In summary, our analysis reveals that the classification of the chemical bond into ionic or covalent in the studied systems based on EDA results can change depending on the choice of the pathways. This issue is, in particular, more pronounced in the case of systems that have mixed ionic-covalent character. Taking the arbitrary border between the ionic and covalent bonds as 50 %, there is a transition from the realm of ionicity to covalency with the change of the selected pathways to perform EDA in the case of six systems (Be2Te2, B2P2, B2P2, B2As2, In2N2, and Tl2N2) among the thirty-one studied. Besides, the nature of bonds in a number of systems varies significantly from ionic to strongly polar covalent like B-Sb bonds.