The wavefunctions corresponding to the peaks k-o are dominated by three nodes in the H-F coordinate, implying the involvement of vHF = 3. Notably, these features reside only slightly above the TS barrier and are considerably broader than the features that precede them. The large difference in geometry between the anion and the RC suggests that these features correspond to vertical transitions that project the anionic wavefunction onto a nuclear configuration that rapidly rearranges. This is mirrored in the simulated spectra, where the widths of features k-m progressively increase in both the high-resolution and convolved spectra.