Coverage (Θ i ) dependency of surface reactions is known to significantly impact the performance of microkinetic models (MKMs) and is usually incorporated into the Arrhenius expression by a correction term, ε i,j , influencing the activation barrier of reaction j at high coverages of surface species i . The desorption of CO from Ni surfaces, for example, is known to be encouraged at high coverages . The additional parameter µ i,j resembling a pseudo power-law expression for surface coverage dependency is rarely tabulated for experimentally or computationally derived kinetics and thus omitted. In other words, we assume µ i,j = 0 throughout this work. It must be noted that this coverage dependency formulation in general applies for all possible surface reactions, adsorptions, and desorptions. However, only the adsorbed surface species are considered when calculating the expression in eq. ( ) as indicated by summing up to m S , the number of surface species . Special care is often taken when considering adsorption. Since adsorption kinetics can be described from a statistical thermodynamics viewpoint, they are oftentimes parameterized using the sticking coefficient, S j , following the formalism depicted in eq. ( ) .