 Pooley akadzokera kumakwikwi ekuchovha bhasikoro muna Gumiguru 2015 paakakwikwidza muChrono des Nations nguva yenguva, kwaakapedza ari wechitanhatu. Muna Zvita 2015 akazivisa kuti aizovavarira kukwikwidza Team GB muna 2016 Summer yeOlympic muRio de Janeiro pashure pokunge pedyo British Cycling kuti zvekushandisa mukuru Shane Sutton, uyo akanga adzidza Olympic mugwagwa mujaho makosi uye vaifunga kuti Pooley aizova mukana wakanaka kuhwina menduru iri nguva muedzo uye kubatsira Lizzie Armitstead kuhwina mugwagwa nhangemutange. Akasimbisawo kuti aizoramba achikwikwidza mumakwikwi e triathlon uye duathlon muna 2016. Pooley akaita chitarisiko chake chekutanga mumakwikwi makuru emugwagwa kwemakore maviri muna Kubvumbi 2016 kuchikwata chenyika cheBritish kuWomens Tour de Yorkshire, kwaakabatsira waanoshanda naye Alice Barnes kunzvimbo yechina. Muna June 2016 vakazivisa kuti Pooley akanga adzokera chikwata nokuda yasara 2016 mwaka, uye kuti aizova chikamu chikwata chikwata nokuda 2016 Giro dItalia Femminile ane basa somunhu mushandi weimba Claudia Lichtenberg. Pamakwikwi eOlympics, Pooley akatasva mubasa raArmitstead munhangemutange yomumugwagwa, nepo mumakwikwi ekudzora nguva akapedza ari wechi14, maminitsi anopfuura maviri shure kwomukundi Kristen Armstrong. 