As shown by the reactions with meta-substituted anilines, this electrocatalytic cascade protocol demonstrates a broad functional group tolerance, allowing the use of several synthetically useful functionalities including boronic acid, halogen, carboxylic acid, ester and keto groups. Also, here a similar trend in terms of electronic effects was observed, where meta-methyl aniline allowed for product 5 to be obtained in quantitative yield during the standard conditions, while other more electron-deficient anilines usually required extended reaction times to give satisfactory yields of products 6-11 (87-95%). The presence of an electron-donating OMe-substituent in the ortho position was found to have less impact on reaction performance resulting in formation of product 12 in 83% yield after 3 h. This can be compared to the reaction of an aniline with an electronwithdrawing COPh-substituent in the ortho position, which required a reaction time of 18 h in order to reach comparable yields of 13. Disubstituted anilines of various patterns and substituents were also well tolerated by this electrocatalytic cascade protocol, as shown by the reactions furnishing products 14-17 in 90-97% yield. When ortho-phenylenediamine was used together with 2 equiv. of acid chloride 2, product 18 resulting from diacylation followed by mono-chlorination, was isolated as the major product in 84% yield after 4 h. Further alkylation of the aniline nitrogen as demonstrated by the reaction forming the tertiary amide products 19 and 20 was found to have a negative effect on the reaction performance. In the case of 19 with a Me-substituent a high yield of 81% could be obtained by simply extending the reaction time to 16 h, while 20 with a Bnsubstituent only could be afforded in 68% yield despite a reaction time of 25 h and an increased current to 10 mA.