Supporting Information. XRD, FT-IR, elemental analysis, electron microscopy, XANES, EXAFS, 57 Fe Mössbauer, and DFT simulations are presented in the Supporting Information. This material is available free of charge via the Internet at . All computational structures associated with the presented work are available from the NOMAD repository (upload ID: pM_C4vbtTFqbg-uwrMe1Qg). All XANES data and meta-data presented is available from the Loughborough University repository (TBC).