While the aforementioned attributes of Ag-Ni based electrocatalytic DCC are attractive from the standpoint of enabling access to new chemical space, the ability to generate libraries and scale up promising structures is critical. In 2019, commercial vendors began selling standardized equipment geared towards synthetic chemists for parallel electrochemical synthesis. More recently, the Lin group in collaboration with Merck revealed another interesting approach to reaction miniaturization. For this study we elected to use the commercial "E-hive" module sold by IKA that conveniently attaches to ElectraSyn 2.0 (Figure ). This device is capable of running 24 reactions in parallel at constant potential. It features a unique design wherein the reaction vessel is itself an electrode (stainless steel) and a small graphite rod (which is part of the cap) is the other electrode. Either one can serve as a cathode or anode depending on the desired setting. To demonstrate the utility of such a setup for library synthesis a set of 12 arenes (screened against 55) and 12 RAEs (screened against 56) were selected. To replicate an actual discovery setting, we deliberately chose substrates that had not been tested before.