NaOH and TBAOH 2NapFF at 25 mg/mL were studied both before and after a heat/cool cycle. Prior to the heat/cool the NaOH sample underwent a rapid thinning process (<1 s) whereas for the TBAOH sample the liquid bridge did not break. Instead, a thin filament formed but after 25 minutes dried out before breaking. After the heat/cool the NaOH sample exhibited solid-like behaviour, where the droplet (prior to touching the substrate) possessed a non-spherical shape. Upon contact with the substrate no thinning is observed and the liquid bridge 'jams'. For TBAOH post-heat/cool, the droplet makes contact with the substrate and broke over the course of 30 -60 s. For the NaOH post-heat/cool and TBAOH preheat/cool, the liquid bridge did not break and the data could not be analysed.