The existence of such descriptors is confirmed by the data of refs, which show correlations of the adsorption energy of neutral molecules on the oxide surface with the HOMO and LUMO energy level and other parameters. Refs. reveals correlations of the solvation energy with hardness. These facts suggest the possibility of a simplified description of the dependence of adsorption and some physicochemical and electrochemical parameters of molecules or ions on the energy level of the orbitals. For better clarity and potential practical application, the present work analyzes the adsorption coupling of various ions on the surface of a dielectric (aluminum oxide (0001) surface), a semiconductor (graphene) and a metal (gold (111) surface). The intermolecular interaction is analyzed by studying the binding of water and dimethyl carbonate (solvents frequently used in chemical and electrochemical practice) to ions of molecules. Correlations between some physicochemical and electrochemical parameters of ions and their electronic structure are also analyzed. The systems under study are a number of surface inactive and active ions, which are used in electrochemical investigations of surface phenomena and electron transfer, organic electrochemistry and potentially applicable in chemical current sources, such as batteries, supercapacitors, etc.