Here, we investigate tBL MoS2 with small twist angles with respect to the high-symmetry bilayer stackings, i.e., metastable 𝑅 ℎ 𝑀 and lowest-energy 𝐻 ℎ ℎ configurations (see Figure ). In both cases, atomistic classical force field structure relaxations of the moiré cells result in two pronounced low-energy stacking domains of high symmetry (Figure ). After validation against density-functional theory (DFT) within the generalized gradient approximation (GGA) for high-symmetry stackings of BL MoS2 (see Fig. ) and for two tBL moiré structures (see Fig. ), we use the density functional-based tight-binding (DFTB) model to calculate the electronic structures of tBL MoS2 for small twist angles with respect to the highsymmetry configurations. In the twisted 𝑅 ℎ 𝑀 case (𝜃 = 2°… 6°), Dirac and kgm bands emerge as all lattice sites are symmetrically equivalent, while in the twisted 𝐻 ℎ ℎ case (𝜃 = 54°… 58°),