-600 mVSHE, the current hysteresis of the original scans is not pseudocapacitive anymore leading to the erroneous determination of capacitance. While this non-capacitive hysteresis is consistent in all measurements, we will ignore it in this study, its contribution not influencing the characteristic H-upd features. Fig. reflects the situation where the molecular hydrogen and hydroxyl ion limiting currents are nearly equal. This leads to the H-upd resembling the acidic pattern in the forward direction, and the alkaline pattern in the backward direction. We call the pH where the two limiting currents are equal the "anion switch pH", a term whose meaning will become apparent later. Additionally, the O-upd, suppressed by chloride in acidic, starts to appear, which will be shortly explained. The fully developed alkaline CV pattern of the H-upd is shown in Fig. . One immediately notices a third peak (counting always from positive to negative potentials) around the OCP value, whose appearance is masked by the HER in the standard H-upd measurements. The O-upd capacitance cannot be trusted as the HOR background correction, at hydrogen partial pressures > 100mbar, is inaccurate at these potentials due to the negative effect of the O-upd on the HOR.