Within this work, we first explain the methods used discussing the general strategy employed for analysing excited-state wavefunctions and proceeding to specifics of the computational details. The results are presented in some detail starting with general structural parameters and frontier orbitals, proceeding to a discussion of the vertical excitations in terms of the state characters present and the computational description, finishing with an exploration of excited-state minima in solution. Before concluding, we proceed by a compact discussion summarising the photophysics, highlighting general differences between singlet and triplet state wavefunctions, and reviewing the most critical methodological aspects.