For LiOH at -0.84 V, the angles have similar characteristics to the ones in pure water, with a broad distribution 60 • < α < 120 • , typical of one-H-down water and (Figure ); the peak of γ at 130 • confirms one-H-down water structure. The smaller peak of γ at 70 • also suggests some waters could be pointing one-H-down, probably because they have turned to point to the Li cation at 8 Å (c.f. 7f). From this, we observe that the water molecules are in position one-H-down and some of them are parallel to the surface. At -0.04 V, the water planes are broadly distributed showcasing parallel and perpendicular water features; from the γ peaks (Fig. ), we observe both one-H-down and O-down water. Finally, at 0.76 V, we notice water reorientation to O-down values and some one-H-down.