radical polymerization faces a series of inherent limitations and challenges. One notable example relates to the homopolymerization of α-olefins, leading to the formation of linear carbon-chain polymers. After forming secondary carbon-centered radicals from α-olefins and their derivatives through various initiators, chain transfer reactions with other monomers may ensue, giving rise to more stable allylic radicals by hydrogen atom transfer (HAT), which poses a significant impediment to the effective assembly of the polymer chains, as depicted in Figure , A . As a result, except ethylene, other olefins-such as propene, 1-butene, and 4-methylpentene-are more commonly polymerized using coordination polymerization techniques instead of traditional radical methods due to these challenges . Furthermore, the escalating demand for advanced-performance materials calls for more stringent controls on the synthesis of polymers, specifically targeted at the main chain structure of the polymer, to influence their physical properties accurately . While monomer design presents a viable pathway to address these issues, recent research has predominantly honed in on established vinyl monomers, to a large extent neglecting the construction of new polymeric monomers and the exploration of novel polymerization models .