Organic electrosynthesis has emerged as a sustainable platform for molecular construction over the past decades, replacing costly and waste-intensive redox agents by prospectively renewable electricity. Very recently, the merger of enantioselective transition metal-catalyzed C-H activation with electrochemistry has been realized. Herein, we extend the Cu/BINOL-system to enantioselective electrosynthesis of planar chiral ferrocenes. Notably, this represents the first enantioselective cupraelectro-catalyzed C-H functionalization reaction. Dialkynylated product 3ac' was obtained in 7% yield. [b] CuI (20 mol%), (S)-L1 (40 mol%) in DMAc (5.0 mL). DEAc, N,N-diethylacetamide. DMAc, N,N-dimethylacetamide.