The OH stretching vibrational spectra of bulky hydroxylamine complexes presented in this work are remarkably narrow under supersonic jet expansion conditions, in contrast to those of related oxime complexes. This allows for the spectral resolution of subtle conformational isomerism and it provides upper bounds for the speed of degenerate hydrogen atom transfer from a hydroxylamine to its associated nitroxyl or aminoxyl radical. We believe that these are the largest neutral radical complexes which have been vibrationally characterised in the gas phase, so far and they are clearly London dispersion stabilised.