While light-driven, dual catalytic reaction systems involving a photocatalyst (PC) and a Ni catalyst have emerged as highly promising methods to form C(sp 2 )-heteroatom bonds under mild conditions with readily available coupling partners, the vast majority of these methods only demonstrate coupling of a single type of nucleophile. In contrast, one of our groups has recently reported a method in which coupling of aryl halides to O, N, or S nucleophiles occurs efficiently without changing the reaction conditions (Fig. ). In addition, with a small change in reaction conditions, SCF3 nucleophiles became effective, with 60 examples demonstrated. This universality of a single method is highly desirable for synthetic organic chemistry, especially in medicinal chemistry where these reactions are used at a high frequency. In the former system, we proposed a mechanistic hypothesis involving an energy transfer quenching event, supported by literature precedent and a stoichiometric nickel study demonstrating that no added sacrificial oxidant/reductant is needed to promote reactivitysomething necessary for photocatalytic cycle turnover in many reductive/oxidative quenching mechanisms.