A combinatorial approach was taken to experimentally examine self-assembly of binary mixtures of ligands with Pd(II). The 12 possible combinations of a 1:1:1 mixture of 1, 2 and [Pd(CH3CN)4](BF4)2 were sonicated in d6-DMSO until a homogenous solution was obtained, and subsequently heated at 50 °C until no further spectroscopic changes were observed by 1 H NMR.