In-situ and time-resolved small-and wide-angle X-ray scattering (SAXS/WAXS) measurements to follow the evolution of mesoporosity were performed at the beamline BM26 of the European Synchrotron Radiation Facility (ESRF). Experiments were performed using a monochromatic X-ray beam at 12.4 keV (λ = 1.00 Å) aligned with a capillary (borosilicate glass, Glass Müller, Berlin ID = 1.498 mm) of the furnace LINKAM DCS 600. All the samples and backgrounds were measured with this setup.