Specifically, the a-di-carbonyl compounds and their derivatives are important structural moieties that have been widely developed their applications in the pharmaceutical industry, organic synthesis, radical polymerization, and in the preparation of sustainable materials like bio-based plastic materials. Selective oxidation of alcohols to carbonyl compounds has been recognized as one of the most efficient, important as well as challenging transformations both in academic and industry. As we all know, traditional selective oxidation processes usually were carried out using stoichiometric oxidants such as hypochlorite , manganese salts , hypervalent iodine reagents , chromium (VI) salts , "activated DMSO" and some other developed methods like Dess-Martin periodinane and Swern oxidation or metal-based systems , such as pyridinium chlorochromate, pyridinium dichromate , and ruthenium tetroxide . Moreover, expensive, toxic, and environmentally hazardous chemicals were mainly utilized and a significant amount of toxic waste or unwanted by-products, over-oxidized and reduced residues of heavy metals, were generated at the same time.