WS22 is a comprehensive database focusing on ten organic molecules, varying in size and complexity, with up to 22 atoms. It includes 1.18 million geometries, encompassing both equilibrium and non-equilibrium states. These geometries are meticulously sampled from specific distributions and further augmented with interpolated structures, resulting in a highly diverse data set. For each geometry, WS22 provides various QM properties, such as potential energies, forces, dipole moments, and electronic energies.