In FIG. , we present the polarization dependence in the static RIXS spectrum for the |F1s -1 6a 1 1g resonance in comparison the experimental spectrum as reported by Ekholm et al. . We see that the simulated spectra reproduced the polarization dependence of different peaks very accurately. The isotropic orientation of the molecule has been taken care of in the computation of the polarization dependence of the RIXS signal using Equation , and thus all peaks have both intensity for both horizon-tal and vertical polarization, and the predominance of any polarization is dictated by the situation when the S-F bond is oriented with the polarization of the incident radiation. Thus though FIG. shows exclusively the presence of either vertical or horizontal polarization for a particular emission, the real spectra contains contains intensity for both polarization for all the emissions. The emission energies of the peaks appear to be shifted to lower emission energies by almost a constant 0.75 eV with respect to the experimental spectrum, when we use the shift used in the XE spectrum. This is due to error in estimation of the valence excited state energies by DFT-ROCIS.