where the summation is over all ionic species. This relation establishes that the osmotic pressure, which is constant throughout the system, can be computed via the kinetic momentum which is transferred to the hard wall by ion collisions. Accurate calculations of these contact values are not easy, since they usually require access to ionic correlations. Size effects, for example, are known to push particle towards the outer walls, increasing the contact values, whereas electrostatic solvation effects leads to ionic depletion. In the case of small ions at concentrations less than 1 M, the latter effect is the dominant one. In view of the observed accuracy of the propose model to reproduce such depletion effects, it can be used as a promising route to efficiently and accurately compute osmotic pressures as a function of pH and electrolyte concentration inside a suspension. For such high volume fractions, the trivalent anions are strongly repelled from the nanoparticle surface and are pushed towards the cell boundary, attracting a large number of monovalent cations into this region as well. This results in a large contact density at the outer SHC surface, leading to a sharp rise in osmotic pressure.