Focusing on enzymatic catalysts as a potential substitute for traditional metal-based catalysts, Candida antarctica lipase B (CAL-B) immobilized on the acrylic resin is the most popular due to its eco-friendliness, recyclability, and high selectivity . The last of the mentioned features results from the unique structure of the active site pocket of CAL-B which contributes to its enantio-, regio-, and stereoselectivity and in consequence leads to the formation of products with well-defined structures . There is a vast body of literature describing the use of enzymes for catalyzing reactions, particularly in the synthesis of polyesters. Among the different types of polyesters, numerous studies have focused on the production of 2,5-furandicarboxylic acid-based , vegetal oil-based , and sugar-based (32) polyesters. A large attention was also given to succinate-based and adipatebased polyesters .