A fully automated reaction profile computation workflow based on autodE and Gaus-sian16 was set up to acquire new reaction data points. As the level of theory for the DFT calculations, CAM-B3LYP in combination with the 6-311++G** basis set in the gas phase was used for the final optimization of all stationary points. The maximum number of conformers generated for single molecules and transition states was set to 1000, using an RMSD cut-off of 0.1 Å to exclude identical conformers. Conformers were ranked based on a loose optimization at CAM-B3LYP/6-31G*, and the lowest energy one was selected for refinement with the larger basis set. The D3 dispersion correction with Becke-Johnson damping was used in all cases. An IRC confirmation at the same level of theory was consistently performed on the final TS. The final functional and basis set were selected with the aim of approaching the level of theory of Prasad et al. as closely as possible.