In the recent years, several electrochemical methods for the functionalization of benzylic C(sp )-H bonds have been reported to form C-N, C-O, C-halogen or even C-C bonds. These processes usually involve the oxidation of the benzylic position of 1 directly at the anode via single electron transfers (SET) or via an electromediator. The resulting benzylic radical A could react with a radical acceptor or be further oxidized into a carbocation that could be intercepted by a nucleophile already present in the reaction media to yield 2 (Scheme 1). Scheme 1. Proposed electrochemical benzylic arylation via convergent paired electrolysis.