We report here the preparation of a novel bifunctional chiral ligand (R) and (S)-1-amminobutan-2-ol (AMOL) containing both an amine and a hydroxyl group and its use in the preparation of chiral lead iodide perovskites. The incorporation of this bifunctional ligand allowed the synthesis of the [(R-/S-)-AMOL]2PbI3•I samples characterized by an uncommon structural motif composed by 1D double chains running along the crystallographic c-axis built up by face-sharing [PbI6] 4-octahedra. Chiroptical properties determination shows and effective chirality transfer from the novel chiral ligands to the inorganic framework with a relevant optical response. The expansion of the library of actually known chiral ligands is fundamental for the design of novel chiral perovskites and to expand the actual knowledge of structure-property correlations in these fascinating materials.