In order to promote a sustainable and environmentally friendly future for the chemical industry, we need to shift our focus beyond just monomers and also prioritize the choice of catalysts and synthesis efficiency. There are two commonly used methods for synthesizing polyesters: ring-opening polymerization of cyclic esters and polycondensation reactions. The traditional polycondensation method involves the polymerization of aliphatic monomers using metal-based catalysts at elevated temperatures . However, this method can suffer from major drawbacks, such as product discoloration, degradation caused by high temperatures, lack of selectivity, and difficulty in removing residual metals from the final product . As a result, there has been a growing interest in developing more eco-friendly alternatives to metal-based catalysts, such as organocatalysts and enzymes, which have their own advantages and limitations.