The ease with which Ni-electrocatalytic cross-couplings can be scaled up has been demonstrated on numerous occasions. As such, GCC could be scaled up on gram-scale in batch or flow modes without any yield diminishment (Figure ). The only modification made to the general procedure was scaling the current linearly to the amount of substrate employed (30 mA/mmol). In a batch setting, structures 16 and 19 could be easily procured on gram scale. When conducting the reaction of decagram scale under flow conditions, GCC proceeded smoothly to deliver 17 in 42% yield. Due to the polar nature of the solvents and additives both modes of scale-up operated under very low potential due to the low resistance of the media.