Since solid-state batteries can utilize cathode materials that do not contain lithium in the as-synthesized state, the exploration of materials systems through iterative insertion of ions into an atomic structure is an important step in identifying new materials for energy storage applications. Effective intercalation electrodes require "topotactic" ion incorporation where working ions (WIs) are integrated into the atomic structure without major perturbations to the host lattice. Recent studies have demonstrated that analysis of the electronic charge The electrode workflow (Fig. ) is composed of a series of repeatable ion-insertion steps that produce the most energetically favorable new structure containing one additional WI.