During both of the plateaus on the electrochemical curve preceding the phase transitions, the mosaicity maps show a rather low heterogeneity of the lattice tilt between different regions of the particle (see Figures , Supplementary Videos 1 (scans 1-18) and 2 scans 20-33)) signifying low defect concentration inside the crystal. The maximum altitude deviation between two pixels of the real-space maps does not exceed 0.1 • . Similar degrees of deviation were observed for pristine LMNO particles measured ex situ , while particles with higher values of tilt misorientation were found in LCO cathode materials using Laue microdiffraction .