In conclusion, we have developed a method for the synthesis of -chiral aliphatic amines from easily accessible -chiral allylic amines using a base catalyst. A subsequent diastereoselective reduction of the chiral imine/enamine intermediate leads to ,chiral -trifluoromethylated amines in excellent yields and with high diastereo-and enantioselectivities. We have shown that the reaction has a broad scope, and the reaction has been run on a gram scale. Thus, this represents a straightforward approach to ,-chiral trifluoromethylated amines from accessible allylic amines.