Based on the QTST formalism, Ref. 377 found that when the cavity photon frequency ω c matches the reactant well frequency ω 0 (i.e., a resonant condition), the ZPE correction κ ZPE is minimized. This is in contrast to the high temperature (classical limit) where the GH theory predicts the transmission coefficient is independent of ω 0 , but depends on ω ‡ . Ref. 377 further shows that it is possible to have chemical kinetics minimizing when ω c is close to ω 0 for specific sets of parameters when k QTST is dominated by κ ZPE (e.g., at low temperatures), and not dominated by κ S . But in general, the rate constant suppression will happen in a broad range of ω c , resulting in a much broader range of the photon frequency that suppresses the rate constant. This is in contrast to the sharp resonant behavior in experiments (see Fig. ). Meanwhile, this work, 377 also shows that the additional quantum tunneling correction κ T in the centroid TST (CTST) theory (where the rate is now k = κ T • k QTST ) is much larger than the ZPE correction κ ZPE . However, this tunneling correction minimizes the chemical rate when the photon frequency is close to the barrier frequency ω ‡ in contrast to ω 0 , a behavior similar to the GH theory. 377 As a result, the overall rate constant also minimizes when ω c is close to ω ‡ . Overall, such quantum corrections, which are included through approximate rate theories, do not bring theoretical predictions closer, and potentially further, from experiments.