Figure depicts the superVolcano trend for lower β values as compared with Figure ; β was lowered to 65 kJ/gmol versus 102 kJ/gmol in Figure . The high γ B-A curves gain two new rate-limiting kinetic regimes, with adsorption limited behavior until an absolute binding energy of 0.4 eV, surface reaction/adsorption until 0.9 eV, surface reaction/adsorption from 0.9 eV to 1.4 eV, and desorption limited behavior from 1.4 eV onwards. As expected, the overall maximum TOF B increases to ~10 5 s -1 since a lower β allows for higher surface Finally, α was raised from the intermediate value of 0.6 to its maximum value of 1.0, such that Figure can be readily compared with Figure since they share all other parameters in common. The maximum TOF B was relatively unchanged, but all volcano curves in Figure exhibit steeper slopes due to the influence of α. The tighter coalescence of all curves below 0.5 eV shows that these systems are largely adsorption limited due to a low δ of 0.5 eV. The desorption lines from 1.3 eV onwards for low γ systems are shifted to higher binding energies as compared with Figure . This is due to the high coverage of A* at binding energies > 1.3 eV, and this limits the desorption TOF. In summary, the superVolcano shape and kinetic behavior is highly sensitive to both the transition state BEP relationship parameters and the binding energy equivalence point, δ. Since these parameters are a strong function of the reaction chemistry and metal crystal face/structure, practical application of dynamic catalysis will be guided by a combination of catalyst design and external stimulus selection to achieve beneficial catalytic reaction control.