To start, we opted to study Roesky's β-diketiminate supported aluminium system on the basis that it is well established within low-oxidation state chemistry literature. Following initial trial and error with an electrochemical set-up inside the glovebox (see SI for details), we found that a threeelectrode system consisting of a glassy carbon working electrode, a platinum counter electrode, and a silver pseudo-reference electrode in a Luggin capillary, along with THF as the solvent and [NBu4][PF6] as the electrolyte, provided an optimal set-up for cyclic voltammetry (CV) experiments.