Electrochemical data that derived from the automated experiments orchestrated with Auto-MISCHBARES platform demonstrated high reliability, with no observable failures or hardware errors that could compromise the results. All the measurements are stored on-the-fly in our DMS. The CV profiles of LFP electrodes, cycled between 1.8 V and 4.7 V at a scan rate of 5 mV/s are presented for two identical experimental sets for comparison, as shown in Fig. and Fig. . The scan rate selected for our study was an order of magnitude higher than typically reported for battery electrodes . This choice aimed to mitigate issues associated with electrolyte evaporation in our open setup. Such evaporation could disrupt electrical contact between the WE and the RE during measurement and increase salt concentrations in electrolyte . However, these effects were minimized by using a fast scan rate and routine flushing of the SDC head with fresh electrolyte after each measurement. The high scan rate can cause the change of slope in current density for CV measurements . In both sets of experiments, anodic and cathodic peaks were observed at approximately 3.8 V and 3.15 V, respectively, with a characteristic pair of redox peaks around 3.47 V corresponding to the charge-discharge reaction of Fe 2+ /Fe 3+ . In the first set, a minor anodic peak at 4.4 V was also detected, the origin of which remains unclear but aligns with findings reported by Chen et al. . Our observed peak values, including anodic ones at 3.7 V, cathodic ones at 3.25 V, and half-wave potentials of 3.4 V at a scan rate of 0.1 mV/s, closely match those documented in their study. It is also important to mention that the reference potential was calibrated against a 5 mM ferrocene solution prior to experimentation.