The chemical phenomena under vibrational strong coupling are still largely unexplored across various research fields. This systematic study revealed the potential for modifying the transport number in ionic conduction through dynamic hydration modifications. Theoretical calculations have also suggested that the dissociation rate of water molecules can be altered under vibrational strong coupling. This experimental investigation on the modification of correlation rates can provide support for the theoretical predictions. Furthermore, the correlation between thermodynamic and kinetic parameters can be utilized for mechanistic investigations. The demonstrated study using vibrational polaritons opens up opportunities for further exploration in the field of chemistry.