Polyvinyl chloride (PVC) is the most plasticized of all polymers, giving it new properties and applications in e.g., packaging, construction materials, toys, healthcare... Over 80 % of plasticizers produced are used for PVC . Phthalates, which are esters of phthalic acids, represent the most common PVC external plasticizers, such as bis(2-propylheptyl) phthalate (DPHP) or diisodecyl phthalate (DIDP), whose structures are shown in Figure . These phthalates have many advantages, such as excellent compatibility, low volatility and low cost . The carbonyl groups are able to form weak bonds with PVC on the C-Cl dipole and thus increase their compatibility and miscibility, forming a network based on weak interactions. In addition, the fatty chains from these plasticizers increase the inter-macromolecular free space between the chains and thus bring mobility. Nevertheless, these external plasticizers can partially migrate outwards by exudation and/or volatilization, leading to problems of phthalate bioaccumulation in the human body and the environment . These fossil-based additives are suspected of causing health problems, such as endocrine disruption. Regulations have long been in place to limit the use of phthalates notably in toys for young children . Then, since 1999, the European Commission has banned the use of phthalates in children's toys. In 2005, an EU directive (2005/84/EC) made this ban permanent. This directive also extended the ban to childcare articles .