For in-depth analysis of phase transformations in LMNO cathode materials during charging both phases involved in the transitions (Li 1 + Li 0.5 or Li 0.5 + Li 0 ) were imaged during the operando measurement. This was achieved by positioning the 2D detector close enough that the Bragg reflections of both phases in the particle during an SXDM scan were recorded. Thus it was possible to obtain two real space maps (either Li 0.5 and Li 1 phases or Li 0 and Li 0.5 phases) of the particle during the phase transition and by juxtaposing them to achieve a more detailed understanding of the morphological evolution of both phases.