These metrics synergically contribute to improved cycling performance for a relatively high areal sulfur loading of 4 mg/cm 2 , exemplified by a specific capacity of 678.8 mAh/gsulfur at a C-rate of C/5 with only 0.12% capacity decay per cycle and a columbic efficiency of 97.4% over extended cycles, demonstrating favorable outcomes compared to existing literature. The proposed design holds promise for broader electrolyte modifications aimed at enhancing electrochemical activity in Li-S batteries.