Alternatively, a larger active system (i.e., more active orbitals) may have to be chosen. Miller and co-workers employed projection-based embedding to predict vertical ionization energies of ethylene carbonate and dimethyl carbonate (DMC) in condensed phase, including mixtures of the two compounds . Especially for DMC it was found that simple dielectric continuum models do not accurately reproduce the reorganization energy obtained from PbE calculations combined with configurational sampling of classical MD snapshots.