This quantity provides a physically intuitive description of the effective Coulombic driving forces that are present in a system. However, these forces do not necessarily represent the mean forces actually experienced by a given charged species in the system. This is because φ and its gradients are native to the influence of a species on its local environment. For example, the local environment of an ion is enriched in counter charge and in addition can include a strongly bound and highly polarized solvation shell. The influences of these molecular effects are integrated out of the mean charge density profile and thus may not be apparent in φ(z) or its gradients.