The table presents the energy minimization and geometry optimization results for cisplatin using Hartree-Fock/LanL2DZ and PBE0/LanL2DZ methods. Both methods yield the same energy values for energy minimization and geometry optimization. However, the PBE0 functional results in lower energy than Hartree-Fock, with a difference of 2.000805557 Hartree. This indicates that the PBE0 method provides a more stable and energetically favourable structure for cisplatin, highlighting its superior accuracy in modelling the molecule's potential energy surface.