Previously, we have shown that the glasses formed via meltquenching HOIPs possess potential as thermoelectric materials, owing to their moderate electrical conductivity as well as very low thermal conductivity values. This study provides a rational for altering the physical properties of the starting perovskite and nonperovskite type ABX3 materials, and at the same time opens up directions in forming further examples of functional liquid and glasses from ABX3 hybrid structures.