The main idea of this work is to use the collective coupling of |G, 1⟩ to the {|XT J , 0⟩} states to enhance free charge carrier generation. Due to the collective Rabisplitting that scales as √ N where N (see Fig. ) is the number of sites, a lower polariton, upper polariton, and N -1 dark states are formed. Because the lower and upper polaritons are energetically shifted, they can be brought closer or further away from the {|CT J , 0⟩} states thereby modifying the free charge carrier generation. They show that by such secondary hybridization, that is between the lower polariton and the |CT 1 , 0⟩, the free charge carrier generation is enhanced, as these two states are energetically brought closer through collective light-matter coupling. However, they also show that when considering cavity loss, the generation of free charge carrier is actually suppressed as the lower polariton has significant photonic character. Overall, they find that free charge carrier generation can be enhanced at short timescales (shorter compared to the cavity lifetime) but is suppressed due cavity loss at longer times.