D ′ (D ′′′ ). The two remaining modes at 400.4 cm -1 under peak D are out-of-plane movements of CN groups which are anti-symmetric with respect to the Fe atom and result in a rigid movement of the Fe(N)4 planar complex. They undergo a small blue-shift to 401.1 and 401.8 cm -1 for CO and 401.1 and 401.4 cm -1 for CO2, respectively. Finally, the vibrational mode at 400.9 cm -1 consists of distortions of the two octahedra resulting primarily from the movement of the Fe atoms which are almost unchanged after adsorption (400.1 cm -1 for CO and 399.9 cm -1 for CO2).