Achieving a single, well-defined emission peak is critical for efficient radiative pumping and condensation. The presence of multiple emission features disperses the population of excited states and, when lacking energetic overlap with the lower polariton branch, provides an exciton reservoir depletion mechanism that limits the efficient feeding of polaritons into their lowest energy state via radiative pumping. Our work highlights the need for advanced material design to control and simplify the emission line shape of 2D perovskites. By engineering the excitonic landscape and suppressing competing emission peaks, these emergent semiconductors can better support polariton condensation and unlock their potential for polariton-based technologies. Our findings advance the understanding of polariton dynamics in 2D perovskite systems and emphasize the critical role of fine-tuning material properties to achieve room-temperature polariton condensation. ~15,000 g/mol) in 1 mL of Toluene (purity> 99.98%) and allowed to dissolve for 24 hours under constant agitation. The dissolved solution was then deposited by spin coating, 80 uL of solution were dropped on the finished perovskite layer and spin coated in a 1 step process, at 6000 rpm, accelerated at 6000 rpm/s. The substrates were then thermally annealed for 5 minutes at 60 °C.