 Nokusvika muplayoffs, Molina akava mubati wokutanga munhau yefranchise kuti aoneke mumwaka mishanu yeCardinals. Akapfura.333 muNLCSvachipesana neMilwaukee, kubatanidza zvibodzwa zvishanu mumitambo misere yeAB mumitambo miviri yokupedzisira. Mumutambo 1 weWorld Series vachipesana neTexas Rangers, Molina akaburitsa Ian Kinsler achiedza kuba muchikamu chekutanga munzira yekukunda 3x2. Kwaiva kuedza bedzi kweRangers kubira mutambo wacho. Kuti akabatwa kuba akapa Molina shanu nomwe zvachose mikana iri 2011 postseason kuti pfungwa; ari Rangers akanga yakabatana pamwe Cardinals kuti vakawanda kuba kuti postseason. Nokuda kwenyaya yacho, Rangers yakaedza kuba mabhesi mana uye yakabudirira kamwe chete. Mumutambo 3, Molina akaunganidza RBI ina, uye mamwe maviri mumwe nomumwe muMitambo 6 ne7. 