Poly(DMAA-co-AAHAQ) was synthesized as previously reported. Poly(NIPAAmco-MAA-co-BPQAAm) was synthesized as previously reported. Benzophenone disulfide was synthesized as reported elsewhere. S1805 resist and AZ303 developer were purchased from BPQAAm] terpolymer) were employed as plasmonic substrates. Briefly, a BK7 glass slide was coated with 2 nm thick chromium layer and 50 nm thick gold layer by thermal evaporation (UNIVEX 450, Helmut Heller GmbH, Germany). Then, S1805 positive photoresist (1:2 ratio diluted with propylene glycol monomethyl ether acetate) was spun on the gold surface yielding a layer with a thickness of 120 nm. A periodic interference pattern was recorded into the photoresist layer by employing a He-Cd laser (λ = 325 nm) with the Lloyd's mirror set-up as previously reported by our group. The well-defined resist particles with sub-wavelength dimensions were etched by using the AZ-303 developer (1:15 ratio with deionized water). Finally, the inscribed pattern was transferred to the gold film by using dry etching with argon milling system (IonSys 500, Roth&Rau, Germany). The remaining photoresist was removed by applying an oxygen plasma treatment. The prepared plasmonic substrate was immersed overnight in a 1 mM solution made of BPdiS dissolved in DMSO in order to form a self-assembled monolayer on the pristine gold surface. The photo-crosslinkable polymer thin film was subsequently spun (from ethanolic described above. The substrate was mounted into the Photonic Professional (GT) system from Nanoscribe for the recording step, with the side carrying the plasmonic architectures facing a clean cover slip. The interface was selected by focusing on the surface with the gold nanoparticle arrays and the correct z plane was set by recording square features with the highest writing speed and laser power PL and visually observing the recording of the µm size features with the equipped microscope camera. Once the proper interface was found, a recording script was loaded and squares (100×100 µm 2 ) with different parameters were inscribed. The scan speed was varied between 10000-2500 µm s -1 and the laser power PL = 2-5 mW. After the recording step, the unbound polymer was removed by rinsing with ethanol.