Modern organic synthesis methodologies aim to efficiently construct important molecular frameworks with the fewest possible steps, optimal convergence, minimal functional group transformations, and importantly reliance on simple, divergent, commercially available or readily accessible starting materials, while often favoring transition metal-free approaches and using friendly reagents. With these ambitious goals in mind, our program aims to focus on the synthesis of important arylated molecules, specifically (unsymmetrical) diarylmethanes and diarylketones. Diarylmethanes and diarylketones have attracted considerable interest due to their unique structural, chemical, and physical properties. They are essential in the synthesis of natural products, bioactive compounds, pharmaceuticals, agrochemicals, and modern synthetic materials. An important focus in organic synthesis is the modular and efficient construction of these scaffolds, particularly their unsymmetrical variants containing two distinct aryl groups.