For the production of customized polymers and copolymers for biomaterials and medicinal applications, controlled radical polymerization of monomers containing amino acids shows promise. Since many different polymers containing amino acid moieties in their main chains or side chains, like poly(glutamic acid) and polyleucine, have been prepared and demonstrated biocompatibility and biodegradability similar to polypeptides, it is anticipated that the amino acidbased polymers will not be toxic In 2016 using the CuBr/bpy catalyst system and HMB or sodium 4-(bromomethyl)benzoate (SBB) using as an initiator in pH =8 ATRP prepared the welldefined poly(AAla). Here the work has shown that the varying molecular weight Polyalanine acrylamide (PAAla) were prepared by very straightforward method. In this work the polymerization condition was EbIB as an initiator and PMDETA/Zn ligand and catalyst system in presence of DMSO. alanine acrylamide (AAla) a monomer derived from alanine, was synthesized by a straightforward reaction and it was characterized using IR and NMR spectroscopy (see Supporting Information, Figures and). The stack plot of alanine and AAla was shown that clear synthesis of amino acid monomer.