These commutator equations are solved via a Davidson iterative diagonalization procedure. Additional theoretical and technical aspects of IP-EOM-CC can be found elsewhere. In this study, we employ the IP-EOM-CCSD* method, which truncates the cluster and eigenvector operators after the second term and then adds the effects of triples perturbatively, which are essential for capturing high orbital-relaxation effects. Several perturbative and iterative methods for improving on IP-EOM-CCSD have been reported in the literature. In IP-EOM-CCSD*, the evaluation of the leading term has the same cost scaling as that of CCSD and accuracy comparable to EOM-CCSDT. We have used the IP-EOM-CCSD and IP-EOM-CCSD* implementations in PySCF and extended them to core-ionization calculations with the core-valence separation approach (CVS). In the CVS-EOM-CC approach, as reported by Coriani and coworkers, the valence parts of the left and right eigenvectors are projected out at each Davidson iteration.