Alkenes are abundant and easily accessible hydrocarbons which are commonly pervasive in both academia and industry, the development of versatile alkene 1,2-bifunctionalization strategies stands out as an appealing approach to forge structural complex molecules. In the past decades, the classical catalytical systems of alkene carboamination , diamination 2 , trifluoromethylamination , trifluoromethylarylation , haloarylation , arylsulfonylation , dicarbonylation , and others 8 have been well-explored to form two stable covalent bonds in a single step. Surprisingly, none of these existed strategies could simultaneously embed two different chemoactive groups on both sides of the carbon-carbon double bonds, albeit high-active groups can easily expand the potential value-added modifications of alkenes through post-chemical transformations .