DLPNO-CCSD(T) electronic energies were corrected with TPSSh free energy terms to add reference lines to BP86 cannot properly describe the relationship between these two intermediates. However, hybrid functionals do not universally remedy this situation, either, since there is a large variation in slope depending on the particular functional used. B3LYP seems to offer a fortuitous balance between TPSSh and PBE0, which seems to be linked to its intermediate proportion of exact exchange.