Heat maps of catalytic turnover frequency to B (TOF B ) were created in Matlab 2019a by interpolating over discrete data sets obtained at varying oscillation amplitudes, oscillation frequencies, and oscillation endpoints. The modified Akima cubic Hermite or spline interpolation method was used to fit data sets and the 'smoothdata' function was employed with the moving average or Savitzky-Golay filter method to average out overshoots due to interpolation. Complete tabulated data sets of all heat maps are provided in the supporting information. state, TS, in between. The overall heat of reaction, ΔH ovr , remains fixed for all conditions of catalyst surface dynamics. Two more variables are required to define the transition state (TS) energy, E a , which will vary with the surface intermediate energies. As stated in Equation , the existing BEP relationships with slope, α, and intercept, β, fully define all possible transition state energies for catalytic systems exhibiting this linear relationship. Two new variables are required to define the variation of surface intermediate energies. Due to the differences in electronic and steric interactions with the surface, variation of surface adsorbate binding energies with external stimuli will not affect all surface adsorbates equally. As depicted in Figure , the binding energy of A* changes less than B* between each of the three potential states resulting from external stimulus. To describe this change differential, the extent of change is defined to be gamma equal to the difference in binding energy of B* divided by the difference in binding energy of A*,