With the optimized conditions in hand, we next turned our attention towards the substrate scope of this cascade protocol. As a part of this investigation, a wide range of aromatic amines and acid chlorides were surveyed in order to provide a detailed picture of the functional group tolerance and limitations of this electrochemical strategy. Looking at the results outlined herein, it can be concluded that the present method is highly general and can be applied to a broad spectrum of substrates of varying structural complexity to furnish various N-aryl amide and carbamate derivatives in good to excellent yields. As depicted in Scheme 1, chlorination occurs predominantly at the para-position (3) of the aromatic amine moiety if no other substituent is already present there. Only for a limited amount of cases, we could observe the formation of side products resulting from either ortho-chlorination or dichlorination; however, this fortunately only occurred to a minor extent (<5%-15%, unless otherwise noted).