Our approach integrates (1) aromaticity of the ligand (NICS), ( ) electrostatic (NBO), and (3) backdonation from the metal center to the click ligand (normal mode frequency) mechanisms to elucidate the diverse stabilization phenomena observed across various compounds. To evaluate the aromaticity based on the magnetic properties of the compound, the nucleus-independent chemical shifts (NICS) were computed. Herein, a more negative value is connected to higher aromaticity of the respective moiety and thus increased stabilization effects. The lowest overall shifts among the investigated complexes for the triazole, pyrazine, and phenyl moieties are observed for the gold complex 20 (Figure ). The same behavior can be noticed when calculating the out-of-plane NICSzz values, a more accurate variant for most applications. This indicates the highest stability for complex 20 among the investigated 1,2,3-triazolylquinoxaline complexes. The NICS values also help to explain why a monodentate complexation of silver tetrafluoroborate with the ligand in bridging conformation is observed for the heteroleptic silver complex 25. The NICSzz values for a hypothetical chelating complexation are higher than for the observed complexation in the bridging conformation, suggesting a lower stability for the chelating complexation (see Table , Supporting Information). The same trend is present when switching the ligand from 5a to 5c; despite the higher steric hindrance of the phenyl residue in the bridging conformation, the monodentate complexation is still assumed to occur in the silver complex. Both 5a and 5c should be aromatic according to the Hückel rule (molecule 5c has 22  electrons and 5a has 14  electrons, both corresponding to 4n+2 rule) and according to the NICS, but NICS alone is usually inadequate for assessing aromaticity due to its locality. Visualizing ring currents reveals the aromatic nature of molecules due to delocalized π electrons, aiding in the identification of aromatic systems. Utilizing CTOCD (continuous transformation of origin of current density) method for gauge selection it is possible to visually inspect the non-local nature of the ring current as well as have structural information. The currents were broken down into currents originating from  manifold and currents from the remaining populated orbitals. When inspecting the molecular current maps (see Figures and, Supporting Information), it was found that the ring current is diatropic mostly from the  orbitals and consistency with NICS was verified.