In the present review, the present state of research in the field of laser AM-based AZ ceramics has been briefly highlighted. The present focus (in this avenue) is to engineer the microstructure (based on optimising a number of process parameters associated with AM-based fabrication techniques) to render these ceramics superior in terms of mechanical properties compared to those fabricated using conventional techniques. However, in the context of eutectic ceramics (including AZ ceramics), characterisation of the different interfaces (mostly, the eutectic boundaries, in the present context) has not been addressed till date. For instance, in the context of laser AM-based AZ ceramics, the case study discussed in section 4 is the only work (till date) which has been successfully able to use FIB-based liftout technique for obtaining electron transparent lamella from both transverse and longitudinal sections in AYZ ceramic in order to determine the orientation relationship between the individual phases (α-Al2O3, YAG and ZrO2) using TKD technique.