(3.8.9) Barone : What is the meaning of the "real world"? All computations are performed on model systems, so that comparison with experiment requires the definition of both the mathematical (here the DFA) and the physical (the system investigated). Since DFT allows us to increase the dimensions of the physical model more than is possible with wave-function methods, we come closer to the "real system". As a result, the discrepancies with experimental results are more probably related to deficiencies of the mathematical model. Of course, here multilayer (QM/QM') models play a significant role, at least for nonperiodic systems.