The 3D printability of the synthesized copolymers was performed by fused filament fabrication (FFF) technique using Anycubic i3 Mega, Shenzhen Anycubic Technology Co.,Ltd 3D printer. The required diameter of the filament for FFF was obtained directly from the reactor by adjusting the speed of collected solidifying polymer melt (filament) into the water bath. A single tool head extruder in 3D printer with 0.25 mm in diameter was used for melting and depositing copolymers according to a given pattern.