Here, 𝑉 is the equilibrium potential difference in NMC622 material. In this model and in contrast to our previous work in [30], we did not account for the volume change in AM during lithiation. As the formation of side products and the loss of contact area due to swelling and shrinking of the AM introduces significant uncertainties in the kinetic parameters, therefore we extract parameters from experiments in the pristine state. Assuming lack of porosity of CBD domain is a first approximation, as one knows that CBD can be porous . All the parameters used in the modeling framework are listed in Table of the Supporting Information.