We have prepared a series of new compounds containing one, two, or three dithiolane rings bonded to an aromatic core. The synthetic procedure is straightforward, and the yields are moderate to excellent yield after chromatographic purification. All these compounds possess multiple sulfur atom and Oximate moiety are thus capable of binding in a multidentate fashion to soft transition metal ions. Reactions of these ligands with late transition metal ions is a current focus in our laboratory.