Ferrocene (dicyclopentadienyl iron (η 5 , FeCp2 or Fc)), discovered in 1951, has since become a cornerstone in organometallic chemistry due to its unique "sandwich" structure, which features a central iron atom coordinated between two cyclopentadienyl rings. This unprecedented configuration not only expanded the understanding of bonding in transition metal complexes but also led to significant advancements in the field of organometallics, earning Geoffrey Wilkinson and Ernst Otto Fischer the Nobel Prize in Chemistry in 1973. Over the decades, ferrocene has garnered attention for its remarkable stability, thermal resistance, and redox properties, making it an attractive scaffold for chemical modifications. Of particular importance is its role in catalysis, where chiral ferrocene ligands have demonstrated exceptional enantioselectivity in various asymmetric catalytic reactions, including hydrogenation, carbon-carbon bond formation, and hydrosilylation. These ligands have become indispensable in both academic research and industrial applications, especially in the production of optically pure compounds, underscoring the broad utility of ferrocene in the development of novel catalytic systems. Furthermore, understanding the adsorption behaviour of ferrocene on metal surfaces is crucial for optimizing its catalytic properties and enhancing the design of functionalized surfaces, as these interactions play a pivotal role in improving the efficiency of catalytic reactions at the atomic level.