Hybrid materials have emerged as promising materials because of their unique and outstanding properties for several domains and applications, including catalysis , optical devices , environmental , medicine , energy storage , among others. Hybrid materials consist of at least two components of different nature to combine their unique physicochemical properties and bind through covalent or non-covalent interaction . In this context, graphene (G), graphene oxide (GO), doped graphene (DG), and graphene quantum dots (GQDs) has been studied due to their attractive mechanical, electrical, and photophysical properties, which can be complemented in the preparation of graphene hybrid based materials (GBMs) . Covalently linked GBMs have been extensively studied, highlighting the particular advantage of the graphene moiety on increased stabilities, charge/discharge kinetics, and capacities, and increased electron transfer processes towards nonlinear optical properties . Among the wide variety of adsorbates, macrocyclic compounds such as porphyrins and phthalocyanines appear as attractive candidates to tune up the properties of hybrid materials. For instance, G surfaces coated with Co-porphyrins and Fe-phthalocyanines showed enhancement of electron transfer process, providing highly active materials for oxygen reduction reactions . Besides, high stability and large electron-conductivity of GQDs/Zn-porphyrins hybrids are observed towards photocatalytic degradation of pollutants . G coated by π-π stacking with a water-soluble phthalocyanine demonstrated large synergism as a photosensitizer suitable for photothermal and photodynamic therapies .