With respect to the SOMOphile scope, we found that different olefins could successfully take part in the transformation (3, 38-44). The product of our benchmark reaction (3) was obtained in 73% yield. Notably, when using phenyl vinyl sulfone (2e), we were able to trap stabilized benzyl radicals, while the reaction with dimethyl maleate (2d) did not afford the expected product. Also, norbornenone, Nphenyl acrylamide, methyl acrylate and diethyl vinyl phophonate could be engaged as SOMOphiles in the reaction protocol showing its tolerance towards a wide variety of functional groups, such as ketones, amides, esters and phosphonates (41-44, 40-59% yield).