Over the past decade, organic electrosynthesis has emerged as a transformative platform for sustainable molecular synthesis enabling electric current as a sustainable alternative to stoichiometric amounts of chemical redox reagents. Thus, diverse electrochemical transformations have been developed, such as radical cyclization, crosscoupling reactions, olefin functionalization, and C-H activation. Despite indisputable advances, achieving full selectivity control in terms of enantioselective electrosynthesis continues to be challenging. Recently, stereocontrol strategies including transition metal catalysis, organocatalysis, and enzymatic catalysis have been gradually applied to this area. Although systems of enantioselective electrocatalysis are described, its application to the synthesis of axially chiral compounds, especially with C-N axial chirality, is in its infancy.