Inclusion of coverage-dependent thermodynamic parameters via analytical expressions, as opposed to evaluating thermochemistry on the fly during the kinetic modeling, has two benefits. First, it is computationally more efficient. Second, this approach helps to alleviate the patchiness of the discrete data due to the finite unit cell size and achieves more smooth and continuous profiles in MKM. We focus only on the results obtained from the global minima hopping for Pt(111) and Co(0001) for the microkinetic modeling. The coverage dependence was parameterized with continuous forms with the four algebraic models, as illustrated in Figure , and the parameters for each model are listed in the SI. For the coverage-dependent heat capacity, which has an additional temperature dependence, a log-quadratic model (Equation ) was fitted as shown in Figure .