Single crystal X-ray diffraction data for MUV-1-F were collected at a temperature of 100 K using Rigaku FR-X rotating anode (Mo-kα, λ = 071073 Ǻ), equipped with a Hybrid Photon detector HyPix-6000HE and an Oxford Cryosystems nitrogen flow gas system. Data was measured and reduced using CrysAlisPro suite of programmes. Absorption correction was performed using empirical methods (SCALE3 ABSPACK) based upon symmetryequivalent reflections combined with measurements at different azimuthal angles. The crystal structures were solved and refined against all F 2 values using the SHELXL and Olex 2 suite of programmes. Despite that the coordination polymers are intrinsically chiral, the centrosymmetric space group C2/c was found as result of the racemic distribution of the disordered layers of the MUV-1-F coordination polymer, as also observed for MUV-1-H, MUV-1-Cl, MUV-1-CH3 and MUV-1-NH2. 8 X-ray powder diffraction and thermogravimetric analysis A polycrystalline sample of MUV-1-F was lightly ground in an agate mortar and pestle and used to fill a 0.5 mm borosilicate capillariy that was mounted and aligned on an Empyrean PANalytical powder diffractometer, using Cu Kα radiation (λ = 1.54056 Å). Three repeated measurements were collected at room temperature (2θ = 5-30 °) and merged in a single diffractogram. Thermogravimetric analysis of MUV-1-F was carried out with a Mettler Toledo TGA/SDTA851e/SF/1100 apparatus in the 25-600 °C temperature range under a 20°C•min -1 scan rate and an air flow of 30 mL•min -1 .