Please do not adjust margins dimethylproplylamine. Al forms a new Al-N bond with NH2 with a bond length of 1.82 Å. Similarly for Al(Me2NEtN t Bu)H2, N1 forms a new N-H bond and Al forms a new Al-N bond with NH2 of 1.85 Å. This results in the formation of N,N-dimethyl-N'-(2methyl-2-propanyl)-1,2-ethanediamine. Compared to H2, NH3 is shown to be a more reactive reducing agent with these Al complexes, therefore shows some promise for AlN deposition.