In a previous paper, we described the use of Bayesian inference for quantitative comparison of voltammetric methods for investigating electrode kinetics. We illustrated the utility of the approach by comparing the information content in both dc and ac voltammetry at a planar electrode for the case of a quasi-reversible one electron reaction mechanism. Using both synthetic and experimental data, we were able to demonstrate that realistic levels of purely random experimental (Gaussian) noise have a relatively minor affect on the inverse problem of recovering both the faradaic (the reversible formal potential, E 0 , the standard heterogeneous charge transfer rate constant k 0 , and the charge transfer coefficient α) and non-faradaic (uncompensated resistance, R u , and double layer capacitance, C dl ) parameters that govern this reaction mechanism. We also demonstrated the clear advantages in terms of accuracy of parameter recovery of the large amplitude ac approach. With this ability of being able to recover parameter values reliably from a single experimental data set in place, we are now in a position to go on to investigate system level variability i.e. if we repeat the same experiment multiple times and implement our Bayesian parameter recovery procedure for each data set independently, how reproducibly do we recover the governing parameters?