Finally, we focused on primary alkyl iodides, which are interesting yet more challenging to engage in the reaction protocol. A slight modification of the reaction conditions (see GP5 in the Supporting Information, including an inverted organic halide/olefin ratio and extended light exposure) resulted in complete conversion and yielded the compounds 32-37 in satisfactory yields (41-69%). Of particular note are the unprotected aliphatic alcohols (34) and easily oxidizable phenols (37).