Due to society's ever-increasing energy demand and resultant environmental degradation from energy consumption, developing sustainable synthetic techniques to replace the fossil-fueldriven industry is rapidly gaining interest. Among such routes is electrocatalysis, which often entails lower CO2 emissions relative to established thermochemical routes to produce the same chemical species. As a key method within chemistry's toolbox, electrochemistry offers routes to precise reaction control by adjusting applied potentials and is thus gaining popularity as a means of precisely controlling reaction pathways towards a desired product. This is particularly important for reactions involving the transformation of CO2 into valuable products as multiple competing reactions could occur under typical reaction conditions. To date, electrosynthetic systems for water electrolysis are technologically mature and systems entailing CO2 reduction (CO2R) are rapidly growing as well. However, the electrosynthetic fabrication of other classes of societally valuable chemicals are still underdeveloped. As one of the most important classes of fertilizers and high-demand chemicals, products containing C-N bonds such as urea, amides, and amines play a pivotal role in society. At the industrial level, the construction of C-N bonds from simple reactants is carried out under harsh thermochemical conditions and finding analogous electrosynthetic routes under mild conditions for these reactions is a challenge for the scientific community. The electrochemical formation of C-N bonds is appealing as it can direct begin with small molecules like CO2 and nitrite, nitrate, ammonia, and even N2 to directly produce value-added C-N bond products. In this context, the C-N bond coupling reaction is primarily carried out through the reduction of CO2 to form an activated electrophilic intermediate and subsequent attack by nucleophilic Ncontaining species. Consequently, the selectivity for C-N bond products reactions rely heavily on the interplay of chemical C-N coupling steps and electrochemical CO2 reduction pathways.