Native Systems: The time series of the VIEs and VEAs values used for the determination of the corresponding ∆E distributions and redox properties are available in the supplementary information (SI) (Figure ). For both cases (regions 1 and 2), the vertical energy gap distributions are Gaussian. They are available in Figure of the SI. For the first G-rich region (region 1), the average VIE and VEA respectively amount to 7.82 ± 0.24 eV and 5.81 ± 0.24 eV. Then, using Equations ( ) and ( ), ∆A R→O = 6.81 ± 0.17 eV and λ = 1.01 ± 0.17 eV. For region 2, the average VIE and VEA are equal to to 8.13 ± 0.