Powder X-ray Diffraction: Samples were suspended in ethanol and drop-cast onto a silicon wafer. Samples were allowed to dry at room temperature. The crystalline structure of the particles was obtained using Malvern Panalytical Empyrean XRD (Materials Characterization Facility, Carnegie Mellon University) with Cu anode K-alpha 1 = 1.540 at 45 mV and 40 mA.