Our main incentive for the TD-DFT benchmark is to assess the performance of modern TD-DFT methods, with and without applied dispersion corrections, based on their resulting dissociation energy curves. For this purpose, we choose SCS-CC2/CBS (3,4) as the reference level for the subsequent study. We would like to point out that the curves discussed herein are an improvement on what has been acceptable in the field as binding energies with basis sets of QZ quality or higher being rare for aromatic exciplexes. Nevertheless, we recommend a future study dedicated solely to (single-reference) WFT methods that addresses CBS extrapolations and BSSE corrections more in detail. As such studies are beyond the scope of this work, we continue with the discussion of the TD-DFT results.