Photochemistry is a powerful tool in polymer science, allowing exogenous control over network architecture and chemical functionality in a temporally and spatially controlled manner. In particular, additive manufacturing technologies (AMT), based on photopolymerisation have recently demonstrated their ability to produce high-resolution complex structures with tuneable mechanical properties e.g. via stereolithography (SLA), digital light processing (DLP) or 3D inkjet printing (3-DP) . Such technologies enable, for example, the direct use of medical imaging to fabricate medical devices such as individualised patient-specific implants, prosthetics and tissue engineering scaffolds . However, there is limited availability of biodegradable photopolymers resins due to the necessity to balance degradation rates with the required functionality for photopolymerization. Established SLA methods, for example, rely heavily on acrylate and methacrylate chemistry, which is able to deliver the required fast-curing kinetics. However, such chemistry inherently produces high molecular weight aliphatic carbon backbone polymers , even when combined with biodegradable feedstocks .