Finally, it is possible to link the calculated PZC values to the experimental scale by adding them to the IUPAC recommended value of 4.44 V, 104 resulting in solvated workfunctions that can be compared to experimental data. Table Along with the RISM (SPC) model, the CANDLE model does not show significant variations in workfunction upon changes in electrolyte concentration. The workfunctions should highly depend on the orientation of water at the interface, which is heavily impacted by ionic adsorption on the surface. However, this explanation cannot be used for both RISM models since ions are not directly adsorbed on the surface (Supporting Information) but are located above the first water layers at the PZC and this behavior does not change with electrolyte concentration. For CANDLE, orientation is not accounted for, and we can conceptually understand the lack of variation. In this case, this also means that ionic concentration alone does not change the workfunction, or that the interface is already saturated at 0.1 M. For RISM models, the water density distributions (O(H 2 O) and H(H 2 O) sites in the Supporting Information) do not show significant variation with electrolyte concentration. However, the charge density plots for the TIP5P model show more important spatial differences as the concentration is changed from 0.1 M to 1.0 M compared to the SPC model (Supporting Information). However, it is clear that such comparisons are far away from what is expected in a typical experimental electrochemical setup due to the absence of ionic adsorption. As a result these discussions are primarily confined to the context of RISM theory, and should be interpreted accordingly.