While solid electrolytes have demonstrated promising performance under standard conditions, processing issues and poor wetting has significantly limited their potential usage in comparison to their liquid counterparts. Due to the limitations imposed by the trapped ionic liquid to the ionogel electrochemical performance, modification of a silica-based system is explored through a solvent exchange process to tune the electrolytic properties as means to suit the application. Here, we demonstrate the ability to achieve a solution-processable, solid electrolyte that has been facilely modified for high power applications through a carbonate electrolyte, low temperature performance through DOL/DME, or high temperature applications by maintaining the base ILE. Solvent exchange is further demonstrated in a complex architecture, unobtainable with most solid-electrolyte processing techniques. This solvent exchange process demonstrates a unique way to tailor a pseudo-solid electrolyte properties to meet the desired application requirements, whether they be constrained by environmental, power, or geometrical limitations. By further incorporating this process into newer fabrication techniques, such as additive manufacturing, improved performance can be obtained in currently infeasible architectures and geometries.