The small but celebrated hemihedral crystal facets of sodium ammonium tartrate gave Pasteur, via manual resolution, evidence of dissymmetric molecular configuration only after solutions of dissolved crystals had been subject to polarimetry. Differences in responses to left and right circularly polarized light are the dominant perturbations to the state of polarization in isotropic solutions. While crystals of tartrate salts are transparent, their solid state optical activity could not be measured straightaway in 1848. The optical activity of anisotropic crystals is remains difficult to measure along low symmetry directions and requires accurate photometry and polarization modulation. Only in 1997, were researchers able to establish the optical rotation (OR) anisotropy of enantiopure tartaric acid crystals, filling a chasm in the history of molecular chirality. These crystals, however, are not manifestly dissymmetric in form, like sodium ammonium tartrate. To the best of our knowledge, chiroptical measurements never have been made of sodium ammonium tartrate, in part because the crystals have remained difficult to grow and their enantiomorphism lacks the clarity of Pasteur's oft-reproduced drawings. More often than not, chirality is veiled when dissymmetries are not manifest in the crystal habit. Therefore, the advent of a new system of enantiomorphous MOF crystals, with clear manifestation of dissymmetry allows us to try to understand the link between symmetry and crystal habit. The break down of Friedel's intensity law can be used to determine the absolute chirality of crystal structures. However, anomalous scattering is unreliable for weakly X-ray scattering crystals that are small or of low-quality. The assignment of absolute structure assignment by 3D ED (three dimensional electron diffraction) is a rising remedy. Here we report the crystal morphologies of a cadmium acetate complex of an organic ligand (AdDB), hereafter compound QW-MOF. Enantiomorphous morphologies were formed of apparently twisted trapezohedra in which the top hexagonal pyramid appears to be rotated anti-clockwise (L) or clockwise (R) with respect to the bottom pyramid. The hexagonal axis is the vertical in the plane of the page (Fig. ). Over time, the bottom pyramid and top pyramid become dissymmetric in size and shape (Fig. ). The bottom pyramid has isohedral faces {111} whereas the top pyramid has enantiomorphous faces either {122} or {212}, respectively. Moreover, additional faces develop. We demonstrate the control of the morphological dissymmetry with growth conditions: the off-set angle between the bottom and top pyramids can be varied by the solvent composition (Fig. ). The crystals are characterized by extensive channels that can be functionalized with dye molecules (sodium resorufin). The alignment of the dye molecules resulted in strong linear dichroism under polarized light (Fig. ). The dissymmetric crystalline forms and crystalline optical activity could be correlated directly along the low symmetry directions presented by the as-grown enantiomorphous trapezohedra. We illustrate the correlation of dissymmetric forms by equal and opposite measurements of circular birefringence (CB) of single crystals in the solidstate (Fig. ).