Pyrazolyltriazoles are most easily obtained via the copper-catalyzed azide-alkyne cycloaddition (CuAAC) from pyrazoloazides (7 and 8). These are usually accessed from the respective amines or organohalides (5 and 6, Scheme 1). Few examples of triazole-pyrazole hybrids, such as 13, have also been synthesized through a modified Sakai reaction , a reaction cascade involving the elimination of an azole or in the n-butyllithium-mediated reaction with alkyl halides . So far, the literature-reported methods are most often limited to N-unsubstituted pyrazoles or triazoles and pyrazoles being fused to a second (hetero)cycle; the synthesis of promising multi-substituted structures such as 1 has not yet been described systematically.