Through the extensive screening protocols outlined in Figure , we identify two molecules with Hund's rule violations, CUYXAV and DIN-GAI01, which both have a structure based on an anthracene-like [14]annulenic perimeter with two linked saturated bridges. In a recent publication, DINGAI01 was also uncovered as a potential case of singlet-triplet inversion by Padula and co-workers via a neural networkbased screening algorithm. However, at the EOM-CCSD/cc-pVDZ level, the Hund's rule violation is between the S 1 and T 3 in the case of CUYXAV, and S 1 and T 2 in DINGAI01 as illustrated in Figure .