Chiral compounds are the most important building blocks in the chemical and pharmaceutical industry, as they are widely employed for the production of fine chemicals and drugs . Moreover, it is increasingly important to synthesize enantiopure drugs for the pharmaceutical industry . More precisely, enantiopure alcohols 51 and amines are key examples of prime importance in the synthesis of pharmaceuticals, but also in the flavors and fragrances industry. Small peptides and short oligosaccharides are other categories of functional molecules that can be accessed via biocatalytic synthesis processes.