In conclusion, we have successfully developed an oxidant-free electrophotocatalytic method for the direct coupling of aldehydes and N-nucleophiles. This new synthetic approach to forming C(sp²)-N bonds is achieved by simultaneously harnessing photons and electrons in a batch reactor. The products are formed through an electrochemically induced radical-polar crossover (RPC) mechanism with hydrogen atom transfer (HAT) photocatalysis, operating under remarkably mild conditions. This method allows for the functionalization of a wide range of organic compounds, facilitating late-stage functionalization in drug development. The electrophotocatalytic amide formation occurs at room temperature, requires no external oxidants, and its overall productivity can be further enhanced using flow systems. Ongoing studies in our lab are focused on expanding the application of this RPC-HAT combination to advance synthetic electrophotocatalysis.