Readily available 1,3-dienes have recently been extensively explored as radical acceptors to generate allylic radical intermediates and trigger radical cross-coupling reactions. In order to further examine the potential of our catalytic system, we preliminarily attempted a three-component cross-coupling reaction between 1phenylbutadiene 11, oxime carbonate 2a, and aryl boronic acid 3b under the standard conditions of Table (Figure ). The reaction indeed worked to afford the 1,2-adduct 12a as the major product with high enantioselectivity (87% ee), though accompanied by small amount of 1,4-adduct 12b, which is highly promising for the future development enantioselective arylative functionalization of 1,3dienes.