Photolysis (l > 335 nm) of a 4:1 MeCN:THF solution of 13a afforded sulfonamide 14 in a 50% yield. Similar reactivity was observed for 13b, 13c, and 13d (55, 70, and 63% yield of 14, respectively). In contrast to iodoamide 13e, photolysis of 13a-13d in the presence of either toluene or styrene does not result in the products of nitrene transfer.