Studies of molecular electrocatalysis are often long and tedious, requiring screening of many catalysts and substrate combinations, different scan rates, and manifold solution conditions and reagent concentrations. Mechanistic studies of mediated electrocatalytic systems often are conducted by titrating in increasing amounts of reactants into the solution and observing the resulting changes of the current-potential curve using cyclic voltammetry (CV). Further, investigations of PCET reactions additionally require screening the behavior of the system by performing CV at different concentrations of acid or base in solution, for which knowledge of pH is essential for mechanistic insight. As the complexity of large experimental campaigns increases, manual experimentation becomes too slow to explore the massive chemical and parameter space needed for comprehensive understanding of molecular electrocatalytic systems. We can turn to laboratory automation to speed up the exploration process, as automation offers a solution to lengthy exploration campaigns that can hinder the discovery of breakthrough electrochemical systems. Automated platforms can increase experimental throughput by improving operational efficiency and enabling passive experimentation over long time frames without interruption. Automation additionally improves the repeatability and reproducibility of experiments, by removing human error and allowing the exact same experimental workflow to be run across replicate experimental platforms. Automated and self-driving laboratories have found use in a broad range of chemistry and materials science problems and are now becoming increasingly mainstream in electrochemistry as well. For example, automated and high throughput platforms for electrochemical experimentation have been used for applications ranging from energy storage these platforms are not designed for the titration-type electrochemical experiments that are crucial in molecular electrocatalysis studies, highlighting the need for a specialized platform for this type of study.