Therefore, Ni-rich cathodes undergo severe structural degradation at lower charging voltages. To date, surface coating and modification stand out as the predominant methodologies for curbing undesirable side reactions between oxide cathodes and solid electrolytes . While irreversible surface degradation plays a role in capacity loss, the significant hurdle arises from crystal defect-induced phase transitions from the layered structure to the spinel-like phase within the interior of cathode particles, posing a formidable barrier to the practical implementation of Ni-rich and Li-rich cathodes . In light of this, it becomes imperative to explore additional approaches that can complement established surface engineering methods.