With the optimized reaction conditions in hand, we next examined the generality of this transformation with different aromatic hydrocarbons. As shown in Figure , organic chemical raw materials such as benzene, toluene, and p-xylene can react smoothly to obtain the desired products (3a-3c). Arenes with methyl, ether, ester, isocyanate, carbonyl, halides, cyano and boronate groups afforded the desired products (3d-3o) in moderate to good yields (28%-84%). In addition, natural products derivatized arene involving boldenone can also be tolerated and obtained the corresponding phenylsulfamoyl fluoride in good yields (3p).