Our approach for computing partial charge is well in line with chemical expectations: LiF computes as ionic and the bonds inside urea between C and heteroatoms appear as polarcovalent. At the same time, the latter example of organic chemistry is portrayed as markedly less ionic compared to QTAIM. In fact, the charges on all atoms in urea are predicted to be smaller in magnitude with our method, and N atoms are particularly affected by the difference in topological analysis. The partial charge predicted for hydrogen atoms 𝑞 * is strikingly (∼50%) different compared to QTAIM. For urea we also provide atomic partial charges inside the isolated molecule (Table ). Even though differences in absolute values between the 𝛸(𝒓)- GaN is an example where our methodology helps to provide a different perspective. Our computed partial charges are in line with a formal Ga +1 N -1 description. In contrast, theoretical analysis based on QTAIM describe Ga-N interactions as predominately ionic (Table ) , and closer to a formal Ga +2 N -2 situation.