Overall, the broad substrate scope, coupled with robust functional group compatibility, underscores the mildness and operational simplicity of this protocol. Additionally, scale-up syntheses with multiple substrates (25, 60, 79, on 10 mmol) showed consistent reaction outcomes without affecting the isolated yields. The transformation enables the synthesis of a wide range of C(sp 3 )-rich alkyl amines, which would be challenging or inaccessible via conventional methodologies.