Given the significance of sultams and sultones in modern synthetic and medicinal chemistry, numerous methods have been developed for their synthesis. These methods predominantly involve the formation of S-N bonds through intramolecular sulfonylation or the formation of other bonds within the sultam fragment (N-C, S-C, and C-C) primarily through alkylation reactions. In most cases, the synthesis requires the use of bi-and polyfunctionalized compounds with reactive groups suitable for cyclization. The other option relied on the presence of the activating groups.