According to this theory, free radicals can participate in diverse reactions, contributing significantly to the construction of chemical bonds such as C-C, C-N, C-B, C-O, and C-F . There are many examples of free-radical reactions that are nucleophilic in nature. As an example, Leonori et al. fabricated C-C bonds in a wide range of redox conversions involving aminoalkyl radicals, aryl halides, and borated azines using an ammoniacal borane reagent via photocatalysis ; Xu et al. devised the cyclisation of free radicals via electrosynthesis to form key C-N bonds; and Patel et al. difunctionalised alkynes to C-O and C-S linkages under mediation by visible light . Similarly, examples of free-radical electrophilic reactions are relatively common. Notable efforts include dual copper-photo-redox catalysis to achieve trifluoromethylation of aryl bromides by MacMillan and co-workers, the development of a photolytic method for direct benzyl fluorination using cheap and readily available diarylketones as catalysts by Chen et al. , a photochemical, three-component Minisci reaction by coupling 1,3-dicarbonyl compounds as reported by Xia et al., and the fabrication of C-N bonds by employing the ability of nitrogen radicals to undergo strain-release reactions with [1.1.1]Propellane as reported by Leonori et al . In addition, Palacios et al. have studied the photo-stimulated reactions between haloarenes and potassium diphenylarsenide in liquid ammonia to successfully synthesise the C-As bond. In another study, Lu et al.