These results highlight the need for a more thorough explorations of conformational space and demonstrate the effectiveness of the VRAI-selectivity algorithm in predicting outcomes of dynamically controlled processes. Our study provides an important step towards a deeper understanding of the complex interplay between reaction dynamics and selectivity in organic synthesis. Moving forward, we encourage the computational organic chemistry community to consider the procedure presented in this paper, which will provide a more comprehensive and accurate understanding of chemical reactivity to drive the development of better catalyst and synthesis strategies.