In summary, we established the humidity treatment strategy to greatly improve the electrochemical performances of the TeO2-V2O5-P2O5 (TVP) glass anodes for LIBs. Remarkably, this strategy led to a significant enhancement of the reversible capacity in TVP glass anode, e.g., from 182 to 442 mA h g -1 at 1 A g -1 upon 200 cycles for TVP glass subjected to the 65% humidity treatment for 120 h at 333 K. This strategy also gives rise to the capacity retention of nearly 100% after 200 cycles at high current density. The incorporated -OH in TVP glass may cause the following aspects such as broadening of the network channels for Li + diffusion and increasing active sites for lithium storage.