To further test the capabilities of the developed methodology, a broad range of terpenes was targeted. The diterpene, ambliol A, first isolated from the marine sponge Dysidea amblia by Faulkner in 1981 off of the Pacific coast (La Jolla) was chosen as an attractive target to synthesize for its antibiotic activity and unique functionality. Only recently (2015) was an enantioselective synthesis of (+)-ambliol A accomplished by Serra et al. utilizing an enzymatic resolution in 16 steps LLS. That synthesis led to a revision of the original enantiomeric assignment. In contrast, a convergent synthesis of (-)-ambliol A utilizing the developed electrochemical conditions was achieved in just five steps LLS by coupling the enantiopure epoxy-acid 21 (confirmed via X-ray, See SI, Figure ) with furan 22 in 47% yield followed by reductive epoxide opening (LiEt3BH) thus unambiguously confirming its stereochemical revision and enabling the first synthetic access to the natural enantiomer.