The utility of the formed products was then investigated (Scheme 3). The allylic C-Cl bond in 2a provided valuable handle for follow-up functional group manipulations. For examples, subjecting 2a to palladium-catalyzed Tsuji-Trost reactions using malonate and sulfinate as nucleophiles delivered the corresponding allylic alkylation (4) and sulfonylation (6) products, respectively, in good yields. A copper-catalyzed displacement of chloride furnished an allyl fluoride 7 without difficulty. In addition, the iodofluorination of the double bond in 2a following our previous protocol produced the α-iodo-β-fluoro-γ-chloroalkyl MIDA boronate 8 (confirmed by X-ray single crystal diffraction analysis) with good regio-and stereoselectivity. And the epoxidation reaction gave efficiently a highly functionalized amphoteric epoxide 9. SCHEME 3. Synthetic derivatizations of 2a.