In the context of SDE by sublimation of leucine, alanine, and proline amino acids, a reverse order in the spontaneous enantioenrichment was observed, leaving an enantioenriched residue starting from scalemates above ca. 50% ee and an enantiodepleted one below that value. Similarly, for the case of SDE by distillation, a unique example of the same order reversal was reported for the distillation of isopropyl trifluorolactate. Thus we wondered if this effect would also occur for (S)-TLA with an ee below 60%. To investigate this point, accelerated sublimations of scalemic mixtures of (S)-TLA with 10% ee, 16% ee, and 20% ee were performed. As shown in Figure virtually no variation (10% ee and 16% ee) or even a higher (20% ee) sublimation rate respect to the racemate was found.