Electrochemical reduction of TEA captured atmospheric CO2 at -0.7 V vs. RHE with CoPcNH2@MWCNT cathode produced negligible CO due to very low captured CO2 availability. Contrarily, CPE of the atmospheric CO2 captured in NaOH/EG solution at -1.85 V vs Fc/Fc + produced CO with 2.9±0.3% FE, showing electrochemical conversion of direct air captured CO2 (Figure ). We note that despite a modest captured CO2 concentration (0.73 M), the FECO is lower compared to CO2 captured from a pure stream (FECO ~20%). This is likely due to the incomplete CO2 capture (owing to equilibrium shift in ultra-low CO2 concentration as per Le Chatelier's principle), which leads to higher alkalinity of the post-capture medium and a more challenging conversion process (supplemental discussion, Figure ). Solar-driven PEC reduction of captured atmospheric CO2 in TEA solution with PVK|CoPcNH2@MWCNT photocathode did not produce any CO. In contrast, the organic NaOH/EG medium was more suitable for the solar-driven conversion of atmospheric CO2. PEC experiment with CO2 captured in glycolic NaOH solution after DAC produced 2.1±0.5 mol cm -2 CO after 110 h under 1 sun irradiation with no applied voltage (Figures ). The CO production rate remained consistent over the reaction period with final FECO and TONCO reaching 2.3±0.4% and 141±38, respectively (Figure ). A control experiment without DAC produced tiny amount of CO due to epoxy degradation in EG medium, that was subtracted for all atmospheric CO2 conversion calculations (Figure ). HPLC analysis of the anolyte showed 61.6±8.3 mol cm -2 GA formation (FEGA 85.7±2.2%) that indicates the completion of overall PEC process. While further optimization is necessary to improve the overall CO formation efficiency, this proof-of-concept study demonstrates the viability of direct long-term solar-driven reduction of atmospheric CO2 to CO following DAC, using perovskite-PEC systems. Future work in this regard would benefit from the use of solar cells with higher VOC to match the stringent thermodynamic demands of air captured CO2 conversion.