In summary, we have synthesized two novel catalysts that combine a chiral phosphoric acid with an organic, donor-acceptor cyanoarene-based photocatalyst moiety. Both are accessible in seven-step syntheses and all the synthetic challenges in accessing these catalysts have been overcome. In proofof-concept reactions, the bifunctional catalysts have shown potential for both enantioselective energy transfer catalysis and photoredox catalysis. To explore the full potential of these novel catalysts, optimization studies need to be carried out to improve both yield and selectivity in the proof-ofconcept examples.