Thiocarbohydrazide 8 (0.212 g, 2 mmol) was added to a solution of cyanoacetamide derivative 1 (0.362 g, 2 mmol) in ethanol (20 ml). After being refluxed for 5 hours, the reaction mixture was allowed to cool to atmospheric temperature. The created solid was extracted using a filter, rinsed with ethanol, and finally dried. triazole-3-thione , was attained by recrystallization from a suitable chemical solvent.