Under argon, the desired amount of degassed styrene was added to the Schlenk flask. The Schlenk flask was then heated with stirring in an oil bath at 60 °C overnight (for AntMAc, AntMA), 115 °C for 2 h (for PyMA), or 80 °C overnight (for the rest monomers). The feed molar fraction of PAM varied from 0.50% to 30.0%. For all monomers except AntMAc and AntMA, the monomer/initiator molar ratio was 80. For AntMAc and AntMA, the monomer/initiator ratio was 160, and 1.0 eq. of CuBr and 1,1,4,7,7-pentamethyldiethylenetriamine (PMDETA) were used. Homopolymerization of 2vinylnaphthalene was done with toluene as the solvent (monomer/solvent 1/1.3, w/w), with monomer/initiator molar ratio of 80, and reaction temperature at 115 °C overnight. The polymers were characterized by 1 H NMR spectroscopy (Figure ) and GPC (Figure ). Note that a slight difference in molecular weight during the synthesis of PDI-tetraPS (DP100) for presented applications was observed due to the batch variation (DP ranging 100-110).