Chiral macrocycles with defined chiral structures and intriguing porous structure, not only display enantioselective recognition, but also engage in other applications related to chirality. Among them, luminescent chiral macrocycles embedded with emissive moieties in the chiral cyclic backbone have further proven their potential in enantio-selective fluorescent sensing, circularly polarized luminescence (CPL), and chiral organic light emitting diodes (OLED) . However, luminescent chiral macrocyclic POPs with hierarchical porous skeleton based on these functional chiral macrocycles are rarely explored owing to their synthetic difficulties. Combing the 3D porous skeleton and luminescent chiral macrocyclic voids, intriguing chiroptical performance and related applications can be evidently anticipated for chiral luminescent macrocyclic POPs.