Compared to α-heteroatom and α-carbonyl stabilized radicals, the enantioconvergent C(sp 3 )-C(sp 3 ) cross-coupling of primary radicals via decarboxylation of unactivated primary aliphatic acids remains underexploited . Additionally, the selection of organometallic partners in asymmetric decarboxylative cross-coupling is largely confined to alkylzinc reagents, which typically involve tedious synthesis procedures such as oxidative insertion into alkyl halides by zinc or transmetalation using zinc salts. These methods suffer from harsh conditions, and a limited substrate scope, restricting their practical utility .