From the 100 uncorrelated snapshots from the ground and excited state AIMD trajectories, we performed VEE/VDE calculations on these snapshots for use in both ensemble and E-ZTFC spectra calculations. After optimizing the excited state geometries in the field of the frozen QM solvent, we observe a significant decrease in the energy fluctuations, see Figure , suggesting that these large fluctuations on the excited state are due to motions of the chromophore degrees of freedom rather than increased strength of chromophore-solvent interactions. Next, we analyze these energies in the context of ensemble absorption and emission spectra.