The melting process of the Co(hmba)3[CoBr4] system is also investigated through analysis of the simulated coordination numbers (CNs) of the two different Co-centers (i.e., the Co-O and Co-Br CNs). Interestingly, we find that the CN of the Co-O and Co-Br correlations differ significantly (see Figure for Co-O and Figure for Co-Br). We note that the stepwise nature of the data in these figures is due to the small number of Co atoms in each simulated box. Upon initializing dynamics at 1000 K of the crystalline system with 0, 1, 2, or 3 water molecules, we observe a major decrease in the Co-O CN (i.e., the network percolating species) from 6 to ~4 within the first 10 ps. This decrease in CN is found to be promoted by the presence of water, as seen from the more rapid decrease of CN in the first picosecond of the simulation with the largest amount of water. To showcase this, we have fitted the data to a stretched exponential decay function,