Starting with the selective complexation of CB with alkyl-and aryl-substituted ammonium ions in solution forming host-guest complexes through hydrophobic and ion-dipole interactions, first studied by Mock , the design and construction of highly ordered advanced supramolecular architectures on the basis of CB has rapidly evolved . The detailed complexation mechanism of CB with various guests in aqueous solution concerning thermodynamic parameters, kinetic investigations, and molecular mechanics calculations was highlighted by Nau and co-workers . The results showed that the complex formation of different amines and polyamines with CB emphasized the formation of complexes with high stability. Due to its symmetrical structure with a rigid hydrophobic cavity and two hydrophilic portals, CB can form polyrotaxane polymers with higher stability compared with cyclodextrins.