The N-acylhydrazone derivatives (4a-h) were obtained through a three-step synthetic pathway starting from furan-2-carboxaldehyde (1). The initial step involved the addition of ethyl chloroacetate to aldehyde (1) in the presence of triphenylphosphine (PPh3) under basic conditions, employing the Wittig reaction. Consequently, the ester (2) was obtained with a yield of 98 %. Subsequently, the ester (2) reacted with hydrazine monohydrate (H2N-NH2.H2O) in ethanol at room temperature to yield the corresponding hydrazide (3) with a yield of 52 %. Finally, a series of acrylohydrazide derivatives (4a-h) was synthesized with yields ranging from 23 % to 96 %. This was achieved by condensing hydrazide (3) with various derivatives of benzaldehyde and acetophenone in ethanol at room temperature for 3 hours, in the presence of a catalytic amount of concentrated hydrochloric acid (HCl) (Scheme 1). The newly synthesized compounds (4a-h) were fully characterized using various analytical methods, notably NMR, which revealed the presence of a dynamic equilibrium between two isomers for each compound in the N-acrylohydrazone series (4a-h). The results of this stereochemical study will be discussed in the following section.