As documented in the literature, racemic compounds in transparent homogeneous solutions are elliptically inactive and display no optical rotation when a plan-polarized light beam transmits through their solutions . This circumstance is attributed to the fact that the equally distributed rightand left-handed enantiomers perturb plane-polarized light in opposite directions. The racemic polymers and oligomers from achiral catalysts in this work should also follow this common acceptance without optical activity in solvents. At first, the solution containing racemic polymer 1C in THF-H2O (20%, v%) cosolvents did show a stable zero optical rotation at the beginning of the optical rotation measurement. Surprisingly, when we kept this solution inside the polarimeter for a prolonged period, optical rotation started to show up with a certain degree of amplification until maximum peaks were reached in ~24 min. The specific rotation then went down to 820 o in about 1 hour. Usually, there was no such phenomenon appearing until the water fraction (fw) was increased to >15% (v%), i.e., in sole THF and its cosolvents with H2O with fw below 15%, no optical rotation was detected throughout the whole period of determination. The cosolvent of THF-H2O with fw of 20% was utilized for the present study because the optical rotation data is relatively more stable.