The frozen-core approximation is used for all correlated computations. The code for our DLPNO-CCSDT(Q) algorithm can currently be found in a developmental plugin branch of the free and open-source Psi4 package. For tensor operations, the Einsums framework is used. Unless stated explicitly, the preceding DLPNO-CCSDT computation for DLPNO-CCSDT(Q) is evaluated using the TightPNO setting for PNOs and the default values, as stated in our prior work for TNOs. All DLPNO-(Q) computations are conducted using the default parameters presented in Table , unless otherwise stated.