The Hirshfeld charge analysis (Table ), in contrast, presents a more uniform distribution of charges for platinum and the surrounding carbon atoms under the same pressures. The electrophilic character of platinum remains relatively stable with values of 0.247 across all pressures, indicating a consistent ability to attract electrons. Similarly, the charges on the adjacent carbons (C2, C6, and C8) show nearly identical values of 0.124 or 0.125, irrespective of the external pressure applied. This stability in charge distribution suggests that the method captures a more averaged (Figure ) or global view of the electronic environment, in contrast to the localized fluctuations observed in Mulliken analysis (Figure ). Such consistency could imply that the overall reactivity of the system remains robust under varying conditions, providing insights into the intrinsic electronic properties of the platinum-doped graphene structure.