The utilization of pyromellitic acid as an exclusive low molecular weight geltor (LMWG) was successfully accomplished for the generation of Zn(II)-based supramolecular metallogel which was formed by the implementation of Zn(II) acetate dihydrate salt as the source of Zn(II) and a polar aprotic solvent like DMF as the gel-immobilized solvent media. Zn-PMA metallogel was achieved by the direct mixing of metal source and LMWG. Two different DMF solutions like 1 mL DMF solution of Zn(II) acetate dihydrate (0.1755 g, 0.8 mmol), and 1 mL DMF solution of pyromellitic acid (0.2033 g, 0.8 mmol) were separately prepared in two distinct glass vials. Thus, the molar ratio of these two individual solutions of Zn(II) source and LMWG in DMF was maintained as 1:1. The mixing of these DMF solutions immediately directed the formation of white-coloured stable Zn-PMA metallogel.