Metal-mediated ammonia synthesis has garnered significant global attention as the only method capable of activating N₂ at ambient conditions and converting it into ammonia . Among the various metal-mediated approaches, lithium-mediated nitrogen reduction reaction (Li-NRR) has been extensively studied and thoroughly explored . Remarkable progress has been made, with Faradaic Efficiencies (FEs) for NH₃ production reaching nearly 100%, achieved through the use of imide-based lithium salts. Additionally, current densities as high as ~-700 mA/cm² have been reported. Fu et al. advanced this method further by developing a continuous flow process, achieving a 61% NH₃ FE via hydrogen oxidation on a Pt-Au alloy anode.