In a continuation of our research in the design of multidentate heteroaromatic ligands , benzyloxyimino-acetic acid , 1,3-Dithialane-methanol and sulfur ethers are successfully formed topological structure with soft transition metals ion. Encouraged by these results, we synthesize and characterize of new aromatic derivatives containing the 1,3-dithiolane and benzyloximate moiety. Such compounds contain multiple sulfur atoms and oximate nitrogen atoms in differing positions and thus have the potential to form new complex structures or networks from interactions with soft transition metal ions.