To elucidate the functional group compatibility of this method, we employed geranyl alcohol as the model substrate to probe its tolerance equipped with diverse functional groups (Scheme 3). Remarkably, unprotected geranyl alcohol gave the desired aziridine 25 in 52% yield under condition . When the hydroxyl group was protected by acetyl (Ac, 26s) and benzoyl (Bz, 27s), the target products were achieved with excellent yields under condition . Interestingly, substrates featuring functional groups such as NPhth (28s), SO2Ph (29s), pyrazinoic acid ester (30s), and ferrocenyl carboxylic acid ester (31s) were efficiently converted to the desired aziridines in good to excellent yields (28-31). Notably, this reaction displayed good compatibility with complex biomolecules, including peptides and glycosyl moieties. Specifically, substrates containing a di-glycine unit (32s) and a Boc-Val-Gly segment (33s) were adeptly transformed into desired products in 79% and 74% yield, respectively. Additionally, compounds derived from L-glucopyranose (34), 𝛽-Dglucuronic ester (35), 𝛼-D-glucuronic ester (36) and zidovudine (37) were synthesized in moderate yields and diastereoselectivities. Particularly noteworthy is the transformation of the olefin substrate containing the pharmaceutical molecule indometacin (38) and mycophenolic acid (39), which were achieved in 84% and 56% yield, respectively. These examples highlight the reaction's broad substrate scopes and robust tolerance towards a wide array of functional groups.