As expected, the polarization angles that maxi-mize the TS barrier energy contain intermolecular electron density depletion, destabilizing the forming bond, as well as electron accumulation in the intramolecular bonding π-orbitals of each reactant molecule. The opposite is again true for the angles that minimize the TS barrier energy, showing electron density accumulation in the intermolecular bonding region. Notably, the intramolecular π-bonding orbitals showcase asymetric accumulation/depletion, similar to the Z-polarization in Fig. . We hypothesize that these critical angles of the field induce a complicated redistribution of electron density, not only from the reactant species to the forming intermolecular bond, but also among themselves in a way that further decreases the energy of the TS geometry. Hence, examining only the principle directions X, Y, and Z as defined by chemical intuition will mostly likely not showcase the maximal effects of the complicated electron-photon correlation (as the black square symbols shown in Fig. ) since the direction of the many coupled permenant and transition dipole matrix elements in the adiabatic electronic basis not straightforward and likely does not relate to a simple and meaningful chemical property.