From the theoretical point of view, it was expected that at lower reaction temperatures and so at lower reaction rates the forming network would be able to relax better, resulting in higher homogeneity. However, at low temperatures, differences in the affinity of the two tetra-stars to the solvents used may become more pronounced resulting in a larger difference in the respective c* values. This may have a negative impact on the network structure. To gain a better insight on the temperature effect on the connectivity distribution, the temperature before and after the gel point was varied. Two different temperature protocols were applied (40 °C pre-and 80 °C post-gel temperature vs. 60 °C during the whole synthesis). Again, the results (see Figure ) show that the temperature has a negligible effect on the connectivity distribution.