The intermediate -loaded adducts can also be used for the preparation of dialkyl phosphates rather than free phosphates. As shown in Figure , alcohol 2 could be loaded with reagent 1 followed by addition of BnOH to deliver dialkyl phosphate 23 in 42% isolated yield (without any additional optimization). The scalability of this reaction was also demonstrated using metronidazole wherein the standard protocol (0.1 mmol scale) could be increased 30-fold while maintaining efficiency. The operationally simple phosphorylation method described herein represents a useful addition to the toolkit for installing this important functional group in a chemoselective fashion and is yet another example of the versatility of the -platform in organic synthesis.