Previously, we have developed LMGs in which linear saturated fatty acids are introduced into the hydroxy groups of a six-membered ring cyclic polyol. We have found that 1,5-anhydro-D-glucitol (1,5-AG), one of the six-membered ring cyclic polyols and a compound in which the anomeric position of D-glucose is deoxygenated, is a good organogelator when linear saturated fatty acids are introduced into all hydroxy groups. Among them, 1,5-anhydro-2,3,4,6-tetra-O-hexadecanoyl-Dglucitol (C16AG) (Figure , compound 8), which has a 16-carbon palmitic acid, was found to have the best gelation ability. Furthermore, it has been found that 1,5-AG derivatives with linear saturated fatty acids containing an amide group can form thinner fibers than those without amide groups, thereby creating stiffer gels. Thus, we retained the six-membered ring structure, which is the sugar backbone, and used this structure to control three-dimensional molecular mobility, thereby improving the packing between molecules and creating a three-dimensional supramolecular structure.