Modulated differen al scanning calorimetry (mDSC) was carried out using a Discovery DSC™ (TA Instruments, New Castle, DE, USA), equipped with a refrigerated cooling system (RCS90). Experiments were performed under dry nitrogen atmosphere at 50 mL/min flow rate, and the temperature was calibrated with pure indium. Tzero aluminum pans (TA Instruments, Switzerland) contained between 2 and 5 mg of each ASD that had previously been cast directly into the pans and vacuum dried. The pans were sealed with Tzero herme c lids with pin holes (TA Instruments, USA). Thermal scans of raw materials and ASDs were acquired at a hea ng rate of 2 °C/min from -20 °C to 180 °C with a modula on of 1°C every 60 seconds.