After having studied the reaction in terms of aromatic amine partners, we then chose to investigate the scope of acid chlorides and chloroformates carrying different aliphatic, cycloaliphatic and benzylic substituents. These gave the corresponding N-aryl amide and carbamate products 21-32 in 91-97% yield within 3 h without any significant amounts of dichlorinated byproducts. When acid chlorides with aromatic substituents were used in the reaction with aniline, slightly lower performance was observed, but still synthetically useful yields in the range of 61-90% of products 33-44 could be achieved with slightly prolonged reaction times (3.5 h). Also 1-naphthoyl and 2-napthoyl chloride were well-tolerated by this electrocatalytic cascade, which enabled access to the products 45 and 46 in 91% and 92% yield, respectively, without any traces of the dichlorinated side products. Similarly, exclusive selectivity towards the parachlorinated products 47 and 48 could be achieved when heteroaromatic acid chlorides were used, as demonstrated by examples carrying benzothiophene and benzofuran as the R 3 group. With benzo[b]thiophene-2-carbonyl chloride, a yield of 84% of 47 could be obtained with the standard conditions, while reaction employing benzofuran-2-carbonyl chloride required a longer reaction of 5 h to give product 48 in 78% yield. Interestingly, a wide range of chloroformate reagents were also compatible with this cascade approach, allowing the synthesis of the carbamate products 49-53 in 87-97% yield within 3 h. We also investigated the versatility of our methodology for piperazine and morpholine carbonyl chlorides, which with extended reaction times afforded the halogenated urea derivatives 54 and 55 in 38% and 57% yield, respectively. Furthermore, to determine whether this method could be applied to ,-unsaturated acid chlorides, 3-methylbut-2-enoyl chloride and cinnamoyl chloride were subjected to this cascade as well. Here, lower currents (1-2 mA) and extended reaction times (18-20 h) proved necessary to afford the amide products 56 and 57 in synthetically useful yields (64% and 50%, respectively).