The (hetero)biaryl motif is a highly privileged structural element in a vast array of biologically active molecules, agrochemicals, ligands, and functional materials . Transition metal catalyzed traditional cross-coupling has revolutionized the landscape of molecule construction over the past several decades by forging C(sp 2 )C(sp 2 ) bond through the linking of a (hetero)aryl halide or pseudohalide with a (hetero)aryl nucleophile . In general, the catalytic paradigm of these cross-coupling reactions involves a combination of three elementary steps--oxidative addition, transmetalation, and reductive elimination, offering a highly modular, although general approach to fragment coupling (Fig. ). Despite its success and versatility, this cross-coupling method suffers from several limiting factors such as: a) poor availability and instability of (hetero)aryl nucleophile equivalents ; b) challenges in the synthesis and purification of (hetero)aryl nucleophile equivalents ; c) highly reactive nature of many organometallic reagents requires elaborate anaerobic conditions and impose restrictions on the use of substrates containing electrophilic functional groups or acidic protons . Therefore, substantial efforts have been devoted into creating a more effective alternative synthetic protocol for building (hetero)biaryls. In this vein, direct C-H arylation and high valent sulfur and phosphorus 19 mediated crosscoupling strategies have been developed which perform remarkably well to access challenging (hetero)biaryls. These methods circumvent some of the obstacles that cross-coupling presents in terms of substrate availability and stability. Nevertheless, substrate specificity and CH bond site-selectivity could be significant limitations of these protocols.