Across all the electrochemical techniques investigated, the experimentally measured decrease in resistance as a function of current density is shown to be fully and quantitatively consistent with the BV equation. The finding that LCO obeys BV kinetics at high current densities can likely be broadly generalized to most other LIB AMs. The deviations from BV kinetics reported for LIB example, the measured electrode pore resistance is three times lower from EIS than from DC measurements . We also previously showed that for nanosized LiFePO4, Rct is immeasurably small with EIS, but measurable with S3E-CP, due to differences in the active particle population dynamics between DC and EIS techniques . To the best of our knowledge, there are no other reports in the literature directly comparing the magnitude of 𝑅 𝑐𝑡 0 measured between DC or EIS techniques. Considering that practical LIB operation occurs only under DC conditions, it may be necessary to quantitatively account for this difference in electrochemical models of LIBs. For example, if the model is parameterized with EIS measurements, it is possible that the resistance under real-world conditions may be underestimated by a factor of √2. Further investigation is needed to better understand the origins and consequences of this phenomenon.