Therefore, the study of copper corroles-graphene hybrids is not only a prominent challenge rather also a rich field for the development of new magnetic, sensing, and optical applications. Finally, the exposed results suggest that aryl-substituted corroles at the meso positions support the augmented magnetic response of the hybrid system, while electrophilicity of hybrids acts to the detriment of the ferromagnetic coupling. Statistical correlation analysis supported the rationalization of the augmented magnetic response and the spin transfer phenomena, indicating that spin transfer is related to kinetic and thermodynamic stability.