PBEsol's 40 tendency towards LDA-like behavior (as µ = µ GE = 10/81 for PBEsol), and the demonstration of the LDA's large over-binding of adsorbates to transition-metal surfaces from makes us expect it to over-bind relative to PBE. Indeed, this is observed in Figures and. In addition, from Figures and of Hammer, Hansen, and Nørskov , revPBE and RPBE favor the reduced density gradients s, so that both revPBE and RPBE destabilize the adsorption system and give less attractive chemisorption energy. From Hammer, Hansen, and Nørskov 38 and Lee, Hyldgaard, and Neaton 34 , we might expect the binding energy to follow the order to LDA ∼ PBEsol > PBE > revPBE ∼ RPBE. Although we didn't do plain revPBE and RPBE, we have shown that PBEsol and PBE follow this trend, and the GD2 correction applied to all four functions maintains this trend, too, for both the single amine and full pore cases.