A unique class of crystalline porous materials called MOF by Yaghi originally appeared in 1995 as a result of the potent interactions between organic ligands and metal ions and has since distinguished itself with persistent porosity and large surface areas . Since the inorganic component in porous hybrid frameworks was either an isolated polyhedron or a small cluster, as in coordination chemistry, coordination polymers were the previous name for these materials. However, it was soon realised that porous hybrid materials might contain inorganic elements with increased dimensionality, leading to MOF, or multi-scale order frameworks . Porous materials were first created in 1989 by Hoskin and Robson, who combined octahedral or tetrahedral arrays of metal centres with organic moieties to create scaffolding-like structural three-dimensional frameworks . Using single crystal XRD, a diamond-like structure called [N (CH3)4][CuZn(CN)4] was successfully created and analysed . A 3D