Computed enthalpies of reaction and estimates of transport parameters and collision models have been used with ab initio-based RRKM theory and the one-dimensional master equation to obtain the microscopic rates, high-pressure-limit canonical rate coefficients, and pressure-dependent kinetics. Both high-pressure-limit and pressure-dependent kinetics are reported in the form of modified Arrhenius expressions that are reasonably well-fitted and are designed for logarithmic interpolation. Computed thermochemical parameters for the perfluoroalkyl radicals and perfluoroalkanes considered in this work have been also been fitted to 7-coefficient NASA polynomials and reported in standardized formats.