However, more detailed analysis is needed to further understand the quantum chemical origins of these intriguing scaling relations governing the binding energies. Electron structure wise, the adsorbate can interact with the metal surface via four distinct mechanisms. Firstly, the adsorbates, especially those with a large dipole moment, can have strong electrostatic interactions with the metal surfaces. Secondly, the adsorbates, again especially those strongly polar ones, can also polarize the metal electron density. The reverse polarization can be equally important, where the metal surface perturbs the adsorbate orbitals and its electron density. Thirdly, charge transfer is also expected to be rather substantial: many metal surfaces can readily lose electrons to the adsorbate, whereas back-donation from the adsorbate may also be significant, especially for surfaces of metal atoms with unfilled d orbitals. Lastly, van der Waals interactions are present to keep the adsorbate not too close to the metal surface (through short-range repulsion) and attract the adsorbates at a good distance away from the surface (through longrange dispersion). Needless to say, a comprehensive understanding of the scaling relationship governing the binding energies should be gained with all these interaction energy components taken into account.