We attempted the growth of single crystal of the lead iodide phases containing the novel chiral ligands without success. Therefore, the crystal structure has been determined by means of powder X-ray diffraction starting from the right-handed enantiomer, revealing the formation of the low-dimensional perovskite with formula [(R)-AMOL]2PbI3•I, crystallizing in the Sohncke space group P212121, leading therefore to a chiral structure. Rietveld refinement of [(R)-AMOL]2PbI3•I against the structural model obtained is reported in Figure , while the analogous refinement for [(S)-AMOL]2PbI3•I is reported in SI together with Le Bail refinements for both and a Table (S1) listing the main structural results.