Materials engineering and catalysis are known as central sciences, which can deeply contribute to the technological development of our nations, and as well as ensure the environmental protection and cleaning from both organic and inorganic contaminants. So, the design and synthesis of powerfully performance materials are required for many technologies, such as in conversion of higher hydrocarbons to lower hydrocarbon as methane (CH4) or to carbon monoxide (CO/CO2), methanol (CH3OH) or even to hydrogen (H2) . Also, performance hybrid materials are also so wanted for recycling waste products such harmless (CO2), and harmful (CO/NOx) to value-added products, because it should be considered as an alternative fuels, which limit the use of feedstock fuels from natural gas reforming or higher hydrocarbons cracking . Hybrid materials elaborations and characterizations allow also the detection and quantification of organic compound in our food products, to limit our exposure in some diseases such as cancer, diabetes, and so fourth . In fact, in the past few decades, many engineering routes have been suggested and and thoroughly discussed in order to find superb materials for considerable technological applications. So that, these ways include : the exploration of metal oxides materials such Alumina, ceria, silica,Manganese oxides , they can be used as a matrix of metallic nanoparticles or as an active catalyst. The development and characterization of many forms of carbons such as nanotubes, nanofibers, polymers, heteroatoms-incorporated carbons, black carbons, and so on, have severely discussed to boost the performance of composite materials . The use of cost-effective metals such as transition cobalt, zinc, nickel, copper, molybdenum hybrid materials, and so fourth have been extensively considered in both catalysis and environmental technologies. Porous materials, such as intelligent as zeolite materials recently are fully regarded as powerfully active catalysts in a wide range of catalysis technologies. Indeed, as explained in Zhang-a's work , It covering a deep range of pore sizes starting from micropores (D < 2 nm), mesopores (2 < D < 50 nm) to macropores ( D > 50 nm), so zeolite materials are versatile and essential in applications such as gas separators, ion exchangers technology, catalysts, for energy holding, in sensor, and beyond. Also, the use of zeolites on multicomponent reactions is introduced in Lima's work . So, it is notified that an increased materials features such as efficiency, catalytic selectivity and activity, along with their beneficial environmental benign, elaboration routes, and material reusability, it gets so distinct the union of heterogeneous catalysis and MCRs exhibits an open framework of opportunities. Moreover, Wang's report showed the synthesis and uses of core-shell, hollow, yolk-shell multifunctional architecture zeolites materials. In fact, the authors deeply discussed the new design strategies for large zeolite-related <<core-shell concept>> and costly affiliated with their preparation and the need for deeper research into their uses exhibit significant challenges. Another important class of materials is also introduced due to their advanced properties such as magnetic (Neodymium), lighting (Lanthanum), Catalytic at high temperature (Cerium/Lanthanum), component of a exceptional sort of glass (Praseodymium), visual displays in devices (Yttrium, terbium, europium), and (Gadolinium) is used in MRI, and X-ray scanning method, and as well as television screens. In addition, as shown here, this class of elements named as rare-earth materials might possess advanced features which would be exploitable for future catalysis/technological composite materials engineering. Therefore, in this review article one focus is dedicated to the novel development and application of hybrid materials made of rare-earth in union with other materials.