Commonly, electronic excitation energies, transition electronic and magnetic dipoles are calculated by the electronic structure approaches like TD-DFT, and pure electronic absorption and CD spectra are thus estimated from Fermi's golden rule. These calculations, however, are in electronic adiabatic states and the characters of electronic states are hard to be distinguished. In addition, the contribution of vibrational states cannot be straightforwardly incorporated. Here, we start from the parameterized Hamiltonian in the diabatic representation to obviously describe the LE states and CT states. The electronic and vibrational properties are described by the Hamiltonian