Our results also demonstrate that when two triflates are in contact with the same cation, forming a Na(OTF)2 substructure, the breaking of the S-C bond in one anion enhances the probability of a similar bond breaking in the second anion, as indicated by ?∆𝐸 𝑑𝑒𝑐 2𝑆-𝐶 ? > 2?∆𝐸 𝑑𝑒𝑐 𝑆-𝐶 ?.