The production of organic hazardous dyes usually takes place in underdeveloped nations from a variety of industrial effluents associated with the food, pharmaceutical, textile, paper, rubber, plastics, and leather industries. In the last few decades, responsive polymers-also referred to as "smart materials" have piqued natural scientists' curiosity. The atom transfer radical polymerization (ATRP), which was initially identified by Matyjaszewski and Sawamoto 2 is of tremendous interest. Precision polymers with adjustable molecular weights, dispersities, macromolecular architecture, and end group functionality may now be produced more easily by reversible deactivation radical polymerization (RDRP) processes. Atom transfer radical polymerization (ATRP) , single electron transfer live radical polymerization (SET-LRP), reversible addition fragmentation chain transfer (RAFT) polymerization , and organometallicmediated radical polymerization are a few of the widely used RDRP processes. The widespread industrial use of acrylate monomer RDRP has been hindered by a number of issues, though: (a) RAFT, which results in undesirable odor, color, and toxicity due to the presence of S-chain ends ; and (b) SET-LRP, which is difficult to remove residual Cu(I)and/or Cu(II) precursors from the final polymers. Excessive amounts of moderate reducing agents are utilized in activators regenerated by electron transfer (ARGET) ATRP which do not yield molecules capable of beginning an ATRP. Reducing agents can be inorganic, like tin (II) 2-ethylhexanoate or zerovalent copper, or organic, such glucose, ascorbic acid, hydrazine, phenols, amines, or even an excess of ligands investigated various inorganic species, including zerovalent metals, Zn0, Mg0, and Fe0, in quest of novel reducing agents. Block copolymers derived from amino acids have garnered significant attention recently. In this regard Acryloyl β-alanine (ABA) was successfully polymerized by ATRP in the presence of CuBr/Bpy water-methanol solutions as a solvent at room temperature, as reported by Chung et al. in 2005. Using the ATRP technique and CuCl/bipy as a catalyst system, a peptide-based monomer bearing the well-known sheet-forming sequence alanine-glycine-alanine-glycine was synthesized in 2005 by Ayres et al. . In 2016, Rafiee et al.