Notably, the challenging di-ortho substituted aryl halide containing a pendant primary amine, 5i, was coupled in lower, but still medicinally useful, yield (22% by 1 H NMR spectroscopy) with 1iodo-3-phenylpropane. Additionally, we isolated the product from the reaction of 5a with 1bromo-3-phenylpropane in good yield (72%) and demonstrated that the reaction is scalable through a coupling using 3 mmol of 5f (see SI) as proof-of-principle that our method will enable the generation of compounds for drug discovery.