 Nyorai kuenderera mberi kweiyi ndima - Williams pakutanga akanyoresa zita rake mu2005 NBA draftuye akapinda mumitambo yokugadzirira kunyorwa, asi akabva muna April asina kuunganidza mumiririri, chimwe chinhu chakamubvumira kudzokera kuWake Forest kwegore rake rokupedzisira. Mumwaka wake wokupedzisira wekoreji basketball Williams akanga ari zvakare mumitambo mishanu yekutanga 34 kubva pamitambo 34, avhareji yemaminitsi 32.6. Akaita kutanga kwake mumutambo wekutanga wemwaka musi waNovember 10, 2005 vachipesana neMississippi Valley State uye akaisa mapoinzi makumi maviri nemaviri uye mapfumbamwe ekudzosa. Musi waNdira 11, 2006 akarekodha mapoinzi makumi maviri nemaviri uye makumi maviri rebounds basa repamusoro kurwisa Clemson. Avhareji yake yemwaka yaive yese yebasa-yepamusoro: 16.3 mapoinzi, 8.9 rebounds, 1 inobatsira, 1.3 inobira uye 1.1 mabhuroko; akatungamirawo ACC muchikamu chemunda chinangwa ne.619, uye aive wechitatu musangano wepakati pekudzorera. Pakupera kwegore iye akatumidzwa muAll-ACC yechitatu timu. 