We combine all electronic structure information derived so far to construct the energy level alignment (ELA) diagrams in deposition the work function increases to 5.3 eV after one monolayer, and no further changes occur for thicker films. These findings suggest that CoPc induces a strong negative dipole change of -0.6 eV at the MoS2 surface. This change of the surface dipole and the accommodated band-banding observed in the core-level shifts is consistent with our previous results with iron-phthalocyanines as well as for other heterostructures of MoS2, for example with cesium carbonate. In contrast, CoPcF16 induces a weak positive dipole change of + 0.2 eV. The optical bandgaps are 1.66 eV and 1.54 eV, consistent with values for similar phthalocyanines (Figures and respectivly). We assume that pure phthalocyanines behave identically to thick multilayers deposited on MoS2 and compare the electronic structure of pure CoPc as well as CoPcF16 with freshly cleaved MoS2 in Figures and, respectively.