The presented results for chosen groups of organoboron compounds suggest that all electrochemically tested oxaboroles[( ),( ), ( )], dibenzoboronines [( ), ( ), ( )], and triarylboranes [( ), (19)] can potentially be used as fluoride ionophores. For those compounds an increase in the ion transfer current was observed with increasing fluoride ion concentration. Only compound (12) allowed for observation of a single ion-transfer process registered in the electrochemical window. All other compounds [( ), ( ), ( ), ( ), ( ), ( ), (19)] showed more complex response, with several ion transfer processes taking place, some independent of the fluoride concentration. More in depth analysis is needed in this case to fully understand the processes taking place in those systems, including formation of complexes of different stoichiometry, possible transfer of the ionophore molecules to the aqueous phase, and adsorption of compounds or ion-pairs at the interface.