The 1 H, F and 11 B NMR spectra of 1-Ln, 3-YbEu and 3-DyYb as recorded in d6-benzene exhibit significant pseudocontact shifts (PCS) from the anisotropic paramagnetic Ln metal centres, causing the resonances to move significantly outside the typical ranges for the ligands. Despite the complex system with up to three different paramagnets, the spectra are fully assignable (see ESI Table ). In fact, the PCS from the Tp-bound paramagnetic Ln 3+ significantly aid assignment of the data.