Oxidative cleavage of the double bond in 6 delivered the corresponding aldehyde 7 in 72% yield with 91% ee. trans-Alkenylated ferrocenes 8 could also be easily prepared in excellent yield via isomerization of cis-alkenylated ferrocenes 6. To be noticed, an oxazoline-olefin chiral ligand 10 was synthesized efficiently in two-steps from 8 by the removal of and the formation of oxazoline (Scheme 4B). Then, the resulting oxazoline-olefin ligand 10 was subjected to a Rh-catalyzed1,4-addition of phenylboronic acid to α, β-unsaturated cyclohexanone. The desired β-arylated ketone product 11 was obtained in 75% yield with a high-level of enantioselectivity (93% ee), which demonstrating that the high potential of the ferrocene products obtained in this work could act as a type of unique chiral ligands in asymmetric catalysis. Moreover, the enantioselective electrocatalysis reaction was also investigated for scalability, whereby efficiency and enantioselectivity could be maintained (Scheme 4C).