As a consequence, when the superlattice enters the conductive regime, the CIT ions at the NP-NP interface act as the "bonding" EAs, keeping the lattice together, while the CIT ions in the cavities behave as conduction EAs, diffusing throughout the lattice. To some extent, this distinction is reminiscent of symmetry breakage and anisotropic distribution of valence electrons and coordination sites around metal atoms in conductive metals. This non-uniformity in the dynamics of charge carriers is reminiscent of the symmetry breakage in the electron behavior in metals, in which some electrons are involved in the stabilization of the material's structure (atomic bonding), while others (free-electrons) allow conductivity in the material. In these colloidal systems, the separation between bound and free CIT charge carriers is less defined than in metals, but nonetheless explicitly evident from our data. Our results demonstrate how, in such NP superlattices, these are collective phenomena, which cannot be explained based, e.g., on the properties of the CIT ions in the individual SOAP environments in the unperturbed systems. On the other hand, this is an emergent behavior, originating from the concerted motions of the ions in response to the stimulus (E). This approach provides a demonstration of the importance of studying such complex molecular systems at sufficiently high resolution to track the individual motion of the ions, while at the same time treating sufficiently large scales to observe collective behaviors. Figure shows the results of the SOAP+PAMM analysis for the same systems at T = 333 K. We note an overall similar behavior to that observed at T = 300 K, with slight differences coherent with the conductivity results of Figure related to increased thermal agitation.