As in our previous report on ag [TPrA][M(dca)3] samples, opaque, glass-like pieces were observed after cooling the melts from their offset of melting near Td (Insets of Fig. ), and found to be amorphous by X-ray diffraction (Figs. and). The glasses, in keeping with existing nomenclature on hybrid glasses, are thus termed ag [TAlA][M(dca)3] (ag: melt-quenched amorphous).