Having established optimized conditions, we embarked on exploring the sulfinylation of the light alkane homologous series (C1-C4) as depicted in Scheme 1. Within this study, we selected various electrophilic traps for the intermediate sulfinic acid, including functionally diverse alkyl bromides such as benzyl, allyl bromide, and α-bromo amide. This series encompasses compounds like benzyl bromide, bromomethyl pyridine, geranyl bromide, as well as structurally intriguing substrates such as tryptophan and quinoline derivatives, each bearing a diverse array of functional groups.