The case study presented in our work focuses on battery cycling experiments. The whole battery cycling process, starting with a successful cell assembly by a purpose-built robot, including the necessary formation cycles and long-term cycling using off-the-shelf equipment, and ending with a discharge step allowing for a safe disposal, is tracked and collated using digital twins. Protocols as well as data are included in the provenance graph. We stress that while the case study focuses on battery testing experiments, the implementation is flexible enough to allow adaptation to other experimental workflows, such as in catalysis.