In order to test the performance of the proposed RLCI method, we have computed potential energy curves for the symmetric dissociation of N 2 , CO, and an H 8 chain. These systems span a range of strong to weak correlation and allow us to evaluate the prototypical performance of RLCI methods for use in quantum chemistry. Note that we assume a point group of C 1 for all systems investigated here, and all data is obtained with an RHF reference wave function using canonical RHF orbitals, and the underlying integrals and Hamiltonians were obtained using an interface to the PySCF software package. Although currently the code is far from optimized, we aim to show that RLCI is a promising route forward for generating highly compact wave functions at chemical accuracy. In this work, we choose α = 0.5 and γ = 0.99 for all cases. Learning rates are not damped to avoid early convergence to local minima, and the somewhat larger value of the learning rate α is suitable considering the deterministic CI environment. The exploration rate decays as a function of episode, with τ = exp (-0.5 • episode). Additionally, all RL runs are terminated within 30 episodes.