According to the importance of energy in the world, in this study it was tried to introduce an important class of materials with potentially be used in energy storage devices. One of the devices which has an important role in electrical energy storage are capacitors, where they store energy in the separated electrical double layers in electrodes and/or via reduction/oxidation reactions. Electrical conductivity in the electrodes is known as a crucial property for electrodes that are used in many studies. Various materials such as graphene, carbon nanotube, metal oxides and conductive polymers have been employed as electrodes in supercapacitors. Another plausible way to improve the capacitance is the introduction of reduction and oxidation ability to the electrode material, which is called pseudo-capacitance. Naturally conductive polymers like polyaniline can reversibly store electrons in redox reaction due to different oxidation states. In this study, our purpose is to produce highly conductive and flexible substrate as a great candidate to be used in flexible electronics and smart wearables. This in-built conductivity can be coupled with environmental stimulants where the textile substrate here provides high surface area. various conductive polymers, like polythiophene, polypyrrole and polyaniline and their electrochemical properties have been studied thoroughly in past decades. polyaniline arguably has the most affordable monomer price and benefits from various facile and scalable synthesis methods among the above-mentioned polymers. oxidation polymerization of aniline has studied by stejskalet al. at different acidity and strength of oxidant. . Kaner et al. proposed rapid shaking at relatively highly acidic medium (1 M hydrochloric acid) in presence of strong oxidant to achieve nanofiber structure disperse in water. . Nadeeka et al. showed molarity of acid plays important role in optimized polymerization condition. They got 1K ohm /cm 2 at 3 M HCl . Herein, in-situ polymerization and covering of polyaniline at 1 M hydrochloric acid aqueous solution with 1:4 ratio of monomer to initiator (Ammonium per sulphate) resulted in fabrics with much higher conductivity than comparable works like bowman et al. where they got 72 S/cm from high molecular weight polyaniline . The substrate, either the textile or the fibres were treated with 6 M sodium chloride prior to polymerization at elevated temperature.