While the full analyses for all disaccharides we have parameterized here are provided in the supplementary information, here we focus on six cases, three of which give clear agreement with atomistic data and three of which differ slightly from the atomistic data. For each of the three disaccharides in their respective categories, two were parameterized via a fully automated approach and one followed the semi-automated parameterization. The following metrics are discussed on a per disaccharide basis; distributions of bond lengths, angles, dihedral angles and solvent-accessible surface area (SASA).