The presence of biopolymers in epoxidized corn oil makes the thermal equilibrium not constant, thus creating more disorder . Also, the long chain structure of DGEBA, with the presence of aromatic compounds making the whole structure, upon application of heat (curing), makes a polymer jigglier, which increases the entropic contribution. We also note that the enthalpy and Gibbs free of energy are much higher than VE_Neat. In terms of bond energies, wherein hydroxyl radicals (O-H), 467 kJ/mol, C-O, 358 kJ/mol, ). Using TGA, the phase transformation shown above shows that the first degradation happens when moisture content is removed upon heat entering the system, also known as dehydration. Thermodynamically, the next phase, second degradation, yields the decomposition stage, wherein most of the samples were rapidly degraded. The last phase transformed into condensation, wherein the residue yield was observed.