Deconstructive transformations in organic synthesis are valuable approaches to utilizing chiral pool materials that include functional groups that can be removed in a synthetic route. Performing deconstruction of Csp 3 -Csp 2 species can be particularly useful in terpene-based frameworks, as these chiral natural products often contain isopropenyl groups that are often not included in the final products. Hydrodealkenylation is a deconstructive transformation that enables the usage of chiral pool starting materials containing excess alkenyl functionality for the overall synthetic route. The ability to remove such groups without interfering with other functional groups already in place in the molecule is a challenge that has been explored briefly wherein ozonolysis is followed by Fe (II)-induced β-fragmentation to generate a number of derivatives (Fig. ) 1 . One caveat to this approach is the usage of ozone, as this electrophilic oxidant is known to react widely with a variety of functional groups. Generally, controlling the stoichiometry of O₃ for reaction with specific functional groups on substrates is challenging due to its gaseous nature. In contrast, under Mukaiyama-type conditions, optimizing reagent loading and catalyst structure allows for monoselective or regioselective functionalization of substrates bearing multiple olefins even in the presence of excess O2 2 .