Introduction Synthetic Organic Electrochemistry (SOE) and visible light PhotoRedox Catalysis (PRC), which offer entries to single electron transfer (SET) chemistry and radical intermediates under mild conditions, have risen to the fore of contemporary organic synthesis. A key factor underpinning the success of PRC is the host of available photocatalyst structures with well-characterized photophysical and redox data, allowing chemists to match a given excited state to a desired process. Although PRC exhibits a selectivity benefit in transferring the energy of visible light photons to a colored transition metal-based or organic dye photocatalyst, its scope of applications are redox potential-limited by the energy of single photons (ca. 1.8-3.1 eV).