Because of the subjective character of UL-94V tests, as discussed above and the complexity in the use of combustion calorimetric methods, our main aim of this study was to develop and confirm if such simple single point TGA measurements, that are most frequently used in flame retardant studies, could be used to determine not only the thermal stability of polymer materials and the remaining residues (char) but also if we could determine the surface ignition temperature (Tign) and kinetic parameters such as Ea and A. This will enable us to use simple TGA technique to quantitatively estimate and predict the correlation between thermal degradation of polymers and their fire behavior, which is one of the main controlling parameters for fire retardancy as discussed above as an alternative to use expensive instruments such as Cone Calorimeter (CC) and combustion calorimeters (MCC, MFC).