Visible light-driven photoredox catalyzed has gained numerous attention as a powerful and energy-efficient method for chemical synthesis. The central of concept is rely on oxidation addition with specific radicals from precursors and trapped by transition metal complex such as nickel, 2 palladium, cooper 4 and so on. After elimination by reduction, the desired crosscoupling product is generated and the metal complex is reduced through the photocatalytic cycle for next process. However, the whole process is highly depended on homogeneous photoresponse catalysts, such as ruthenium, iridium or organic dyes 8 in numerous reports. It is a pity that these homogeneous photocatalysts are also accompanied by weaknesses such as expensive expenses, separation from products, unable to recycle which limits the actual industrialized application to a certain extent.