For instance, AzoDiGua remains photoswitchable and enables photoreversible assembly/disassembly of the aggregates by short UV/blue irradiation pulses for several consecutive cycles. Similarly, intrinsic chelation properties and enzymatic reactivity of ATP could be exploited to dynamically trigger fast disassembly of the structures by the action of metal cations or enzymes. Third, fluorescence appeared as an emerging property arising from the self-assembly itself. Indeed, although ATP and AzoDiGua have only very weak fluorescent properties when they are individually dispersed in solution, their co-assembly lead to significantly fluorescent superstructures. Such aggregation-induced fluorescence of azobenzene is a well-known phenomenon but is in many case obtained with pure azobenzene compounds loosing most of their phoswitchability in the aggregated state. Here, the coassembly with ATP allowed us not only to combine both aggregation-induced fluorescence and photoswitchability in the same system, but also to realize multi-stimuli responsive fluorecence.