When submitting the peak picking data from paclitaxel to SMART-NMR, it promptly suggested "taxol" as the heighest score and the users are directed to the GNPS MSMS-based database to enable a complementary compound identification. The HSQC data from azythromycin was matched to azythromycin within the 7 top scores, together with other close-related structures (e.g.: erythomycin, Iankamycin, clarithromycin). The identity of ginsenoside RG1 was not suggested directly from HSQC data, but it suggested closely related structures that can certainly be helpfull to structure elucidation. Even the early classification of the core structure of complex natural product serves as a great aid in the identification of new compounds. Notably, the suggested candidates and the links to interact with other databases can be usefull for data interpretation.