Please do not adjust margins Please do not adjust margins modulated by the strength of the Lewis base or the rigidity of the Lewis acid, offering opportunities for precise control of interaction strength and bonding character. Ultimately, our work underscores the continuum nature of Lewis acid-base interactions, demonstrating how subtle manipulations of acid or base properties can transition complexes between donor-acceptor and van der Waals-like bonding regimes. This emphasis on the strength rather than the nature or classification of these interactions not only enriches our understanding of molecular assembly but also establishes a framework for the design of tailored chemical systems. These insights have far-reaching implications for advancing the field of chemical bonding and for developing innovative molecular assemblies and materials.