In recent years, crystal engineering and construction of coordination networks with fascinating structural topologies have attracted great attention owing to their potential as functional materials. Concurrently, the development of multidimensional networks based primarily on linking metal centers with rigid bridging components, such as 4,4`bipyridine has been initiated. Since then chemiluminescence's of 3-aminophthalhydrazide was first investigated by Albrecht, the acyl hydrazides are growing interest in the development of luminescent materials due to their potential application in emissive devices. Moreover, the attractive and promising practical applications in many other areas have stimulated further investigations in light-emitting devices, nonlinear optics, and functional films, conjugated polymers, logic functions of molecularscale, uranyl salts, saccharides, and aromatic organic molecular crystals which exhibit tribofluorescence or tribophosphorescence from the molecules comprising the crystal and/or nitrogen emission triboluminescence, azopolymers. Metal directed assembly have been used to generate luminescent materials based on complexation of transition metal and multifunctional bridging ligands and is one of many useful strategies to design extended frameworks of various topology and dimensionality. Ligands with amino group of anthranilic acid derivative backbones may affect the properties of the resulting emissions by promoting the coupling of metal atoms through its emission systems. It has been of interest to use photoactive ligands as building blocks to generate supramolecular polymers. Some of these workers have been concerned with the influence of structural changes upon the chemiluminescent properties.