Based on the new PES-2024 surface, QCT dynamics calculations were performed at room temperature for a direct comparison with the Butkovskaya and Setser's experiments, with attention being focused on the well-studied H2O(v1,v2,v3) product vibrational populations. It was found that the largest fraction of available energy was deposited as water vibrational energy, ∼49%. In addition, the water product vibrational population was inverted in the stretching and non-inverted in the bending modes, reproducing the experimental evidence, which represents a third test of quality of the PES-2024 and of the theoretical tools used, the QCT and NMA methods. However, compared with experiments, a lower bending vibrational excitation was found and this discrepancy was explained by the artificial transfer of energy between modes due to the classical nature of the QCT method.