95% yields with 90% to 93% ee values. Aryl bromides bearing these susceptible moieties, including trimethylsilyl (3f), alkene (3h), halogen (3i for F, 3j for Cl) and ester (3l) groups, all participated in this reaction successfully as considerable reactivities and enantioselectivities were obtained. In addition, we demonstrated the feasibility of utilizing meta-methoxy-substituted aryl bromide and found that the desired chiral alkene (3m) was produced in 95% yield with 92% ee. The steric hindrance of aryl bromides seems have trivial effects, where aryl bromides with ortho substituents such as methyl or methoxy went through this coupling reaction effectively and delivered the chiral products (3n, 3o) in 95% yield with 91% ee, 96% yield with 95% ee, respectively. For the di-or tri-substituted aryl bromides, the corresponding axially chiral four-membered cyclic alkenes (3p-3s) were produced in excellent yields (91%-95% yields) with high enantioselectivities (90%-94% ee values). Besides, heteroaryl bromides were capable of this coupling as well and the desired products (3t-3w) were obtained of acceptable enantioselectivities (89%-90% ee values), albeit in relatively lower yields (54%-81% yields). The more complicated menthol-derived aryl bromide could be engaged in the coupling with N-tosylhydrazones 2a successfully, thus providing product 3x in 76% yield with 90% de.