The deployment of alkylzirconocenes has emerged as a powerful platform for the construction of valuable C(sp 3 )-C(sp 3 ) bonds . This versatile organometallic specie demonstrates exceptional functional group tolerance, unique photochemical reactivity, and the capacity to facilitate remote C-H functionalization through their intriguing "chain-walking" ability. Notably, alkylzirconocenes can be readily prepared from abundant and readily available feedstock chemicals, such as alkenes . The confluence of these desirable reactivity features and their synthetic accessibility renders alkylzirconocenes highly attractive synthetic intermediates for the efficient assembly of complex molecular architectures. The ongoing exploration of the photoreactivity exhibited by alkylzirconocenes has opened up new avenues for the development of asymmetric photoredox methodologies . Recognizing the advantages of both aliphatic acids and alkylzirconocenes, we have developed a visible-light-induced, Ni-catalyzed enantioconvergent C(sp 3 )-C(sp 3 ) cross-coupling of unactivated primary aliphatic acid NHPI esters with gem-borazirconocene alkanes, yielding a diverse range of chiral alkylboron derivatives (Figure ).