To demonstrate the scalability and synthetic utility of the cobalt-catalyzed ACT process, we performed a gramscale reaction that scaled to 5 mmol, achieving a 77% yield of the desired product 2h. Subsequent transformations illustrated the versatility of the rearranged allyl carboxylate products: hydrogenation yielded the saturated ester 3 with a 95% yield; epoxidation of the newly formed alkene was successful using meta-chloroperoxybenzoic acid (m-CPBA); ozonolysis produced a 2-carboxylate ketone 5 with an 81% yield, showcasing diverse synthetic pathways. Additionally, an organo-photocatalyzed hydrothiolation reaction demonstrated potential applications in ligation and material science. The Tsuji-Trost reaction with diethyl malonate as the nucleophile produced allylation products 7 and 8 with a 66% yield. Finally, dibromination with bromine generated the 1,2-dibromo product 9, further demonstrating the versatility of the products.