Chromatographic and spectroscopic fingerprints reveal known and/or unknown constituents by being targeted and/or untargeted, respectively. Of the most suitable untargeted techniques, NMR and FT-IR, NMR provides the more dispersed spectra with less signal overlap and, thereby, offers better capabilities for both targeted and untargeted analysis. This dual capability of (q)NMR, in combination with simultaneous quantification, was highlighted by the present outcomes of the present CDS analyses.