In conclusion, we have developed an enantioselective ironcatalyzed multicomponent radical cross-coupling reaction that enables to 1,2-dicarbofunctionalization of vinyl boronates with diverse (fluoro)alkyl halides and aryl Grignard reagents. Mechanisitic studies are consistent with radical translocation to form a α-boryl radial that is rapidly intercepted by a chiral monoaryl bisphosphine-iron leading to enantioselective carbon-carbon bond formation. Further studies are underway to expand the scope of asymmetric multicomponent radical cross-coupling reactions with well-defined and readily available iron catalysts.