In light of the ever-growing consequences of fossil fuel consumption, the development of green, low-emitting technologies like electrosynthesis is becoming increasingly important. The last decades of work in this field have focused on water electrolysis to produce H2 as an energy vector and chemical feedstock as well as CO2 reduction to generate carbon-based fuels and commodity chemicals. However, these two classes of products do not fully meet the needs of society and the chemical industry. Against this backdrop, a recent push in the field of electrocatalysis has been to expand the scope of products that can be generated from abundant building blocks (e.g. CO2, N2, H2O…) and this includes directions such as H2O2 electrosynthesis from water and O2, N2 reduction for NH3 production, and the formation of products with C-N bonds. Despite sulfur's abundance on earth and the importance of molecules with C-S bonds in biology, pharma, 10 agriculture, battery technologies and optoelectronic materials, the electrosynthesis of such species remains unexplored. Though the organic chemistry of C-S bond formation is established with strategies such as Diels-Alder reactions, allylic or methane sulfonation and sulfa-Michael addition , they face limitations of complex synthetic methodology, toxic byproducts/solvents and scalability limits thus hampering their sustainable implementation in the chemical industry at large. In contrast, renewable energy-driven routes have begun to be explored with photochemical C-S bond formation as an example that has been attained with carbon nitride photocatalysts in which C-S coupling occurred through radicalbased routes or through the addition of H2S onto C=N bonds. Methane sulfonation under high pressure conditions, presumably through radical-based C-S coupling in the electrolyte, has also begun to be explored. However, direct electrochemical C-S bond coupling under ambient conditions using starting reactants like CO2, is still to be realized.