leading to 𝐺 𝑝ℎ /𝜙 0 ≈ 252 kPa for a quick quantitative test of the rheology data. A power law fit of the rheology data is in accord with 𝐺 𝑝ℎ ≈ 𝜙 0 1.22±0.5 × 64 kPa, with an extrapolated amplitude at 𝜙 0 = 1 almost a factor of 4 below the expectations. The exponent for 𝜙 0 is somewhat larger than unity similar to related work , indicating corrections due to entanglements for the largest 𝜙 0 and a growing impact of a decreasing conversion and formation of finite loops towards small 𝜙 0 . Rheology during gelation indicates qualitatively that kinetics might be somewhat slower in toluene than in THF (a quantitative discussion of these results is omitted here due to the solvent evaporation observed in these measurements). Nevertheless, we expect a conversion of at least 0.8 for our samples when reacted overnight, which suffices to explain a drop in modulus only up to 40 %. Moreover, for our particular network architecture, the small loop corrections above the overlap threshold are too small to close the gap to the measurements. In a closely related work, amphiphilic co-networks were synthesized using the same molecular architecture, similar molar masses of the star polymers, and a similar range of 𝜙 0 with a quicker kinetics than in our study.