Both electron-withdrawing and -donating substituents substituted phenols underwent the SuFEx to give the corresponding products in high yields (3b-3g). In addition, different positions of the substituents on the aromatic rings of phenols had no apparent effects on the reaction yield (3h-3l). Pinacol boronic ester substituted phenol 2m participated in the reaction to afford 3m in 83% yield. The Bpin group provides good opportunities for further derivation through classical coupling reactions.