We started to arylate secondary benzylic positions. Apart from para-ethyl biphenyl 1a, parasubstituted ethyl benzene derivatives were able to deliver the desired targets with a modest yield for the para-bromo derivative 4b but with more success with electron donating groups such as para-methoxy 4c or para-ethyl 4d. Symmetrical ortho-ethyl benzene also led to arylated product 4e. We further exhibited the compatibility of this benzylic electrochemical arylation to longchain alkyl-substituted para-methoxy benzenes, such as protected alcohol (4f), ester (4g), and ketone (4h). Cyclic substrates fused with the aromatic ring proved to be amenable to producing the desired arylation products such as indane 4i, and tetrahydronaphtalene derivatives 4j,k. The tertiary benzylic position of iso-propyl-biphenyl could also be arylated (4l) albeit in a moderate yield probably due to steric hindrance. Primary benzylic position of para-substituted toluene derivatives are also prone to react with the formation of para-methyl, t-butyl and methoxy biarylmethane products 4m-o. para-Ethyle toluene reacts mainly on the ethyl (4p) over the methyl (4q) which could be explained by the favoured stabilisation of the secondary radical over the primary one. It should be noted that in some cases (4c,d,j, m, n, o), a minor amount of the ortho-substituted arylation product respectively to the cyano benzene part has been formed as it has been observed previously. 14e Subsequently, 1,4-dicyanobenzene derivatives which display an additional substituent such as a cyano group (4r), and heteroaromatic substituents (benzofurane and thiophene) (4s,t), could also deliver the arylation products as a mixture of two regioisomers from para-ethyl biphenyl.