Tables and show the computed tunneling characteristics and conductance of BDA and BDT junctions with silver or copper electrodes, respectively, at a bias voltage of 0.1 V. While some trends between BDA-atop, BDT-atop, and BDT-FCC junctions are preserved across gold, silver, and copper electrodes, certain important differences emerge due to change in electrodes. For example, the lowest conductance with each type of electrode is shown by BDT-atop whereas the maximum conductance is shown by BDT-FCC with Au electrodes but BDA-atop with Ag or Cu electrodes. Notably, Tables and show that BDA-atop has similar φ b and G as BDT-FCC when bridged between Ag or Cu electrodes, but quite different φ b and G when bridged between Au electrodes. Further, there are large quantitative variations between junctions with the same bridging molecule and binding site but different Group 11 metal electrodes. Upon changing from gold to silver electrodes, φ b increases by ∼0.7 eV for the BDA-atop junction and ∼0.9 eV for the BDT-atop and BDT-FCC junctions. Further, the inter-electrode distance elongates due to weaker nitrogen-silver and sulphur-silver bonds compared to their gold counterparts, such that a increases by between 0.41 Å to 0.65 Å for the BDAatop, BDT-atop, and BDT-FCC junctions. Consequently, the conductance values of the three junctions are 4 to 8 times lower with silver electrodes than with gold electrodes.