[n]CPPs, commonly referred to as 'nanohoops', are a type of carbon nanomaterial described as the shortest crosssection of an armchair carbon nanotube. First synthesized in 2008 by Jasti and Bertozzi, [n]CPPs are unique from other nanocarbons in their ability to be precisely synthesized via bottom-up methodologies with common synthetic starting materials and reagents (Figure ). This buildingblock approach has led to the synthesis of a number of different-sized [n]CPPs from [5]CPP- [18]CPP (where 'n' is the number of phenylene rings) along with numerous functionalized derivatives. The centrosymmetric nature of the nanohoops coupled with their strained radially oriented pi-conjugated systems also enables several intriguing optoelectronic properties. First, unlike linear pi-conjugated molecules, these strained macrocycles have shrinking HOMO-LUMO gaps with decreasing ring size. Consistent with this trend, the [n]CPPs have a red-shifting emission as the CPP ring size decreases. However, [n]CPPs possess a common absorption at 340 nm regardless of ring size or number of rings. This unique feature is ideal for multiplexing applications where only one excitation source is required . Moreover, it is noteworthy that these nanohoops have molar absorption coefficients on the order of 10 5 M -1 cm -1, which coupled with the high quantum yield leads to exceptionally bright fluorescent material. Interestingly, only one study has utilized the optoelectronic properties of [n]CPPs as an additive in a polymeric material . It was reported that the addition of [6]CPP up to 5 wt.% improved the stretchability of a diketopyrrolopyrrole-based semi-conducting polymer while maintaining its mobility. However, to our knowledge, no study has probed the possibility of