The transfer of other alkyl or acyl groups on benzothiazoline was investigated. p-Methyl and p-fluorobenzyl groups underwent the transfer reaction smoothly to give 5a-5c with high to excellent enantioselectivities. The tert-butyl group gave 5d and 5e with 71% ee and 75% ee, respectively. The transfer of benzoyl and acetyl groups also proceeded to furnish 5f and 5g in modest yields and with moderate enantioselectivities probably due to the undesired interaction of the carbonyl moiety with 1a.