Catalyst design has historically focused on selecting the optimum catalytic active site within a material which provides a balance of strong and weak adsorbate binding energies . Strong binding is rate limiting in desorption resulting in rate inhibition from the product, while weak binding is limiting in dissociative adsorption or surface reaction . The original strategy in these systems tuned catalyst characteristics to exist at the maximum possible turnover frequency (i.e., the Sabatier volcano peak) . More recent strategies aim to shift the volcano peak via alteration of the linear scaling relations, which describe the predicted surface activation energy as a function of surface reaction enthalpy . Varying of the linear scaling relations of surface reaction activation energies has the potential to Abstract. Catalytic reactions on surfaces with forced oscillations in physical or electronic properties undergo controlled acceleration consistent with the selected parameters of frequency, amplitude, and external stimulus waveform. In this work, the general reaction of reversible A-to-B chemistry is simulated by varying the catalytic (heat of reaction, transition state and intermediate energies) and oscillation parameters (frequency, amplitude, endpoints, and waveform) to evaluate the influence on the overall catalytic turnover frequency and steady state extent of conversion. Variations of catalytic cycle energies are shown to comprise a superVolcano of superimposed individual Balandin-Sabatier volcano plots, with variations in linear scaling relationships leading to unique turnover frequency response to forced oscillation of the catalyst surface. Optimization of catalytic conditions identified a band of forced oscillation frequencies leading to resonance and rate enhancement as high as 10,000x above the static Sabatier maximum. Dynamic catalytic reactions conducted at long times achieved oscillatory steady state differing from equilibrium consistent with the imposed surface oscillation amplitude acting as a 'catalytic pump' relative to the Gibbs free energy of reaction. change the shape of Sabatier volcano plots and shift the maximum possible turnover frequency.