We introduce a full set of hyperbranched metal-organic superstructures. The hedrites, sheafs and spherulites shown in Scheme 1 are formed from rods that evolve into thermodynamically favored branched morphologies. The size and morphology of these crystals are manipulated by using the same building blocks under different reaction conditions. The hyperbranched structures were obtained without the use of external modulators. The crystallinity of our materials is evident from detailed crystallographic and electron diffraction studies of sections of the crystals. These studies show that the crystallographic orientation of the nanorods of the fantails deviates slightly from each other. However, their crystallographic structure is identical. These structural features are consistent with noncrystallographic branching, except such MOFs are unusual. The level of branching can be controlled: crystals were formed with several generations of branching or with as single generation. The lack of subsequent branching of branches is the most characteristic feature of a spherulite. We postulate that their growth differs from the accepted mechanism for hyperbranched crystalline minerals where actual splitting of these materials occur. It is likely that defects formed during the fast growth of initial MOFs act as secondary nucleation centers.