The turnover frequency response of the catalytic system to external oscillating stimuli depends on the kinetics of the surface mechanism and the resulting shape of the Balandin-Sabatier volcano curve . A catalytic system may exhibit a linear Brønsted-Evans Polanyi (BEP) relationship with slope, α, and intercept, β, relating the surface reaction thermodynamics to the surface reaction transition state. However, another consideration in volcano plot architecture is the dynamic response of individual surface species (e.g., A*, B*) to external stimulus. For variation of any descriptor (e.g. binding energy of an intermediate or single atom), surface species exhibit differing binding energies with the surface. In our previous work on surface resonance of the reversible A to B reaction , the considered catalytic system exhibited two-fold variation in the binding energy of B* relative to A* for the same extent of external stimulus. A broader understanding of this ratio (referred to here as gamma, γ) on the structure of volcano plots is required to predict the potential of imposed external dynamic stimulus across a broad range of catalytic chemistries and materials.