The unique structural and electronic properties of K3C6O6 merits us to consider it a potential superconductor. One reason 80 behind this suspicion is again the large number of states N near the Fermi level. A characteristic of the K3C6O6 DOS near the Fermi level is its peaked shape. Such DOS topologies are rare, and reminiscent of what can be found in some high pressure materials such as the 150 GPa Im-3m phase of SH3, which features a critical superconducting temperature, Tc, of 203 K. Nature tend to abhor such electronic features at ambient conditions of pressure, where they are usually avoided through structural symmetry breaking that causes the formation of electronic gaps or pseudo gaps. K3C6O6 is different because the levels near its Fermi level are all bonding, and responsible for covalent interactions along the direction of rhodizonates stacking (Figure ). Meanwhile, structural symmetry breaking is resisted by electrostatic repulsions between equally (and largely) charged neighboring anions.