Periodically, our knowledge of chemistry is enriched with new transformations that provide significant breakthroughs by enabling new synthetic strategies. Such examples in recent years include olefins metathesis as well as C-C and C-N coupling reactions , among the most obvious examples. While these reactions undoubtedly had very significant impacts on the development of much cleaner and efficient chemical synthesis strategies, the early days of all new transformations are invariably challenging, with very slow and protracted paths from the initial discoveries to the demonstrations of broad substrate applicability and robustness, that are expected of industrial catalytic processes. Today, there exist a number of fairly recently (re)discovered transformations, that are of potential high industrial significance, and where one can observe the same problem of a lack of robustness. Thus, any approach that may speed-up the transition from a discovery of a new transformation to it becoming a robust synthetic strategy, is highly desired.