 Del Piero parizvino ndiye muItaly wechina-wechina-wenguva dzose anotungamira zvibodzwa, pamwe naRoberto Baggio, aine zvibodzwa makumi maviri neshanu mumitambo makumi mapfumbamwe nemapfumbamwe, aine zvibodzwa zviviri zveItaly zvinouya mumitambo gumi nembiri yeNdebe yeNyika uye chibodzwa chimwe mumitambo gumi nematatu yeEuropean Championship; pamwe naEnrico Chiesa, iye zvakare ane rekodhi rakasarudzika rezvinangwa zvakawandisa zvakaitwa nemutambi weItaly wepasi rose semutsivi 5. Del Piero pakutanga akatambira divi reItaly U-21 pazviitiko gumi nezviviri, achihwina zvibodzwa zvitatu, uye aive nhengo yechikwata chakakodzera uye chakazohwina 1996 European Under-21 Championship, vachioneka mumakwikwi emakota ekupedzisira. Del Piero akaita mutambo wake wekutanga pasi paArrigo Sacchi pazera remakore makumi maviri, musi wa25 Kurume 1995, mukukunda 4-1 pamusoro peEstonia mumutambo weEuro 1996 unokodzera. Del Piero akarova chibodzwa chake chekutanga kuItaly musi wa15 Mbudzi 1995, mukukunda 4-0 pamusoro peLithuania mumutambo wekukwanisa kuenda kuEuro 1996. Mutambo wake wokutanga waiva pa UEFA Euro 1996, apo akaita chitarisiko chake chokutanga muchikamu chekutanga chechikwata che 2 × 1 kukunda mumutambo wekutanga weboka neRussia, achitamba semubatsiri wekuruboshwe pakati, akapfeka nhamba ye14 shati, asati atorwa muhafu yehafu naRoberto Donadoni. 