To explore the potential for decarbonization of energy and chemicals manufacturing by means of CCU, we sought to investigate all feasible process configurations that include wellunderstood, scalable process options for capture and utilization sections. We illustrate this approach with a case study of a hypothetical industrial park, which is powered by natural gas, and delivers electricity and liquid fuels as main products. In the reference case, where no carbon capture is deployed, all CO2 emissions arising from electricity production are vented to the atmosphere. In case of integration of CCU, these CO2 emissions will be captured and converted to fuels, thus reduce the input of petrochemical resources to the chemical synthesis and consequently decrease the carbon footprint of the industrial park. The industrial park is presumed to contain two natural gas combined cycle (NGCC) power plants. One NGCC is equipped with MEA, while the other is coupled with a PSA, as to capture CO2. The CO2 fraction of flue gas is concentrated from ~4 to ~90% by MEA and PSA, respectively. Following this, with the co-feed of NG and steam, the concentrated CO2 is reformed to syngas, which is further converted to fuels, being reviewed as one of the most promising product type for carbon utilization. Among different liquid fuels used on large-scales, methanol, gasoline, and diesel are reported as the crucial for the mobility sector, because of their high energy density, and convenient handling. Hence, we focused on Fischer-Tropsch (FT) and methanol synthesis (MS) to manufacture fuel products (gasoline, diesel, and methanol). Overall, the proposed industrial park can be compatible with the existing industry in: (1) the upstream -by decarbonizing the energy sector, (2) the downstream -by supplying fuels to the mobility sector. The model of the industrial park is based on the following assumptions: