To further analyze the contributions to the DOS of rhombohedral Prussian white, the orbital-decomposed DOSs of the Fe-d states for high-spin and low-spin Fe are presented in of the minority spin direction. All majority spin states shift down in energy, therefore being far from the Fermi level. All states shown from -6 eV to 0 eV do not contain contributions from high spin Fe either. Conversely, it can be observed that the state lying on the Fermi energy is purely constructed from the high spin Fe orbitals. They can be attributed to the a 1g -states formed during the rhombohedral phase transition. Also visible are the still unoccupied e g -states at around 1.8 eV above the Fermi energy. The minority spin e g -states are again shifted out of frame, this time to values higher than 6 eV.