Last, for Ada-CN + we also considered excitation to the higher energy window of eV (Fig. ). In this case, the most populated states at t = 0 are D 10 (0.34) and D 11 (0.31), and next most populated states are D 8 (0.18) and D 9 (0.10). D 10 and D 11 decay giving rise to growth of the D 8 and D 9 populations, which, in turn, decrease after 86 fs and 25 fs, respectively. The lower states are slightly populated, e.g., a maximum in the D 3 population of 0.17 is observed at 176 fs , and the D 1 population reaches the maximal value of 0.13 at 222 fs. Eventually, the D 0 state is populated with the time constant of ∼300 fs as already stated above.