Our ongoing project is to obtain new multilayer folding polymers and oligomers for enhancing their electro and optical properties by taking advantage of palladium-catalyzed polymerization. To our surprise, racemic polymers resulting from achiral catalyst-based systems showed asymmetric elliptical polarization and optical rotation in homogeneous solutions, which contracts the common knowledge and differs from spontaneous symmetric breaking reports on interfaces as documented in the literature. In this letter, we would like to disclose our preliminary results of this discovery.