The successful fabrication of this compositional series highlights the benefits of combining existing materials, inorganic and hybrid, to create novel glasses with markedly different mechanical and thermal properties. By doing so, the respective advantages of structurally and chemically diverse glass types can be combined, which opens the door to a realm of potential new applications. Furthermore, exploration of these materials also contributes to understanding the underlying interfacial interactions in a more general way for select applications, e.g., in adherent laminate structures or for hybrid solder applications.