With increasing temperature, the RDFs exhibit a slightly less ordered structure than at low temperatures. For both interactions, the population of the first solvation sphere decreases due to the higher mobility and, thus, higher fluctuations of the particles. However, the temperature effect is minimal. Figure illustrates the center-of-mass RDFs for x [Li][NTf 2 ] = 1/3 and 0.5 at different temperatures. From this, it may be concluded that the structural pattern of the lithium environment does not primarily depend on the temperature for the equimolar mixture. However, at lower salt concentrations, an increase in temperature leads to a significantly higher population of the first solvation sphere, while the opposite effect is visible for the coordination sphere of G3. Consequently, at higher temperatures, for mixtures with a smaller salt ratio, G3 molecules in the coordination sphere are to some extent exchanged for [NTf 2 ] -anions. The site-site RDFs between [Li] + and coordinating anions reveal the detailed structure of the complexes. Figure shows RDFs between [Li] + and oxygen atoms of G3 and anions at 303 K. As the lithium salt ratio increases, the number of G3 oxygen atoms in the first solvation sphere decreases significantly. Coordinating G3 oxygens are located at 2.0 Å from [Li] + (Figure ). At 303 K, anions rarely coordinate [Li] + in mixtures with low [Li][NTf 2 ] content (Figure ). The first peak in the anion oxygen RDFs diminishes at low salt fractions but increases at higher [Li][NTf 2 ] content, with a peak at 2.1 Å. This suggests similar interaction strengths for both G3 and anion oxygens, as their coordination distances to [Li] + are comparable (∼2 Å). Temperature-dependent RDFs for two mixing ratios are provided in the SI, showing minimal temperature dependence in the relevant region.