We furthermore evaluated the corrections on a more intricate system, namely the [Fe(bpy)3] 2+ complex in water. We observe that larger excluded volumes require larger R-values to reach convergence, thus requiring larger simulation cells. For this system, only the van der Vegt correction managed to flatten out the I(0; R)-signal within the limits of the range of the sampled RDF. This system also illustrated the intricate nature and m-extension dependence of the excluded volume concept for real systems.