Polar crystals have found widespread applications across various fields, including electronics, optics, and pharmaceuticals. This broad utility stems from their unique directional properties, where molecular arrangements create a net dipole moment along a defined axis, leading to valuable characteristics such as piezoelectricity and nonlinear optical behaviour. Quartz exemplifies these properties, demonstrating how polar symmetry enables precise electromechanical coupling and optical phenomena essential for technological applications. Building upon these fundamental principles, polar organic cocrystals represent an emerging class of materials that combine the advantages of polar symmetry with the versatility of organic chemistry. These crystalline solids comprise two or more distinct molecular or ionic components in specific stoichiometric ratios, forming ordered lattices with polar symmetry. The strategic combination of organic components offers excellent synthetic flexibility and diversity through molecular engineering, enabling precise control over crystal properties. This tunability surpasses traditional inorganic materials, opening new possibilities for tailored functional materials. However, as noted by Curtin and coauthors , the significance of polar symmetry in organic systems often remains underappreciated, particularly among synthetic chemists, resulting in relatively limited exploration compared to inorganic compounds.