In this study, we focus on co-reducing NO3 -and CO2 electrochemically to synthesize urea. Direct electrochemical co-reduction of NO3 -and CO2 is attractive as green urea can be produced in a decentralized manner with lower capital costs. Also, this study would help us provide insights into the electrochemical C-N coupling, which is not explored extensively in the literature. Understanding electrochemical C-N coupling would enable selective synthesis of chemicals such as urea, methyl amine, acetamide, and benzamide, which is used as a precursor in the synthesis of several commercial drugs such as analgesics, antiemetics, antipsychotics, etc. The objective of the current study is a selective electrochemical synthesis of urea from NO3 -and CO2.