In our recent report, we presented a facile synthesis strategy for the simultaneous incorporation of pyrazine and catechol units into organic cathode materials. Extending the molecular structure with additional quinoxaline units enabled newly synthesized tetraquinoxalinecathechol (TQC) to deliver one of the best cycling stabilities of small organic materials in a Li-organic battery, reaching a capacity retention of 82 % after 300 cycles at a current of 50 mAg -1 . In the Zn-organic battery with the aqueous electrolyte, TQC showed higher capacity in comparison with the Li-organic battery but worse cycling stability.