In this context, we introduce a straightforward one potsynthetic method to prepare seven Cu cluster assembled materials (CAMs) with varying dimensionalities through a liquidliquid interface crystallization technique. Our findings demonstrate a clear relationship between the choice of linker molecules and the structural rearrangement of the cluster node, as well as the overall framework dimensionality. By utilizing different N-coordinating linkers, this approach provides a novel and versatile strategy to expand research in this area. Additionally, we uncover the significant influence of the solvent medium on the structural arrangement of the cluster node during synthesis which corelates with their solid-state absorbance properties. We believe that the ability to control and manipulate these factors could lead to major advancements in the development of Cu-based materials with tailored properties for specific applications.