Figure demonstrates how the lack of data in the COD can impact qualitative assessments of torsional preferences. The correlation between the experimental COD and computed gas-phase torsions (left and middle panels) is 0.58. The experimental torsions show a mild preference around 60 • and 120 • , with a lot of noise between, while the calculated torsions have more defined peaks at 50 • , 90 • , and 132 • . Much like the case above, the 10x increase in the number of torsions in the combined set was able to provide enough data to discern preferential angles.