The Schlenk flask was then heated with stirring in an oil bath at 60 °C overnight (for AntMAc, AntMA), 115 °C for 2h (for PyMA), or 80 °C overnight (for the rest monomers). In the case of 1VNaph, the liquid monomer was combined with styrene before being deoxygenated with argon. The feed molar fraction of PAM varied from 0.10% to 15.0%. For most monomers except AntMAc and AntMA, the monomer/initiator ratio was 80. For AntMAc and AntMA, the monomer/initiator ratio was 160, and 1.0 eq. each of CuBr and 1,1,4,7,7pentamethyldiethylenetriamine (PMDETA) were used.