In summary, we developed an orange MR-TADF emitter, DDiKTa-A, based on a design that bridges two DiKTa units via a central aniline. The synergistic combination of a compound containing para-N-p-N conjugation and two emissive luminophores resulted in a significantly redshifted emission from blue (lPL = 453 nm) for DiKTa to orange (lPL = 562 nm) for DDiKTa-A in toluene solution. In 2 wt% doped films in mCP, DDiKTa-A emits at 562 nm, with a high F PL of 92% and a t d of 279 µs. Notably, in 2-MeTHF, the emission of DDiKTa-A displayed a spectral sensitivity to temperature over 123 to 298 K, reflecting temperature-dependent changes in the environment. The OLEDs with DDiKTa-A exhibited an EQE max of 20.3% but that showed considerable efficiency roll-off, with an EQE 100 of 13.2%. The device performance was markedly improved by employing a hyperfluorescence device stack with 4CzIPN as the assistant dopant, leading to a high EQE max of 24.3% and a reduced efficiency roll-off with EQE100 of 22.5% and EQE1000 of 14.6% at lEL of 574 nm. This emitter design, where a central aniline bridges two MR-TADF units, provides a straightforward approach to developing MR-TADF compounds where the emission is significantly red-shifted to lower energy.