The emergence of chiral perovskites as an exciting field of research stems from both their inherent structural complexity and their remarkable potential for innovative technological applications. By introducing chirality into the perovskite framework, researchers have unlocked novel functionalities, such as circular dichroism (CD), circularly polarized luminescence (CPL), second harmonic generation (SHG), and topological quantum states. In addition, the potential applications of chiral perovskites extend well beyond conventional optoelectronics. Their unique properties may also find use in spintronics, quantum computing, and emerging fields such as topological photonics. Understanding the underlying principles of chiral perovskites and their interactions with external stimuli will be vital in harnessing their full potential for future technologies. To date, all the chiral perovskites reported are based on the few commercially available chiral amines, with methylbenzylamine, MBA, and its halogenated derivatives, as the most widely used ligands. Clearly, in order to enhance the understanding of chirality in metal halide perovskite, unraveling unexplored properties, advance the optoelectronic devices including chiral perovskites, as well as to gain a deeper comprehension of the chirality transfer mechanism and structure-property correlations in this emerging area, it is important to extend the library of available ligands. Such extension should also involve the design of multi-functional ligands where, in addition to the amine moiety, other functional groups are present. This is of particular interest in the field of metal halide perovskites where the structural topology, and in turn the optoelectronic properties, are strongly connected to the ability of the organic cation of hydrogen bonding to the inorganic framework. Therefore, the design and use of chiral bifunctional ligands, not yet reported in the current literature, could widen the scope of chiral perovskite engineering and helping in shedding light on the role of intermolecular interactions on structural motifs and functional properties.