A technique that does offer more chemical information and that is gaining traction in MOF research is NMR spectroscopy. These experiments can either be performed in solid state (using magic angle spinning, MAS), examining the MOF directly, or in liquid state, for which the MOF has to be digested. Tang et al. used a fast 1 H MAS NMR approach to quantify the relative linker fractions in MTV-MOFs (based on UiO-66) and compared this with liquid-state NMR of the digested samples. They obtained a perfect correspondence between the two techniques, while being able to extract additional information on the spatial arrangement of the functional groups on the linker from the solid-state spin diffusion experiments. A different showcase of the use of solid-state NMR techniques for methoxide-capped defect quantification in a Ti(IV) MOF is given by Smolders et al., who also found a good correlation between solidstate NMR, solution-state NMR and TGA mass loss. Yin et al. approached the defect quantification problem differently, using phosphorus containing probe molecules of different sizes in solid-state P NMR to both quantify and obtain site-specific information on the defects, finding a linear correlation with the TGA analysis. While clearly being very informative, solid-state NMR spectroscopy is much less accessible than its liquid-state counterpart. Liquid-state NMR analysis of digested MOF samples is frequently used to determine relative ratios of different linkers, modulators and guests in (MTV-)MOFs, ligand-exchanged MOFs or guest@MOF systems. Several studies point to the complementary character of NMR and TGA, since TGA provides a quantitative mass loss, but no direct information as to its origin, while standard solution-state NMR provides the identity of the constituent organic molecules and -if done correctlytheir relative concentration. Chen et al. compared the TGA and NMR linker quantification for UiO-66, assuming for the NMR part that every cluster is 6-fold coordinated and the ligands can either be formic acid, modulator or linker. Interestingly, they note that larger crystalline domains might lead to a better agreement between NMR and TGA results. In order to obtain additional information from the NMR spectroscopy experiments, qNMR can be performed. This allows for an independent quantification of the amount of organic molecules in the digested solution. Marreiros et al. used a procedure adapted from literature to analyse mixed ZIF-8 and ZIF-90 samples as well as UiO-66. For the latter case final values for the number of linkers per cluster were calculated by averaging the independent values obtained from TGA and qNMR. To obtain such an independent value from TGA, assumptions like those listed above were made. When calculating the number of linkers per cluster solely from qNMR, the researcher determines the organic molecules and the mass they have with respect to the total digested mass, but still has to make assumptions on the constituency of the rest of this total mass. We propose to integrate these two experiments differently, by using only the residue mass from the thermogram, from which the maximal number of clusters is calculated, and using the qNMR data to determine the total number of ligands. In this way several of the potential sources of errors listed earlier can be eliminated.