The treatment of a mixture of pyrazole 2 and AgNO3 in methanol with triethylamine afforded {[2']Ag}3 (2' = deprotonated 2) as a white solid in 90% yield. Complex {[64b']Ag}3 (64b' = deprotonated 64b) was obtained from pyrazole 64b analogously in methanol-acetonitrile mixture in 85% yield. These compounds were insoluble in dichloromethane, chloroform, toluene, benzene, and acetone, but somewhat soluble in tetrahydrofuran and dimethyl sulfoxide. Unfortunately, they did not provide crystalline material suitable for single crystal X-ray structure determination. Based on the literature analogy, as well as mass spectroscopic data of {[2']Ag}3 and {[64b']Ag}3, we believe that they exist in the typical trinuclear form. In order to further confirm the identity of {[2']Ag}3 and {[64b']Ag}3, we prepared their phosphine complexes by treating their suspension with PPh3 in dichloromethane. These reactions produced {[2']Ag(PPh3)}2 and {[64b']Ag(PPh3)}2, respectively, in essentially quantitative yield. They are air stable, white solids. Both complexes were soluble in common organic solvents allowing convenient characterization by multi-nuclear NMR spectroscopy, and recrystallizations to generate X-ray quality crystals.