Based on the actual background and requirement, in recent years, some representative heterogeneous catalyst such as g-CN, 9 TiO2, 10 CdS 11 involved in photoredox process has been gradually developed. König' groups 9a reported ligand-free mpg-CN/Ni dual photoredox catalytic protocols for C-N bond formation, and explored mpg-CN/Ni-dual catalysis for C(sp 2 )-C(sp 3 ) cross-coupling reactions yielding diarylmethanes analogously. Pieber and Seeberger reported mpg-CN in combination with nickel catalysis can induce selective C-O cross-couplings of carboxylic acids with aryl halides. 9c Meanwhile, they also reported g-CN/Ni with light-mediated cross-couplings of aryl bromides with alcohols via C-O bond formation. Inspired by previous investigation, 12 we hence developed mpg-CN/Ni dual catalysis sulfone compounds synthesized which are widely found in several drug-active molecules such as Dapsone, Vismodegib and Intepirdine (Scheme 1a) via C(sp 2 )-SO2Ar bond formation. Compared with the traditional method (Scheme 1b), this kind of heterogeneous photocatalyst involved in photoredox has the potential for industrial and large-scale development due to its advantages including mild conditions, visible light-driven, base-free, high-yield outcomes and reutilization.