Such map, showed in Figure , provides a coarser description of the internal structure/dynamics of fiber (2), where again the transition probabilities between the higher level purple-green-orange states are obtained directly from the PAMM analysis (transition probability matrices of Figure ). This is a simpler scheme where monomers in the ordered interior of the fiber (purple) can dynamically become defects (green) with a probability of ∼5%, while such defects then have a probability of ∼13% to be reabsorbed/repaired (green-to-purple) and ∼2.5% to transform into monomers that can be exchanged and can diffuse as absorbed onto the fiber surface (green-to-orange). As a direct consequence of detailed balance, transitions from disordered to ordered states happen with higher probabilities than transition to more disordered configurations. In more disordered and random aggregates (e.g., nanoparticles, micelles, etc.), where the cores of the monomers are not likely to be ordered/coordinated to each other, the picture would be reversed, reflecting the lower stability of ordered domains.