We have established the feasibility of zero-field NMR detection of small molecules hyperpolarized via dissolution dynamic nuclear polarization. Although a limited number of molecules have been observed with parahydrogen-based hyperpolarization at zero field , our combined experimental setup enabled us to acquire zero-field spectra of arbitrary sample mixtures thanks to the generality of d DNP as a hyperpolarization method, providing signal enhancements of several orders of magnitude compared with thermal prepolarization at 2T. We estimated the expected broadening due to paramagnetic relaxation of the free radicals commonly used in DNP, and found consistency with the spectra of the hyperpolarized samples.