(3) Figure displays the electrochemical parameters. Before the rate test, the D and i 0 of p-ZNCC-Li are 3.02×10 -11 cm 2 S -1 and 3.69×10 -4 mA cm -2 , respectively (Figure , Table ). However, after the rate test, the D and i 0 increased to 1.26×10 -10 cm 2 S -1 and 2.20×10 -3 mA cm -2 , respectively (Figure , Table ). The increasement indicates an erase of surface oxidation layer on Li anode after cycling and the activation of the electrodes. Moreover, most of the data of p-ZNCC-Li is more than 1 order of magnitude better than the other three samples, demonstrating the significant advantages of lithiophilic ZnO, N-dually doped hollow carbon web in facilitating Li-ion diffusion and reversibility. In summary, we have developed a tight and uniform growth of ZIF-8 on oxygen plasma activated carbon cloth and synthesized ZnO-N dual doped hollow carbon nanoweb. XPS and synchrotron XANES demonstrate the oxygen plasma introduces C=O bonds and the N species of p-ZNCC are the most lithiophilic pyrrolic N. The presence of hollow nanoweb and evenly distributed N, ZnO dual lithiophilic sites promotes accelerated Li-ion diffusion and inhibits dead Li accumulation during cycling. This characteristic contributes to an extended lifespan of 3000 h, with a voltage hysteresis of 36 mV observed at 10 mA cm -2 -10 mAh cm -2 . The analyzed EIS spectra indicate effective charge transfer and diffusion coefficient of p-ZNCC-Li. This study offers novel insights into designing a plasma-activated