Increasing the НОМЕС´s contribution is achieved: -by using a catalyst Q with a lower value of the standard potential E 0 (absolute value); -by decreasing the electrode potential E; -by increasing the concentration of catalyst; -by a special switch-on-and-off electrolysis mode (intermittent generation of the active form of the catalyst Q .-,"pure" НОМЕС process). The NELTO theory should be based on the solution of diffusion-kinetic equations for each concrete process and specific experimental conditions (kinetics of individual process stages, concentrations, solution viscosity, diffusion coefficients, etc.), the result is summarized as x = f (L) (1), where x is the ratio of quantities of the "indicator" products of electrolysis and L is the distance from the electrode surface. To find kinetic data here it can be useful to exploit the numerical -analytical method (NAMBE) developed jointly with Yuri Bendersky for a number of variants, including partial deactivation of catalyst Q . Comparison (1) with the collective characteristic X = F (L) (2) allows to establish the connection of molecular reactivity with the characteristics of the near-electrode zone. As mentioned, the discovered molecular effects may be related to the hypothetical superviscosity of the nearelectrode medium. A suitable tool to estimate the boundary viscosity is AFM, and developing the classic techniques we designed a n elect r ochemica l EC-AFM, which enables us to control the potentials both of the AFM sample and the tip -the circuit included a bipotentiostat . Unfortunately, the device was not adapted for DMSO, and measurements were performed with an aqueous solution.