Recently, cooperative transitions have been observed in key organic semiconductor molecules such as 6,13-bis(triisopropylsilylethnyl) pentacene (TIPS-P), among other p-type semiconductors . Cooperativity in TIPS-P led to fast switching of the electronics coupled with large recoverable crystal shape change , resulting in super-and ferro-elastic mechanical effects . In the case of TIPS-P, the rotation of the TIPS groups played a key role in the observed cooperative phenomena . Besides dynamic rotation, other systems have shown the importance of molecular tilting and order-disorder mechanisms to resolve cooperative behaviors . The switching of electronic properties coupled with the rapid mechanical effects of cooperative phase transitions presents a wide design space for novel organic electronics such as thermally activated actuators and highly flexible devices .