To increase the accuracy of the quantitative phase analysis (QPA), all CA-binders were subjected to an additional grinding step. 4 g of samples was subjected to wet grinding for 15 min in a McCrone micronizing mill, utilizing 6 mL isopropanol as grinding medium. Following this, solid and liquid components were separated through centrifugation (8500 rpm for 10 min), the isopropanol was decanted, and subsequently, the binders underwent drying in a nitrogen flow. For XRD measurement, the samples were prepared using the backloading method. Scans were acquired between 7 -70°2θ with a step size of 0.016°2θ using a V ÅNTEC-1 detector. Recorded diffractograms were evaluated with Topas Academic software (Version 7) to determine the phase contents. The crystal structures used for the Rietveld refinement are given in Table . Maslen The Blaine surface area was determined according to DIN EN 196-6. All binders were measured three times, and the arithmetic average was calculated. The different powders were characterized by particle size distribution (PSD) using a laser granulomere Cilas1064 (Cilas Company, Marseille, France). The dispersion was treated with ultrasound to disperse agglomerates before the experiment.