Inspired by the excellent performance of complex A in the hydroboration of C≡N bonds, we next examined its application in Nheteroarene hydroboration. It was found that a higher catalytic loading of A was required in comparison to the nitriles (5 mol%), and longer reaction times of 1-48 hours. Pyridine and its derivatives gave excellent isolated yields, with moderate selectivity, pyridine itself furnished the 1,4-hydroborated dearomatized product in 99% yield within 1 hour. When the N-heteroarenes contained substituents in the 4position, 1,2-dearomatization products were favored 5b' and 5c'. Comparable yields were obtained irrespective of the electronic properties of the para-substituent, with excellent yields for both t-butyl and dimethylamine