We performed three benchmarking experiments that were designed to identify a lower limit of volume that could reliably be dispensed. Initially, we performed a gravimetric calibration experiment, where we used the automated solution handling equipment to dispense a target amount of water onto a balance, where the corresponding mass of the dispensed water was measured. Next, an acid-base titration of 0.1 M H3PO4 with 1 M NaOH as the titrant was performed. Lastly, diffusion coefficient measurements of TEMPO at varied concentrations and scan rates demonstrated the limits of our automated electrochemical platform for CV measurements.