cm -1 , comparable to organic perovskite solar cells. showing a positive ΔG value of 0.21, 1.03 and 1.12 eV for the formation of H*, respectively, contributing to an uphill free energy profile of the first HER step as indicated in Figure . The ηHER is calculated to be 0.21, 1.03 and 1.12 V for CTPAB, OTPAB and MTPAB (Equation S17), respectively (details can be found in the SI).