Electrostatically bound complexes can be characterized by two properties, inter-monomer distance and very low dispersion/electrostatic ratio (hereafter D/E) as computed from SAPT analysis. In most cases, the D/E < 0.5. Therefore the qualitative pictures for the interaction energies are essentially obtained from DF methods(see Fig. ). The -D2, -D3 and QDO correction on the DF interaction energies provide more accurate PEC. To analyze further, the deviation of interaction energy by PBE-D2 (∆E P BE-D2 ) and PBE-QDO (∆E P BE-QDO ) from benchmark coupled-cluster energies are plotted in Fig. A close inspection of Fig. can reveal the nature and origin of the errors resulted in PBE-QDO method. For most of the complexes, our method predicts under-binding. This may occure due to the absence of dipole-quadrupole and higher order terms. Since 3-body ATM correction is also important in such systems, inclusion of it may further correct our results. The overall deviation of our method along with pure PBE and PBE-D2 from CCSD(T) is tabulated in Table-1. QDO correction lowers the error of pure PBE significantly.