Direct enantioselective functionalization of C(sp 3 )-H bonds in organic molecules is one of the ultimate goals of organic synthesis due to its remarkable atom-economy and step-economy . Methods such as the enantioselective oxidation of the C(sp 3 )-H bonds, which involve directly introducing oxygen functionalities into alkanes, hold significant potential for the discovery and development of new pharmaceuticals . Chiral oxygenated aliphatic structures are common in bioactive compounds such as natural products and pharmaceuticals . Recent progress has been made in enantioselective C-C and C-N bond formation from C(sp 3 )-H bonds using transitionmetal catalysts . However, the enantioselective formation of C-O bonds by C(sp 3 )-H oxidation remains a formidable challenge (Fig. ) . This difficulty stems from oxygen's tendency as a harder base to coordinate strongly with hard acids according to the Hard and Soft Acids and Bases (HSAB) theory . Oxygen often exhibits poor coordination with latetransition metals, which are soft acids . This mismatch results in low reactivity and enantioselectivity in these oxidation reactions and frequently causes overoxidation to ketones. .