These studies are shown by red crosses in Fig. strategy is broadly successful at leading to fast kRISC but does not necessarily lead to the highest J90. This is because kISC also increases, or 𝑘 ! " decreases. This is captured by the FOM as can be seen from the red crosses in Fig. being in the same region as other materials. At the same time, incorporation of these larger atoms that result in weaker bonds also leads to faster non-radiative pathways.