MD simulations of various systems were carried out, all of them are summarized in Table . As water model for pure water and water mixtures, we relied on the TIP4P/2005 model , which has been demonstrated to accurately describe the properties of water compared to other simple rigid nonpolarizable water models. . To model methanol, the rigidnonpolarizable OPLS/2016 model introduced by Gonzales-Salgado and Vega was used , which provides an excellent representation of both, methanol's liquid properties, as well as the solid-liquid equilibrium. For modeling dimethyl ether, the united atom forcefield TraPPE-UA was employed, which provides an accurate representation of the vapour-liquid equilibrium. As forcefield for Triglyme, we have relied on the modified TraPPE-UA forcefield of Fischer et al. , which is well-suited for describing mixtures of polyethers with water , and has recently recently been compared favorably to various other forcefields. To simulate the ionic liquid [BMim][PF 6 ], the "coarse-grained" ILM2 model of Roy and Maroncelli was used since it provides an excellent representation of both it's thermodynamical and dynamical features.