Neat grinding of TBZ with H2OX or HSAC yielded identical salts to those grown as single crystals using solvothermal methods. However, when neat grinding was performed with H2MA, a salt with a different crystal structure was obtained. Introducing a solvent in the grinding process for H2MA (liquid-assisted grinding, LAG) allowed for the preparation of a salt identical to the salt obtained by solvothermal methods. This result suggests that TBZ has the potential to form different salts under varying mechanochemical conditions, offering broad possibilities for LAG and ion-assisted grinding . Mechanochemistry also enables the direct and convenient synthesis of binary phase mixtures of TBZ salts. Typically, milling of TBZ with a combination of acids results in physical mixtures of the corresponding salts (Figures ).