Here, we continue the search for new types of compounds with excited-state Hund's rule violations by significantly expanding our previous high-throughput screening approach. Given how rare Hund's rule violations are, this task turns out to be an effort of finding a few needles in a haystack. From the FORMED database, 26 we uncover two bridged [14]annulenes. With these two molecules as base structures, we go on to expand a class of bridged annulene perimeter systems with excited-state Hund's rule vio-lations.