Once again, we find that all solvation schemes afford similar descriptions of the state energies and characters, with the exception of the T 4 state at the S 1 geometry, which is swapped in order with the almost degenerate S 1 state. The small influence of the LR-and SS-solvation schemes can be understood by the fact that the influence of non-polar solvent like toluene on the excited state energies and characters is small; more polar solvents are expected to lower the energy of charge transfer states and reduce ∆E ST under the SS-PCM solvation scheme.