For the CAMY-B3LYP functional, the lowest-energy Q band is essentially a pure phenoxide-to-LUMO transition, while the higher-energy Q band has a more conventional four-orbital composition, with comparable contributions from the a1u and a2u MOs. A similar situation also holds for the Soret regime. The lowest-energy Soret transition is essentially a phenoxide-to-LUMO+1 transition, while the higher-energy transition has a more conventional four-orbital composition involving both the a1u and a2u MOs.