The impact of amphiphile on the surface morphology is further accessed by the distribution of the area of coarse-grained water droplets in the absence and presence of the amphiphile (Figure ). The addition of amphiphiles increases the surface area of the water droplet (as shown by the broader distribution of the surface area and shift in the distribution maxima to a higher value), is primarily due to the formation of protruding water structures. This occurs because amphiphiles, disrupt the smooth spherical shape of the droplet. The hydrophilic heads interact with water molecules, while the hydrophobic tails avoid water, leading to the formation of micelle-like structures or partial solubilization at the water-oil interface. This behavior reduces surface tension and allows the development of complex surface structures, such as water fingers or buds. The protruding water structures indicate a significant alteration in the droplet's interfacial properties, highlighting the complex interplay between amphiphiles and water molecules.