The adjustability of MOFs largely stems from their modular synthesis: metal atoms or metal-oxo clusters ["secondary building units" (SBUs)] [ ] coordinate to organic linker molecules to form an extended network. The abundance of compatible metals/SBUs and linkers, assembling within different topologies, gives many possible structures. Postsynthetic modification (PSM) [ ], building block replacement (BBR) , and mixing linkers and/or metals [ ] grant further structural and chemical tunability. E.g., in covalent PSM, a reaction on the MOF can install a new chemical functionality on its linkers.