The new NMR peak at 5.5-6.2 (amino acid and monomer Figure ) clearly confirms the formation of a comonomer of alanine acrylamide. The IR peak of alanine, monomer (Figure ) and it's polymer copolymers exhibited characteristic absorption band corresponding to PAAla segment (at 1725 and 1650 cm -1 corresponding to the C=O stretching vibration of the amide functionalities) and alanine (1151 cm -1 ), attributed to the stretching vibrations C-N functionality, (3100-3300, cm -1 assigned to the ester N-H stretching, the broad spectra of 3400 cm -1 attributed to the OH vibration. A range of homopolymerization syntheses carried out just varying monomer/initiator.