The field of organic electronics requires affordable, flexible, transparent, and robust thin film electrodes to replace the current industry standard of indium tin oxide (ITO)-a substance plagued by its fragility and high cost. Important candidates for ITO replacement are semiconducting polymers due to their mechanical flexibility, electrical conductivity, and conformability. These properties enable many applications in organic electronics, such as sensors, supercapacitors, and solar cells. Poly(3,4-ethylenedioxythiophene) (PEDOT) has emerged as a promising candidate due to its superior electronic and ionic conductivities, desirable optical properties, and resistance to humidity and oxidants. However, PEDOT is insoluble in most organic and aqueous solvents, so it is typically combined with PSS, allowing PEDOT to be dispersed in aqueous solutions to enhance its processability. Additionally, PSS serves as a dopant, and the presence of PSS has been shown to result in a more crystalline PEDOT structure. Unfortunately, PSS also has its drawbacks. It is an insulator that can potentially limit PEDOT's conductivity, it is acidic, and can lead to material incompatibility issues, and the thermal stability of PSS is such that it can limit the processing options for manufacturing. Thus, in many applications, PEDOT: PSS films must undergo post-treatment to remove the PSS. To address these challenges, we used films of overlapping large-flake graphene exfoliated through solvent interface trapping as a dopant for PEDOT. We synthesized PEDOT-graphene films with conductivities reaching 1070 S/cm, surpassing those of comparable films previously reported.