We started with synthesizing a series of amphiphilic block copolymers of different compositions and chain lengths using reversible addition-fragmentation chain transfer (RAFT) polymerization in order to test our automated machine on a variety of compounds. The model block copolymers that were chosen for this study were poly(ethyl methacrylate)-block-poly ( ). In PEMA75-b-PDMAEA50, PEMA served as the hydrophobic core with a degree of polymerization (DP) of 75, and PDMAEA was the hydrophilic part with a DP of 50. The nomenclature of the following polymers is according to this example. It should be noted that we did not choose these polymers for specific reasons, they merely present a variation of nature of polymers and chain lengths in order to provide a variation in the nanoaggregates that are formed. In fact, some of these block copolymers have been previously studied, and the chosen vinyl monomers are commonly known to be used in applications such as therapeutic drug delivery and stimuli responsive materials in previous studies. All characterization information about the block copolymers including NMR spectra and SEC profiles is collated in supporting information.