The validation of the parameterization approaches to produce accurate structural quantities are reassuring for subsequent work and provides a jumping off point for larger scale studies of the methods described here for polymeric MD in future studies. The approaches in this paper described are applicable in the near-term to the development of high-throughput polymer MD workflows, which can be used to automate MD-based generation of polymer property data. This data, along with databases of chemical information and charges, would pave the way forward for both direct simulation-based design, as well as targeted application of ML to polymer systems with high degrees of crosslinking and dynamic covalent bonds.