Using our method for generating the configurations, qualitative PESs were generated for three chemical systems: the two simple tetrafluorides 1 and 2, and the chiral silane 3a-R. The tetrafluorides represent the two paradigmatic geometries of the AB4 T-4 E-mode configuration space: tetrahedral (1) and square planar (2), and the chiral silane illustrates the many details that emerge with more general chemical implementations of the analysis. Please do not adjust margins Allowing for bond-length relaxation, trajectories approaching to the six "fusion" configurations results in the system dissociating to give "F2 + Si + F2" with a linear arrangement at infinite separations and with the F2 fragments at right angles to the dissociation trajectory (See Discussion). The relative orientations between the two F2 fragments is dependent upon which direction in the adjacent configuration space the symmetric linear SL-4 configuration is approached. Consequently, the SL-4 configurations are not uniquely defined for chemical embodiments. The PES is monotonically increasing for all direct approaches towards these symmetric linear SL-4 configurations.