Herein, mathematical models and electrochemical techniques are developed to measure the interfacial charge-transfer kinetics of LIB AMs at high current densities. First, a comprehensive treatment of Butler-Volmer kinetics is provided: starting with a generalized formulation of the BV equation, which assumes symmetry, but is agnostic to the specific reaction mechanism(s), a series of equations are derived which can be used to fit the apparent values of α and I0 from the experimental electrochemical data. Specifically, equations are developed to describe the dependence of charge-transfer resistance and differential charge-transfer resistance on current density. We develop three electrochemical techniques for interfacial kinetic measurements at high current density: pseudo-steady-state extrapolation chronopotentiometry (S3E-CP), largeamplitude galvano EIS (LA-GEIS), and operando galvano EIS (O-GEIS). We discuss in detail the practical considerations of conducting electrochemical kinetic measurements at high current densities, and quantitatively show that each technique is capable of accurately and precisely measuring the values of α and I0 while satisfying the necessary conditions of stability, stationarity, and linearity. Lithium cobalt oxide (LiCoO2) symmetric cells are used as an exemplary model system to demonstrate the theory and methods developed in this work, and preliminary measurement results are reported and discussed.