With the growing climate impact of increasing concentration of CO2 in the atmosphere, it is clear that the emission of CO2 needs to be brought to a complete stop. This will be an especially challenging transition since many of the processes that emit CO2 will still need to continue for a functioning society. To be able to achieve these crucial steps, technologies need to be developed to both capture CO2 and convert it into useful products such as fuels and feedstocks. Considering the scale at which these technologies need to operate on they need to be made of cheap and accessible materials that can be available all over the world. One of the approaches that could fit the requirements is the use of molecular redox carriers to bind up and release the CO2 or even form new chemicals at different redox states. This approach is appealing due to the mild environments of electrochemical methods compared to commonly used thermochemical alternatives, as well as the ease of tuning the properties of this class of molecules. Ideally, the synthetic routes to these molecular redox carriers should be simple and they should be prepared from cheap and abundant elements. A group of molecules that fits these requirements is that of small organic redox active molecules. Typical binding modes to CO2 can be through free electron pairs of either O or N or to the π-π interaction of conjugated bonds, as shown in several published systems, with examples such as quinones, pyridines. and thiols. Moreover, very similar types of molecules with highly conjugated nitrogen-rich systems, for example, benzimidazoles have been used as hydride donor that facilitate electrochemical reduction of CO2 to formic acid and when used in cascade catalytic systems can produce methanol under photoelectrochemical conditions .