This approach has been extended to complex multi-electron and multi-step reactions. The original report on the kinetic zone diagram by Su and Savéant was formulated for single-electron EC' mechanisms, however the concepts and trends are generalizable to other systems. For example, an ECEC' system was experimentally tuned to navigate across all kinetic regimes of the kinetic zone diagram. The generalizability and intuitive encoding of the complex relationship between CV profiles and experimental conditions has made the kinetic zone diagram an indispensable tool for electrochemists. Because of the usefulness of kinetic zone diagrams in manual electrochemistry experiments, we sought to rethink the concept in the context of autonomous electrochemistry.