Using a high-throughput screening algorithm on the FORMED database, we assessed the vertical excitation energies of 4070 molecules at the CC2/aug-cc-pVDZ level and uncovered two molecules with excited-state Hund's rule violations, of which one had also recently been reported by Padula and co-workers. We explore these two molecules as part of a class of bridged annulene perimeters that we expand based on parent annulenes and previously synthesized annulene perimeters. We report many bridged [10]-and [14]annulene perimeters with excited-state Hund's rule violations at the EOM-CCSD/cc-pVDZ level, which have a great geometrical variety.