The CVs of pDTCz-DPmS show both chemically irreversible oxidation and reduction waves, while 4CzIPN exhibits an irreversible oxidation wave and reversible reduction wave in most solvents (Figure ). The redox potentials for both compounds are provided in Table . While the ground state oxidation potentials in DCM of 4CzIPN and pDTCz-DPmS are similar at 1.51 V and 1.57 V, respectively, the latter compound exhibits a significantly more negative ground state reduction potential (-1.21