We also synthesized an elongated analogue (6gD) of amphetamine (a synthetic stimulant-type medication) and a structural analogue (10 and 11) of coniine (a polyketide-derived alkaloid) in short synthesis steps. We further demonstrated the utility of this temperature-regulated migratory hydroalkylation by employing isomeric mixtures of alkenes (Figure ). Our protocol exhibited both regiodivergence and regioconvergence, delivering each predictable regioselective product 4ba or 5ba with high regioselectivity from isomeric mixtures of the alkene substrates.