 Fiore akaita mitambo misere kuchikwata cheItaly cheU-21, uye mitambo mitatu kuchikwata cheU-23, icho chaakakunda nacho Mitambo yeMediterranean muna 1997. Akaita kutanga kwake kweItaly nhabvu nhabvu nhabvu panguva yake neUdinese, pasi pemurairidzi Dino Zoff, musi wa 23 Kukadzi 2000, achitora chikamu mukukunda 10 mumutambo weushamwari wepasi rose neSweden, muPalermo. Chimiro chakanaka chaFiore panguva ya1999-2000 Serie A mwaka yakakurumidza kumubvumidza kuti ave nhengo isingagumi uye yakakosha yechikwata chenyika, zvichimuwanira nzvimbo muchikwata chenyika chaDino Zoff cheEuro 2000. Akaita mutambo wakabudirira zvikuru uye akarova zvibodzwa zvaifungidzirwa nevakawanda sechinangwa chemutambo uyu mukukunda 20 pamusoro pevaBelgium, mumutambo wechipiri weItaly; akabatsirawo chinangwa chechikwata chake chekugadzira, chinotyisa chepakati chechikwata Francesco Totti mumakwikwi ekupedzisira emutambo, kukunda 20 pamusoro peRomania, iyo yakavhara nzvimbo yeItaly mumakwikwi ekupedzisira nevakagamuchira vaNetherlands. Fomu rake rakanaka rakaramba richienderera mberi sezvo akaenderera mberi kutora chikamu mumitambo yese yeItaly mumakwikwi ese, sezvo vakasvika kumagumo, chete kuti vakunde vanodzivirira World Champions France pane chinangwa chegoridhe munguva yekuwedzera. 