According to this process when the simple bidentate dpb linker was introduced in a DMAc medium, Cu6-dpb crystals were obtained. The SCXRD analysis confirmed that the crystals formed in an orthorhombic system with the space group of Pnma (62). The detailed analysis reveals that the repeating cluster node consists of six Cu(I) atoms, each coordinated by four S t Bu -ligands. These six Cu(I) atoms are arranged in an octahedral geometry, but with an average interatomic distance of 3.3488 ± 0.114 Å, which is too large to support significant cuprophilic interactions. Instead, the Cu(I) atoms are held together by thiolate bridges, where each thiolate ligand adopts a µ3 bridging mode, coordinating three Cu atoms simultaneously (Fig. ). The average Cu-S bond distance in this arrangement is 2.2315 ± 0.00567 Å. The attainment of this specific structural geometry is not random; rather, literature repeatedly highlights the stability of the Cu₆(SR)₆ cluster node conformation, first reported in the Cu-thiolate nanocluster structure by Gao et al. Here, however, we observed two