Plots of the average turnover frequency as a function of surface binding energy oscillation amplitude and frequency (i.e., heat maps) were generated in Matlab 2018b using the jet color scheme to indicate low and high TOF, ranging from dark blue to dark red. The heat map data consists of a modified Akima cubic Hermite fit through discrete data points calculated at 0-1.0 eV ΔBE. Data points are tabulated in supporting information section S5. This data was obtained for symmetric dynamic catalysis starting at the volcano peak (ΔBE ~ -0.05 to 0.05 eV) and oscillating the same amplitude in each direction (from 0-0.75 eV). Data was also obtained for asymmetric dynamic catalysis where the end points were chosen based on extrapolated linear fits of each side of the volcano curve. These lines were set equal with a specified oscillation amplitude between 0-1.5 eV, and the end points were chosen by drawing a vertical line down to the volcano plot. Frequency response figures were generated for scenarios with varying BEP relationships where the BEP slope ranged from zero to one.