Recent work from our laboratory has focused on the development of glycosylation through the union of glycosyl fluoride donors and silyl ethers as glycosyl acceptors using B(C6F5)3 as the catalyst. This method offers advantages of ease of operation, stereochemical tuning through the implementation of inter-and intramolecular versions, and iterative applications that allow assembly of oligosaccharides from monosaccharide precursors in a one-pot operation. Our initial explorations, however, offered limited advancement with aminosugar derivatives and were limited to phthalimido derivatives. Methods involving the use of highly electrophilic Lewis acids such as B(C6F5)3 in our approach are often plagued by the Lewis basic nature of common protected forms of the amino functionality such as simple amide and carbamate derivatives.