Within each system, the initially stretched-out hydrophilic A blocks rapidly condense onto the hydrophobic B blocks, albeit the protonated and rather flexible PipBoc/Pid termini orient themselves outwards and remain relatively solvent-exposed. CUR molecules get entangled quickly between the polymer chains and show very limited movement once this has occurred. All micelles reach a radius of gyration (Rg) between 4.2 and 4.8 nm, with [10/6] systems showing slightly higher values (Figure ).