1.31 g of tin pellet (from tin powder) was made using a hydraulic press. Electrosynthesis was performed to produce three different sizes by applying constant potentials of -7 V for 6, 12, and 16 h respectively, using an inert platinum wire as the counter electrode and a silver wire as the quasi-reference electrode using 0.5 M LiClO4 in Acetonitrile as electrolyte. After the time interval, it was kept in ethanol for 12 h until the effervescence settled down. Optical properties corresponding to the size variations were analyzed using UV-Vis and photoluminescence (PL) spectroscopy at room temperature in ethanol. Structural characteristics and changes in size were investigated with Fourier transform infrared (FT-IR) spectroscopy, powder X-ray diffraction (PXRD), and X-ray photoelectron spectroscopy (XPS), while the sizes were confirmed through transmission electron microscopy (TEM).