For the inspection of the microstructural pattern of Zn-PMA metallogel the air-dried xerogelstate of supramolecular metallogel of Zn(II) has been employed. Field emission scanning electron microscope (FESEM) microstructural pattern of xerogel obtained from Zn-PMA metallogel was explored (Figure ). Morphology of Zn-PMA metallogel exhibits the internal network with the highly flexible type fibres having the inter-connected association. This ultimately leads to the three dimensional assembly of semi-solid Zn-PMA gel and this directs the hierarchical structure for getting stable metallogel system. Special nano-ranged sizecriteria of Zn-PMA xerogel is the exclusive one for getting scrupulous mechanical flexibility of the metallogel. FESEM-based morphological idea also clearly shows the critical type nano-sized breadth of the nano-fibre collecting to get stable metallogel. Possible supramolecular non-covalent type interactions acting among the gel-constructing agents like Zn(II) acetate dihydrate and pyromellitic acid might be effective for the generation of stable metallogel structure. Verification of the metallogel-forming agents has been executed by the EDAX elemental study connected with FESEM imaging set-up with the help of elemental mapping and EDX spectral analysis. This confirms the presence of C, N, O, and Zn elements.