Most of these effects are well-known, however, the early introduction of a C-2 azido substituent as a determining factor is surprising. We, therefore, sought to investigate the full tree in depth to see if we could both rediscover other well known-trends and find new trends, with a primary focus on finding "α-selective" glycosylations with glycosyl donors that have a -1 configuration of the C-2 and finding "β-selective" glycosylations with glycosyl donors that have a 1 configuration of the C-2. Or, in more general terms, finding decision nodes yielding the 1,2-cis product, as this would be opposed to the "norm" established from our simplified decision tree, that is the major anomer is the 1,2-trans product.