Earlier our group contributed in this direction by developing a novel imidazolidine-derived chiral acid for the first enantioselective cobalt(III)-catalyzed C-H activation. Now, with our continuous interest in enantioselective cobaltaelectro-catalyzed C-H activations, we intended to corroborate κ 2 -N,O-oxazoline-enolates and κ 2 -N,O-oxazolineamidates as viable ligand classes in this platform. Notably, these ligand classes structurally mimic the -ketoenolate and -ketoiminate ligands and selected transition metal complexes have been synthesized with κ 2 -N,O-oxazolineenolates as ligands (Figure ). It is noteworthy Shi and Niu showcased the applicability of salicyloxazoline (Salox) ligands for oxidative enantioselective cobalt(III)-catalyzed C-H activations. Numerous cobaltaelectro-catalyzed C-H activations with cobalt acetylacetonato (acac) complexes reported by our and other groups and mechanistic understanding with electrochemically synthesized isolated cobaltacycle intermediates encouraged us to assess the applicability of chiral κ 2 -N,O-oxazoline enolates, and amides in enantioselective C-H activations. These ligands are accessible with modifiable steric and electronic features from simple precursors. To our delight, despite considerable prospects in asymmetric synthesis, these classes of oxazolines are still in a rudimentary stage of evolution and the reactivity and modularity of these ligand classes have never been systematically studied. In an early study, Andersson attempted a copper-mediated enantioselective aziridination of styrene utilizing κ 2 -N,O-oxazoline-enolates, albeit with moderate enantioselectivity. Nevertheless, the application of these ligand classes is still elusive in asymmetric transition metal catalysis, especially for enantioselective organometallic C-H activation reactions. Hence, we have capitalized on this synthetic space evaluating the feasibility of these ligands for cobaltaelectro-catalyzed C-H activations along with understanding the key features of the ligand classes through dataguided analysis (Figure ).