The electronic structure of these metallocorroles has been already studied by DFT so we will refrain from the discussion of the electronic structure from DFT. The Fe[TPC]Cl is supported to contain the non-innocent corrole 2-• antiferromagnetically coupled to S=3/2 Fe (III) center by magnetic susceptibility measurements and DFT calculations. Similarly, the Fe[TPC]Ph complex has been extensively characterized employing a combination of spectroscopic techniques, X-ray crystallography, and DFT calculations. These investigations suggest the presence of a low-spin iron species coordinated to a closed-shell corrolate trianion and a phenyl monoanion. From the DFT spin-density picture, it is inferred that the complex exhibits a mixture of Fe(IV) and Fe(III) oxidation states, as illustrated by the representation: