For 𝜃 = 2°, a filled Dirac band marks the valence band maximum and kgm bands are just below. Note that these superlattice bands are filled with a total of 10 electrons, while the bulk of the bands hosting the remaining 29402 valence electrons is in the same energy range as the dispersed bands of MoS2 BL (see Fig. ). Further note that the number of valence electrons scales with the area of the moiré cells, while the number of electrons in the superlattice bands remains constant. As shown in Figure , the superlattice features in the valence band emerge for small twist angles, at about 3°, with respect to the high-symmetry stackings 0° and 60° (band structures for more twist angles are shown in Figure ). There are five characteristic superlattice bands below the Fermi level. The two bands at the valence band maximum form a Dirac point for twist angles close to 0°, while for 60° they are well separated. The dispersion of the bands reduces with increasing size of the moiré cell, that is, for smaller twist angles. Remarkable is the flat valence band for 𝜃 = 58°. The smaller dispersion for small twist angles towards 0° results in a close proximity of the two highest valence bands, while the separation between the two highest bands remains nearly constant for small twist angles towards 60°. The next three bands are characteristic for a kgm lattice. Similar to the top bands, for small twist angles towards 0°, the kgm signature is well pronounced, while for the 60°, a gap opens at the Dirac point. All these band features remain stable when going to smaller twist angles with respect to the high-symmetry configurations. The stacking domains for small twist angles with respect to the 𝑅 ℎ 𝑀 configuration are subject to the spin-orbit splitting: spin occupations are opposite in these domains at the K and K' valleys. Contrary, the H-type domains have inversion symmetry centers and, therefore, no spin polarization (Figure ).