In systems with constant potential boundaries (such as the electrodes we employ), the variance in P (U α ) exhibits a pronounced position dependence. Specifically, it has been noted multiple times in the literature that electrostatic potential fluctuations systematically narrow for species approaching the surface of a constant potential surface (such as the electrodes we employ in our simulations). This narrowing is illustrated in Fig. , which shows the variance of P (U α ) for several species in solution as a function of their position between the two constant potential electrodes. At all positions in the nanoscale system, even well beyond the Debye screening length, the fluctuations in U α increase away from the electrodes. This is, yet again, a manifestation of the long-range nature of Coulomb interactions that can complicate the physical interpretation of these microscopic statistical properties.