Electrospinning can be carried out with a range of macromolecules including many different polymers. With this polymer model in mind, we explored our 2NapFF solutions. Solutions of 2NapFF-Na were able to successfully begin forming thin, short electrospun fibers at a concentration of 40 mg/mL, improving significantly at 50 mg/mL (Figure ). These fibres exhibited a broad range of diameters from 0.1-3.5 μm (Figures and). In comparison, no successfully electrospun structures were formed from 2NapFF-TBA at any concentration trialed under otherwise identical experimental conditions as 2NapFF-Na (Figure ). In polymer-based electrospinning, chain entanglement and intermolecular forces, along with other well-known factors, play critical roles in jet elongation and subsequent fiber formation. Our results can be understood through the conceptualization of wormlike micelles behaving as supramolecular polymer chains, with increasing concentration resulting in increased chain entanglement, as observed with the 2NapFF-Na series. Excessive viscosity as shown by 2NapFF-TBA can be problematic in electrospinning due to the short time frame in which fiber formation occurs, where high viscosity samples do not allow adequate mobility of the molecules into elongated fibrous structures during the brief window of jet formation. In comparison, the 2NapFF-TBA is the preferred solution for the formation of threads. The high extensional viscosity for 2NapFF-TBA means it is possible to drag a solution between a gap and form persistent threads as long as 25 cm (Figure and). In the analogous experiment with 2NapFF-Na, the thread breaks almost immediately (Figure ). The properties of the 2NapFF-TBA therefore allow web-like structures to be formed by extruding across space (Figure ). Once bridged, the liquid threads are stable and can be dried (Figure ). By sequentially adding and joining multiple threads, a web-like structure can be formed and dried overnight. Alternatively, once the liquid thread structure has been formed, concentrated HCl can be added to the bottom of the beaker. The acidic vapor gels the threads, resulting in increased opacity and robustness (Figure ).