are featured with *OOH_S1→H2O2 as the limiting step for the H2O2 dissociation pathway, where optB86b has a competing *OH reduction step along with this. All the thermochemical reactions such as *O2 dissociation, *OOH dissociation, and *H2O2 dissociation are featured with high negative free energies for all the methods. This can be ascribed to the more closed occupation of the dissociated intermediates towards the surface compared to the reactant species located at a higher distance from the surface, being part of the disrupted water network. This can be rationalized based on the similarity in the rate-limiting *OH_S1→*+H2O step as well as similar *OH adsorption free energy originating from scaling relations for Ir, Pd, Pt (111) surfaces in their work and similar extent of solvent assisted stabilization across these dispersion correction methods in our study (Table ).