The hydrolytic separation of complexes 22, 23, and 24 yields three primary organic products, identified by MALDI-TOF as MS 128.1728, MS 140, and MS 152, respectively (Figure ). These products correspond to distinct stages of the chain-growth process. Furthermore, these intermediates demonstrate versatility through subsequent transformations, such as acid-catalyzed double-bond hydration, producing a hydrated derivative (MS 176.93), or partial hydrogenation, yielding MS 156. These pathways highlight the catalytic system's capability to generate a diverse array of organic molecules through targeted modifications of the initial products. The MALDI-TOF MS data points 199, 216, and 231.939 correspond to three sequentially hydrated C 9 unsaturated organic compounds, as illustrated in Figure . These structures are identified as hydrated derivatives of a parent C 9 unsaturated α-carboxylic acid-ω-aldehyde compound. However, the exact formation mechanism of this parent compound remains unclear and could not be conclusively determined. This ambiguity underscores a critical gap in understanding the cascade reaction process, necessitating further investigation into the pathways responsible for the generation of these hydrated organic derivatives.. The organic products corresponding to MS 216 and MS 231.939, both C 9 hydrated unsaturated derivatives, are involved in coupling reactions with a PI radical. In these reactions, the PI radical facilitates the extension or functionalization of the C 9 framework.