In addition, we observe that the distribution of static HOMO energies strongly deviates from a Gaussian distribution. While the distribution has a long tail towards lower HOMO energies, it sharply cuts off at higher energies, which has important consequences for hole transport in PEDOT:PSS(:sorbitol) films as well as attempts to model charge transport in such systems. Holes prefer to be localized on PEDOT molecules with high HOMO energies, where, due to missing tail states (shallow traps), the effective energy disorder is even lower than that of the full distribution. As a consequence, the hole mobility of PEDOT will be higher than that of another material with the same energy disorder parameter but with a Gaussian distribution of energy levels.