With this in mind, therefore, the purpose of the current study is to present detailed dynamical insights of such hybrid electrolytic systems, and their mixtures with ethylene carbonate (EC) and dimethyl carbonate (DMC), which are potential candidates for next generation LIB electrolytes. We report on the molecular level study of the self-diffusion coefficients, molar conductivity and transference numbers, and discuss on the influence of adding carbonate cosolvents, and explore the nature of these molecular transport properties. The article is structured as follows. First, we give a brief overview over the computational methods employed in this work. This is followed by the discussion of the mean square displacement of the ions (MSD). The details of self-diffusion coefficients (D s ), molar conductivity (ᴧ), and transference numbers are discussed by analyzing trajectories, and how this behavior is influenced by the EC/DMC content. We end this article with conclusions.