Owing to the facile synthesis of this new system, and the ubiquity of the pyrazine moiety in state-ofthe-art TADF materials across the electromagnetic spectrum from the deep blue to the near-infrared (NIR), this concept has great promise for generality. NIR TADF emitters in particular are poised to benefit from the enhancement in radiative transitions offered by homoconjugation and will be explored in future work.