 - Procedure: Each participant will undergo additional MRI sequences hyperpolarized 13C pyruvate MRS with an additional length of approximately 30-60 minutes that will be performed on the day of or in advance of the particpants routine radiation planning scan prior to radiation treatment In addition, each particpant will undergo one non-rountine MRI scan with a length of approximately 60-90 minutes at a time point of 1-5 days following radiation treatment. 