We first discuss the classification of the lowest excited TDDFT states as MC and MLCT ones. For MLCT states, we always find a clear dominant character contributing 60-80% to the state vector allowing for an easy assignment, as shown by the red boxes in the uppermost panels in Fig. . For singlet MLCT states, the increase of α leads to a slight decrease of percentage of MLCT character (left-hand side), while the MLCT character in the triplet states is constant for the entire α range (right-hand side). For predominant MC states (bottom panels in Fig. ), the state composition is more diverse with a notable admixture of MLCT character. Upon increasing α, however, the MC character (blue boxes) increases leading to a clearer assignment of both singlet and triplet states as MC ones.