Main Text: Self-organization through non-covalent intermolecular interactions guided by selfrecognition is considered the path to achieving the highest level of matter complexity. Complexity is the key to unlocking advanced functions, characteristic of living systems, such as replication, evolution, and communication . Recent studies have shown that the outcome of the self-organization process is determined by an interplay between thermodynamic and kinetic factors , both of which can be exploited to achieve well-defined architectures. For instance, the cooperative process, which undergoes a nucleation/elongation mechanism, has been widely used to control the supramolecular polymers length (5). Indeed, the growth of large aggregates in the elongation phase is thermodynamically more favorable than the formation of small oligomers in the nucleation phase . Kinetic control, instead, is typically achieved by introducing competing off-pathways . Examples of living supramolecular polymerizations have been realized by combining seed-induced growth with the ability to kinetically trap monomers into off-pathway aggregates . Additionally, the formation of intramolecular hydrogen bonds can be used to inhibit spontaneous polymerization of monomers, triggering it on demand or with tailored initiators .