In this study, we have reported an approach for the fabrication of morphologycontrolled mesoporous materials with P4VP-functionalized pore walls. In the presence of diols as 'non-covalent cross-linking agents', e.g., NPG, EG, and BPS, the selfassemblies of PS-P4VP-PLA triblock terpolymer (SVA) can be effectively retarded, due to the coordination of OH groups of diols and pyridine rings of mid-block.