The molar mass of the polymer is very relevant because it is the key to the determination of the catalytic cycles, turnover number, frequency of catalytic cycling, and turnover frequency. The hydrolysis of starch produces fragments during investigative research to ascertain the efficiency and other vital attributes of the enzyme for both laboratory (research) and industrial applications. Such fragments boast the time-dependent evolution of crowding effects that can compromise the efficiency of the free enzyme molecules. Apart from the effect of high viscosity, the frequency of collisions and nonspecific interactions of the enzyme with surrounding fragments, some of which present Preprint submitted to ChemRxiv, Jun 05, 2023 noncatalytic configurational orientation to the enzyme, can increase the residence time of the enzyme molecules in any non-catalytically oriented complex . This can further be orchestrated by the increased surface area presented by the numerous shorter fragments than the parent polysaccharide, a scenario known to slow down the diffusion of water molecules .