Recent discoveries and upsurge of research in the photo-and electrochemistry domain offer an alternative to classical metal-mediated reaction conditions to construct pyridine rings. Wang, Meng, and co-workers reported a photocatalytic [2+2+2] cyclization of aromatic alkynes with nitriles for the synthesis of 2,3,6trisubstituted pyridines using a pyrylium salt as the photoredox catalyst (Figure ) 25 that was able to overcome the high oxidation potentials of alkynes being the major challenge in this type of transformation. Electrochemistry has the advantage of employing electrons as traceless redox reagents for activating common and inert organic molecules, particularly alkynes, 26 for generating highly reactive intermediates. Recently, electrochemical transformations have undergone a renaissance, and in the context of this study, [2+2+2] electrochemical homo cyclotrimerizations of alkynes to arenes have been explored recently (Figure ). We demonstrate here an intermolecular cyclization strategy of alkynes and nitriles providing 2,3,6-tri-substituted pyridines via constant-current electrolysis using the combination of a catalytic amount of triphenylamine (TPA) and benzoic acid as a redox shuttle which obliviates the use of metals and other external additives (Figure ). The cross-cyclization of two different alkynes is especially possible, being to the best of our knowledge, unprecedented. Moreover, a competitive alkyne [2+2+2] cyclotrimerization is not observed.