The phenanthrene was on nitration gives phenthroline-5-nitro in 32% yield. The corresponding amine was synthesized in two different methods, palladium/charcoal and stannous chloride in 90% and 51% respectively. (scheme-4) Ruthenium carbonate is prepared in two steps by treating 2,2-bipyridyl with ruthenium trichloride to obtained intermediate product in 40% yield, which on treated with sodium carbonate under Argon atmosphere gives ruthenium carbonate in 67% yield. Ruthenium carbonate on treated with compounds 26 under heating condition to obtained the pure product Conclusion: In summary, A manageable synthetic route for dipeptides and rutheniumphenanthrene-amine was established. This work provides valuable information for the discovery of novel strategies in exploring novel molecules having combined properties of electronic channel and photoredox properties of ruthenium and its amide coupling with dipeptides suitable for biological applications.