The time-temperature dependence of bulk relaxation, such as macroscopic viscous flow and local segmental motion , is well-studied for a wide range of polymers. However, it is not clear whether the relaxation process of the nanoscopic structures and mechanical properties on the interfaces also exhibit the time-temperature dependence similar to the bulk relaxation. Therefore, analyzing and determining the temperature dependence of molecular-scale relaxation phenomena on the interface are essential for revealing the mechanisms of relaxation processes both on the interface and in bulk.