polyesters are materials that offer versatility, chemical resistance, and ease of processing, making them suitable for a wide range of applications. They exhibit good dimensional stability, mechanical properties, and UV stability, while their recyclability and aesthetic options make them highly desirable in industries such as textiles, packaging, and automotive . Polyesters have been developed using a variety of compounds derived from biomass, such as building blocks or monomers . Adipic acid and its derivatives as well as aliphatic linear diols such as 1,4butanediol which were specifically used in this work are one of the top renewable building blocks which have been widely used in polyester synthesis . However, plant oils, as well as fatty acid derivatives, have proved to be also a useful basis for developing biobased monomers . In our previous study, we demonstrated that dilinoleic diol (DLD) possessing a long aliphatic chain (C36) is a promising starting compound of novel polymeric materials . Besides being an almost readily available, natural fatty acid derivative obtained via linoleic and oleic acid dimerization , it can be used as a comonomer to produce polymeric materials with improved flexibility .