As a final test of our DLPNO-CCSDT(Q) algorithm, we performed timings on a series of linear alkanes and water clusters, in the cc-pVTZ basis (geometries available in the supplementary material). The results are shown in Figures and. The total DLPNO-(Q) wall time (in minutes) is evaluated with respect to the number of carbon atoms in the case of alkanes and molecules for the waterclusters. For clarity, this represents the time spent only in the quadruples portion of the algorithm, and not the preceding DLPNO-CCSDT computation. In addition, the timings for the iterative (Q) portion of the computation are also presented. In our timings, for consistency, we scale the raw times for the iterative (Q) portion of the computation to how much time it would take for three iterations (the typical number of iterations it takes to converge), regardless of how many iterations were required for convergence in the computation. This is also reflected in the total wall time. System sizes range from 1 to 10 carbons (86 to 604 basis functions) for the alkanes, and 4 to 49 waters for the waterclusters (232 to 2842 basis functions). Default parameters are used (Table I). As shown in Figures and, the short range nature of coupled-cluster quadruples mean that linear scaling behavior can be seen even in smaller systems relative to DLPNO-CCSD/(T)/T. To numerically evaluate this, log-log regression of the per-iteration wall time with the number of basis functions is performed, fitting the function t = a • N b , where t is the wall-time, a is a pre-factor, N the number of basis functions, and b the observed scaling.