Developing reliable combustion models is one of the main objects in the field of combustion chemistry. By utilizing combustion models, a comprehensive understanding of the combustion process can be achieved, leading to improved efficiency and better control over pollutant emissions. The reliability of combustion model is closely related to the accuracy of kinetic parameters of associated chemical reactions, such as rate constants. However, it is generally very difficult to yield accurate reaction rate constants in the combustion circumstance both experimentally and theoretically.