In materials research and applications, conductive polymers have been playing an important role, in which electronic delocalization acts as a major pathway for photoelectronic, charge, and energy transformations . In the meanwhile, through-space conjugation has emerged as an alternative pathway for this purpose . Recently, our lab has designed and developed a series of novel enantiomerically enriched polymers and oligomers of folding chirality via multistep synthesis and Suzuki-Miyara cross-coupling . In these chiral targets, parallel uniformed aromatic bridges exist between two columns of naphthalene-holding skeletons as revealed by X-ray diffraction analysis of relevant monomeric derivatives. These polymers were found to display strong photoluminescence (PL) in both solutions and solid states under UV irradiation. As anticipated, the resulting enantiomerically enriched multilayer polymers exhibited asymmetric circular lighting polarization and optical rotation activity.