This work describes the synthesis, characterisation and adsorption and photocatalytic properties of a new family of MOFinorganic glass composites containing different proportions of a Ti-MOF (MIL-125-NH2) and a phosphate glass (20%Na2O-10%Na2SO4-70%P2O5). Each synthetic step was monitored by PXRD showing that the Ti-MOF maintains its crystallinity within the composite using the optimised synthetic conditions. The composites' microstructure was characterised by SEM showing a smooth distribution of the MOF-crystallites in the bulk of the pellets. EDS showed a homogeneous distribution of the P and Ti in ~270 µm 2 areas, but having ~30 µm 2 domains of each precursor material, according to the mapping analyses. Thermal characterisation of these composites has identified a Tg that is lower than that of the pristine inorganic glass, indicating a partial depolymerisation of the glass network upon heating. This is likely because of the presence of water in the composite surface.