In this work, we developed an automated high-throughput platform to screen the conductivity of neat RTILs (details provided in Table of the Supporting Information) and the mixture of RTILs and EG. For this purpose, we designed an electrode holder cell set for a robotic hand whose maneuvering was controlled by custom-built software for measuring the solution resistance. The measured resistance was then used to calculate the conductivity of that solution. A novel theoretical framework that relates ion dissociation with measured conductivity and concentration-dependent ion mobility has also been developed. The variation of ion dissociation with cation and anion type and their concentrations shed light on the mechanism of conductivity in the mixture of RTILs and EG. Finally, the migration-assisted moisture gradient (MAMG) process for carbon capture was tested as a potential application of enhanced conductivity in an ionic liquid and EG mixture.