In this work, we have carried out an extensive DFT-MD thermodynamics study of metal-water interfaces. We report metal-water interfacial free energies, surface tensions, and works of adhesion for a range of FCC(111) surfaces. With the help of the 2PT model, our results explicitly account for the contributions of entropy. In addition, we establish correlations between the thermodynamic quantities, structural, and electronic properties of the metal-water interfaces studied. Our work provides detailed fundamental understanding of metalwater interface thermodynamics and establishes a DFT-level benchmark dataset that can be used to guide the development of empirical force fields and implicit solvent models.