In this study, we searched for unimolecular reactions of ĖF with two recently published reaction exploration methods, CTY-TAD and PESmapping. The results show that both methods are able to find the three elementary and unimolecular ĖF pathways of the 1,3-dioxolane combustion mechanism as proposed by Wildenberg et al.: decomposition, cyclization, and hydrogen migration. Therefore, all expected reaction paths are found during the reaction exploration for ĖF, showing that RMD reaction exploration tools like CTY-TAD and PESmapping are valuable tools to support the development of chemical mechanisms in combustion applications.