We have achieved an excellent agreement (within 1% or less) with the measured STS gaps ("bulk" and "surface") for the known 5-, 7-and 9-AGNRs, although the "surface" gaps, as is illustrated in Table . Namely: a) For the 5-AGNRs the measured 8 gap value is 0.85 eV. The calculated here gap with DFT/PBE0 is 1.07, whereas the TDDFT/PBE0 value is exactly 0.85 eV, indicating also that this is a ΔΕzz gap.