Again, we computed all γ cleave for both complexes. Note, that for these reactions, the asso-ciation barrier was of interest, which is why the fully dissociated complex has been set to 0 kJ mol -1 . The determined Gibbs free association curves and barriers for PdL 2 are depicted in Figure . With our methodology, we obtain dissociation barriers of PdL 2 between 48.9 and 18.0 kJ mol , γ cleave values between 0.001 and 0.05, while for γ cleave =0.1, no barrier was found.