Naphthyl amines proved to be excellent substrates for this electrochemical cascade as well, working well with a broad scope of acid chlorides and chloroformates carrying both aliphatic and aromatic groups. For 2-naphthyl amines, chlorination was found to occur exclusively at the 1position of the naphthyl ring giving the products 66-77 in high to excellent yield (66-97%) under the optimized standard conditions. Different acid chlorides and chloroformates were similarly reacted with 4-methoxyaniline over extended times (16 h) and using modified reaction conditions. When a lower current of 2 mA was used, the ortho-substituted products 78-82 could be obtained in 64-82% yields.