In the case of bulk systems, the activation energies are not dependent on the ionic species for the vehicle mechanism. This is usually explained by the competition between viscosity and migration effects in ion conduction. Under the conditions of vi-brational strong coupling, the hydrogen bonding network can be modified even in the absence of light. The coherent interaction of the hydrogen bonding environment in the water cavity can lead to the modification of the dynamic hydration network. energies of σcav (red) and σbulk (black). The hydration enthalpy values or hydration entropy values were adopted from the literature.