Aligned with our previous investigations characterizing benzimidazoles Nacylhydrazones and acylhydrazones derived from nitroimidazo [1,2-a]pyridine, intimately linked to (E)-3-(furan-2-yl) acrylohydrazides by their fundamental structure, this study endeavors to comprehensively explore the preferential conformation of these newly synthesized molecular entities. Employing a rigorous synthetic approach coupled with structural analyses, encompassing NMR, HRMS, UV-visible, and cyclic voltammetry, our objective is to delve into the optoelectronic properties of (E)-3-(furan-2-yl) acrylohydrazides.