or GMS taking longer to converge, due to slower transitions of the OFM tailgroup between solvent layers. Subsequently, the hard-disk surface area has been estimated using annealing simulations of pre-formed monolayer films at different surface coverages. The results show that the hard-disk area increases in the order: SA < GMS ∼ GMO. The adsorption energy and hard-disk area are used to calculate the adsorption isotherm using the MTT model.