This comprehensive study, conducted in collaboration with multiple companies, addresses many of the less publicized limitations with this powerful transformation. Foremost in our view were the scope limitations apparent on both the arene and carboxylic acid-based fragments. To be sure, electron rich arenes, diverse heterocycles, and highly functionalized carboxylic acids are all highly coveted coupling partners. To vividly demonstrate this challenge, the present work benchmarks state-of-the-art conditions across the entire scope explored. Overall, the present Ag-Ni electrocatalytic protocol appears to have superior generality. In addition, it features high simplicity, robustness, and short reaction times (2.5 h). Several examples are highlighted wherein the success of these uniquely enabled reactions can have a simplifying effect on synthesis. This reaction has been extensively field-tested amongst our collaborators and works on a wide range of additional proprietary structures not depicted herein. Finally, for this reaction to have maximal impact it must be useful in real-world scale regimes. Thus, a demonstration of parallel synthesis to rapidly generate analog libraries, subsequent scale-up for more meaningful quantities, and a simple recirculating-flow setup for decagram scale and beyond are reported.