Bromotriazine (1)was obtained in quantitative yield following a Lewis acid-catalyzed cyclization of 4-bromobenzoyl chloride and benzonitrile using antimony pentachloride in DCM, followed by the addition of 35% ammonia. The triazine is then coupled to DMAC through a Buchwald-Hartwig coupling in 40% yield. 3 DMAC-TRZ (2) was then quantitatively dibrominated using 2.2 equivalents of NBS in THF, shielded from light. Finally, the DMAC-TRZ derivatives were accessed via a Suzuki-Miyaura cross-coupling of 3 with the corresponding aryl-boronic acid, the reaction was carried out in a pressure vessel at 110 °C for 48 h to improved the yield of the coupled products.