In our continuous effort in finding the shorter and economic synthetic methods via palladium catalysis, we have achieved a synthesis of phenanthridines and its analogs in this chapter. Our aim was to find out one step method for the synthesis of phenanthridine. We envisioned that Suzuki coupling between 3.36 and 3.37 would be very effective for the construction of phenanathridine 3.38 in one-pot (Scheme 3.11).