The compound TiZnO₃, metastable with respect to disproportionation into ZnO and TiO2, combines fivefold coordinated Ti and tetrahedral Zn. This may reflect the training data where Ti can adopt a wide range of coordination environments, while Zn predominantly maintains a +2 oxidation state with a tetrahedral coordination. Structures such as this highlights the potential for generative models to sample unconventional bonding arrangements. Indeed, one sampled metastable structure for TiZnO, which may be challenging for an inorganic chemist to anticipate, separates into alternating layers of TiO and metallic Zn.