At last, we aim at shedding light on a property of these systems that has been largely investigated as well as debated: solvent encapsulation. Past experimental endeavors, as documented in several studies, have grappled with determining the exact number of chloroform molecules dynamically encapsulated within a capsule. Notably, Shivanyuk and Rebek posited that an average of one chloroform molecule is encapsulated for each resorcinarene subunit, translating to at least six solvent molecules in the overall assembly.