C-N axial chirality became a crucial structural feature in numerous bioactive molecules, natural products, and advanced materials. This unique form of chirality, resulting from the restricted rotation around carbon-nitrogen bonds, offers distinct stereochemical characteristics that often play a key role in modulating biological activity, molecular recognition, and material properties. Despite its significance, efficient catalytic methods for generating C-N axially chiral compounds remain limited. The development of sustainable, enantioselective routes to streamline the access of these class of molecules is thus essential. In this context, electrocatalytic C-H activation has received considerable attention, as pre-functionalized starting materials can be avoided. Combined with electricity from renewable resources, this methodology allows the direct catalytic functionalization of otherwise inert C-H bonds in a sustainable fashion. Furthermore, cathodic proton reduction leads the formation of hydrogen gas: a key energy resource for a decarbonized economy. Distinct strategies were established for the generation of C-N atropoisomers by electrocatalytic C-H activation. Hence, enantioselective C-H olefinations through oxidative palladium electrocatalysis were accomplished. Furthermore, atropo-enantioselective C-H annulations were shown to be viable by cobalt- electrocatalysis (Scheme 1A). The versatility was emphasized by the diastereo-and enantioselective synthesis of dihydroisoquinolinones featuring both C-N axial and C-central chirality (Scheme 1A). Scheme 1. Strategies for C-N atropo-enantioselective C-H activations.