The MD-based results provide a diverse pool of systematically altered ligands from which to extract design rules. The overall stabilization rates for ligands in the OE-mono, OE-dimer, and OE-4mer series were 100%, 98.12%, and 87.00%, respectively. These high overall stabilization rates reflect the dramatic diversity of functional ligands that can be incorporated into 2D perovskites. A reduction in stabilization rate with increasing ligand body length is also evident, but this reflects the peripheral side-chain substitutions of the OE-4mer series that were not conducted for the others. These results thus validate the baseline design rule that ligand length is relatively unrestricted for successful perovskite incorporation.