Steady state and transient absorption spectroscopy were employed in order to investigate the ground and excited state properties of the homoleptic ALDIPYs. The photophysical data of these complexes may resemble other trivalent metal complexes (ML3) of Co(III), Ga(III), In(III), Rh(III). . Fluorescence studies have been reported but singlet oxygen determination and triplet state properties have yet to be explored. Notably, the triplet excited state properties of the aforementioned complexes have remained unexplored until now.