Panels (d)-(h) of Fig. illustrate the configuration of chains with varying block ratios m : n for c s = 0.1 M when N DCPAM = 5. As n increases, the total charge of the polymer increases correspondingly, enhancing the electrostatic repulsion between chains within the simulation box. This enhanced repulsion increases the spacing between chains, reducing the probability of aggregation between chains. Notably, the 16 : 4 DCPAM chains exhibit a strong tendency to aggregate, clustering into a single cohesive structure. This behavior is due to the reduced charge density in the B-block, which weakens the electrostatic repulsion between chains and allows hydrophobic interactions to dominate, facilitating aggregation. In contrast, the 0 : 20 CPAM chains, which consist entirely of the charged monomers, remain completely separated. The high polymer charge in this configuration maximizes electrostatic repulsion, preventing aggregation and maintaining well-dispersed chain conformations. These analyses further indicate the critical role of block architecture in the balance between electrostatic and hydrophobic interactions. Similar trends have been reported in Ref. .