The synthesis of chiral secondary alcohols has been a subject of intense study for more than 40 years (Figure ). Retrosynthetically, two main pathways to access aryl-alkyl substituted secondary alcohols employ either nucleophilic addition to an aldehyde 2 or asymmetric reduction of the corresponding ketone. Early catalytic manifestations of the former process date back to the work of Noyori on highly stereocontrolled organozinc additions to aldehydes whereas the latter strategy originated from the findings of Landor ultimately leading to modern methods such as the venerable CBS 6 reduction. The Nozaki-Hiyama-Kishi (NHK) reaction, first discovered in 1977 and formalized in 1986 8 usually involves the cross-coupling of an alkenyl halide with an aldehyde through the use of stoichiometric Cr and catalytic Ni to afford an allylic alcohol product. The corresponding alkyl-variant of this reaction is seldom employed with a variety of alkyl nucleophile surrogates being disclosed over the years such as alkyl iodides, carboxylic acids [via redoxactive esters (RAEs)], olefins, 12 or even unactivated C-H bonds (Figure ). Those variants, however, have not been employed in a catalytic, highly enantioselective fashion. In 2021, an electrocatalytic decarboxylative variant of the NHK reaction was disclosed by this team demonstrating a racemic proof of concept for such a bond forming strategy. In this Article we disclose a broadly useful method that now achieves synthetically useful yields and enantiomeric excesses through a combination of fine-tuned electrochemical parameters, enabling additives, and an optimized chiral ligand. The high functional group tolerance of this reaction