Thus, in the light of the previous studies, EDOT-ECL mixture was successfully photopolymerized in one-pot by using PAB to yield PEDOT-PCL scaffold. Besides, we proceeded with separate photopolymerization reactions of EDOT and ECL using PAB and DPIBr, respectively. This allowed us to compare the experimental results of the PEDOT-PCL scaffold with those of pristine PEDOT and PCL. The trials revealed that in the absence of EDOT in the reaction mixture, PAB does not initiate the polymerization of ECL due to the lack of HBr release. To simulate the light-induced release of HBr, we utilized DPIBr, which is known to generate HBr through the H + abstraction of bromide ions from the solvent or the other components under 300 nm irradiation. The summarized pathways for all the light-induced polymerization reactions are presented in Scheme 1, along with images of the resulting polymeric products. Scheme 1. Summarized reaction pathways for the light-induced polymerizations and images of the resulting polymers.