These results open the way to interesting perspectives in the field of organic synthesis. Given the recyclability of the receptor, different successive reactions, such as peptide coupling reactions with different amino acids, can be envisaged in a one-pot process using a difunctional substrate. With a molecular container displaying a chiral cavity, high stereoselectivity should also be possible, in addition to the chemo-, regio-and iteroselectivities. Automation of the process could lead to large scale syntheses, and the grafting of the receptor on a surface would enable an easier separation of the product and recycling of the host. Current research in our group is focused on the extension of the methodology to other types of host-guest systems and other types of stimuli for the control of the capture/release of the guest. The use of receptors with an extended cavity, in order to have a better control over the host-guest stoichiometry and thus the iteroselectivity, is also under investigation.