Organic thermally activated delayed fluorescence (TADF) materials have attracted significant attention as emitters for organic light-emitting diodes (OLEDs) due to their efficient exciton harvesting capabilities to produce high efficiency devices and their tunable emission as a function of their structure. The ability of these materials to convert triplet excitons into singlets via reverse intersystem crossing (RISC) relies on a relatively small singlet-triplet energy gap (ΔEST). Achieving a small ΔEST involves spatially separating the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO), typically by increasing the twist angle between the electron donor (D) and acceptor (A) units within the emitter. However, a large twist angle generally leads to a weak oscillator strength for the S1-S0 transition, resulting in slow radiative decay and low photoluminescence quantum yield (ΦPL). Furthermore, as the emission shifts to lower energy, the radiative decay rate (kr) decreases while the nonradiative rate (knr) increases, following the energy gap law, leading to poorly emissive red-to-NIR compounds. Balancing these two criteria to achieve bright materials in this region remains a challenging task.