To demonstrate the synthetic potential of the method, this enantioselective electrocatalysis was then tested using a continuous flow electrochemical reactor avoiding the use of a supporting electrolyte. Hence, we observed that the continuous flow setup allowed to provide the desired product 3 in high yield with excellent enantioselectivity after minor adjustments of the reaction parameters. To compare with the results obtained in a batch reactor, representative substrates were explored in continuous flow (Scheme 6). The reactions proceeded efficiently to give the C-N axially chiral products with high levels of enantiocontrol. To further demonstrate the practicality of the method, a decagram scale electrolysis (27 mmol) was performed, using the same flow electrochemical reactor (Scheme 7A). A higher current (10 mA) and a higher concentration (0.2 M) thereby enabled the formation of the product 3 in 68% yield with 99% ee. As shown in Scheme 7B, synthetic transformation of product 3 was also conducted. The atropoisomer 3 could be chemoselectively reduced to the tertiary phosphine compound 47 in 72% yield with 94% ee, which might be applied as axially chiral P,N-ligand. -0.