In molecular self-assembly, molecules are designed to interact with one another to form larger, supramolecular complexes. The assembly process alters the material properties of the system, which gives rise to supramolecular materials. In recent years, there has been a focus on dynamic supramolecular materials, i.e., materials that change and adapt to their environment. In such materials, molecules are designed to assemble or disassemble in response to a trigger. For example, peptides can be designed to assemble or disassemble upon enzymatic phosphorylation, dephosphorylation, or an increase in pH. In these dynamic assembly mechanisms, kinetic traps can occur those trap molecules in their assembly because the thermal energy available is insufficient to overcome the energy barrier for disassembly. As molecules and their assembly become increasingly more complex; it becomes more challenging to predict whether such unwanted kinetic trapping will occur.