In summary, we investigated catalytic activity trends of AOR on 26 d-block transition metals using DFT calculations and microkinetic modeling. By including the electrochemical bond formation steps in the microkinetic modeling, we enabled the quantitative comparison of various mechanisms and catalysts. Combined with the scaling relations, BEP relations and the microkinetic modeling, we constructed the kinetic volcano plot to predict TOF of catalysts using binding energies of two adsorbates as descriptors. The volcano plot suggested the catalyst design strategy to combine two elements with the opposite N-affinities, and we found a few candidates after performing the computational screening based on this strategy. Our study would provide the fundamental understanding of AOR and the basis of developing new active catalysts.