For this particular plot (Protocol-1 or 2) greater peak height in the structured region signifies a substantial deviation from the tetrahedrality. Conversely, as we move towards a less structured region (𝑞 𝑡𝑒𝑡 < 0.5), the dip is maximum for W-UC (8:4) system as an increase in reline wt% shows a greater population in the disordered region. We find a similar trend for Protocol-1 and 2, as can be seen in either of the plots. We also encounter an enhanced tetrahedrality in Protocol-2 than Protocol-1 for all the systems under investigation.