Figure illustrates an average convergence behavior for the "SOM III" model system. For a more detailed explanation with additional illustrations, please refer to the Supporting Information (Figure ). The convergence behavior results in a relatively low deviation for a high number of conformers. For example, the relative deviation from the mean for 1000 conformers averaged over all bonds in the system is around 1 ‰ (0.001). Overall, the data points follow a convergence behavior proportional to 1/ √ n. The angle values (please see Figure in the Supporting Information) show slightly higher deviations, which can be attributed to the associated higher number of degrees of freedom compared to the bonds. Based on this analysis, it is concluded that 1000 conformers are sufficient. This number was utilized for the parametrization of all the other SOM systems, which is discussed in Section 3.2.