Introduction: Homometallic compounds of Fe III have played a central role in the history of molecular magnetism, proving key to the development and understanding of an array of physical properties. For example, the study of oxo-bridged [Fe2] dimers allowed the development of detailed magnetostructural correlations that can be translated to larger species, antiferromagnetically coupled [Fe6-12] ferric wheels revealed interesting quantum size effects manifested in stepped magnetisation, [Fe17/19] was an early example of a molecule possessing a very large spin ground state, [Fe8] was the second known example of a Single-Molecule Magnet, [Fe14] was an early example of a compound displaying an enhanced magnetocaloric effect, and cages ranging in nuclearity from [Fe13] to [Fe34] have structures that conform to Archimedean and Platonic solids which aid understanding of the selfassembly of molecular oxides en route to mineral phases. High symmetry clusters are of particular interest as they may possess geometric spin frustration, a phenomenon whose definition has evolved from its strict initial derivation. Frustration can lead to some unusual and potentially useful lowtemperature physics, a beautiful example being the [Mo72Fe30] icosidodecahedron which shows anomalous magnetisation behaviour in an applied magnetic field. One synthetic methodology proven to enable the construction of such species is hydro/solvothermal synthesis, which typically exploits superheating reaction solutions under autogenous pressure. In the chemistry of polynuclear cluster compounds of paramagnetic transition metal ions, the temperature regimes employed (which are typically below 250 °C) can lead to enhanced solubility, reduced solvent viscosity and increased reagent diffusion. The result is often the synthesis of metastable kinetic products of high symmetry, with slow cooling enabling pristine crystal growth directly from the reaction mixture. Results and Discussion: The solvothermal reaction of FeCl3, Fe(ClO4)3•6H2O and teaH3 (triethanolamine) in a basic MeOH solution results in the formation of red/brown crystals upon cooling (see the experimental section in the SI for full details). Crystals of [Fe III 15O6(tea)8Cl6](ClO4)3 (1, Fig. , S1; Table ) were found to be in a trigonal crystal system, and structure solution was performed in the R-3 space group (see the crystallographic section in the SI for full details). The metallic skeleton of 1 describes a centred tetrakis hexahedron (Fig. ), a Catalan solid which is the dual of the truncated octahedron, an Archimedean solid. The central Fe ion (Fe4) is octahedral, being bonded to six oxide ions ([FeO6]; O5 and symmetry equivalent; Fe-O5 = 1.999 Å). O5 bridges to two further Fe ions in the peripheral shell (O5-Fe1 = 1.925 Å; O5-Fe2 = 2.025 Å) and is thus three coordinate and trigonal planar. There is a fourth, longer contact to Fe3 (O5-Fe3 = 2.492 Å), so O5 may be considered pseudotetrahedral if one considers this interaction significant (Fig. , S2-3). The outer shell is decorated with a combination of halide and tea 3-ions. The former are monodentate, coordinated to Fe2 (Fe2-Cl, 2.315 Å). The latter are tetradentate, chelating either Fe1 or Fe3 with each O-atom µ-bridging to a second Fe ion (Fe2). Thus Fe1 is five-coordinate ([FeO4N]) and trigonal pyramidal, Fe2 is six-coordinate ([FeO5Cl)] and octahedral, and Fe3 is four coordinate([FeO3N]) and trigonal prismatic, or seven coordinate ([FeO6N)] and a capped octahedron if the Fe-O5 bonds are included (Fig. ). A review of the Cambridge Structural Database (CSD) for Fe-O bond lengths in any Fe-O-Fe moiety produces 3378 different compounds and 12361 bond lengths ranging from a minimum value of 1.651 Å to a maximum value of 2.629 Å, as depicted in the histogram in Fig. . The [Fe15O30] core displays a breadth of different Fe-O-Fe angles, ranging from a minimum of 86.67° (Fe4-O5-Fe3) to a maximum of 140.82° (Fe4-O5-Fe2). Angles from the central Fe4 ion to the peripheral Fe1 and Fe2 ions via the O5 oxide are 140.82° and 117.41°, while those connecting the outer Fe1, Fe2 and Fe3 ions together via the oxides and alkoxides range between 86.7-129.39° (Table ). The closest