moieties, particularly without the usage of oxidative/corrosive trifluoromethyl sources (Togni, Umemoto reagents, etc.), are still underdeveloped. There is only one example for the synthesis of 𝛾-chiral enamides, described by the group of Li through an elegant Ir-catalyzed hydroalkenylation strategy of unactivated 𝛼-olefins promoted by a chiral ligand (Scheme 2A). This method involves pre-protected substrates and the scope is limited to aliphatic alkenes. According to our previous interest, we recently developed a one-pot stereoselective isomerization method of 𝛼-chiral allylic amines catalyzed by 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) as a simple organocatalyst followed by a diastereoselective reduction of the imine-tautomer with DIBAL-H to obtain 𝛼, 𝛾-chiral aliphatic amines (Scheme 2B). 70