Finally, we briefly examined the generality of this protocol by reacting a representative set of oxime carbonates with 1a and 3a (Table ). These redox-active oxime carbonates were easily prepared from the cyclobutanone precursors. Importantly, variations in the substituents in the parent scaffold has no obvious deleterious effect on the reaction. For example, the more sterically encumbered 3,3-disubstituted oxime carbonates 2b and 2c participate in the reaction to furnish the expected products 5u and 5v with high yields (80-82%) and enantioselectivity (94% ee). The reaction of sterically less bulky 3-phenyl-substituted oxime carbonate 2d afforded product 5w with good yield and enantioselectivity, but as a mixture of diastereomers (1:1.2 d.r.) because of an initial unselective radical addition. Oxime carbonate 2e derived from oxetan-3-one was also suitable for the reaction, with the desired product 5x being isolated with synthetically useful yields and enantioselectivity. Moreover, benzocyclobutenone-derived oxime carbonate 2f is a viable substrate, affording 5y in modest yield and with 85% ee. Collectively, the broad generality and scope render this protocol to be convenient and practical process to prepare a variety of chiral cyano-alkylated 1,1-diarylalkanes.