Relevant properties of phosphorene are high electrical conductivity (2•10 5 cm 2 V -1 s -1 ), high carrier mobility (≈1000 cm 2 V -1 s -1 ), high thermal conductivity (4840-5300 W m -1 K -1 ), and high tensile strength up to 130 GPa . Phosphorene also displays a remarkable ability to bind organic/inorganic molecules through covalent or non-covalent interactions, mainly favored by electrostatic attraction ; thus, phosphorene emerges as an ideal template for the formation of well-ordered structures for assembly of fullerenes and related phosphorene/organic nanostructures. Furthermore, surface coordination of phosphorene has been shown to enhance its stability under air/water dispersion, which is a major challenge in practical applications . Despite widespread works on hybrids of fullerenes with other 2D nanomaterials, studies on Phosphorene-Fullerene hybrids have infrequently been reported and mainly focused on C60 adsorption. Experimentalists and theoreticians have synthesized/proposed Phosphorene-C60 nanostructures with relevant properties for technological applications such as high specific capacity battery electrode materials , solar energy conversion , new molecular doped crystalline superlattices for semiconductor industry , and heterojunction photodetectors . In this way, properties of phosphorene and fullerenes are compensated synergistically; for example, it is found in photovoltaic research that fullerenes act as excellent electron acceptors in polymer solar cells, while phosphorene improves the energy alignment in the devices, which lead to improved power conversion efficiency by favoring the charge transfer and exciton dissociation .