Among the numerous methods developed in the past decades, the most common and powerful approach are coupling of aniline with, thiol, 2 N-thio Succinimide , Chloro with thiol , iodo with thiol , reductive methods such as sulfinic acid, Tosylhdyrazine 7 and disulfide , thiol and rearrangement of sulfonamide in triflic acid . Even though there are large reported methods for thioethers, there is always room for improvement and to find a novel and efficient method, especially were by using readily available, inexpensive, and easily handled reagent.