In summary, this study highlights the potential of AI and large language models (LLMs) as powerful tools in electrochemistry research. I encourage broader adoption of AI in this field, anticipating its growing impact. However, given the current limitations of LLMs, it is essential to view them as supportive tools rather than definitive sources. Careful review and validation of AI-generated output are crucial to ensure accurate and reliable scientific results. To bridge the gap between macroscopic reaction rate constants and microscopic particle interactions, we can use the Smoluchowski theory of diffusion-controlled reactions. This theory relates the diffusion coefficients of the reacting species, the reaction (collision) radius, and the macroscopic reaction rate constant.