F-doped SnO 2 (FTO) or Al-doped ZnO (AZO) display mobilities and conductivities below that of ITO, which limits their application in display screen technologies. However, ITO is not considered for large area applications such as in photovoltaics or smart window applications, despite recent improvements in the efficiency of indium based TCOs via innovative doping (Mo and Ce), due to the expense and scarcity of indium. Therefore, there is a drive to try to increase the performance of the known earth abundant TCOs, or more unusually, to discover new TCOs. The last "new" TCOs were the thin film correlated metals SrVO 3 and CaVO 3 in 2015 and single crystal La-doped BaSnO 3 in 2012. In terms of materials design, the common trend in the majority of the effective n-type TCOs is the presence of post-transition metal cations with the electronic structure (n -1)d 10 ns 0 np 0 . In these materials, the valence s orbitals of the cation hybridise with oxygen s states yielding conduction bands with low electron effective masses. Indeed the majority of the cations in the industrially relevant TCOs are limited to groups 12, 13 and 14 of the periodic table.