To continue the further development of the RP-type intercalation-based cathodes within FIBs, it is of interest to investigate the role of multi-cation-containing RP cathodes. In the field of LIBs, it was observed that multi-transition metal ion-containing cathodes demonstrate improved rate capabilities and cyclability, e.g., LiMn1-x-yNixCoyO2 . In this work, we report for the first time the battery characteristics of a multi-metal RP-type cathode material with composition La2Ni0.75Co0.25O4.08 which would have a theoretical capacity of 134 mAh g -1 for an uptake of two fluoride ions per formula unit. As a model system of choice and our previous results, La2NiO4 was chosen due to its excellent performance as the cathode candidate within FIBs and Co was chosen as the dopant, which has been a common dopant for nickelates in LIB chemistry as well. By combining different experimental techniques (X-ray diffraction, X-ray absorption spectroscopy, magnetic characterisation, electron microscopy), we determine the The precursor La2Ni0.75Co0.25O4.08 was synthesized via a solid-state reaction. Stoichiometric ratios of La2O3 (Alfa Aesar, 99.9 %, pre-dried at 1200 °C for 12 hrs before use), NiO (Sigma Aldrich, 99.99 %, pre-dried at 700 °C for 12 hrs before use), Co3O4 (Alfa Aesar, 99.99 %) were ball milled in ZrO2 jars for 1 hr with the rotational speed of 600 rpm using a small amount of isopropanol as a dispersing agent. Then the mixture was heated at 1450 °C for 24 hrs under flowing Argon (99.9 %, 0.4 SLM (standard litre per minute) flow). The heating and cooling rates were 2 and 1 °C/min respectively.