Changing the nickel source minimally impacted the reaction, as nickel bromide delivered nearly identical yields (Table , Entry 7). Encouragingly, the reaction was found to be complete after 30 minutes of irradiation (Table , Entry 8). Extended irradiation times did not result in any detectable product decomposition, even after 3 hours of irradiation. Therefore, for the sake of generality, we established 3 hours as the ideal reaction time to carry out the reaction scope. Notably, the transformation proceeded smoothly even with reduced loading of both the photocatalyst and the nickel catalyst (Table , Entry 9). The aforementioned results highlight the robustness of this B-alkyl SMC methodology, which is particularly useful to facilitate process chemistry applications. Next, several control experiments were conducted, demonstrating that the absence of either the photocatalyst or the nickel catalytic system resulted in no product formation (Table , Entries 10 and 11). Furthermore, omission of the base yielded only traces of 3 (Table , Entry 12); a similar result was obtained when performing the reaction at elevated temperatures in the dark (