Another type of C-C coupling involves intermediates with double or triple bonds, such as CO2* and CO*, as well as bridge-bonded CHx* (x = 1-2). In these cases, the bond multiplicity in the CO-or CO2-containing moiety decreases, while the CHx moiety becomes singly bonded to the surface, leading to the formation of a new C-C bond. Due to this bond redistribution, this class is designated as metathesis (dark orange data in Figure ). Linear regression of all data points calculated on Pd catalysts yields an RMSD of 0.14 eV. On Cu, the BEP relationship for all such steps has an RMSD of 0.44 eV (solid orange line in Figure ), which decreases to 0.20 eV if one outlier, CH* coupling with CO*, is removed from the analysis (dashed orange line in Figure ; see the structure in Figure ). Such deviation of CH*-CO* coupling from the common trend indicates that the transition state for this reaction on Cu may need to be attributed to another TS class, which has not been comprehensively represented in the considered reaction network.