The effects of chirality and halogens on the assembling patterns of SubPc have been discussed. Two enantiomers are randomly arranged in F-containing crystals. No difference exists in the assembling patterns between the crystals with pure enantiomers and racemic mixtures. Meanwhile, the assembling patterns of Cl-, Br-, and I-containing crystals differ between enantiomers and racemic mixtures. In general, the crystal structures between enantiomers and racemic mixtures are different. Hence, the formation of the same structures between enantiomers and racemates by the SubPc-3F series is an exception.