Hydroamidations have attracted very attentions for it's an atomic-economy way to construct enamides . Further, the substrates of this reaction are easily-accessible. Hydroamidations are not spontaneous mainly due to the relatively high barrier of nucleophilic process . Lewis-acid or transition metals are often used to catalyze this reaction. Significant progresses have been made in catalyzed hydroamidation and high levels of chemo-, regio-, and stereo-selectivity have been reported . However, current reported successful examples are mainly center on intramolecular hydroamidation or hydroamidation involving terminal alkynes , and relatively high temperature is required in the most case.