We also evaluated naphthyl and thiophene substrates, which could be converted to the expected products in high yields (81-97%) and outstanding enantioselectivities (99% ee). Furthermore, benzamides bearing substituents at the C7 position of the quinoline ring were also tested (Scheme 3B). Here, methoxy-and bromo-substituents on the quinoline ring were well compatible in the cobaltaelectro-catalyzed atroposelective C-H annulation. The connectivity and absolute configuration of isoquinolinones 4, 17, and 19 were determined by X-ray diffraction analysis featuring a (R)-configuration. Next, we explored the generality of the approach by testing a variety of allenes (Scheme 3C). Diversely substituted allenes efficiently reacted with benzamides to afford as single regioisomer in good to excellent yield and high enantioselectivity (20-25). The broad functional-group tolerance was further evidenced by late-stage annulation of a series of biologically relevant molecules, such as probenecid, tamibarotene, menthol and cholesterol (Scheme 3D).