Choi et al. detected ~3% of total Fe over their ini�al 20 CVs in Ar-satura�on (100 mV s -1 , 0.8 mg Fe-N-C cm -2 ) for their purely microporous ZIF-derived Fe-N-C. While a�er 50 CVs (50 mV s -1 , 0.4 mg Fe-N-C cm -2 ), TAP 900@ 57 Fe shows 15.2 ± 3.3% Fe detected. This again points to the different porosity and structure in TAP-and ZIF-derived materials, leading to different accessibility of Fe sites. Although, it should be noted, according to our previous ex situ TAP900@ 57 Fe Mössbauer assignments, ca. 11% of the Fe existed as inac�ve FeCl 2 •4H 2 O. This species may represent some or all of the ini�ally dissolved Fe species.