In summary, a parameterisation methodology is outlined, which uses electrochemical and thermal techniques, illustrating the parameter variability caused by local and global changes in temperature or lithium concentration. This methodology is chemistry and format-agnostic and can be applied to different cell types to increase the availability of 3D thermal-electrochemical parameters. Insight into the diffusion and reaction rate kinetics show the limiting electrodes. Further work with these parameters would be to design, predict and validate faster charging and discharging protocols, through understanding the changes in rate kinetics at different states of charge and with temperature.