Another noticeable difference between the chair and boat isomers arises in the deshielded group (δC > 45 ppm), particularly in the (C1, C2) and (C3, C4) pairs of carbons. In the chair configuration, the ΔδC (difference between the δC's) between C1(C2) and C3(C4) is as large as 8.28 ppm, indicating a more pronounced distinction in their chemical environments. However, in the boat configuration, this difference narrows to 5.53 ppm, suggesting that the chemical environments of these carbons become less different. This variation of δC in the boat isomer can be attributed to structural changes that reduce the electronic and spatial differences between these carbon pairs. The through-space interactions between hydrogens, particularly those associated with C5-H(15) ••• H(26)-C10, contribute to the changes in δC in the boat configuration. These interactions influence the overall electron distribution around these carbons, bringing the chemical environments of C1-C4 closer together in the boat form comparing to the chair form.