intermolecular interactions are between the monodentate Cl ions on Fe2 and the C-atoms of the tea 3-ligands on neighbouring molecules (Cl1...C7, ~3.43 Å), and between the perchlorate O-atoms and the C-atoms of the tea 3- ligands (O6...C4, ~3.43 Å; Fig. ). This results in an aesthetically pleasing honeycomb-like network when viewed down the c-axis of the cell. A search of the CSD reveals that just three [Fe15] clusters have been reported previously, with 1 being the first example of a [centred] tetrakis hexahedron. Perhaps more surprisingly, given the widespread use of the H3tea ligand in 3d coordination chemistry, there are very few homometallic Fe III clusters of this ligand deposited. Indeed, they are limited to [Fe5], [Fe6] wheels (both unsupported and supported ), [Fe7], [Fe8] (including an [Fe8] cluster self-assembled into a [Fe64] cage ), and [Fe10]. Heterometallic Fe-Ln species are far more prevalent. The direct-current (dc) molar magnetic susceptibility, χ, of a polycrystalline sample of 1 was measured in an applied magnetic field, B, of 0.1 T, over the 2-300 K temperature, T, range. The results are plotted in Fig. in the form of χT product, where χ = M / B with M the magnetisation. At room temperature, the χT product is 28.67 emu K mol -1 , much lower than the Curie constant expected for fifteen uncorrelated S = 5/2 centres (65.625 emu K mol -1 ) with g = 2. On lowering the temperature, the χT product decreases rapidly, reaching a value of 11.05 emu K mol -1 ) at T = 10 K, before decreasing even more abruptly to a value of 7.74 emu K mol -1 at T = 2 K. The data suggest a ground state spin of S ≈ 9/2 (compare arrows in Fig 3). Variable-temperature-variable-field (VTVB) dc magnetisation measurements in the temperature range 2-6 K and in applied magnetic fields up to 7 T reach a maximum value of just M = 8.35 µB (Fig. ), well below the upper limit expected for a ferromagnetically coupled system (M = 75 µB for g = 2). This behaviour is clearly indicative of relatively strong antiferromagnetic interactions between the Fe III ions, consistent with the Fe-O distances and Fe-O-Fe angles present. It is computationally impossible to quantitatively analyse the magnetic data of a molecule containing 15 x S = 5/2 spins via conventional matrix diagonalisation techniques since the dimension of the Hilbert space is 470,184,984,576, and thus we turn to the finite-temperature Lanczos method. Even here, several assumptions must be made. (A) Despite the presence of eight independent exchange interactions, we reduce this to four based on similar Fe-O bond lengths and Fe-O-Fe angles (Fig. ). These are: Jcube along edges of the cube; Jpyramid along the four edges from the top of each pyramid to the respective base square of cube; Jc,cube from central Fe inside the cube to vertices of the cube; and Jc,pyramid from central Fe ion to the tops of pyramids. (B) We simulate the data using isotropic S = 3/2 spins rather than isotropic S = 5/2 spins and scale the resulting data accordingly. The corresponding isotropic spin-Hamiltonian is: A rather good theoretical representation of the data (Fig. ) was obtained with Jcube = -17.4 cm -1 , Jpyramid = -17.4 cm -1 , Jc,cube = -17.4 cm -1 and Jc,pyramid = -3.5 cm -1 , scaled by 9/25 to meet a Hamiltonian with spins S = 5/2. Such a scaling approach can only provide "an order of magnitude" estimate of the exchange constants, rather than a precise derivation, albeit the numbers are entirely consistent with experimentally and computationally derived magneto-structural correlations for O-bridged Fe III clusters. The exchange constants are indicative of a highly frustrated system, as one might expect from the structural symmetry. Heat capacity, C, measurements were collected between ~0.3 K and 30 K, for B = 0, 3 and 7 T (Fig. ). Below ~3 K, the heat capacity depends significantly on B, the zero-field C showing essentially flat behaviour and reaching values close to ~0.5R, where R is the gas constant. This behaviour is similar to that recently reported for an [Fe III 10Gd wheel and consistent with the presence of a large density of low-lying states, likely resulting from competing antiferromagnetic interactions.