The sesquiterpenes (E)-α-and β-bisabolenes (23 and 24), which function in nature as pheromone molecules for a number of insects, were an opportunity to test the electrochemical cross-coupling on secondary acids. Targeting the central sp 2 -sp 3 junction for disconnection, syntheses of 23 and 24 diverged from secondary acid 25 and enlisted vinyl iodide 26 or 27 to furnish 23 and 24 in 72% and 64% yield, respectively. The more stabilized secondary radical generated from the acid behaved admirably under the standard reaction conditions providing access to both natural products in three steps LLS.