reported that the electrical conductance of phenothiazine based radical cation is enhanced by upto 200 times as compared to neutral state. From STM measurements, Matsuda et al. observed that iminonitroxide radical substituted wires has 3.2 times larger conductance than the methyl-substituted reference. A recent report by Vezzoli et al. also evidenced a similar enhancement of conductance for oxoverdazyl based radical with almost one order of magnitude than its closed shell counterpart. The underlying mechanism behind the radicalassisted enhanced conductivity is outlined in an early theoretical report by Stellacci et al. In typical closed shell electronic configurations, electrons are paired in delocalized molecular orbitals (MO) that are either completely filled or empty. The energy difference between the frontier MOs, i.e., the highest occupied (HOMO) and the lowest unoccupied (LUMO) orbital derives the electrical conductance of molecular junction. Contrastingly, a radical moiety is characterized by an unpaired electron residing in non-bonding singly occupied MO (SOMO) lying at intermediate energies between HOMO and LUMO. Due to its single occupation, the SOMO of the radical has a tendency to gain or lose an electron and is thus efficiently pinned near the Fermi energy of the electrode. This eventually results in sharp transport resonances near Fermi energy in the transmission function imparting enhanced conductance.