Recognizing the value of adhesion mapping by AFM for the observation of alcohol group termination in the 'down-chain' orientation (Figure ), we acquired further AFM data for the binary mixtures in the 'down-chain' orientation. Figure presents height and adhesion mapping by AFM of 0%, 30%, 50%, and 100% C30H61OH prepared by drop-casting on mica as well as matched low-angle ADF-STEM images from SED prepared by drop-casting onto continuous carbon TEM grids. For 0% and 30% C30H61OH, the images all show faceted crystals with terraces (height images) with consistent adhesion. The low-angle ADF-STEM images exhibit some bend contour contrast but otherwise show smoothly varying contrast within micron-sized regions. At 50%, both AFM and low-angle ADF-STEM highlight pronounced differences: The AFM height image shows a much more substantial variation in height at the sub-micrometer length scale. As with the pure alcohol, the adhesion values at 50% C30H61OH are bimodal, seen more clearly in Figure . The adhesion image likewise exhibits sub-micrometer variations, and contrast variations with irregular contours at similar length scales were also recorded in low-angle ADF-STEM. At 100% C30H61OH, the AFM height once again was comprised of terraces with the characteristic bimodal adhesion variation between steps. The low-angle ADF-STEM image for C30H61OH also shows faceted crystals with micrometre-scale limited intensity variation within plates.