To further characterize complex 5, the TDM was analyzed to determine each transition's CT character. This was done for the spectra obtained using the LC-BLYP functional and TDA. The latter approximation was required for convergence in case of 2 and 4 and yielded the benefit of all TDMs being normalized to 1. This analysis was performed for the singlet absorption spectrum, as well as for the triplet spectrum in the triplet equilibrium geometry.