Encouraged by the efficient and highly general C-H chlorination, we became interested in investigating if an analogous acylation/bromination approach would be possible. To our delight, both aromatic and heteroaromatic amines was found to react effortlessly with various acid bromides, leading to the formation of the corresponding C-H brominated products in good to excellent yields (Scheme 5). In contrast to chlorination, the bromination reaction needs a higher current of 15 mA in order to give fast conversions. When the para position of the amine was not occupied, the corresponding 4-Br products 117-124 could be synthesized in 62-95% yields by employing either alkyl or aromatic acid bromides. In the case of aromatic amine partners lacking accessible para-positions, we saw similar regioselectivity outcomes as for the corresponding C-H chlorination reactions, and consequently the positions directly adjacent to the amide group were brominated in high selectivity instead. For example, 2-aminonaphthalene reacted in high efficiency with a variety of acid bromides to give the 2-brominated products 125-129 in 81-91% yield. It is worth noting that heterocyclic amines also reacted effortlessly with propionyl bromide to produce products 130-132 in 73-97% yield. Also, by increasing the equivalents of the acid bromide partner to 2 equiv. and extending the reaction time to 5-6 h, it proved possible to direct this electrochemical cascade protocol towards the dibrominated products, as demonstrated by the reactions giving products 133-137 in 59-90% yield.