After the successful synthesis of the two novel bifunctional catalysts PCI and PCII, we first wanted to test their ability to induce chirality in known photochemical reactions. We were particularly interested in investigating whether the two catalysts can promote both asymmetric energy transfer and photoredox catalysis. For this purpose, two proof-of-concept dual catalytic reactions were picked from the literature to evaluate the competency and performance of our catalysts. In both reactions, the original conditions relied upon a chiral phosphoric acid for asymmetric induction and a discrete photocatalyst for substrate activation.