It is worth noting that although Fig. (b) focuses on the ω c values for which there is a maximum suppression, there is nevertheless a clear effect of the cavity on the isomerization probability. In other words, for a specific value of η there exists a ω c = ωc for which cavitymediated modulation of the ⟨P iso ⟩ can occur. However, in contrast to the usual VSC experiments, ωc may not be resonant with a specific molecular transition in case of single molecule models with only the reactive mode coupled to the cavity. This observation is seemingly at odds with the typical resonance arguments that are invoked while interpreting the VSC results. Nevertheless, Fig. ) does indicate that substantial modulation of ⟨P iso ⟩ occurs in the vicinity of ω c ≈ ω 10 .