The small BT-MCAF and BT-DCAF molecules of this study were synthesized via Suzuki-Miyaura coupling protocol in aqueous micellar media (Schemes S1 and S2). Benzothiadiazole (BT) derivatives represent an important class of redox-active molecules. The chemical design of the two compounds in this study allows to assess the relationship between structure and electrochemical properties of benzothiadiazole derivatives.