Our MD simulations suggest that the structural properties of binary mixtures of [Li][NTf 2 ] and G3 depend strongly on the mixture composition. The populations of the different structural motifs, however, are remarkably temperatureinsensitive within the investigated temperature range of 263 K to 483 K. Since the balance between different structural features remains mostly unaffected with varying temperature, the transition entropies related to those underlying structure/cluster-equilibria need to be very small.